EA201070482A1 - Удаление аммиака из текучих сред - Google Patents

Удаление аммиака из текучих сред

Info

Publication number
EA201070482A1
EA201070482A1 EA201070482A EA201070482A EA201070482A1 EA 201070482 A1 EA201070482 A1 EA 201070482A1 EA 201070482 A EA201070482 A EA 201070482A EA 201070482 A EA201070482 A EA 201070482A EA 201070482 A1 EA201070482 A1 EA 201070482A1
Authority
EA
Eurasian Patent Office
Prior art keywords
fluid
ammonia
decomposition
oxidation unit
removal
Prior art date
Application number
EA201070482A
Other languages
English (en)
Inventor
Теуво Маунула
Матти Хяркенен
Original Assignee
Экокат Ой
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Экокат Ой filed Critical Экокат Ой
Publication of EA201070482A1 publication Critical patent/EA201070482A1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8634—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/58—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B01J35/19—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0242—Coating followed by impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/02—Preparation of nitrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/22—Nitrous oxide (N2O)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/12—Separation of ammonia from gases and vapours
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1021—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1025—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1026—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1028—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/104—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/106—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/406—Ammonia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Предметом изобретения являются способ и устройство для удаления аммиака из жидких промышленных отходов, дымовых газов или сточных вод, содержащих кислород. Способ включает в себя, по меньшей мере, следующие стадии: часть текучей среды подают в блок разложения/окисления и часть текучей среды направляют в байпасную линию; часть текучей среды, содержащей аммиак, окисляют в блоке разложения/окисления аммиака; текучую среду, окисленную в блоке разложения/окисления, и текучую среду, подававшуюся в байпасную линию, смешивают в смесителе с образованием текучей смеси, текучую смесь подают в блок селективного восстановления.
EA201070482A 2007-10-19 2007-10-19 Удаление аммиака из текучих сред EA201070482A1 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/FI2007/000253 WO2009050323A1 (en) 2007-10-19 2007-10-19 Removal of ammonia from fluids

Publications (1)

Publication Number Publication Date
EA201070482A1 true EA201070482A1 (ru) 2010-10-29

Family

ID=40567050

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201070482A EA201070482A1 (ru) 2007-10-19 2007-10-19 Удаление аммиака из текучих сред

Country Status (5)

