EP0012874B1 - Method for sealing the valve of a packing container - Google Patents
Method for sealing the valve of a packing container Download PDFInfo
- Publication number
- EP0012874B1 EP0012874B1 EP79104795A EP79104795A EP0012874B1 EP 0012874 B1 EP0012874 B1 EP 0012874B1 EP 79104795 A EP79104795 A EP 79104795A EP 79104795 A EP79104795 A EP 79104795A EP 0012874 B1 EP0012874 B1 EP 0012874B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- valve
- sealing
- channel
- bag
- fluid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007789 sealing Methods 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title claims description 10
- 238000012856 packing Methods 0.000 title 1
- 238000004806 packaging method and process Methods 0.000 claims abstract description 7
- 239000011888 foil Substances 0.000 claims abstract description 5
- 239000012530 fluid Substances 0.000 claims abstract 6
- 239000007788 liquid Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000565 sealant Substances 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- 239000007789 gas Substances 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D31/00—Bags or like containers made of paper and having structural provision for thickness of contents
- B65D31/14—Valve bags, i.e. with valves for filling
Definitions
- the invention relates to a method for sealing a packaging container valve according to the preamble of the main claim.
- a method of this type known for example from FR-A-13 60 753
- a valve closure is produced on bags made of plastic film by welding the two layers of film while leaving a channel.
- the area of the film surface delimiting the channel is moistened with a liquid before the valve closure is formed by welding the film layers. Since the liquids in question cannot always be applied as uniform strips and, if the application is too thick, they flow away when the foils are pressed together for welding, and since these liquids prevent a welded joint, it is difficult to produce valve channels with specific dimensions that relate to a specific one Have the response pressure set.
- the sealing method according to the invention with the characterizing feature of the main claim has the advantage that tight valve channels can be manufactured with the required accuracy. Furthermore, the metering of the liquid sealant is easier since the liquid applied at the end of the channel is distributed throughout the valve channel by capillary action and even forms a small reserve at the other end. A major advantage can also be seen in the fact that the sealant can be introduced into the valve regardless of the time at which it is formed. This is the case, for example, when valve bags are made in stock, which are then closed after filling by a simple, continuous night of closure and whose valve channel is sealed with a liquid sealant immediately before or after filling, so that evaporation of the sealant during Storage of the bags is avoided.
- the method according to the invention can also be used to seal, for example, valves known from US Pat. No. 2,946,502, which are manufactured separately from the packaging containers and are only glued to them later.
- These known valves consist of a perforated base plate and a flexible foil plate covering this, which is glued to the base plate along two opposite edge regions, so that the non-adhesive central region delimits a valve channel starting from the opening in the base plate.
- the subsequent sealing is particularly advantageous since the liquid sealant cannot migrate into the adhesive layer while the valves are being stored.
- the implementation of the method according to the invention is seen particularly in connection with the packaging of roasted coffee.
- Coffee is filled into bags in the absence of air and sealed airtight.
- the gases released from the coffee can escape through a valve glued to the bag above an opening.
- valves which have one or more ventilation channels, are glued in the packaging machine to the bags or to the packaging material from which the bags are formed.
- a small amount of silicone oil is applied to the valve in the area of the free end of the valve channel.
- the liquid can also be sprayed as a drop through a nozzle onto the free end of the valve channel. Due to capillary action, the somewhat excess silicone oil is drawn into the valve channel and fills it. As has been shown, even a small part is deposited on the other end of the valve channel facing the inside of the bag.
