CN101821308A - 用于封闭模具应用的、具有发泡特性的能交联的发泡聚酯-聚氨酯(混杂)树脂模塑组合物 - Google Patents
用于封闭模具应用的、具有发泡特性的能交联的发泡聚酯-聚氨酯(混杂)树脂模塑组合物 Download PDFInfo
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- CN101821308A CN101821308A CN200880110952A CN200880110952A CN101821308A CN 101821308 A CN101821308 A CN 101821308A CN 200880110952 A CN200880110952 A CN 200880110952A CN 200880110952 A CN200880110952 A CN 200880110952A CN 101821308 A CN101821308 A CN 101821308A
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- polyester
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- foaming
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/635—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto unsaturated polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/68—Unsaturated polyesters
- C08G18/683—Unsaturated polyesters containing cyclic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2270/00—Compositions for creating interpenetrating networks
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249987—With nonvoid component of specified composition
- Y10T428/249991—Synthetic resin or natural rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
- Y10T428/31583—Nitrile monomer type [polyacrylonitrile, etc.]
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
多元醇1 | 多元醇2 | 多元醇3 | |
富马酸(摩尔份) | 0.67 | ||
马来酸酐 | 0.67 | 0.55 | |
间苯二甲酸 | 0.33 | 0.33 | 0.45 |
乙二醇 | 0.66 | 0.66 | 0.66 |
新戊二醇 | 0.66 | 0.66 | 0.66 |
B1中的苯乙烯重量/重量% | 30 | 30 | 30 |
氧化二丁基锡(ppm) | 500 | 500 | 500 |
氢醌(ppm) | 150 | 150 | 150 |
萘醌(ppm) | 75 | 75 | 75 |
酸值(以固体物计)单位mg KOH/g | 3 | 5 | 5 |
羟基值(以固体物计)单位mg KOH/g | 110 | 130 | 115 |
BI | BII | BIII | BIV | |
多元醇1(B1) | 50 | 25 | 25 | 25 |
多元醇2(B1) | 25 | |||
多元醇3(B1) | 25 | 25 | ||
碳酸钙(B7) | 50 | 50 | 45 | 45 |
二乙基苯胺(B5) | 0.2 | 0.1 | 0.1 | 0.1 |
五甲基二亚乙基三胺(B4) | 0.1 | |||
三甲基氨乙基乙醇胺(B4) | 0.1 |
BI | BII | BIII | BIV | |
二月桂酸二丁基锡(B4) | 0.1 | 0.1 | ||
氧化二丁基锡(B4) | 0.2 | 0.2 | ||
水(B2) | 0.5 | 0.35 | 0.5 | 0.5 |
%H2O/OHB中总量(%当量比) | 29% | 22% | 28.5% | 27% |
1 | 2 | 3 | 4 | 5 | |
MDI A1/(重量份) | 15 | 20 | 15 | 15 | 15 |
多元醇BII*(重量份) | 85 | 80 | 85 | 85 | 85 |
NCO/OH总(B中OH)(当量比) | 1.25 | 1.74 | 1.25 | 1.25 | 1.25 |
多元醇温度(℃) | 30 | 30 | 30 | 25 | 30 |
混合时间(s) | 20 | 20 | 20 | 30 | 10 |
模具温度(℃) | 35 | 35 | 20 | 37 | 35 |
部件密度(g/ml) | 0.7 | 0.65 | 0.7 | 0.8 | 可变化 |
部件一致性 | 整个部件均匀 | 整个部件均匀 | 底部变形 | 光泽可变 | 基料外表层潮标(tidemark) |
挠曲强度(MPa) | 40 | 35 | 30 | 35 | 15 |
挠曲模量(GPa) | 2.0 | 2.5 | 1.8 | 1.8 | 1.5 |
Claims (28)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07254003.2 | 2007-10-09 | ||
EP20070254003 EP2048172A1 (en) | 2007-10-09 | 2007-10-09 | Crosslinkable and foaming polyester-polyurethane (hybrid) resin moulding compositions, with foaming characteristics for closed mould applications |
PCT/EP2008/008281 WO2009046902A1 (en) | 2007-10-09 | 2008-09-29 | Crosslinkable and foaming polyester-polyurethane (hybrid) resin moulding compositions, with foaming characteristics for closed mould applications |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101821308A true CN101821308A (zh) | 2010-09-01 |
CN101821308B CN101821308B (zh) | 2013-10-09 |
