EA201201355A1 - Способ восстановления третичного фосфиноксида до соответствующего третичного фосфина в присутствии катализатора и применение третичного фосфина для восстановления третичного фосфиноксида в присутствии катализатора - Google Patents
Способ восстановления третичного фосфиноксида до соответствующего третичного фосфина в присутствии катализатора и применение третичного фосфина для восстановления третичного фосфиноксида в присутствии катализатораInfo
- Publication number
- EA201201355A1 EA201201355A1 EA201201355A EA201201355A EA201201355A1 EA 201201355 A1 EA201201355 A1 EA 201201355A1 EA 201201355 A EA201201355 A EA 201201355A EA 201201355 A EA201201355 A EA 201201355A EA 201201355 A1 EA201201355 A1 EA 201201355A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- catalyst
- restoration
- tertiary
- phosphine
- treadic
- Prior art date
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title abstract 8
- 229910000073 phosphorus hydride Inorganic materials 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 150000003004 phosphinoxides Chemical group 0.000 title 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical group P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/505—Preparation; Separation; Purification; Stabilisation
- C07F9/509—Preparation; Separation; Purification; Stabilisation by reduction of pentavalent phosphorus derivatives, e.g. -P=X with X = O, S, Se or -P-Hal2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5022—Aromatic phosphines (P-C aromatic linkage)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5027—Polyphosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Описывается способ конверсии третичного фосфиноксида в соответствующий третичный фосфин, включающий взаимодействие указанного третичного фосфиноксида с восстанавливающим третичным фосфином в присутствии катализатора, который катализирует конверсию.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE1050311 | 2010-03-31 | ||
US38769710P | 2010-09-29 | 2010-09-29 | |
PCT/SE2011/050355 WO2011123037A1 (en) | 2010-03-31 | 2011-03-29 | A process for the reduction of a tertiary phosphine oxide to the corresponding tertiary phosphine in the presence of a catalyst and use of a tertiary phosphine for reducing a tertiary phosphine oxide in the presence of a catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
EA201201355A1 true EA201201355A1 (ru) | 2013-03-29 |
EA024399B1 EA024399B1 (ru) | 2016-09-30 |
Family
ID=44080239
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201201355A EA024399B1 (ru) | 2010-03-31 | 2011-03-29 | Способ восстановления третичного фосфиноксида до соответствующего третичного фосфина в присутствии катализатора и применение третичного фосфина для восстановления третичного фосфиноксида в присутствии катализатора |
Country Status (13)
Country | Link |
---|---|
US (1) | US8735629B2 (ru) |
EP (1) | EP2552928B1 (ru) |
JP (1) | JP5409958B2 (ru) |
KR (1) | KR20130040812A (ru) |
CN (1) | CN102947319B (ru) |
AU (1) | AU2011233746B2 (ru) |
CA (1) | CA2792478C (ru) |
DK (1) | DK2552928T3 (ru) |
EA (1) | EA024399B1 (ru) |
ES (1) | ES2541276T3 (ru) |
PL (1) | PL2552928T3 (ru) |
PT (1) | PT2552928E (ru) |
WO (1) | WO2011123037A1 (ru) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101648744B1 (ko) * | 2014-10-07 | 2016-08-17 | 한국화학연구원 | 환원된 산화 그래핀 및 이의 제조방법 |
WO2016159788A1 (en) * | 2015-04-02 | 2016-10-06 | Powerbyproxi Limited | Inductive power transmitter |
WO2017041250A1 (en) * | 2015-09-09 | 2017-03-16 | Rhodia Operations | Phosphine oxides reduction |
WO2020077582A1 (en) * | 2018-10-18 | 2020-04-23 | Rhodia Operations | A process for preparing tertiary phosphines |
CN116273160B (zh) * | 2023-02-17 | 2024-08-30 | 中山大学 | 一种用于五价磷化合物制备三价磷化合物的催化剂 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3847999A (en) * | 1973-09-21 | 1974-11-12 | Hoffmann La Roche | Preparation of triaryl phosphines |
DE2714721A1 (de) | 1976-05-17 | 1977-12-01 | Texas Alkyls Inc | Reduktion von triphenylphosphinoxid zu triphenylphosphin |
US4507504A (en) | 1983-11-25 | 1985-03-26 | Ethyl Corporation | Process for preparing tertiary phosphines |
DE3523320A1 (de) * | 1985-06-29 | 1987-01-08 | Basf Ag | Reduktion von tertiaeren phosphinoxiden, -sulfiden oder -dihalogeniden mit kohlenwasserstoffen |
JP3770639B2 (ja) * | 1995-10-31 | 2006-04-26 | 高砂香料工業株式会社 | 光学活性ジホスフィンの製造方法 |
JP2001131192A (ja) * | 1999-10-29 | 2001-05-15 | Takasago Internatl Corp | 新規な光学活性ジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒。 |
US7491779B2 (en) | 2002-06-05 | 2009-02-17 | Imperial College Of Science, Technology And Medicine | Polyvinyl ethers |
CN102164937A (zh) | 2008-07-29 | 2011-08-24 | 促进学术皇家学院/麦吉尔大学 | 两性离子鏻盐 |
JP5665003B2 (ja) * | 2010-04-16 | 2015-02-04 | 国立大学法人 岡山大学 | ホスフィンオキシド誘導体からのホスフィン誘導体の直接製造法 |
-
2011
- 2011-03-29 EP EP11715084.7A patent/EP2552928B1/en active Active
- 2011-03-29 WO PCT/SE2011/050355 patent/WO2011123037A1/en active Application Filing
- 2011-03-29 DK DK11715084.7T patent/DK2552928T3/en active
- 2011-03-29 CN CN201180017856.4A patent/CN102947319B/zh active Active
- 2011-03-29 EA EA201201355A patent/EA024399B1/ru not_active IP Right Cessation
- 2011-03-29 PL PL11715084T patent/PL2552928T3/pl unknown
- 2011-03-29 JP JP2013502534A patent/JP5409958B2/ja active Active
- 2011-03-29 ES ES11715084.7T patent/ES2541276T3/es active Active
- 2011-03-29 US US13/636,152 patent/US8735629B2/en active Active
- 2011-03-29 CA CA2792478A patent/CA2792478C/en active Active
- 2011-03-29 KR KR1020127026315A patent/KR20130040812A/ko not_active Application Discontinuation
- 2011-03-29 PT PT117150847T patent/PT2552928E/pt unknown
- 2011-03-29 AU AU2011233746A patent/AU2011233746B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
KR20130040812A (ko) | 2013-04-24 |
WO2011123037A1 (en) | 2011-10-06 |
AU2011233746A1 (en) | 2012-10-18 |
EA024399B1 (ru) | 2016-09-30 |
PT2552928E (pt) | 2015-07-28 |
CN102947319B (zh) | 2016-11-09 |
ES2541276T3 (es) | 2015-07-17 |
CN102947319A (zh) | 2013-02-27 |
US8735629B2 (en) | 2014-05-27 |
CA2792478A1 (en) | 2011-10-06 |
EP2552928A1 (en) | 2013-02-06 |
CA2792478C (en) | 2019-02-19 |
JP5409958B2 (ja) | 2014-02-05 |
AU2011233746B2 (en) | 2014-12-04 |
PL2552928T3 (pl) | 2015-09-30 |
EP2552928B1 (en) | 2015-04-15 |
DK2552928T3 (en) | 2015-07-06 |
JP2013523727A (ja) | 2013-06-17 |
US20130012725A1 (en) | 2013-01-10 |
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Legal Events
Date | Code | Title | Description |
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MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ KZ KG MD TJ TM |