EA200200583A1 - Микропористые материалы (tiq-6 и metiq-6) с большой площадью поверхности, проявляющие активность в окислительных реакциях - Google Patents

Микропористые материалы (tiq-6 и metiq-6) с большой площадью поверхности, проявляющие активность в окислительных реакциях

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Publication number
EA200200583A1
EA200200583A1 EA200200583A EA200200583A EA200200583A1 EA 200200583 A1 EA200200583 A1 EA 200200583A1 EA 200200583 A EA200200583 A EA 200200583A EA 200200583 A EA200200583 A EA 200200583A EA 200200583 A1 EA200200583 A1 EA 200200583A1
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EA
Eurasian Patent Office
Prior art keywords
tiq
metiq
reactions
oxidating
surface area
Prior art date
Application number
EA200200583A
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English (en)
Other versions
EA004784B1 (ru
Inventor
Авелино Корма Канос
Висенте Форнес Сегуль
Урбано Диас Моралес
Марсело Эдуардо Домине
Original Assignee
Консехо Супериор Де-Инвестигасионес Сиентификас
Универсидад Политекника Де-Валенсия
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Publication of EA200200583A1 publication Critical patent/EA200200583A1/ru
Publication of EA004784B1 publication Critical patent/EA004784B1/ru

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B43/00—Formation or introduction of functional groups containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C07B45/04—Formation or introduction of functional groups containing sulfur of sulfonyl or sulfinyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/23—Ferrierite, e.g. SR-D ZSM-33

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

В заявке описаны микропористый материал, в состав которого входят кислород, кремний, германий, алюминий, бор, галлий, цирконий и/или титан, обозначаемый как TIQ-6, способ его приготовления и его применение в качестве катализатора в реакциях окисления. Способ приготовления материала TIQ-6 основан на синтезе геля с титановым и/или циркониевым компонентом, его гидротермической обработке в регулируемых условиях и обработке образующегося пластинчатого материала раствором органического соединения, включающего акцептирующую протон группу. Получаемый набухший материал подвергают особой обработке с получением расслоившегося твердого материала с развитой внешней поверхностью. Описан также материал METIQ-6, аналогичный материалу TIQ-6, но содержащий органические группы, закрепленные на его поверхности, внедренные проведением процесса постсинтезной обработки материала TIQ-6.Отчет о международном поиске был опубликован 2002.03.14.
EA200200583A 1999-11-24 2000-11-24 Микропористые материалы (tiq-6 и metiq-6) с большой площадью поверхности, проявляющие активность в окислительных реакциях EA004784B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES009902655A ES2178910B1 (es) 1999-11-24 1999-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion. tiq-6 y metiq-6.
PCT/ES2000/000456 WO2001037629A2 (es) 1999-11-24 2000-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidación. tiq-6 y metiq-6

Publications (2)

Publication Number Publication Date
EA200200583A1 true EA200200583A1 (ru) 2003-04-24
EA004784B1 EA004784B1 (ru) 2004-08-26

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Application Number Title Priority Date Filing Date
EA200200583A EA004784B1 (ru) 1999-11-24 2000-11-24 Микропористые материалы (tiq-6 и metiq-6) с большой площадью поверхности, проявляющие активность в окислительных реакциях

Country Status (13)

Country Link
US (1) US6843978B2 (ru)
EP (1) EP1243333B1 (ru)
JP (1) JP2003514751A (ru)
CN (1) CN1191884C (ru)
AT (1) ATE286432T1 (ru)
AU (1) AU782301B2 (ru)
DE (1) DE60017286T2 (ru)
DK (1) DK1243333T3 (ru)
EA (1) EA004784B1 (ru)
ES (2) ES2178910B1 (ru)
IN (1) IN2002KO00840A (ru)
NZ (1) NZ519657A (ru)
WO (1) WO2001037629A2 (ru)