Family
ID=39148092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2008801109521A Active CN101821308B (zh) | 2007-10-09 | 2008-09-29 | 用于封闭模具应用的、具有发泡特性的能交联的发泡聚酯-聚氨酯(混杂)树脂模塑组合物 |
Country Status (14)
Country | Link |
---|---|
US (1) | US8497316B2 (zh) |
EP (2) | EP2048172A1 (zh) |
KR (1) | KR20100084508A (zh) |
CN (1) | CN101821308B (zh) |
AU (1) | AU2008310034B2 (zh) |
BR (1) | BRPI0817496B1 (zh) |
CA (1) | CA2702074C (zh) |
EA (1) | EA020294B1 (zh) |
ES (1) | ES2453967T3 (zh) |
MX (1) | MX340599B (zh) |
MY (1) | MY160144A (zh) |
PL (1) | PL2201056T3 (zh) |
WO (1) | WO2009046902A1 (zh) |
ZA (1) | ZA201001923B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103965604A (zh) * | 2013-01-29 | 2014-08-06 | 康廷南拓结构塑料有限公司 | 热固性多元醇组合物及其使用方法 |
CN107216427A (zh) * | 2017-06-15 | 2017-09-29 | 中山市大涂料有限公司 | 一种不饱和聚酯树脂嵌段改性聚氨酯/丙烯酸酯乳液及其制备方法 |
CN108467472A (zh) * | 2018-04-01 | 2018-08-31 | 黎明化工研究设计院有限责任公司 | 一种无溶剂聚氨酯树脂及其在高剥离水性/无溶剂聚氨酯合成革中的应用 |
CN108706953A (zh) * | 2018-06-29 | 2018-10-26 | 南京红宝丽新材料有限公司 | 一种匀质低导热无机保温板及其制备方法 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CL2009000032A1 (es) * | 2008-01-11 | 2009-06-12 | Sherwin Williams Co | Composicion de revestimiento que comprende un sistema de resina que contiene al menos un poliol de poliester insaturado libre de resina acrilica y un agente de curado, adecuada para su aplicacion directa a los sustratos de metal; metodo para la imprimacion de un sustrato de metal; y composicion imprimadora. |
GB2469317B (en) * | 2009-04-08 | 2012-12-12 | Trayco Ltd | A method of making a composite body, and a composite body made by the method |
US10035872B2 (en) | 2010-04-01 | 2018-07-31 | Ppg Industries Ohio, Inc. | Branched polyester-urethane resins and coatings comprising the same |
CN103917146B (zh) | 2012-10-25 | 2017-03-15 | 科勒公司 | 工程复合材料和由其生产的产品 |
CN107108849B (zh) * | 2014-11-24 | 2022-05-10 | Ppg工业俄亥俄公司 | 用于三维打印的共反应性材料和方法 |
US9744694B2 (en) * | 2015-04-02 | 2017-08-29 | The Boeing Company | Low-cost tooling and method for manufacturing the same |
ES2595932B1 (es) * | 2015-07-01 | 2017-10-24 | Construplas, S.L. | Procedimiento de moldeo de plancha sobre soporte |
US11008438B2 (en) | 2016-12-02 | 2021-05-18 | Composite Technologies International, Llc | Composition and method to form a composite core material |
EP3589675A1 (en) | 2017-03-03 | 2020-01-08 | Resinate Materials Group, Inc. | Sustainable, energy-curable polyester polyols and coatings or rigid foams therefrom |
EP3962983A1 (en) * | 2019-04-29 | 2022-03-09 | Covestro Intellectual Property GmbH & Co. KG | Rigid polyurethane foam |
EP3747924A1 (en) * | 2019-06-06 | 2020-12-09 | Covestro Deutschland AG | Rigid polyurethane foam |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3348251A (en) * | 1965-01-22 | 1967-10-24 | United Shoe Machinery Corp | Shoe manufacturing |
GB1382986A (en) * | 1971-08-18 | 1975-02-05 | Ici Ltd | Foamed shaped article |
US4460714A (en) * | 1983-12-01 | 1984-07-17 | Pennwalt Corporation | Unsaturated polyester resin foams using inorganic iron salts |
