EA202091675A1 - Катализаторы дегидрирования и способы их получения и использования - Google Patents

Катализаторы дегидрирования и способы их получения и использования

Info

Publication number
EA202091675A1
EA202091675A1 EA202091675A EA202091675A EA202091675A1 EA 202091675 A1 EA202091675 A1 EA 202091675A1 EA 202091675 A EA202091675 A EA 202091675A EA 202091675 A EA202091675 A EA 202091675A EA 202091675 A1 EA202091675 A1 EA 202091675A1
Authority
EA
Eurasian Patent Office
Prior art keywords
composition
range
amount
present
methods
Prior art date
Application number
EA202091675A
Other languages
English (en)
Inventor
Жун Син
Владимир Фридман
Original Assignee
Клариант Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Клариант Корпорейшн filed Critical Клариант Корпорейшн
Publication of EA202091675A1 publication Critical patent/EA202091675A1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/896—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8966—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8986—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Изобретение относится к катализаторам, включающим галлий, церий и носитель из смешанных оксидов, пригодных для дегидрирования углеводородов, к способам получения таких катализаторов и к способам дегидрирования углеводородов с такими катализаторами. Например, в одном осуществлении каталитическая композиция включает оксид галлия, присутствующий в композиции в количестве в диапазоне около 0,1-30 мас.%, оксид церия, присутствующий в композиции в количестве в пределах диапазона около 0,1-15 мас.%, промотор M1, выбранный из Pt, Ir, La или их смеси, присутствующий в композиции в количестве в диапазоне около 0,005-4 мас.%, промотор M2, выбранный из элементов 1 группы (например, Li, Na, K, Cs), присутствующий в композиции в количестве в диапазоне около 0,05-3 мас.%, и носитель S1, выбранный из оксида алюминия, диоксида кремния, диоксида циркония, диоксида титана или их смеси, присутствующий в композиции в количестве в диапазоне около 60-99 мас.%.
EA202091675A 2018-01-26 2019-01-14 Катализаторы дегидрирования и способы их получения и использования EA202091675A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201862622201P 2018-01-26 2018-01-26
PCT/US2019/013438 WO2019147424A1 (en) 2018-01-26 2019-01-14 Dehydrogenation catalysts and methods for preparing and using them

Publications (1)

Publication Number Publication Date
EA202091675A1 true EA202091675A1 (ru) 2020-10-08

Family

ID=65516718

Family Applications (1)

Application Number Title Priority Date Filing Date
EA202091675A EA202091675A1 (ru) 2018-01-26 2019-01-14 Катализаторы дегидрирования и способы их получения и использования

Country Status (10)

Country Link
EP (1) EP3743206B1 (ru)
JP (1) JP7496775B2 (ru)
KR (1) KR20200111205A (ru)
CN (1) CN111491728A (ru)
CA (1) CA3088314A1 (ru)
DK (1) DK3743206T3 (ru)
EA (1) EA202091675A1 (ru)
MX (1) MX2020007463A (ru)
SA (1) SA520412419B1 (ru)
WO (1) WO2019147424A1 (ru)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113286653A (zh) * 2018-10-30 2021-08-20 科莱恩国际有限公司 脱氢催化剂及其制备和使用方法
KR20210126414A (ko) 2020-04-10 2021-10-20 에스케이이노베이션 주식회사 알칼리 금속 및/또는 알칼리토금속이 도핑된 전이금속-수소 활성화 금속 복합 산화물 촉매 및 이를 이용한 부타디엔의 제조방법
WO2021250567A1 (en) * 2020-06-10 2021-12-16 Sabic Global Technologies B.V. A process for reconstructing a spent dehydrogenation catalyst
CN115697548A (zh) 2020-06-10 2023-02-03 Sabic环球技术有限责任公司 脱氢催化剂
CN113426437B (zh) * 2021-07-16 2023-03-31 广西化工研究院有限公司 一种镓基丙烷脱氢制丙烯的催化剂及其制备方法
CN115779885B (zh) * 2021-09-10 2024-05-03 中国石油化工股份有限公司 一种轻烃脱氢催化剂及其制备方法和应用
WO2023244943A1 (en) * 2022-06-14 2023-12-21 Dow Global Technologies Llc Methods for making light olefins by dehydrogenation using catalysts that include manganese
CN115350652B (zh) * 2022-08-04 2023-06-20 西南化工研究设计院有限公司 一种使用脱氢催化剂的流化床丙烷脱氢装置及其工艺