- the silicone oil in the valve channels fills the tiny cavities caused by the grain of the surface of the walls of the valve channels and thus seals the valve channel against the penetration of air from the atmosphere. If the pressure inside a bag pack increases due to the development of gas, the flexible film is lifted off the base plate of the valve in the area of the valve channel, the silicone oil film being split. After the excess pressure in the inside of the bag has been released by the release of a quantity of gas, the flexible film rests on the base plate, so that the two films adhering to the surfaces reunite and the sealing effect reappears.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Making Paper Articles (AREA)
- Containers And Plastic Fillers For Packaging (AREA)
- Bag Frames (AREA)
- Packages (AREA)
- Closures For Containers (AREA)
- Vacuum Packaging (AREA)
- Safety Valves (AREA)
- Closing Of Containers (AREA)
Abstract
Description
Die Erfindung geht aus von einem Verfahren zum Abdichten eines Verpackungsbehälterventils nach der Gattung des Hauptanspruchs. Bei einem beispielsweise durch die FR-A-13 60 753 bekannten Verfahren dieser Art wird an Beuteln aus Kunststoffolie ein Ventilverschluß durch Verschweißen der beiden Folienlagen unter Belassung eines Kanals erzeugt. Zum Abdichten dieses Kanals wird der den Kanal begrenzende Bereich der Folienoberfläche mit einer Flüssigkeit befeuchtet bevor der Ventilverschluß durch Verschweißen der Folienlagen gebildet wird. Da die infrage kommenden Flüssigkeiten sich nicht immer als gleichmäßige Streifen auftragen lassen und bei einem zu dicken Auftrag beim Aufeinanderpressen der Folien zum Verschweißen wegfließen, und da diese Flüssigkeiten eine Schweißverbindung verhindern, ist es schwierig, Ventilkanäle mit bestimmten Abmessungen herzustellen, die sich auf einen bestimmten Ansprechdruck einstellen lassen.The invention relates to a method for sealing a packaging container valve according to the preamble of the main claim. In a method of this type, known for example from FR-A-13 60 753, a valve closure is produced on bags made of plastic film by welding the two layers of film while leaving a channel. To seal this channel, the area of the film surface delimiting the channel is moistened with a liquid before the valve closure is formed by welding the film layers. Since the liquids in question cannot always be applied as uniform strips and, if the application is too thick, they flow away when the foils are pressed together for welding, and since these liquids prevent a welded joint, it is difficult to produce valve channels with specific dimensions that relate to a specific one Have the response pressure set.
Durch die DE-A2643831 ist ferner ein auslaufsicheres Verschließen von Füllventilen an Ventilsäcken nach dem Befüllen bekannt. Hierbei wird auf die bei Zugabe von Wasser klebrig werdenden Innenteile des weit geöffneten Füllventils Wasser oder Wasserdampf aufgespritzt oder aufgesprüht und darauf das Füllventil zum Verkleben zusammengedrückt.From DE-A2643831 leak-proof closing of filling valves on valve bags after filling is also known. Here, water or steam is sprayed or sprayed onto the internal parts of the wide-open filling valve, which become sticky when water is added, and the filling valve is pressed together for gluing.
Das erfindungsgemäße Abdichtverfahren mit dem kennzeichnenden Merkmal des Hauptanspruches hat demgegenüber den Vorteil, daß dichte Ventilkanäle mit der erforderlichen Genauigkeit hergestellt werden können. Ferner ist die Dosierung des flüssigen Dichtmittels einfacher, da sich die am Ende des Kanals aufgetragene Flüssigkeit durch Kapillarwirkung im ganzen Ventilkanal verteilt und sogar am anderen Ende noch eine kleine Reserve bildet. Ein wesentlicher Vorteil ist aber auch darin zu erkennen, daß das Dichtmittel unabhängig vom Zeitpunkt der Bildung des Ventils in dieses eingebracht werden kann. Dies ist beispielsweise der Fall, wenn Ventilbeutel auf Vorrat gefertigt werden, die dann nach dem Füllen durch eine einfache, durchgehende Verschlußnacht verschlossen werden und deren Ventilkanal unmittelbar vor oder nach dem Befüllen mit einem flüssigen Dichtmittel abgedichtet wird, so daß ein Verdunsten des Dichtmittels während der Lagerung der Beutel vermieden wird.The sealing method according to the invention with the characterizing feature of the main claim has the advantage that tight valve channels can be manufactured with the required accuracy. Furthermore, the metering of the liquid sealant is easier since the liquid applied at the end of the channel is distributed throughout the valve channel by capillary action and even forms a small reserve at the other end. A major advantage can also be seen in the fact that the sealant can be introduced into the valve regardless of the time at which it is formed. This is the case, for example, when valve bags are made in stock, which are then closed after filling by a simple, continuous night of closure and whose valve channel is sealed with a liquid sealant immediately before or after filling, so that evaporation of the sealant during Storage of the bags is avoided.
