EA201600533A1 - Катализатор и способ ароматизации c-cгазов, легких углеводородных фракций и алифатических спиртов, а также их смесей - Google Patents

Катализатор и способ ароматизации c-cгазов, легких углеводородных фракций и алифатических спиртов, а также их смесей

Info

Publication number
EA201600533A1
EA201600533A1 EA201600533A EA201600533A EA201600533A1 EA 201600533 A1 EA201600533 A1 EA 201600533A1 EA 201600533 A EA201600533 A EA 201600533A EA 201600533 A EA201600533 A EA 201600533A EA 201600533 A1 EA201600533 A1 EA 201600533A1
Authority
EA
Eurasian Patent Office
Prior art keywords
catalyst
mass
zeolite
amount
hydrocarbon
Prior art date
Application number
EA201600533A
Other languages
English (en)
Other versions
EA031119B1 (ru
Inventor
Иосиф Изралиевич Лищинер
Ольга Васильевна МАЛОВА
Андрей Леонидович ТАРАСОВ
Original Assignee
Акционерное Общество Нгт Глобал
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Акционерное Общество Нгт Глобал filed Critical Акционерное Общество Нгт Глобал
Publication of EA201600533A1 publication Critical patent/EA201600533A1/ru
Publication of EA031119B1 publication Critical patent/EA031119B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/065—Catalytic reforming characterised by the catalyst used containing crystalline zeolitic molecular sieves, other than aluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J2029/062—Mixtures of different aluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Изобретение относится к технологии переработки углеводородного сырья, в частности к катализаторам и технологии ароматизации углеводородных газов C-С, легких низкооктановых углеводородных фракций и кислородсодержащих соединений (алифатических спиртов C-C), а также их смесей с получением концентрата ароматических углеводородов (КАУ). Катализатор содержит механическую смесь 2 цеолитов, первый из которых охарактеризован силикатным модулем SiO/AlO=20, предварительно обработан водным раствором щелочи и модифицирован оксидами редкоземельных элементов в количестве от 0,5 до 2,0 мас.% от массы первого цеолита, а второй охарактеризован силикатным модулем SiO/AlO=82, содержит остаточные количества оксида натрия 0,04 мас.% от массы второго цеолита, модифицирован оксидом магния в количестве от 0,5 до 5,0 мас.% от массы второго цеолита, причем цеолиты использованы в массовом соотношении от 1,7/1 до 2,8/1, а связующее содержит, по меньшей мере, оксид кремния и использовано в количестве от 20 до 25 мас.% от массы катализатора. Процесс проводят с использованием разработанного катализатора в изотермическом реакторе без использования рециркуляции газов сепарации путем контактирования стационарного слоя катализатора с испаренным и нагретым в преднагревателе газообразным сырьем. Технический результат - достижение более высокого выхода АрУ при практически полной конверсии у/в сырья и оксигенатов, повышенной селективности в отношении образования ксилолов в составе КАУ, при одновременном упрощении технологического оформления процесса за счет использования пониженного (в том числе атмосферного) давления.
EA201600533A 2014-01-28 2014-12-17 Катализатор и способ ароматизации c-cгазов, легких углеводородных фракций и алифатических спиртов, а также их смесей EA031119B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2014102625/04A RU2544017C1 (ru) 2014-01-28 2014-01-28 Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей
PCT/RU2014/000953 WO2015115932A1 (ru) 2014-01-28 2014-12-17 Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций и алифатических спиртов, а также их смесей

Publications (2)

Publication Number Publication Date
EA201600533A1 true EA201600533A1 (ru) 2016-11-30
EA031119B1 EA031119B1 (ru) 2018-11-30

Family

ID=53290370

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201600533A EA031119B1 (ru) 2014-01-28 2014-12-17 Катализатор и способ ароматизации c-cгазов, легких углеводородных фракций и алифатических спиртов, а также их смесей

Country Status (9)