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ES2179753B1 (es) 2000-10-11 2005-02-16 Universidad Politecnica De Valencia Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion gasolina.
ES2183710B1 (es) 2001-04-12 2004-01-16 Univ Valencia Politecnica Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.
WO2005012458A1 (en) * 2003-08-01 2005-02-10 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
US7491316B2 (en) * 2004-07-29 2009-02-17 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
ES2281299B1 (es) * 2006-03-15 2008-12-16 Universidad Politecnica De Valencia Un procecimiento para la sintesis de esteres.
GB0702327D0 (en) * 2007-02-07 2007-03-21 Leuven K U Res & Dev Zeolite materials and synthesis method thereof
CN101602012B (zh) * 2008-06-12 2012-04-18 中国石油化工股份有限公司 含有芳烃磺酸基团的介孔材料及其制备方法和应用
TWI399242B (zh) * 2009-12-11 2013-06-21 China Petrochemical Dev Corp Taipei Taiwan Method for preparing large-diameter titanium-silicon molecular sieve and method for producing cyclohexanone oxime using the molecular sieve
US9522390B2 (en) * 2010-12-10 2016-12-20 The Regents Of The University Of California Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation
US8735614B2 (en) 2011-01-27 2014-05-27 Solvay Sa Process for the manufacture of 1,2-epoxy-3-chloropropane
CN102442683A (zh) * 2011-09-27 2012-05-09 华东理工大学 一种制备多级孔道含钛沸石的溶剂挥发法
KR101394133B1 (ko) * 2012-08-22 2014-05-15 주식회사 이엔에프테크놀로지 몰리브덴 합금막 및 인듐 산화막 식각액 조성물
WO2014191475A1 (en) * 2013-05-29 2014-12-04 Basf Se Process for the oxidation of sulfoxides
FR3007405B1 (fr) * 2013-06-21 2016-07-29 Centre Nat De La Rech Scient (C N R S ) Procede de preparation d'une composition comprenant des particules silico/germano-metalliques fonctionnalisees et composition obtenue
CN111278552A (zh) * 2017-10-30 2020-06-12 巴斯夫欧洲公司 由层状硅酸盐前体制备包封过渡金属纳米粒子的沸石的方法
CN108947939B (zh) * 2018-08-16 2022-03-11 福州大学 一种异松油烯4,8-环氧化物的合成方法
CN111924852B (zh) * 2019-04-26 2023-11-03 中国石油大学(华东) 一种钛硅分子筛的制备方法
CN110902691B (zh) * 2019-11-25 2021-07-20 北京化工大学 一种y型分子筛疏水改性的方法
CN111167471B (zh) * 2020-01-17 2020-10-02 浙江新和成股份有限公司 一种金属氧化物涂覆的陶瓷波纹板催化剂、制备及其在制备柠檬醛关键中间体中的应用
TW202346272A (zh) * 2022-04-25 2023-12-01 日商住友化學股份有限公司 含鈦氧化矽之製造方法、環氧化物之製造方法、及含鈦氧化矽

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Also Published As

Publication number Publication date
ES2178910B1 (es) 2003-12-16
EP1243333B1 (en) 2005-01-05
AU1708501A (en) 2001-06-04
ATE286432T1 (de) 2005-01-15
ES2236000T3 (es) 2005-07-16
CN1424938A (zh) 2003-06-18
WO2001037629A3 (es) 2002-03-14
DK1243333T3 (da) 2005-04-25
IN2002KO00840A (ru) 2006-03-10
EP1243333A2 (en) 2002-09-25
WO2001037629A8 (es) 2003-02-06
EA004784B1 (ru) 2004-08-26
US20020193239A1 (en) 2002-12-19
AU782301B2 (en) 2005-07-14
US6843978B2 (en) 2005-01-18
DE60017286T2 (de) 2005-12-08
JP2003514751A (ja) 2003-04-22
DE60017286D1 (de) 2005-02-10
CN1191884C (zh) 2005-03-09
ES2178910A1 (es) 2003-01-01
WO2001037629A2 (es) 2001-05-31
NZ519657A (en) 2004-01-30

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