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0328507B1 (en) * 1988-02-11 1991-06-19 Fina Research S.A. Process for preparing catalysts containing a metal of the platinum group, and uses thereof
DE19937106A1 (de) * 1999-08-06 2001-02-08 Basf Ag Multikomponenten-Katalysatoren
US20040133054A1 (en) * 2002-12-06 2004-07-08 Pelati Joseph E. Dehydrogenation catalyst and process for preparing the same
DE10333755A1 (de) * 2003-07-24 2005-03-31 Basf Ag Verfahren zur Dehydrierung von Carbonylverbindungen
JP4119980B2 (ja) * 2003-08-04 2008-07-16 独立行政法人産業技術総合研究所 プロパン脱水素反応用触媒
WO2005046855A2 (en) * 2003-10-16 2005-05-26 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same
US20080177117A1 (en) * 2006-10-16 2008-07-24 Abraham Benderly Integrated catalytic process for converting alkanes to alkenes and catalysts useful for same
CN103140459A (zh) * 2010-09-30 2013-06-05 陶氏环球技术有限责任公司 改善的非氧化脱氢的方法
US20140371501A1 (en) * 2012-02-20 2014-12-18 Dow Global Technologies Llc Reconstituted dehydrogenation catalyst showing slowed activity loss when compared with fresh catalyst
WO2014035590A1 (en) * 2012-08-28 2014-03-06 Dow Global Technologies Llc Catalyst composition and reactivation process useful for alkane dehydrogenations
US9415378B2 (en) * 2013-12-02 2016-08-16 Saudi Basic Industries Corporation Dehydrogenation catalyst, its use and method of preparation
CN105582929B (zh) * 2014-10-24 2018-06-08 中国石油化工股份有限公司 低碳烷烃脱氢催化剂、制备方法及其用途
CN106607026B (zh) * 2015-10-22 2020-06-09 中国石油化工股份有限公司 异丁烷脱氢制异丁烯催化剂及其制备方法
US10307737B2 (en) * 2015-11-03 2019-06-04 Sk Innovation Co., Ltd. Transition metal-noble metal complex oxide catalyst for dehydrogenation prepared by one-pot synthesis and use thereof

Also Published As

Publication number Publication date
EP3743206A1 (en) 2020-12-02
JP7496775B2 (ja) 2024-06-07
EP3743206B1 (en) 2023-02-01
CN111491728A (zh) 2020-08-04
MX2020007463A (es) 2020-09-14
JP2021511199A (ja) 2021-05-06
KR20200111205A (ko) 2020-09-28
CA3088314A1 (en) 2019-08-01
SA520412419B1 (ar) 2023-10-02
WO2019147424A1 (en) 2019-08-01
DK3743206T3 (da) 2023-02-27

Similar Documents

Publication Publication Date Title
EA202091675A1 (ru) Катализаторы дегидрирования и способы их получения и использования
EA202090773A1 (ru) Катализаторы дегидрирования
BR112021016609A2 (pt) Composições de partículas de sílica mesoporosa para entrega viral
BR112018003127A2 (pt) purificação de fkpa e usos do mesmo para produzir polipeptídeos recombinantes
US20220168709A1 (en) Reconstituted dehydrogenation catalyst showing slowed activity loss when compared with fresh catalyst
JP2018506286A5 (ru)
ES2193445T3 (es) Catalaizadores para deshidrogenacion de etilbenceno a estireno.
AR092796A1 (es) Composicion particulada de tipo viral
US20210001316A1 (en) Method of preparation of dehydrogenation catalyst with high chromium content
Oliver‐Kozup et al. The group A streptococcal collagen‐like protein‐1, Scl1, mediates biofilm formation by targeting the extra domain A‐containing variant of cellular fibronectin expressed in wounded tissue
BR112014024751A2 (pt) antígenos de clostridium difficile
AR109450A1 (es) Moléculas de unión a ilt7 y métodos de uso de las mismas
EA201790013A1 (ru) Способ получения бензола из смеси c-c-углеводородов
AR113318A1 (es) Un proceso y un sistema para la producción selectiva y estable de olefinas c₂ a c₅
EA202191028A1 (ru) Катализаторы дегидрирования и способы их приготовления и использования
RU2008117404A (ru) Модифицированный pt/ru катализатор для раскрытия кольца и способ использования этого катализатора
JP2021505375A (ja) 残油分解触媒のための反応性シリカ−アルミナマトリックス成分組成物
EA201990391A1 (ru) Твердые фосфорнокислые катализаторы
AR117356A1 (es) Métodos para producir parafinas c₂ a c₅ usando un catalizador híbrido que comprende óxido de metal de galio
TH2001003918A (th) แคทาลิสท์ดีไฮโดรจีเนชั่นและวิธีการเตรียมและการใช้แคทาลิสท์นี้
AR022003A1 (es) COMPOSICIoN CATALIZADORA PARA EL ENRIQUECIMIENTO DE HIDROCARBUROS QUE TIENEN TEMPERATURAS DE EBULLICIoN DENTRO DEL RANGO DE LAS NAFTAS, PROCEDIMIENTO PARA LA PREPARACIoN DE DICHAS COMPOSICIONES CATALIZADORAS Y PROCEDIMIENTO PARA LA DESULFURACIoN DE MEZCLAS DE HIDROCARBUROS C4, CON RANGO DE EBULLICIo
TW202216286A (zh) 脫氫觸媒及其使用方法
RU2361667C1 (ru) Катализатор для дегидрирования олефиновых углеводородов
US3297773A (en) Manufacture of aromatic hydrocarbons
TWI639468B (zh) 穩定之錸系異相催化劑及其應用