Nach dem erfindungsgemäßen Verfahren lassen sich auch durch beispielsweise die US-A-2946502 bekannte Ventile abdichten, welche getrennt von den Verpackungsbehältern hergestellt und erst später auf diese aufgeklebt werden. Diese bekannten Ventile bestehen aus einer gelochten Grundplatte und einem sich mit dieser deckenden nachgiebigen Folienplättchen, das entlang zweier gegenüberliegender Randbereiche mit der Grundplatte verklebt ist, so daß der nicht klebende mittlere Bereich einen vom Durchbruch in der Grundplatte ausgehenden Ventilkanal begrenzt. Bei solchen geklebten Ventilen ist die nachträgliche Abdichtung besonders vorteilhaft, da das flüssige Dichtmittel während der Bevorratung der Ventile nicht in die Klebstoffschicht imigrieren kann.The method according to the invention can also be used to seal, for example, valves known from US Pat. No. 2,946,502, which are manufactured separately from the packaging containers and are only glued to them later. These known valves consist of a perforated base plate and a flexible foil plate covering this, which is glued to the base plate along two opposite edge regions, so that the non-adhesive central region delimits a valve channel starting from the opening in the base plate. With such glued valves, the subsequent sealing is particularly advantageous since the liquid sealant cannot migrate into the adhesive layer while the valves are being stored.
Als besonders geeignetes Dichtmittel hat sich bei Versuchen Silikonöl gezeigt.In tests, silicone oil has proven to be a particularly suitable sealant.
Die Durchführung des erfindungsgemäßen Verfahrens wird besonders im Zusammenhang mit dem Verpacken von geröstetem Kaffee gesehen. Kaffee wird unter Luftausschluß in Beutel eingefüllt und dieser luftdicht verschlossen. Die sich aus dem Kaffee lösenden Gase können durch ein am Beutel über einem Durchbruch angeklebtes Ventil entweichen.The implementation of the method according to the invention is seen particularly in connection with the packaging of roasted coffee. Coffee is filled into bags in the absence of air and sealed airtight. The gases released from the coffee can escape through a valve glued to the bag above an opening.
Die Ventile, die einen oder mehrere Entlüftungskanäle aufweisen, werden in der Verpackungsmaschine auf die Beutel oder auf den Packstoff, aus dem die Beutel geformt werden, aufgeklebt. Vor dem Befüllen oder auch kurz danach wird Silikonöl im Bereich des freien Endes des Ventilkanals auf das Ventil in geringer Menge aufgetragen. Dazu dient ein mit Silikonöl getränkter Pinsel, Docht oder Tupfer. Die Flüssigkeit kann auch als Tropfen durch eine Düse auf das freie Ende des Ventilkanals aufgespritzt werden. Durch Kapillarwirkung zieht das etwas im Überfluß aufgetragene Silikonöl in den Ventilkanal ein und füllt diesen aus. Wie sich gezeigt hat, lagert sich sogar ein geringer Teil am anderen, dem Beutelinnern zugekehrten Ende des Ventilkanals ab.The valves, which have one or more ventilation channels, are glued in the packaging machine to the bags or to the packaging material from which the bags are formed. Before filling or shortly thereafter, a small amount of silicone oil is applied to the valve in the area of the free end of the valve channel. Use a brush, wick or swab soaked with silicone oil. The liquid can also be sprayed as a drop through a nozzle onto the free end of the valve channel. Due to capillary action, the somewhat excess silicone oil is drawn into the valve channel and fills it. As has been shown, even a small part is deposited on the other end of the valve channel facing the inside of the bag.
