EA201290812A1 - Способ риформинга газа газификации - Google Patents

Способ риформинга газа газификации

Info

Publication number
EA201290812A1
EA201290812A1 EA201290812A EA201290812A EA201290812A1 EA 201290812 A1 EA201290812 A1 EA 201290812A1 EA 201290812 A EA201290812 A EA 201290812A EA 201290812 A EA201290812 A EA 201290812A EA 201290812 A1 EA201290812 A1 EA 201290812A1
Authority
EA
Eurasian Patent Office
Prior art keywords
metal catalyst
catalyst
noble metal
gasification gas
reforming method
Prior art date
Application number
EA201290812A
Other languages
English (en)
Other versions
EA025607B1 (ru
Inventor
Пекка Симелл
Эса Куркела
Илькка Хильтунен
Original Assignee
Несте Оил Ойй
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Несте Оил Ойй filed Critical Несте Оил Ойй
Publication of EA201290812A1 publication Critical patent/EA201290812A1/ru
Publication of EA025607B1 publication Critical patent/EA025607B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/34—Purifying combustible gases containing carbon monoxide by catalytic conversion of impurities to more readily removable materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/023—Reducing the tar content
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)

Abstract

Способ риформинга газа, полученного в процессе газификации, для разложения содержащихся в нем органических примесей и новое применение катализатора на основе благородного металла для предриформинга газа, полученного в процессе газификации. В данном способе газ приводят в контакт с металлическим катализатором в присутствии окислителя. Согласно настоящему изобретению риформинг осуществляют в нескольких блоках, причем по меньшей мере в одном из первых блоков используют катализатор на основе благородного металла, а во втором блоке, который расположен после первого блока, катализатором является металлический катализатор. Использование катализатора на основе благородного металла снижает риск деактивации металлических катализаторов и поэтому увеличивает срок службы катализаторов.
EA201290812A 2010-03-03 2011-03-03 Способ риформинга газа газификации EA025607B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20105201A FI123686B (fi) 2010-03-03 2010-03-03 Menetelmä kaasutuskaasun reformoimiseksi
PCT/FI2011/050181 WO2011107661A1 (en) 2010-03-03 2011-03-03 Method of reforming gasification gas

Publications (2)

Publication Number Publication Date
EA201290812A1 true EA201290812A1 (ru) 2013-03-29
EA025607B1 EA025607B1 (ru) 2017-01-30

Family

ID=42074320

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201290812A EA025607B1 (ru) 2010-03-03 2011-03-03 Способ риформинга газа газификации

Country Status (9)

Country Link
US (1) US8936658B2 (ru)
EP (1) EP2542654B1 (ru)
CN (1) CN102812110B (ru)
BR (1) BR112012021962B1 (ru)
CA (1) CA2787672C (ru)
EA (1) EA025607B1 (ru)
ES (1) ES2625783T3 (ru)
FI (1) FI123686B (ru)
WO (1) WO2011107661A1 (ru)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI123686B (fi) 2010-03-03 2013-09-30 Neste Oil Oyj Menetelmä kaasutuskaasun reformoimiseksi
EP2484427B1 (en) 2011-02-08 2017-07-19 Neste Oyj A two-stage gas washing method
US20120291351A1 (en) * 2011-05-16 2012-11-22 Lawrence Bool Reforming methane and higher hydrocarbons in syngas streams
ES2785988T3 (es) 2011-05-30 2020-10-08 Neste Oyj Procedimiento de producción de una composición de hidrocarburo
ES2666417T3 (es) 2011-08-31 2018-05-04 Neste Oyj Método de lavado de gas en dos etapas aplicando precipitación de sulfuro y absorción alcalina
ES2710851T3 (es) * 2011-09-02 2019-04-29 Neste Oyj Método para reformar gas de gasificación
CN104017610B (zh) * 2014-05-29 2015-12-02 中国天辰工程有限公司 一种高温条件下降解褐煤气化合成气中酚类的方法
JP6596888B2 (ja) * 2015-04-02 2019-10-30 株式会社Ｉｈｉ タール改質装置
US10584052B2 (en) * 2017-01-27 2020-03-10 American Air Liquide, Inc. Enhanced waste heat recovery using a pre-reformer combined with oxygen and fuel pre-heating for combustion
US20190113223A1 (en) * 2017-10-18 2019-04-18 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude METHOD FOR MINIMIZING NOx EMISSIONS DURING POX BASED SYNGAS PLANT STARTUP
SI25770A (sl) * 2019-01-07 2020-07-31 Teos Perne Postopek uplinjanja trdnih materialov z vsebnostjo ogljika, s poudarjeno koncentracijo katranov in njihovo katalitsko pretvorbo v ogljikov monoksid in vodik
WO2021069799A1 (en) * 2019-10-08 2021-04-15 Teknologian Tutkimuskeskus Vtt Oy Method and apparatus for removing impurities from gasification gas and use
CN110846090A (zh) * 2019-12-09 2020-02-28 中城绿建科技有限公司 裂解气化装置

