EA200700095A1 - Способ удаления cos из потока синтез-газа, включающего hs и cos - Google Patents
Способ удаления cos из потока синтез-газа, включающего hs и cosInfo
- Publication number
- EA200700095A1 EA200700095A1 EA200700095A EA200700095A EA200700095A1 EA 200700095 A1 EA200700095 A1 EA 200700095A1 EA 200700095 A EA200700095 A EA 200700095A EA 200700095 A EA200700095 A EA 200700095A EA 200700095 A1 EA200700095 A1 EA 200700095A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- cos
- gas stream
- synthesis gas
- synthesis
- gas flow
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8606—Removing sulfur compounds only one sulfur compound other than sulfur oxides or hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/52—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
- C01B3/54—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids including a catalytic reaction
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20707—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/30—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/306—Organic sulfur compounds, e.g. mercaptans
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Industrial Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Изобретение предлагает способ удаления COS из первого потока синтез-газа, включающего COS и HS, которые имеет следующие стадии: (а) превращение COS в первом потоке синтез-газа в HS путем контактирования первого потока синтез-газа с катализатором гидролиза COS в присутствие воды в зоне гидролиза, с получением второго потока синтез-газа, очищенного от COS и обогащенного HS; (b) удаление HS из второго потока синтез-газа путем контактирования второго потока синтез-газа с твердым адсорбентом в зоне удаления HS, с получением третьего потока синтез-газа, очищенного от COS и очищенного от HS.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04254366 | 2004-07-22 | ||
PCT/EP2005/053563 WO2006008317A1 (en) | 2004-07-22 | 2005-07-22 | Process for the removal of cos from a synthesis gas stream comprising h2s and cos |
Publications (2)
Publication Number | Publication Date |
---|---|
EA200700095A1 true EA200700095A1 (ru) | 2007-06-29 |
EA010025B1 EA010025B1 (ru) | 2008-06-30 |
Family
ID=34930513
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA200700095A EA010025B1 (ru) | 2004-07-22 | 2005-07-22 | Способ удаления cos из потока синтез-газа, включающего hs и cos |
Country Status (10)
Country | Link |
---|---|
US (1) | US7846325B2 (ru) |
EP (1) | EP1791622B1 (ru) |
CN (1) | CN101031350A (ru) |
AT (1) | ATE433793T1 (ru) |
AU (1) | AU2005263776B2 (ru) |
DE (1) | DE602005015007D1 (ru) |
EA (1) | EA010025B1 (ru) |
MY (1) | MY140997A (ru) |
WO (1) | WO2006008317A1 (ru) |
ZA (1) | ZA200700161B (ru) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1973841A1 (en) * | 2006-01-18 | 2008-10-01 | Shell Internationale Research Maatschappij B.V. | Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream |
KR101512672B1 (ko) * | 2006-12-08 | 2015-04-16 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 정제된 합성가스 스트림의 제조 공정 |
US8258193B2 (en) | 2007-06-18 | 2012-09-04 | Shell Oil Company | Process for removal of hydrogen cyanide and ammonia from synthesis gas |
CN101121123B (zh) * | 2007-07-25 | 2010-05-19 | 太原理工大学 | 中温二硫化碳水解催化剂及其制备方法与用途 |
UA100395C2 (en) * | 2007-10-26 | 2012-12-25 | Haldor Topsoe As | Process for a reduction in the amount of sulphur compounds, hydrogen cyanide and formic acid in synthesis gas |
US7682424B2 (en) * | 2008-01-31 | 2010-03-23 | Conocophillips Company | Contaminant removal from a gas stream |
CN101224871B (zh) * | 2008-02-03 | 2011-02-16 | 湖北省化学研究院 | 合成气的深度净化方法 |
DE102008032166A1 (de) * | 2008-07-08 | 2010-01-14 | Karl-Heinz Tetzlaff | Verfahren und Vorrichtung zur Herstellung von teerfreiem Synthesgas aus Biomasse |
US7909913B2 (en) | 2008-07-17 | 2011-03-22 | Air Products And Chemicals, Inc. | Gas purification by adsorption of hydrogen sulfide |
DK200801093A (en) * | 2008-08-13 | 2010-02-14 | Topsoe Haldor As | Process and system for removing impurities from a gas stream |
FR2940919B1 (fr) * | 2009-01-12 | 2011-12-09 | Inst Francais Du Petrole | Utilisation d'une composition a base de tio2 pour la captation de composes halogenes contenus dans un melange gazeux |
FR2940920B1 (fr) * | 2009-01-12 | 2011-10-21 | Inst Francais Du Petrole | Procede d'elimination d'impuretes soufrees, azotees et halogenees contenues dans un gaz de synthese |
EP2414074A1 (en) * | 2009-03-30 | 2012-02-08 | Shell Internationale Research Maatschappij B.V. | Process for producing purified synthesis gas |
AU2010230280B2 (en) * | 2009-03-30 | 2013-08-29 | Shell Internationale Research Maatschappij B.V. | Process for producing a purified synthesis gas stream |
US8974758B2 (en) * | 2009-05-07 | 2015-03-10 | American Air Liquide, Inc. | Methods of purifying COS |
CN102463129B (zh) * | 2010-11-17 | 2013-12-04 | 中国石油化工股份有限公司 | 用于羰基硫水解的催化剂 |