Das in den Ventilkanälen befindliche Silikonöl füllt die winzigen, durch Körnung der Oberfläche der Wände der Ventilkanäle hervorgerufenen Hohlräume aus und dichtet so den Ventilkanal gegen das Durchdringen von Luft aus der Atmosphäre ab. Bei durch Gasentwicklung steigendem Druck im Innern einer Beutelpackung wird im Bereich des Ventilkanals die nachgiebige Folie von der Grundplatte des Ventils abgehoben, wobei der Silikonölfilm gespalten wird. Nach Abbau des Überdrucks im Beutelinnern durch Entströmen einer Gasmenge, legt sich die nachgiebige Folie wieder auf die Grundplatte, so daß die beiden an den Oberflächen haftenden Filme sich wieder vereinigen und aufs neue die Dichtwirkung eintritt.The silicone oil in the valve channels fills the tiny cavities caused by the grain of the surface of the walls of the valve channels and thus seals the valve channel against the penetration of air from the atmosphere. If the pressure inside a bag pack increases due to the development of gas, the flexible film is lifted off the base plate of the valve in the area of the valve channel, the silicone oil film being split. After the excess pressure in the inside of the bag has been released by the release of a quantity of gas, the flexible film rests on the base plate, so that the two films adhering to the surfaces reunite and the sealing effect reappears.
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT79104795T ATE813T1 (en) | 1978-12-23 | 1979-12-01 | METHOD OF SEALING A PACKING CONTAINER VALVE. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2856021 | 1978-12-23 | ||
DE19782856021 DE2856021A1 (en) | 1978-12-23 | 1978-12-23 | METHOD FOR SEALING A PACKAGE CONTAINER VALVE |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0012874A1 EP0012874A1 (en) | 1980-07-09 |
EP0012874B1 true EP0012874B1 (en) | 1982-04-07 |
Family
ID=6058299
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP79104795A Expired EP0012874B1 (en) | 1978-12-23 | 1979-12-01 | Method for sealing the valve of a packing container |
Country Status (7)
Country | Link |
---|---|
US (2) | US4290253A (en) |
EP (1) | EP0012874B1 (en) |
JP (1) | JPS5929501B2 (en) |
AT (1) | ATE813T1 (en) |
CA (1) | CA1149658A (en) |
DE (2) | DE2856021A1 (en) |
ES (1) | ES253698Y (en) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3202851A1 (en) * | 1982-01-29 | 1983-08-11 | Robert Bosch Gmbh, 7000 Stuttgart | METHOD AND DEVICE FOR SEALING A PACKAGE CONTAINER VALVE |
DE3526602A1 (en) * | 1985-07-25 | 1987-01-29 | Bosch Gmbh Robert | METHOD FOR PRODUCING A PACKAGING CONTAINER WITH A RBERPRESSURE VALVE |
JPS6234660U (en) * | 1985-08-16 | 1987-02-28 | ||
US4718215A (en) * | 1985-11-27 | 1988-01-12 | Baxter Travenol Laboratories, Inc. | Apparatus and method for attaching fitments to flexible containers |
JPS6361666U (en) * | 1986-10-11 | 1988-04-23 | ||
US5048846A (en) * | 1988-09-12 | 1991-09-17 | Fujimori Kogyo Co., Ltd. | Method for sealing gas release valve |
DE4008097A1 (en) * | 1990-03-14 | 1991-09-19 | Bosch Gmbh Robert | METHOD AND DEVICE FOR SEALING A PACKAGING CONTAINER PRESSURE VALVE |
DE4116370A1 (en) * | 1990-05-23 | 1991-11-28 | Tetra Pak Gmbh | Filling and sealing machine for fluid containers - has intermediate transport boxes to process groups of packages simultaneously |
EP0513439A1 (en) * | 1991-05-18 | 1992-11-19 | Tetra Laval Holdings & Finance SA | Device for the filling and closing of packages for flowable products |