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3388074A (en) * 1963-12-26 1968-06-11 Catalysts & Chem Inc Two-stage steam reforming with rapid warm-up in first stage by means of a promoted catalyst
US4005996A (en) * 1975-09-04 1977-02-01 El Paso Natural Gas Company Methanation process for the production of an alternate fuel for natural gas
FI110691B (fi) 2001-06-21 2003-03-14 Valtion Teknillinen Menetelmä kaasutuskaasun puhdistamiseksi
US7753973B2 (en) 2002-06-27 2010-07-13 Galloway Terry R Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions
ES2381105T3 (es) * 2003-02-05 2012-05-23 Haldor Topsoe A/S Procedimiento para el tratamiento de gas de síntesis
US20050095183A1 (en) 2003-11-05 2005-05-05 Biomass Energy Solutions, Inc. Process and apparatus for biomass gasification
MY151832A (en) * 2004-06-28 2014-07-14 Osaka Gas Co Ltd Reformed gas production method and reformed gas production apparatus
FI118647B (fi) 2006-04-10 2008-01-31 Valtion Teknillinen Menetelmä tervamaisia epäpuhtauksia sisältävän kaasun reformoimiseksi
DE102008021081A1 (de) * 2008-04-28 2009-10-29 Süd-Chemie AG Verfahren zur katalytischen Verringerung des Teergehalts in Gasen aus Vergasungsprozessen unter Verwendung eines Katalysators auf Edelmetallbasis
DE102008021084A1 (de) 2008-04-28 2009-10-29 Süd-Chemie AG Verwendung eines Katalysators auf Edelmetallbasis zur Verringerung des Teergehalts in Gasen aus Vergasungsprozessen
CN102159500A (zh) * 2008-08-18 2011-08-17 辛吉斯特公司 由生物质生产氨的方法
US20100187479A1 (en) 2009-01-23 2010-07-29 Carbona Oy Process and apparatus for reforming of heavy and light hydrocarbons from product gas of biomass gasification
FI123686B (fi) 2010-03-03 2013-09-30 Neste Oil Oyj Menetelmä kaasutuskaasun reformoimiseksi

Also Published As

Publication number Publication date
WO2011107661A1 (en) 2011-09-09
BR112012021962A2 (pt) 2016-06-07
FI20105201A0 (fi) 2010-03-03
ES2625783T3 (es) 2017-07-20
US20130047511A1 (en) 2013-02-28
CA2787672C (en) 2018-09-18
CN102812110B (zh) 2015-04-22
CA2787672A1 (en) 2011-09-09
FI123686B (fi) 2013-09-30
EA025607B1 (ru) 2017-01-30
US8936658B2 (en) 2015-01-20
BR112012021962B1 (pt) 2018-09-25
EP2542654A1 (en) 2013-01-09
FI20105201A (fi) 2011-09-04
EP2542654A4 (en) 2014-12-03
CN102812110A (zh) 2012-12-05
EP2542654B1 (en) 2017-04-19

Similar Documents

Publication Publication Date Title
EA201290812A1 (ru) Способ риформинга газа газификации
ES2421741T1 (es) Procedimiento para la reducción de la concentración de aldehído en una corriente gaseosa
ATE552210T1 (de) Verfahren zur reinigung von chlorwasserstoff
EA201590443A1 (ru) Реактор и катализатор для превращения природного газа в органические соединения
MX2012004110A (es) Proceso para purificar (hidro) fluoroalquenos.
EA201491067A1 (ru) Катализаторы из нанопроволоки и способы их применения и получения
WO2012118331A3 (ko) 소음감쇄 구조를 갖는 배기가스 탈질시스템
IN2014DN07432A (ru)
EA201270504A1 (ru) Способ окисления органических соединений
MX341767B (es) Fluoracion catalitica en fase gas.
EA201490510A1 (ru) Способ риформинга газа, полученного газификацией
PL2257372T3 (pl) Proces regeneracji katalizatora zawierającego ruten lub związki rutenu, zatrutego siarką w postaci związków siarki
CL2012000244A1 (es) Medio de absorción para retirar gases ácidos de una corriente de fluidos, que comprende una solución acuosa de (a) una sal de metales alcalinos de un acido n,n-di-c1-c4-alquilaminocarboxilico y (b) n-hidroxietilpiperazina; y proceso para retirar gases ácidos de una corriente de fluidos poniéndola en contacto con dicho medio de absorción.
EA201390930A1 (ru) Каталитическая система и ее использование для производства винилхлорида гидрохлорированием ацетилена
PT2255879E (pt) Catalisador portador de metal perfurado para purificação de gás de escape
MY171117A (en) A catalyst for treating exhaust gas of natural gas vehicles
BRPI0904848A2 (pt) Catalisador para oxidação parcial catalítica de hidrocarbonetos, e processo para produzir um gás de síntese
EA201591183A1 (ru) Способ гидрогалогенирования ненасыщенного углеводорода
BR112013018701A2 (pt) catalisador de aromatização de metano, e, processos para preparar um catalisador de aromatização de metano e para produzir hidrocarbonetos aromáticos
TN2014000178A1 (en) PROCESS FOR THE CATALYTIC REMOVAL OF CARBON DIOXIDE, NOx FROM EXHAUST GASES
CL2012001300A1 (es) Proceso de preparación de un compuesto de fórmula (i) en forma de sal iónica, que comprende las etapas de i) hidrogenar un compuesto de fórmula (ii) usando un catalizador metálico con hidrógeno y ii) filtrar el catalizador seguido de tratamiento con una solución ácida o gas.
BR112012013909A2 (pt) processo para reagir dióxido de carbono com hidrogênio
EA201290700A1 (ru) Способ обработки каталитического реактора
BRPI1011010A2 (pt) processo para oxidação catalítica de cloreto de hidrog~enio.
DE502005002665D1 (de) Katalytische entfernung von gelöstem sauerstoff aus organischen flüssigkeiten

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM RU