Country Link
US (2) US10131592B2 (ru)
EP (1) EP3100784A4 (ru)
CN (1) CN106163661B (ru)
AU (1) AU2014380443B2 (ru)
BR (1) BR112016017158A2 (ru)
CA (1) CA2945839A1 (ru)
EA (1) EA031119B1 (ru)
RU (1) RU2544017C1 (ru)
WO (1) WO2015115932A1 (ru)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2544241C1 (ru) 2014-01-22 2015-03-20 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения ароматических углеводородов из природного газа и установка для его осуществления
RU2558955C1 (ru) 2014-08-12 2015-08-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из жидких углеводородных фракций и установка для его осуществления
RU2550354C1 (ru) 2014-03-28 2015-05-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из легких алифатических углеводородов и установка для его осуществления
RU2544017C1 (ru) 2014-01-28 2015-03-10 Ольга Васильевна Малова Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей
WO2015195430A1 (en) * 2014-06-20 2015-12-23 3M Innovative Properties Company Repair compound and methods of use
US9845272B2 (en) * 2015-09-25 2017-12-19 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion
US9988325B2 (en) * 2015-09-25 2018-06-05 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion
WO2017155424A1 (en) 2016-03-09 2017-09-14 Limited Liability Company "New Gas Technologies-Synthesis" (Llc "Ngt-Synthesis") Method and plant for producing high-octane gasolines
US20200291303A1 (en) 2016-03-09 2020-09-17 LLC "NGT-synthesis" Method and catalyst for producing high octane components
RU2671568C1 (ru) * 2016-09-27 2018-11-02 Михайло Барильчук Комплексная установка для переработки смеси углеводородов с1-с10 различного состава и кислородсодержащих соединений
EP3318619A1 (de) * 2016-11-03 2018-05-09 Wolfdieter Klein Consulting GmbH Oel- und Gastechnologie Verfahren zur herstellung von kraftstoffen aus gaskondensaten
US11198822B2 (en) * 2019-04-10 2021-12-14 Exxonmobil Research And Engineering Company Processes to convert naphtha to heavier products
US10844295B1 (en) 2019-10-11 2020-11-24 Saudi Arabian Oil Company Systems and processes to deolefinate aromatic-rich hydrocarbon streams