US5277741A (en) * | 1992-08-06 | 1994-01-11 | Bartlett Tool And Manufacturing, Inc. | Sealing apparatus |
US5419638A (en) * | 1993-05-06 | 1995-05-30 | Jamison; Mark D. | Pressure sensitive gas valve for flexible pouch |
GB2293134A (en) * | 1994-11-10 | 1996-03-20 | Grace W R & Co | Supply of fitments on a flexible tape |
JP2691881B2 (en) * | 1995-05-31 | 1997-12-17 | 株式会社サンエー化研 | Packaging bag with check valve having filtration surface and manufacturing apparatus thereof |
FR2746371B1 (en) * | 1996-03-20 | 1998-05-22 | Int Paper Emballages Liquides | PROCEDURE FOR IMPLEMENTING A DEVICE FOR OPENING AND CLOSING A PACKAGING |
JP4416213B2 (en) * | 1998-08-06 | 2010-02-17 | フォイト ズルツァー パピーアテヒニク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | Apparatus and method for actively dampening undesired vibrations of a rotating roll |
US20040173626A1 (en) * | 2003-03-07 | 2004-09-09 | Jeor Bret De St | Pressure vacuum release hermetic valve for rigid container packages |
US7004632B2 (en) | 2003-03-31 | 2006-02-28 | The Glad Products Company | Ventable storage bag |
US7244223B2 (en) | 2003-05-30 | 2007-07-17 | Avery Dennison Corporation | Food bag release valve |
BRPI0608477A2 (en) | 2005-03-12 | 2010-01-05 | Sealed Air Corp | inflatable containers |
US8191469B2 (en) * | 2005-05-27 | 2012-06-05 | The Glad Products Company | Device and method for evacuating a storage bag |
DE102006016594A1 (en) * | 2006-04-06 | 2007-10-18 | Tesa Ag | Pressure relief valve for a packaging container |
US7328543B2 (en) * | 2006-05-17 | 2008-02-12 | Plitek, L.L.C. | Apparatus and method for the application of pressure relief valves |
US20080028730A1 (en) * | 2006-08-02 | 2008-02-07 | Savicki Alan F | Device and Method For Evacuating A Storage Bag |
US8522926B2 (en) * | 2006-08-16 | 2013-09-03 | Plitek, L.L.C. | Apparatus and method for lubricating pressure relief valves |
US9821528B2 (en) * | 2006-08-16 | 2017-11-21 | Plitek, L.L.C. | Method for lubricating pressure relief valves |
US20090026199A1 (en) * | 2007-07-27 | 2009-01-29 | Jeor Bret De | Pressure vacuum release hermetic valve for rigid container packages |
US8539741B2 (en) * | 2010-02-10 | 2013-09-24 | Triangle Package Machinery Company | Seal and cut method and apparatus |
US9896224B2 (en) * | 2014-03-24 | 2018-02-20 | Fres-Co System Usa, Inc. | Form, fill and seal apparatus and methods for applying one-way valves to flexible packages |
US10358244B2 (en) | 2015-10-26 | 2019-07-23 | Triangle Package Machinery Co. | Rotatable sealing jaw assembly for a form, fill and seal machine |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2092445A (en) * | 1934-03-09 | 1937-09-07 | Doulgheridis Alcibiad Michael | Method of sealing containers |
CH301664A (en) * | 1952-08-14 | 1954-09-15 | Dreyer Andre | Watertight container for liquids. |
US2946502A (en) * | 1954-11-10 | 1960-07-26 | Melvin R Metzger | Valve-equipped containers |
US2927722A (en) * | 1954-11-10 | 1960-03-08 | Melvin R Metzger | Vacuum type valve-equipped containers |
GB819758A (en) * | 1956-05-04 | 1959-09-09 | Henri Marcel | A new or improved capsule for bottles and other containers |
GB917300A (en) * | 1959-09-02 | 1963-01-30 | Harry Jock Freestone | Improved closure for containers |
GB975181A (en) * | 1960-03-11 | 1964-11-11 | Bowater Res & Dev Co Ltd | Mulitply paper sacks |
