EA201490510A1 - Способ риформинга газа, полученного газификацией - Google Patents

Способ риформинга газа, полученного газификацией

Info

Publication number
EA201490510A1
EA201490510A1 EA201490510A EA201490510A EA201490510A1 EA 201490510 A1 EA201490510 A1 EA 201490510A1 EA 201490510 A EA201490510 A EA 201490510A EA 201490510 A EA201490510 A EA 201490510A EA 201490510 A1 EA201490510 A1 EA 201490510A1
Authority
EA
Eurasian Patent Office
Prior art keywords
metal catalyst
reforming
gasification
gas obtained
reforming gas
Prior art date
Application number
EA201490510A
Other languages
English (en)
Other versions
EA024259B1 (ru
Inventor
Пекка Симелл
Эса Куркела
Илькка Хильтунен
Сами Топпинен
Исто Эйлос
Original Assignee
Несте Оил Ойй
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Несте Оил Ойй filed Critical Несте Оил Ойй
Publication of EA201490510A1 publication Critical patent/EA201490510A1/ru
Publication of EA024259B1 publication Critical patent/EA024259B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/023—Reducing the tar content
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/092—Wood, cellulose
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
  • Industrial Gases (AREA)

Abstract

Способ риформинга газа, полученного газификацией, для разложения содержащихся в нем загрязнений и новое применение катализатора на основе драгоценного металла при предриформинге газа, полученного газификацией. В данном способе газ приводят в контакт с металлическим катализатором в присутствии окислителя. Согласно настоящему изобретению риформинг осуществляют в несколько стадий, причем в по меньшей мере одной из первых каталитических зон используют катализатор на основе благородного металла, а на второй стадии риформинга, которая следует за первой, используемым катализатором является металлический катализатор. Кислород подают раздельно в каждую из каталитических зон. Использование катализатора на основе благородного металла снижает риск деактивации металлических катализаторов и поэтому увеличивает срок службы катализатора.
EA201490510A 2011-09-02 2012-09-03 Способ риформинга газа, полученного газификацией EA024259B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161530431P 2011-09-02 2011-09-02
EP11179907.8A EP2565155B1 (en) 2011-09-02 2011-09-02 Method of reforming gasification gas
PCT/FI2012/050851 WO2013030463A2 (en) 2011-09-02 2012-09-03 Method of reforming gasification gas

Publications (2)

Publication Number Publication Date
EA201490510A1 true EA201490510A1 (ru) 2014-08-29
EA024259B1 EA024259B1 (ru) 2016-08-31

Family

ID=44674424

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201490510A EA024259B1 (ru) 2011-09-02 2012-09-03 Способ риформинга газа, полученного газификацией

Country Status (9)

Country Link
US (1) US20130058855A1 (ru)
EP (1) EP2565155B1 (ru)
CN (1) CN104024150B (ru)
BR (1) BR112014004278B1 (ru)
CA (1) CA2846936C (ru)
EA (1) EA024259B1 (ru)
ES (1) ES2710851T3 (ru)
UY (1) UY34304A (ru)
WO (1) WO2013030463A2 (ru)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9637433B2 (en) 2014-11-28 2017-05-02 Pioneer Energy, Inc. Systems and methods for manufacture of methanol from natural gas and flare gas feedstock
US11213794B2 (en) 2016-06-10 2022-01-04 Haldor Topsøe A/S CO rich synthesis gas production
BR102017021428B1 (pt) * 2017-10-05 2022-04-19 Petróleo Brasileiro S.A. - Petrobras Processo para preparação de um catalisador de pré-reforma
US20200406212A1 (en) * 2017-12-08 2020-12-31 Haldor Topsøe A/S System and process for synthesis gas production
EP3805340B1 (de) * 2019-10-09 2023-06-07 Reissner, Markus Verfahren und verwendung einer anlage zur erzeugung eines kohlenwasserstoff- und wasserstoff-haltigen gasgemisches aus kunststoff