Country Link
US (1) US8337793B2 (ru)
EP (1) EP2200734A4 (ru)
CN (1) CN101970083A (ru)
EA (1) EA201070482A1 (ru)
WO (1) WO2009050323A1 (ru)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2612706B1 (en) * 2010-08-31 2019-10-30 Hitachi Zosen Corporation Process for producing hydrogen
WO2014014619A1 (en) * 2012-07-19 2014-01-23 Invista North America S.A.R.L. Corrosion control in ammonia extraction by air sparging
CN102921433B (zh) * 2012-10-09 2014-06-11 常州大学 一种促进味精废水中氨氮转化的催化剂制备方法
DE102013000013A1 (de) 2013-01-02 2014-07-03 Thyssenkrupp Industrial Solutions Gmbh Beseitigung von Ammoniak und niederen Alkanen und/oder Wasserstoff in Abgasströmen in Industrieanlagen
CN103846086A (zh) * 2014-03-05 2014-06-11 四川大学 一种用于氨气催化氧化制备氮氧化物的催化剂
US9849444B2 (en) 2014-09-15 2017-12-26 Paccar Inc Urea hydrolysis reactor for selective catalytic reduction
CN105664669B (zh) * 2014-11-20 2018-01-09 中国石油化工股份有限公司 丙烯腈反应装置中未反应氨的处理方法
EP3162427A1 (en) 2015-10-28 2017-05-03 Casale SA A method and apparatus for removing nox and n2o from a gas
US10058819B2 (en) 2015-11-06 2018-08-28 Paccar Inc Thermally integrated compact aftertreatment system
US10835866B2 (en) 2017-06-02 2020-11-17 Paccar Inc 4-way hybrid binary catalysts, methods and uses thereof
US10675586B2 (en) 2017-06-02 2020-06-09 Paccar Inc Hybrid binary catalysts, methods and uses thereof
CN109289906B (zh) * 2018-09-26 2020-09-25 中国科学院生态环境研究中心 一种氨气净化催化剂及其制备方法和用途
US11007514B2 (en) 2019-04-05 2021-05-18 Paccar Inc Ammonia facilitated cation loading of zeolite catalysts
US10906031B2 (en) 2019-04-05 2021-02-02 Paccar Inc Intra-crystalline binary catalysts and uses thereof
CN110102338A (zh) * 2019-04-30 2019-08-09 昆明贵研催化剂有限责任公司 一种高氮气选择性的氨氧化催化剂及其制备方法
US10934918B1 (en) 2019-10-14 2021-03-02 Paccar Inc Combined urea hydrolysis and selective catalytic reduction for emissions control
CN110759575B (zh) * 2019-11-11 2021-10-12 浙江晶立捷环境科技有限公司 工业高盐废水脱盐方法
CN110642365B (zh) * 2019-11-11 2021-10-12 浙江晶立捷环境科技有限公司 一种用亚临界氧化技术深度处理废水的方法
CN111068512B (zh) * 2019-12-26 2021-06-18 南京工大环境科技有限公司 一种降低尾气氨排放的集成式催化转化系统及其方法
CN114471667B (zh) * 2022-04-13 2022-07-01 山东恒昌圣诚化工股份有限公司 一种用于氨气分解的催化剂及其制备方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4571329A (en) * 1984-08-13 1986-02-18 Babcock-Hitachi Kabushiki Kaisha Ammonia reduction-denitration process and apparatus therefor
DE3442927A1 (de) * 1984-11-24 1986-06-05 Kali-Chemie Ag, 3000 Hannover Abgasbehandlungsverfahren
JPH01119341A (ja) 1987-10-30 1989-05-11 Nkk Corp アンモニア分解用触媒
FI89810C (fi) 1990-09-24 1993-11-25 Valtion Teknillinen Foerfarande foer rening av foergasningsgas fraon kvaeve- och svavelfoereningar samt organiska foeroreningar
DE4204603C2 (de) 1992-02-15 1996-02-29 Hager & Elsaesser Vorrichtung zur mehrstufigen, katalytischen Verbrennung von stickstoffhaltigen Gasen
DE4314896A1 (de) 1992-05-18 1993-11-25 Siemens Ag Verfahren und Einrichtung zur selektiven katalytischen Umsetzung von Ammoniak in ammoniakhaltigem Abgas
JPH06165919A (ja) * 1992-11-30 1994-06-14 Ishikawajima Harima Heavy Ind Co Ltd 亜酸化窒素の除去方法
JP3427581B2 (ja) * 1994-09-13 2003-07-22 トヨタ自動車株式会社 内燃機関の排気浄化装置
NO313494B1 (no) * 2000-07-05 2002-10-14 Norsk Hydro As Katalysator for spalting av dinitrogenoksid og fremgangsmåte ved utförelse av prosesser hvor det dannes dinitrogenoksid
US7160527B2 (en) 2000-08-09 2007-01-09 Babcock-Hitachi-Kasushiki-Kaisha Method for treating amonia-containing effluent water
US20040116276A1 (en) * 2002-02-12 2004-06-17 Aleksey Yezerets Exhaust aftertreatment emission control regeneration
DE10215605A1 (de) 2002-04-09 2003-10-30 Uhde Gmbh Entstickungsverfahren
US20050022450A1 (en) * 2003-02-12 2005-02-03 Cher-Dip Tan Reformer system, a method of producing hydrogen in the reformer system, and a method of using the reformer system
WO2004071646A2 (en) * 2003-02-12 2004-08-26 Delphi Technologies, Inc. SYSTEM AND METHOD OF NOx ABATEMENT
DE10349876A1 (de) * 2003-10-25 2005-05-25 Daimlerchrysler Ag Brennkraftmaschine mit Abgasreinigungsanlage und Verfahren zur Reinigung des Abgases einer Brennkraftmaschine
JP2007032472A (ja) * 2005-07-28 2007-02-08 Hitachi Ltd 尿素水を用いた排気処理装置
US7810316B2 (en) * 2006-12-29 2010-10-12 Cummins Filtration Ip, Inc Apparatus, system, and method for exhaust aftertreatment efficiency enhancement

Also Published As

Publication number Publication date
US8337793B2 (en) 2012-12-25
US20100266469A1 (en) 2010-10-21
EP2200734A4 (en) 2012-04-18
EP2200734A1 (en) 2010-06-30
WO2009050323A1 (en) 2009-04-23
CN101970083A (zh) 2011-02-09

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