US3085705A (en) * | 1960-09-29 | 1963-04-16 | Brunswick Corp | Closures for laboratory glassware |
US3191360A (en) * | 1961-04-10 | 1965-06-29 | Fmc Corp | Apparatus for adhesively bonding surfaces |
FR1360753A (en) * | 1963-03-11 | 1964-05-15 | Improvement of sachets and other similar containers incorporating a plastic valve | |
GB1064422A (en) * | 1964-03-06 | 1967-04-05 | William Rhodes Ltd | Improvements in packing of mattresses |
US3302859A (en) * | 1964-12-21 | 1967-02-07 | Bemis Co Inc | Bag |
US3442061A (en) * | 1965-09-10 | 1969-05-06 | Hesser Ag Maschf | Method of producing filled and sealed packages |
US3432087A (en) * | 1966-09-01 | 1969-03-11 | Alfred P Costello | Package valve |
FR1527058A (en) * | 1967-04-14 | 1968-05-31 | Novampoule A G | Enhancements to Soft Syringe Ampoules |
DE1704101C3 (en) * | 1967-07-12 | 1974-09-26 | Fr. Hesser Maschinenfabrik Ag, 7000 Stuttgart | Shaping mandrel for a machine for producing bags or similar packaging containers from packaging materials that can be heat-sealed on at least one side |
SE332384B (en) * | 1968-02-09 | 1971-02-01 | Billeruds Ab | |
FR1583447A (en) * | 1968-03-20 | 1969-10-31 | ||
DE1910575A1 (en) * | 1969-03-01 | 1970-09-10 | Behn Verpackung Erwin | Cross bottom bag valve insert inside seal |
DE7106198U (en) * | 1971-02-18 | 1971-05-27 | Biotest Serum Institut Gmbh | |
CH603168A5 (en) * | 1975-03-21 | 1978-08-15 | Dematex Dev & Invest | |
US4204606A (en) * | 1975-03-21 | 1980-05-27 | Dematex Development & Investment Establishment | Tube and stopper combination with venting structure |
US4000846A (en) * | 1975-06-30 | 1977-01-04 | Dunkin' Donuts Incorporated | Pressure relief valve and bag incorporating same |
GB1538876A (en) * | 1975-10-03 | 1979-01-24 | American Colloid Co | Valve-type bags and method of sealing them |
US3989182A (en) * | 1976-02-12 | 1976-11-02 | Great Plains Bag Corporation | Vented bag |
US4070249A (en) * | 1976-06-08 | 1978-01-24 | American Home Products Corporation | Apparatus for compensating for pressure within a biological test device |
US4166482A (en) * | 1978-06-19 | 1979-09-04 | Union Camp Corporation | Lubricated valve bag and method of lubricating valve spout |
DE2862303D1 (en) * | 1978-11-28 | 1983-09-15 | Dematex Dev & Invest | Tube and stopper for blood-sampling systems |
-
1978
- 1978-12-23 DE DE19782856021 patent/DE2856021A1/en not_active Withdrawn
-
1979
- 1979-12-01 EP EP79104795A patent/EP0012874B1/en not_active Expired
- 1979-12-01 DE DE7979104795T patent/DE2962478D1/en not_active Expired
- 1979-12-01 AT AT79104795T patent/ATE813T1/en not_active IP Right Cessation
- 1979-12-18 US US06/104,898 patent/US4290253A/en not_active Ceased
- 1979-12-20 JP JP54164883A patent/JPS5929501B2/en not_active Expired
- 1979-12-21 CA CA000342514A patent/CA1149658A/en not_active Expired
-
1980
- 1980-10-17 ES ES1980253698U patent/ES253698Y/en not_active Expired
-
1982
- 1982-03-08 US US06/356,160 patent/USRE32018E/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US4290253A (en) | 1981-09-22 |
DE2856021A1 (en) | 1980-07-03 |
JPS5589071A (en) | 1980-07-05 |
ES253698Y (en) | 1981-09-16 |
JPS5929501B2 (en) | 1984-07-20 |
ATE813T1 (en) | 1982-04-15 |
EP0012874A1 (en) | 1980-07-09 |
CA1149658A (en) | 1983-07-12 |
DE2962478D1 (en) | 1982-05-19 |
USRE32018E (en) | 1985-11-05 |
ES253698U (en) | 1981-03-01 |
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