Family Cites Families (83)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3756942A (en) 1972-05-17 1973-09-04 Mobil Oil Corp Process for the production of aromatic compounds
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
US3911041A (en) 1974-09-23 1975-10-07 Mobil Oil Corp Conversion of methanol and dimethyl ether
US4159282A (en) 1978-06-09 1979-06-26 Mobil Oil Corporation Xylene isomerization
US4211640A (en) 1979-05-24 1980-07-08 Mobil Oil Corporation Process for the treatment of olefinic gasoline
US4227992A (en) 1979-05-24 1980-10-14 Mobil Oil Corporation Process for separating ethylene from light olefin mixtures while producing both gasoline and fuel oil
US4356338A (en) 1979-07-27 1982-10-26 Mobil Oil Corporation Extending catalyst life by treating with phosphorus and/or steam
US4424401A (en) * 1980-08-12 1984-01-03 The Broken Hill Proprietary Company Limited Aromatization of acetylene
US4499314A (en) 1982-03-31 1985-02-12 Imperial Chemical Industries Plc Methanol conversion to hydrocarbons with zeolites and cocatalysts
US4523049A (en) 1984-04-16 1985-06-11 Atlantic Richfield Company Methane conversion process
US4456527A (en) 1982-10-20 1984-06-26 Chevron Research Company Hydrocarbon conversion process
US4463204A (en) 1983-04-22 1984-07-31 Exxon Research & Engineering Co. Process for alkylating toluene with methanol to form styrene using a low sodium content potassium/cesium modified zeolite catalyst composition
US4465886A (en) 1983-06-09 1984-08-14 Mobil Oil Corporation Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes
US4554260A (en) 1984-07-13 1985-11-19 Exxon Research & Engineering Co. Two stage process for improving the catalyst life of zeolites in the synthesis of lower olefins from alcohols and their ether derivatives
US4590321A (en) 1985-06-12 1986-05-20 Mobil Oil Corporation Aromatization reactions with zeolites containing phosphorus oxide
US4899011A (en) 1986-01-15 1990-02-06 Mobil Oil Corporation Xylene isomerization process to exhaustively convert ethylbenzene and non-aromatics
US4720602A (en) 1986-09-08 1988-01-19 Mobil Oil Corporation Process for converting C2 to C12 aliphatics to aromatics over a zinc-activated zeolite
US5306411A (en) 1989-05-25 1994-04-26 The Standard Oil Company Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions
US4853202A (en) 1987-09-08 1989-08-01 Engelhard Corporation Large-pored crystalline titanium molecular sieve zeolites
US5178748A (en) 1988-12-22 1993-01-12 Imperial Chemical Industries Catalytic reactions using zeolites
US4963337A (en) 1989-07-07 1990-10-16 Chevron Research Company Zeolite SSZ-33
FR2659648B1 (fr) * 1990-03-13 1993-02-12 Michelin Rech Tech Procede pour preparer un produit aromatique alkyle avec une zeolithe d'alkylation et une zeolithe de dealkylation.
US5173461A (en) 1990-03-21 1992-12-22 Mobil Oil Corporation Toluene disproportionation catalyst
GB9013916D0 (en) 1990-06-22 1990-08-15 Ici Plc Zeolites
US5516736A (en) 1992-03-12 1996-05-14 Mobil Oil Corp. Selectivating zeolites with organosiliceous agents
US5498814A (en) 1992-03-12 1996-03-12 Mobil Oil Corp. Regioselective methylation of toluene to para-xylene
US5321183A (en) 1992-03-12 1994-06-14 Mobil Oil Corp. Process for the regioselective conversion of aromatics to para-disubstituted benzenes
CN1030287C (zh) * 1992-10-22 1995-11-22 中国石油化工总公司 制取高质量汽油、丙烯、丁烯的烃转化催化剂
US5365003A (en) 1993-02-25 1994-11-15 Mobil Oil Corp. Shape selective conversion of hydrocarbons over extrusion-modified molecular sieve
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
CN1036320C (zh) * 1993-11-23 1997-11-05 中国石油化工总公司石油化工科学研究院 一种制备异丁烯和异戊烯的裂化催化剂
KR100364182B1 (ko) 1994-11-23 2003-02-07 엑손모빌 케미칼 패턴츠 인코포레이티드 제올라이트결합제올라이트촉매를사용한탄화수소의전환방법
DE19533484A1 (de) 1995-09-12 1997-03-13 Basf Ag Monomodale und polymodale Katalysatorträger und Katalysatoren mit engen Porengrößenverteilungen und deren Herstellverfahren
US5952535A (en) * 1996-09-18 1999-09-14 Catalytica, Inc. Selective catalytic conversion of a C9 aromatic feedstock containing substantial amounts of ethyl substituted aromatic components to a product rich in toluene and/or xylenes
US6046372A (en) 1996-10-02 2000-04-04 Mobil Oil Corporation Process for producing light olefins
US6423879B1 (en) 1997-10-02 2002-07-23 Exxonmobil Oil Corporation Selective para-xylene production by toluene methylation
US6063724A (en) 1998-04-06 2000-05-16 The Board Of Regents Of The University Of Oklahoma Sulfur-tolerant aromatization catalysts
US6143166A (en) 1998-08-17 2000-11-07 Chevron Chemical Co. Llc Process for production of aromatics in parallel reformers with an improved catalyst life and reduced complexity
US6699811B1 (en) * 1999-05-05 2004-03-02 Exxon Mobil Chemical Patents Inc. Tailored zeolite bound zeolite catalyst and its use for hydrocarbon conversion
ES2250072T3 (es) 1999-06-24 2006-04-16 Eni S.P.A. Composicion catalitica para la aromatizacion de hidrocarburos.
US6277355B1 (en) * 1999-07-13 2001-08-21 Exxonmobil Chemical Patents Inc. Synthesis of ZSM-5 and ZSM-11
KR20020061011A (ko) 1999-12-28 2002-07-19 코닝 인코포레이티드 제올라이트/알루미나 촉매 지지체 조성물 및 이의 제조방법
RU2165293C1 (ru) * 2000-03-09 2001-04-20 Фалькевич Генрих Семенович Катализатор и способ превращения алифатических углеводородов c2-c12 в высокооктановый компонент бензина или концентрат ароматических углеводородов