US5344852A (en) | 1992-01-16 | 1994-09-06 | Aristech Chemical Corporation | Unsaturated polyester-polyurethane hybrid resin foam compositions |
JP2003002947A (ja) * | 2001-06-25 | 2003-01-08 | Hitachi Chem Co Ltd | 発泡不飽和ポリエステル樹脂組成物 |
US6756416B2 (en) * | 2002-02-12 | 2004-06-29 | Foamex L.P. | Hydrophilic ester polyurethane foams |
US8742054B2 (en) * | 2005-08-23 | 2014-06-03 | Ccp Composites Us | Polyester-polyurethane hybrid resin molding compositions comprising polyurethane with units derived from aliphatic isocyanates |
-
2007
- 2007-10-09 EP EP20070254003 patent/EP2048172A1/en not_active Withdrawn
-
2008
- 2008-09-29 EA EA201070445A patent/EA020294B1/ru not_active IP Right Cessation
- 2008-09-29 MY MYPI2010001147A patent/MY160144A/en unknown
- 2008-09-29 ES ES08802709T patent/ES2453967T3/es active Active
- 2008-09-29 BR BRPI0817496-2A patent/BRPI0817496B1/pt active IP Right Grant
- 2008-09-29 US US12/682,499 patent/US8497316B2/en active Active
- 2008-09-29 MX MX2010003529A patent/MX340599B/es active IP Right Grant
- 2008-09-29 WO PCT/EP2008/008281 patent/WO2009046902A1/en active Application Filing
- 2008-09-29 PL PL08802709T patent/PL2201056T3/pl unknown
- 2008-09-29 KR KR1020107007696A patent/KR20100084508A/ko active IP Right Grant
- 2008-09-29 AU AU2008310034A patent/AU2008310034B2/en active Active
- 2008-09-29 CN CN2008801109521A patent/CN101821308B/zh active Active
- 2008-09-29 EP EP20080802709 patent/EP2201056B1/en active Active
- 2008-09-29 CA CA2702074A patent/CA2702074C/en active Active
-
2010
- 2010-03-17 ZA ZA2010/01923A patent/ZA201001923B/en unknown
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103965604A (zh) * | 2013-01-29 | 2014-08-06 | 康廷南拓结构塑料有限公司 | 热固性多元醇组合物及其使用方法 |
CN103965604B (zh) * | 2013-01-29 | 2018-02-16 | 康廷南拓结构塑料有限公司 | 热固性多元醇组合物及其使用方法 |
CN107216427A (zh) * | 2017-06-15 | 2017-09-29 | 中山市大涂料有限公司 | 一种不饱和聚酯树脂嵌段改性聚氨酯/丙烯酸酯乳液及其制备方法 |
CN108467472A (zh) * | 2018-04-01 | 2018-08-31 | 黎明化工研究设计院有限责任公司 | 一种无溶剂聚氨酯树脂及其在高剥离水性/无溶剂聚氨酯合成革中的应用 |
CN108467472B (zh) * | 2018-04-01 | 2021-02-09 | 黎明化工研究设计院有限责任公司 | 一种无溶剂聚氨酯树脂及其在高剥离强度水性/无溶剂聚氨酯合成革中的应用 |
CN108706953A (zh) * | 2018-06-29 | 2018-10-26 | 南京红宝丽新材料有限公司 | 一种匀质低导热无机保温板及其制备方法 |
CN108706953B (zh) * | 2018-06-29 | 2019-07-23 | 南京红宝丽新材料有限公司 | 一种匀质低导热无机保温板及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
MX2010003529A (es) | 2013-06-28 |
AU2008310034A1 (en) | 2009-04-16 |
ES2453967T3 (es) | 2014-04-09 |
WO2009046902A1 (en) | 2009-04-16 |
BRPI0817496A2 (pt) | 2015-09-08 |
CA2702074C (en) | 2014-11-04 |
PL2201056T3 (pl) | 2014-06-30 |
EA020294B1 (ru) | 2014-10-30 |
KR20100084508A (ko) | 2010-07-26 |
CN101821308B (zh) | 2013-10-09 |
AU2008310034B2 (en) | 2013-05-02 |
EA201070445A1 (ru) | 2010-08-30 |
CA2702074A1 (en) | 2009-04-16 |
MX340599B (es) | 2016-07-18 |
US20100239847A1 (en) | 2010-09-23 |
EP2201056B1 (en) | 2014-01-08 |
US8497316B2 (en) | 2013-07-30 |
MY160144A (en) | 2017-02-28 |
ZA201001923B (en) | 2010-11-24 |
EP2201056A1 (en) | 2010-06-30 |
EP2048172A1 (en) | 2009-04-15 |
BRPI0817496B1 (pt) | 2019-06-04 |
BRPI0817496A8 (pt) | 2018-06-12 |
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