US8501135B1 (en) * | 2012-02-17 | 2013-08-06 | Archon Technologies Ltd. | Process for the removal of sulfur compounds from gas streams |
CN103055661A (zh) * | 2012-12-31 | 2013-04-24 | 东南大学 | 一种高温脱除烟气中酸性气体的装置及其方法 |
JP6122664B2 (ja) * | 2013-03-05 | 2017-04-26 | 三菱重工業株式会社 | ガス精製装置およびガス精製方法 |
CN106563475B (zh) * | 2016-11-04 | 2020-04-03 | 昆明理工大学 | 一种同时催化水解羰基硫和二硫化碳的改性硅基催化剂的制备方法 |
CN107649176B (zh) * | 2017-09-22 | 2019-12-24 | 昆明理工大学 | 一种用于氰化氢催化水解的催化剂及制备方法 |
US20190233734A1 (en) * | 2018-01-26 | 2019-08-01 | Greyrock Energy, Inc. | Micro-scale process for the direct production of liquid fuels from gaseous hydrocarbon resources |
CN112423860A (zh) * | 2018-07-17 | 2021-02-26 | Sabic环球技术有限责任公司 | 在环境温度从富一氧化碳气流中去除硫化物的方法 |
US11508490B2 (en) | 2020-03-11 | 2022-11-22 | Henry Crichlow | Managing volatiles in nuclear waste vitrification |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
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GB1068588A (en) * | 1963-12-23 | 1967-05-10 | Gas Council | Method of treating gases |
US3441370A (en) | 1966-04-25 | 1969-04-29 | Catalysts & Chem Inc | Method of removing sulfur compounds from gases |
US3974256A (en) * | 1974-05-07 | 1976-08-10 | Exxon Research And Engineering Company | Sulfide removal process |
US4254094A (en) | 1979-03-19 | 1981-03-03 | Air Products And Chemicals, Inc. | Process for producing hydrogen from synthesis gas containing COS |
GB8610196D0 (en) * | 1986-04-25 | 1986-05-29 | Ici Plc | Sulphur compounds removal |
US4888131A (en) | 1988-03-28 | 1989-12-19 | Exxon Research And Engineering Company | Synthesis gas preparation and catalyst therefor |
NL9002661A (nl) | 1990-12-04 | 1992-07-01 | Pacques Bv | Werkwijze voor de verwijdering van h2s uit gas. |
CA2104158C (en) * | 1992-08-18 | 2005-11-15 | Jacobus Eilers | Process for the preparation of hydrocarbon fuels |
DE4321542C1 (de) * | 1993-06-29 | 1994-09-01 | Bfi Entsorgungstech | Verfahren zur getrennten Entfernung von Schwefelverbindungen und CO¶2¶ aus Gas |
GB9404191D0 (en) | 1994-03-04 | 1994-04-20 | Imperial College | Preparations and uses of polyferric sulphate |
US5463168A (en) | 1994-08-17 | 1995-10-31 | Mobil Oil Corporation | Process for the removal of hydrogen cyanide from FCC hydrocarbon product gas streams |
DE4431788A1 (de) | 1994-09-07 | 1996-03-14 | Huels Chemische Werke Ag | Katalysator und Verfahren zur Zersetzung von HCN in Gasen |
EP0757969B1 (en) | 1995-08-08 | 2000-03-29 | Exxon Research And Engineering Company | Process for removing hydrogen cyanide from synthesis gas |
FR2740704B1 (fr) * | 1995-11-03 | 1997-12-26 | Elf Aquitaine | Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre |
JP5214080B2 (ja) | 1997-12-30 | 2013-06-19 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 触媒の製造方法、コバルト系フィッシャー・トロプシュ合成用触媒及び炭化水素の製造方法 |
US5882614A (en) * | 1998-01-23 | 1999-03-16 | Exxon Research And Engineering Company | Very low sulfur gas feeds for sulfur sensitive syngas and hydrocarbon synthesis processes |
US6168768B1 (en) | 1998-01-23 | 2001-01-02 | Exxon Research And Engineering Company | Production of low sulfer syngas from natural gas with C4+/C5+ hydrocarbon recovery |
US6322763B1 (en) * | 1998-12-15 | 2001-11-27 | Teco, Inc. | Method and apparatus for removing carbonyl sulfide from a gas stream via wet scrubbing |
GB0118416D0 (en) * | 2001-07-30 | 2001-09-19 | Ici Plc | Desulphurisation |
-
2005
- 2005-07-21 MY MYPI20053368A patent/MY140997A/en unknown
- 2005-07-22 EA EA200700095A patent/EA010025B1/ru not_active IP Right Cessation
- 2005-07-22 US US11/632,883 patent/US7846325B2/en not_active Expired - Fee Related
- 2005-07-22 AT AT05767964T patent/ATE433793T1/de not_active IP Right Cessation
- 2005-07-22 WO PCT/EP2005/053563 patent/WO2006008317A1/en active Application Filing
- 2005-07-22 DE DE602005015007T patent/DE602005015007D1/de active Active
- 2005-07-22 CN CNA2005800246693A patent/CN101031350A/zh active Pending
- 2005-07-22 AU AU2005263776A patent/AU2005263776B2/en not_active Ceased
- 2005-07-22 EP EP05767964A patent/EP1791622B1/en not_active Not-in-force
-
2007
- 2007-01-05 ZA ZA200700161A patent/ZA200700161B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EA010025B1 (ru) | 2008-06-30 |
US7846325B2 (en) | 2010-12-07 |
US20080242749A1 (en) | 2008-10-02 |
AU2005263776A1 (en) | 2006-01-26 |
EP1791622B1 (en) | 2009-06-17 |
CN101031350A (zh) | 2007-09-05 |
EP1791622A1 (en) | 2007-06-06 |
MY140997A (en) | 2010-02-12 |
ATE433793T1 (de) | 2009-07-15 |
DE602005015007D1 (de) | 2009-07-30 |
WO2006008317A1 (en) | 2006-01-26 |
ZA200700161B (en) | 2008-06-25 |
AU2005263776B2 (en) | 2008-07-31 |
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Legal Events
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QB4A | Registration of a licence in a contracting state | ||
MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM |
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MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): RU |