EA201390375A1 - Способ удаления химических органических соединений и металлорганических комплексов из отработанной воды или других потоков горно-обогатительного комбината с применением цеолита - Google Patents

Способ удаления химических органических соединений и металлорганических комплексов из отработанной воды или других потоков горно-обогатительного комбината с применением цеолита

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Publication number
EA201390375A1
EA201390375A1 EA201390375A EA201390375A EA201390375A1 EA 201390375 A1 EA201390375 A1 EA 201390375A1 EA 201390375 A EA201390375 A EA 201390375A EA 201390375 A EA201390375 A EA 201390375A EA 201390375 A1 EA201390375 A1 EA 201390375A1
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Eurasian Patent Office
Prior art keywords
zeolite
deta
complexes
waste water
metal
Prior art date
Application number
EA201390375A
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English (en)
Inventor
Цзе Дун
Маньцюй Сюй
Кеннет Эрвин Скоули
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Вале С/А
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Publication date
Application filed by Вале С/А filed Critical Вале С/А
Publication of EA201390375A1 publication Critical patent/EA201390375A1/ru

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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/165—Natural alumino-silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/14—Base exchange silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C02F1/683—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of complex-forming compounds
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/62—Heavy metal compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/004—Sludge detoxification
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C02F2001/425—Treatment of water, waste water, or sewage by ion-exchange using cation exchangers
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C02F2101/22—Chromium or chromium compounds, e.g. chromates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/303—Complexing agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/38—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/16—Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/06—Controlling or monitoring parameters in water treatment pH
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00—General aspects of water treatment
    • C02F2301/02—Fluid flow conditions
    • C02F2301/024—Turbulent
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/16—Regeneration of sorbents, filters
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/18—Removal of treatment agents after treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Nanotechnology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treatment Of Sludge (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Water Treatment By Sorption (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

Настоящее изобретение относится к способу удаления химических органических соединений и металлорганических комплексов (органических комплексов тяжелых металлов) с применением цеолита из потоков отработанной воды или хвостов горно-обогатительного комбината, где в качестве флотационного реагента применяется диэтилентриамин (DETA) или триэтилентетрамин (ТЕТА), и DETA-металлические комплексы попадают в потоки отработанной воды или хвостов обогащения. В предпочтительном варианте осуществления изобретения потоки отработанной воды или хвостовой пульпы горно-обогатительного комбината, содержащие DETA, DETA-металлические комплексы и остаточные тяжелые металлы, подвергают контактированию с природным цеолитом. Такое контактирование можно осуществлять путем добавления природного цеолита к технологическим потокам (пульпам) во время смешивания в механическом смесителе для эффективной адсорбции DETA, DETA-металлических комплексов и тяжелых металлов из технологический потоков (пульп) на цеолите. Затем нагруженный цеолит утилизируют с флотационными хвостами.
EA201390375A 2010-09-13 2011-09-13 Способ удаления химических органических соединений и металлорганических комплексов из отработанной воды или других потоков горно-обогатительного комбината с применением цеолита EA201390375A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US38210110P 2010-09-13 2010-09-13
PCT/BR2011/000328 WO2012034202A2 (en) 2010-09-13 2011-09-13 A method for the removal of organic chemicals and organometallic complexes from process water or other streams of a mineral processing plant using zeolite

Publications (1)

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EA201390375A1 true EA201390375A1 (ru) 2013-08-30

