EA201070445A1 - Формуемые композиции сшиваемой и вспениваемой сложнополиэфирной-полиуретановой (гибридной) смолы, обладающие пенообразующими свойствами, применяемые для формования в закрытой пресс-форме - Google Patents

Формуемые композиции сшиваемой и вспениваемой сложнополиэфирной-полиуретановой (гибридной) смолы, обладающие пенообразующими свойствами, применяемые для формования в закрытой пресс-форме

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Publication number
EA201070445A1
EA201070445A1 EA201070445A EA201070445A EA201070445A1 EA 201070445 A1 EA201070445 A1 EA 201070445A1 EA 201070445 A EA201070445 A EA 201070445A EA 201070445 A EA201070445 A EA 201070445A EA 201070445 A1 EA201070445 A1 EA 201070445A1
Authority
EA
Eurasian Patent Office
Prior art keywords
component
parts
ethylenically unsaturated
polyester
polyol
Prior art date
Application number
EA201070445A
Other languages
English (en)
Other versions
EA020294B1 (ru
Inventor
Пол Дарби
Фил Дин
Original Assignee
Крэй Вэлли Лтд.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Крэй Вэлли Лтд. filed Critical Крэй Вэлли Лтд.
Publication of EA201070445A1 publication Critical patent/EA201070445A1/ru
Publication of EA020294B1 publication Critical patent/EA020294B1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/635—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto unsaturated polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C08G18/683—Unsaturated polyesters containing cyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0066—≥ 150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2270/00—Compositions for creating interpenetrating networks
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987—With nonvoid component of specified composition
    • Y10T428/249991—Synthetic resin or natural rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
    • Y10T428/31583—Nitrile monomer type [polyacrylonitrile, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Изобретение относится к формуемой композиции сшиваемой и вспениваемой сложнополиэфирной-полиуретановой смолы, включающей компонент А, включающий: А1) по меньшей мере одно полифункциональное изоцианатное соединение и А2) по меньшей мере один инициатор свободнорадикальной полимеризации; компонент В, включающий по массе: В1) 100 частей по меньшей мере одной полиоловой смолы, включающей В11) от 50 до 80 частей по меньшей мере одного этиленненасыщенного сложного полиэфирполиола, В12) от 20 до 50 частей по меньшей мере одного этиленненасыщенного мономера, причем В11) представляет собой продукт реакции: а) кислого компонента, включающего: а1) по меньшей мере одну этиленненасыщенную дикислоту и а2) по меньшей мере одну насыщенную дикислоту, причем молярное отношение а1/а2 изменяется так, что содержание ненасыщенности в В11) изменяется от 0,25/1 до 5/1, и b) диолового компонента в избытке относительно компонента а); В2) от 0,01 до 1,1 частей воды; В3) необязательно до 35% по меньшей мере одного гидроксиалкил(мет)акрилата; В4) по меньшей мере один катализатор реакции изоцианата/гидроксила; В5) по меньшей мере один ускоритель разложения свободнорадикального инициатора; В6) по меньшей мере один стабилизатор пены; В7) необязательно, наполнители и/или другие добавки, причем указанная композиция свободна от какого-либо первичного или вторичного амина и полиола, имеющего низкую Mn, удлинителя цепи. Изобретение дополнительно относится к способу получения и определенным применениям легковесных изделий в санитарии, строительстве или в автомобилях.
EA201070445A 2007-10-09 2008-09-29 Формуемые композиции сшиваемой и вспениваемой сложнополиэфирной-полиуретановой (гибридной) смолы, обладающие пенообразующими свойствами, применяемые для формования в закрытой пресс-форме EA020294B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP20070254003 EP2048172A1 (en) 2007-10-09 2007-10-09 Crosslinkable and foaming polyester-polyurethane (hybrid) resin moulding compositions, with foaming characteristics for closed mould applications
PCT/EP2008/008281 WO2009046902A1 (en) 2007-10-09 2008-09-29 Crosslinkable and foaming polyester-polyurethane (hybrid) resin moulding compositions, with foaming characteristics for closed mould applications

Publications (2)

Publication Number Publication Date
EA201070445A1 true EA201070445A1 (ru) 2010-08-30
EA020294B1 EA020294B1 (ru) 2014-10-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EA201070445A EA020294B1 (ru) 2007-10-09 2008-09-29 Формуемые композиции сшиваемой и вспениваемой сложнополиэфирной-полиуретановой (гибридной) смолы, обладающие пенообразующими свойствами, применяемые для формования в закрытой пресс-форме

Country Status (14)