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI110691B (fi) 2001-06-21 2003-03-14 Valtion Teknillinen Menetelmä kaasutuskaasun puhdistamiseksi
US7753973B2 (en) * 2002-06-27 2010-07-13 Galloway Terry R Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions
US20050095183A1 (en) * 2003-11-05 2005-05-05 Biomass Energy Solutions, Inc. Process and apparatus for biomass gasification
FI118647B (fi) 2006-04-10 2008-01-31 Valtion Teknillinen Menetelmä tervamaisia epäpuhtauksia sisältävän kaasun reformoimiseksi
JP5487607B2 (ja) * 2008-12-16 2014-05-07 Ｊｆｅスチール株式会社 冶金炉発生排ガスの改質方法およびその装置
US20100187479A1 (en) * 2009-01-23 2010-07-29 Carbona Oy Process and apparatus for reforming of heavy and light hydrocarbons from product gas of biomass gasification
FI123686B (fi) * 2010-03-03 2013-09-30 Neste Oil Oyj Menetelmä kaasutuskaasun reformoimiseksi

Also Published As

Publication number Publication date
WO2013030463A2 (en) 2013-03-07
BR112014004278A2 (pt) 2017-03-21
EA024259B1 (ru) 2016-08-31
CA2846936A1 (en) 2013-03-07
CA2846936C (en) 2021-05-04
CN104024150B (zh) 2017-05-10
BR112014004278B1 (pt) 2021-11-03
EP2565155B1 (en) 2018-12-05
WO2013030463A3 (en) 2013-08-01
ES2710851T3 (es) 2019-04-29
EP2565155A1 (en) 2013-03-06
US20130058855A1 (en) 2013-03-07
UY34304A (es) 2013-04-05
CN104024150A (zh) 2014-09-03

Similar Documents

Publication Publication Date Title
EA201290812A1 (ru) Способ риформинга газа газификации
EA201490510A1 (ru) Способ риформинга газа, полученного газификацией
MX345655B (es) Metodo para producir un alcano que contiene fluor.
EA201491067A1 (ru) Катализаторы из нанопроволоки и способы их применения и получения
MX341767B (es) Fluoracion catalitica en fase gas.
ES2421741T1 (es) Procedimiento para la reducción de la concentración de aldehído en una corriente gaseosa
MX343621B (es) Fluoracion catalitica en fase gas.
ECSP11011404A (es) Método para la producción de carbono sólido mediante la reducción de óxidos de carbono
EA201491059A1 (ru) Устройство и способ для устранения noи no
EA201391598A1 (ru) Способ извлечения серы с одновременным получением водорода и нулевыми выбросами
DE502007006609D1 (de) Verfahren zur herstellung von chlor durch gasphasenoxidation
AR092990A1 (es) Bifosfito asimetrico utilizado en una composicion catalitica para la reaccion de hidroformilacion
EA201591041A1 (ru) Способ окислительного дегидрирования н-бутенов в бутадиен
AR090926A1 (es) Un catalizador para la deshidrogenacion oxidativa de alcanos y/o la oxidacion de alquenos
MY157440A (en) Catalyst composition for selective catalytic reduction of exhaust gases
EA201491921A8 (ru) Способ снижения концентрации оксида азота в отходящем газе в установке для получения азотной кислоты во время отключения и/или запуска установки и установка для получения азотной кислоты, пригодная для осуществления способа
NO20076579L (no) Forbedringer i katalysatorer
TN2014000178A1 (en) PROCESS FOR THE CATALYTIC REMOVAL OF CARBON DIOXIDE, NOx FROM EXHAUST GASES
EA201390930A1 (ru) Каталитическая система и ее использование для производства винилхлорида гидрохлорированием ацетилена
BRPI0407852A (pt) método de fabricação de óxido de etileno
AR116284A1 (es) Métodos para operar procesos de deshidrogenación en condiciones anormales de funcionamiento
EA201591040A1 (ru) Способ окислительного дегидрирования н-бутенов в бутадиен
EA201590045A1 (ru) Способ реформинга углеводородов и способ инициирования процесса газ-в-жидкость
EA201301250A1 (ru) Способ обработки синтез-газа и система, использующая медный катализатор в двухступенчатых реакциях при 475-525°c и 250-290°c
IN2015DN01420A (ru)

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG TJ TM RU