RU2163623C1 (ru) 2000-06-29 2001-02-27 Колесников Сергей Иванович Способ переработки низкооктановых бензиновых фракций
KR100557558B1 (ko) 2000-11-30 2006-03-03 에스케이 주식회사 탄화수소 혼합물로부터 방향족 탄화수소 및 액화석유가스를 제조하는 방법
CA2369318A1 (en) 2002-01-28 2003-07-28 Universite Concordia Hybrid catalysts for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks for the selective production of light olefins
US6995111B2 (en) 2002-02-28 2006-02-07 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US7208442B2 (en) 2002-02-28 2007-04-24 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
US6906232B2 (en) 2002-08-09 2005-06-14 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US6784333B2 (en) 2002-08-06 2004-08-31 Saudi Basic Industries Corporation Catalyst for aromatization of alkanes, process of making and using thereof
US7122493B2 (en) 2003-02-05 2006-10-17 Exxonmobil Chemical Patents Inc. Combined cracking and selective hydrogen combustion for catalytic cracking
US7122492B2 (en) 2003-02-05 2006-10-17 Exxonmobil Chemical Patents Inc. Combined cracking and selective hydrogen combustion for catalytic cracking
EP1479662B1 (en) 2003-05-17 2008-10-22 Haldor Topsoe A/S Process for conversion of oxygenates to hydrocarbons and composition of use therein
US7186871B2 (en) 2003-12-30 2007-03-06 Saudi Basic Industries Corporation Process for alkane aromatization using platinum-zeolite catalyst
CA2563262C (en) 2004-03-31 2012-07-10 China Petroleum & Chemical Corporation A zeolite-containing hydrocarbon-converting catalyst, the preparation process thereof, and a process for converting hydrocarbon oils with the catalyst
RU2277524C1 (ru) 2004-12-16 2006-06-10 Генрих Семёнович Фалькевич Способ получения ароматических углеводородов
FR2886636B1 (fr) 2005-06-02 2007-08-03 Inst Francais Du Petrole Materiau inorganique presentant des nanoparticules metalliques piegees dans une matrice mesostructuree
KR100645659B1 (ko) * 2005-06-21 2006-11-14 에스케이 주식회사 탄화수소 혼합물로부터 벤젠을 증산하는 방법
CN100391610C (zh) 2005-08-15 2008-06-04 中国石油化工股份有限公司 含分子筛的催化裂解流化床催化剂
WO2007021394A2 (en) 2005-08-18 2007-02-22 Exxonmobil Chemical Patents Inc. Catalytic conversion of oxygenates to olefins
JP4714589B2 (ja) * 2006-01-20 2011-06-29 石油コンビナート高度統合運営技術研究組合 重質油の接触分解触媒及びオレフィンと燃料油の製造方法
US7932425B2 (en) 2006-07-28 2011-04-26 Chevron Phillips Chemical Company Lp Method of enhancing an aromatization catalyst
PL2698416T3 (pl) 2007-03-08 2021-02-08 Virent, Inc. Synteza paliw ciekłych z węglowodorów zawierających tlen
US8017818B2 (en) 2007-03-08 2011-09-13 Virent Energy Systems, Inc. Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
CN101279287B (zh) 2007-04-04 2011-07-13 中国石油化工股份有限公司 用于催化裂解制烯烃的催化剂
RU2337127C1 (ru) 2007-05-02 2008-10-27 Институт проблем переработки углеводородов Сибирского отделения Российской Академии Наук (ИППУ СО РАН) Способ каталитического риформинга бензиновых фракций
EP2082803A1 (en) 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining catalyst composites comprising MeAPO and their use in conversion of organics to olefins
RU2372988C1 (ru) 2008-03-04 2009-11-20 Общество с ограниченной ответственностью "СИНТОН" Катализатор для превращения алифатических углеводородов c2-c12 и/или алифатических кислородсодержащих соединений c1-c12, способ его получения и способ получения высокооктанового бензина или ароматических углеводородов
CA2648856A1 (en) 2008-12-22 2010-06-22 Martin Chang Production of light grade liquid hydrocarbons from ethanol
KR101922828B1 (ko) 2010-02-01 2018-11-27 존슨 맛쎄이 퍼블릭 리미티드 컴파니 압출된 ｓｃｒ 필터
CN102971075B (zh) 2010-05-20 2016-02-17 沙特基础工业公司 预碳化钼改性沸石催化剂及其用于低级烷烃芳构化的用途
RU2440189C1 (ru) * 2010-07-08 2012-01-20 Открытое Акционерное Общество "Gtl" Катализатор и способ получения высокооктановых бензинов с низким содержанием бензола и дурола
RU2429910C1 (ru) * 2010-07-08 2011-09-27 Андрей Леонидович Тарасов Катализатор и способ совместной переработки низкооктановых углеводородных фракций и алифатических спиртов и/или диметилового эфира
DE102011013908A1 (de) 2011-03-15 2012-09-20 Süd-Chemie AG Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen
CN103827058B (zh) 2011-06-15 2016-08-17 Ut-巴特勒有限责任公司 醇转化为碳氢化合物的沸石催化
CN103537315B (zh) 2012-07-12 2015-11-25 中国石油化工股份有限公司 甲醇制芳烃催化剂及其制备方法
US9434658B2 (en) 2013-03-06 2016-09-06 Ut-Battelle, Llc Catalytic conversion of alcohols to hydrocarbons with low benzene content
RU2558955C1 (ru) 2014-08-12 2015-08-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из жидких углеводородных фракций и установка для его осуществления
RU2544017C1 (ru) 2014-01-28 2015-03-10 Ольга Васильевна Малова Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей
RU2550354C1 (ru) 2014-03-28 2015-05-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из легких алифатических углеводородов и установка для его осуществления
RU2544241C1 (ru) 2014-01-22 2015-03-20 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения ароматических углеводородов из природного газа и установка для его осуществления
WO2017155424A1 (en) 2016-03-09 2017-09-14 Limited Liability Company "New Gas Technologies-Synthesis" (Llc "Ngt-Synthesis") Method and plant for producing high-octane gasolines