Country Link
US (1) US8497316B2 (ru)
EP (2) EP2048172A1 (ru)
KR (1) KR20100084508A (ru)
CN (1) CN101821308B (ru)
AU (1) AU2008310034B2 (ru)
BR (1) BRPI0817496B1 (ru)
CA (1) CA2702074C (ru)
EA (1) EA020294B1 (ru)
ES (1) ES2453967T3 (ru)
MX (1) MX340599B (ru)
MY (1) MY160144A (ru)
PL (1) PL2201056T3 (ru)
WO (1) WO2009046902A1 (ru)
ZA (1) ZA201001923B (ru)

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US20090182084A1 (en) * 2008-01-11 2009-07-16 The Sherwin-Williams Company Metal coating composition
GB2469317B (en) * 2009-04-08 2012-12-12 Trayco Ltd A method of making a composite body, and a composite body made by the method
US10035872B2 (en) 2010-04-01 2018-07-31 Ppg Industries Ohio, Inc. Branched polyester-urethane resins and coatings comprising the same
WO2014066693A1 (en) 2012-10-25 2014-05-01 Kohler Co. Engineered composite material and products produced therefrom
CN103965604B (zh) * 2013-01-29 2018-02-16 康廷南拓结构塑料有限公司 热固性多元醇组合物及其使用方法
CA2968670C (en) * 2014-11-24 2019-08-27 Ppg Industries Ohio, Inc. Methods for reactive three-dimensional printing by extrusion
US9744694B2 (en) * 2015-04-02 2017-08-29 The Boeing Company Low-cost tooling and method for manufacturing the same
ES2595932B1 (es) * 2015-07-01 2017-10-24 Construplas, S.L. Procedimiento de moldeo de plancha sobre soporte
CA2987622A1 (en) * 2016-12-02 2018-06-02 Stephen Gleason Composition and method to form a composite core material
CN110382584A (zh) 2017-03-03 2019-10-25 瑞森内特材料集团有限公司 可持续、可能量固化的聚酯多元醇及由其制得的涂层或硬质泡沫
CN107216427A (zh) * 2017-06-15 2017-09-29 中山市大涂料有限公司 一种不饱和聚酯树脂嵌段改性聚氨酯/丙烯酸酯乳液及其制备方法
CN108467472B (zh) * 2018-04-01 2021-02-09 黎明化工研究设计院有限责任公司 一种无溶剂聚氨酯树脂及其在高剥离强度水性/无溶剂聚氨酯合成革中的应用
CN108706953B (zh) * 2018-06-29 2019-07-23 南京红宝丽新材料有限公司 一种匀质低导热无机保温板及其制备方法
JP2022531206A (ja) * 2019-04-29 2022-07-06 コベストロ・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・アンド・コー・カーゲー 硬質ポリウレタンフォーム
EP3747924A1 (en) * 2019-06-06 2020-12-09 Covestro Deutschland AG Rigid polyurethane foam

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US3348251A (en) * 1965-01-22 1967-10-24 United Shoe Machinery Corp Shoe manufacturing
GB1382986A (en) * 1971-08-18 1975-02-05 Ici Ltd Foamed shaped article
US4460714A (en) * 1983-12-01 1984-07-17 Pennwalt Corporation Unsaturated polyester resin foams using inorganic iron salts
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US8742054B2 (en) * 2005-08-23 2014-06-03 Ccp Composites Us Polyester-polyurethane hybrid resin molding compositions comprising polyurethane with units derived from aliphatic isocyanates

Also Published As

Publication number Publication date
EP2201056A1 (en) 2010-06-30
MX2010003529A (es) 2013-06-28
CN101821308A (zh) 2010-09-01
WO2009046902A1 (en) 2009-04-16
ES2453967T3 (es) 2014-04-09
MY160144A (en) 2017-02-28
EP2048172A1 (en) 2009-04-15
CN101821308B (zh) 2013-10-09
AU2008310034B2 (en) 2013-05-02
ZA201001923B (en) 2010-11-24
BRPI0817496B1 (pt) 2019-06-04
US8497316B2 (en) 2013-07-30
MX340599B (es) 2016-07-18
PL2201056T3 (pl) 2014-06-30
BRPI0817496A8 (pt) 2018-06-12
US20100239847A1 (en) 2010-09-23
EA020294B1 (ru) 2014-10-30
CA2702074C (en) 2014-11-04
BRPI0817496A2 (pt) 2015-09-08
AU2008310034A1 (en) 2009-04-16
EP2201056B1 (en) 2014-01-08
CA2702074A1 (en) 2009-04-16
KR20100084508A (ko) 2010-07-26

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