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US (1) US8920655B2 (ru)
EP (1) EP2616395A4 (ru)
JP (1) JP2013537105A (ru)
KR (1) KR20140007795A (ru)
CN (1) CN103237762A (ru)
AP (1) AP2013006810A0 (ru)
AU (1) AU2011301719A1 (ru)
BR (1) BR112013005957A2 (ru)
CA (1) CA2812120A1 (ru)
CL (1) CL2013000683A1 (ru)
CO (1) CO6710900A2 (ru)
CU (1) CU20130035A7 (ru)
DO (1) DOP2013000057A (ru)
EA (1) EA201390375A1 (ru)
EC (1) ECSP13012550A (ru)
GT (1) GT201300065A (ru)
MA (1) MA34595B1 (ru)
MX (1) MX2013002900A (ru)
PE (1) PE20140056A1 (ru)
RS (1) RS20130088A1 (ru)
WO (1) WO2012034202A2 (ru)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150041393A1 (en) * 2011-09-12 2015-02-12 William G. Smith Method and apparatus for treatment of wastewater
US11174441B2 (en) 2018-10-22 2021-11-16 Saudi Arabian Oil Company Demetallization by delayed coking and gas phase oxidative desulfurization of demetallized residual oil
CN110642425B (zh) * 2019-10-12 2021-10-08 广州超邦化工有限公司 包含氢氟酸和羧酸的三价铬钝化废水的处理方法
CN110642395B (zh) * 2019-10-12 2021-10-08 广州超邦化工有限公司 含氟离子的硫酸盐三价铬镀铬废水的处理方法
CN112279565B (zh) * 2020-09-16 2022-05-31 中冶南方都市环保工程技术股份有限公司 钢铁行业固体废物胶结重金属尾砂制备矿山充填物的方法
CN113457637A (zh) * 2021-06-30 2021-10-01 广东牧人王电器有限公司 一种锅具排毒处理工艺
CN115651760B (zh) * 2022-09-21 2024-09-20 新疆冠农股份有限公司 一种棉籽混合油精炼方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR207144A1 (es) * 1974-04-15 1976-09-15 Reynolds Tobacco Co R Material para fumar en forma semejante a relleno de cigarrillos o tabaco cortado para pipa
NL7503293A (nl) * 1975-03-19 1976-09-21 Leuven Res & Dev Vzw Werkwijze voor het verwijderen van metalen uit oplossing.
US4167481A (en) * 1975-03-19 1979-09-11 Leuven Research & Development Vzw Process for the removal of metals from solution
SE7710010L (sv) * 1976-10-11 1978-04-12 Mueller Hans Forfarande och anordning for filtrering av vetskor och gaser samt anvendning av forfarandet resp anordningen
US4659512A (en) * 1983-12-21 1987-04-21 Pedro B. Macedo Fixation of dissolved metal species with a complexing agent
JPS6439600A (en) * 1987-08-06 1989-02-09 Ebara Corp Treatment of radioactive waste liquid containing salts at high concentration
US5053139A (en) * 1990-12-04 1991-10-01 Engelhard Corporation Removal of heavy metals, especially lead, from aqueous systems containing competing ions utilizing amorphous tin and titanium silicates
US5443736A (en) 1993-10-20 1995-08-22 Shipley Company Inc. Purification process
DE4407854B4 (de) 1994-03-09 2008-03-27 Röhm Gmbh Bohrfutter
US6326326B1 (en) 1998-02-06 2001-12-04 Battelle Memorial Institute Surface functionalized mesoporous material and method of making same
GB0017675D0 (en) * 2000-07-20 2000-09-06 Rhodia Cons Spec Ltd Treatment of iron sulphide deposits
JP3770538B2 (ja) * 2001-08-24 2006-04-26 独立行政法人科学技術振興機構 重金属の吸着剤及びこれを用いた重金属の除去方法
JP3963101B2 (ja) * 2001-12-25 2007-08-22 栗田工業株式会社 バナジウム含有水のイオン交換方法および装置
JP2003334568A (ja) * 2002-05-16 2003-11-25 Taiheiyo Cement Corp 重金属を含む排水の処理方法
GB0413630D0 (en) 2004-06-18 2004-07-21 Avecia Ltd Process
CN101124161B (zh) * 2004-11-12 2010-09-01 苏德-化学股份公司 用二亚乙基三胺合成沸石β的方法

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CL2013000683A1 (es) 2013-11-08
GT201300065A (es) 2016-05-09
CN103237762A (zh) 2013-08-07
ECSP13012550A (es) 2013-06-28
PE20140056A1 (es) 2014-02-12
MX2013002900A (es) 2013-08-08
EP2616395A4 (en) 2014-03-26
BR112013005957A2 (pt) 2016-05-17
US8920655B2 (en) 2014-12-30
MA34595B1 (fr) 2013-10-02
JP2013537105A (ja) 2013-09-30
CU20130035A7 (es) 2013-08-29
DOP2013000057A (es) 2013-07-15
AP2013006810A0 (en) 2013-04-30
US20120175311A1 (en) 2012-07-12
CO6710900A2 (es) 2013-07-15
EP2616395A2 (en) 2013-07-24
KR20140007795A (ko) 2014-01-20
AU2011301719A1 (en) 2013-04-04
WO2012034202A8 (en) 2012-05-18
WO2012034202A3 (en) 2012-12-27
CA2812120A1 (en) 2012-03-22
RS20130088A1 (en) 2014-02-28
WO2012034202A2 (en) 2012-03-22

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