Also Published As

Publication number Publication date
US10894752B2 (en) 2021-01-19
AU2014380443A1 (en) 2016-08-25
RU2544017C1 (ru) 2015-03-10
EP3100784A1 (en) 2016-12-07
US20170007992A1 (en) 2017-01-12
CA2945839A1 (en) 2015-08-06
BR112016017158A2 (pt) 2017-10-03
EP3100784A4 (en) 2017-09-27
AU2014380443B2 (en) 2018-08-02
EA031119B1 (ru) 2018-11-30
WO2015115932A1 (ru) 2015-08-06
US10131592B2 (en) 2018-11-20
US20190100477A1 (en) 2019-04-04
CN106163661B (zh) 2019-09-06
CN106163661A (zh) 2016-11-23

Similar Documents

Publication Publication Date Title
EA201600533A1 (ru) Катализатор и способ ароматизации c-cгазов, легких углеводородных фракций и алифатических спиртов, а также их смесей
AR104069A1 (es) Proceso integrado de deshidrogenación de hidrocarburos c₃₋₄
RU2017140846A (ru) Способы конверсии co2 в синтез-газ
RU2017113364A (ru) Способ получения бутадиена и водорода из этанола в одну реакционную стадию при низком расходе воды и энергии
NO20073194L (no) Fremgangsmate for fremstilling av 1,2-dikloretan
WO2015147700A1 (ru) Способ получения концентрата ароматических углеводородов из легких алифатических углеводородов и установка для его осуществления
RU2015105406A (ru) Способ получения олефинов посредством термического парового крекинга в крекинг-печах
EP2940103B1 (en) A method for obtaining biofuels using ethanol, or mixtures of alcohol as biofuel or biocomponent
ES2820564T3 (es) Método para producir un hidrocarburo aromático con un oxigenato como materia prima
EA201691716A1 (ru) Способ получения бензола, толуола, ксилола (бтк) из смеси углеводородов с-с
AU2012357510A1 (en) Catalyst used in the production of ethylene and propylene from methanol and/or dimethyl ether, method for preparing the same and method for using the same
JP2015537052A (ja) フェノール化合物を芳香族炭化水素に転化する方法
JP2006116439A (ja) エチレン製造用触媒およびこの触媒を用いるエチレンの製造方法
JP4734671B2 (ja) エチレン製造用触媒
BR112021011508A2 (pt) Processo de produção de butadieno a partir de etanol com regeneração in situ do catalisador da segunda etapa reacional
HUE028269T2 (hu) Eljárás 1,3-butadién elõállítására
JP2013515714A5 (ru)
RU2015142880A (ru) Алюмосиликатные молекулярные сита mfi-типа и способы их применения при изомеризации ксилола
EA200900409A1 (ru) Способ переработки смеси водорода и оксидов углерода (варианты)
EA201990391A1 (ru) Твердые фосфорнокислые катализаторы
RU2010135608A (ru) Катализатор для глубокой переработки метанола в бензол и метилбензолы и способ переработки метанола в бензол и метилбензолы
RU2012145446A (ru) Катализатор и способ синтеза олефинов из диметилового эфира в его присутствии
RU2016114420A (ru) Каталитическая композиция и способ ее применения для алкилирования ароматических углеводородов спиртами или смесями спиртов и олефинов
IN2013MU03669A (ru)
JP2015518511A5 (ru)

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG TJ TM RU