WO2001037629A3 - Materiales microporosos de alta superficie activos en reacciones de oxidación. tiq-6 y metiq-6 - Google Patents

Materiales microporosos de alta superficie activos en reacciones de oxidación. tiq-6 y metiq-6 Download PDF

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Publication number
WO2001037629A3
WO2001037629A3 PCT/ES2000/000456 ES0000456W WO0137629A3 WO 2001037629 A3 WO2001037629 A3 WO 2001037629A3 ES 0000456 W ES0000456 W ES 0000456W WO 0137629 A3 WO0137629 A3 WO 0137629A3
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WO
WIPO (PCT)
Prior art keywords
tiq
metiq
oxidation reactions
synthesis
zirconium
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PCT/ES2000/000456
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English (en)
French (fr)
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WO2001037629A2 (es
WO2001037629A8 (es
Inventor
Canos Avelino Corma
Segui Vicente Fornes
Morales Urbano Diaz
Marcelo Eduardo Domine
Original Assignee
Consejo Superior Investigacion
Univ Valencia Politecnica
Canos Avelino Corma
Segui Vicente Fornes
Morales Urbano Diaz
Marcelo Eduardo Domine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CNB008186006A priority Critical patent/CN1191884C/zh
Application filed by Consejo Superior Investigacion, Univ Valencia Politecnica, Canos Avelino Corma, Segui Vicente Fornes, Morales Urbano Diaz, Marcelo Eduardo Domine filed Critical Consejo Superior Investigacion
Priority to ES00979683T priority patent/ES2236000T3/es
Priority to DK00979683T priority patent/DK1243333T3/da
Priority to AT00979683T priority patent/ATE286432T1/de
Priority to EP00979683A priority patent/EP1243333B1/en
Priority to JP2001539268A priority patent/JP2003514751A/ja
Priority to EA200200583A priority patent/EA004784B1/ru
Priority to DE60017286T priority patent/DE60017286T2/de
Priority to AU17085/01A priority patent/AU782301B2/en
Publication of WO2001037629A2 publication Critical patent/WO2001037629A2/es
Publication of WO2001037629A3 publication Critical patent/WO2001037629A3/es
Priority to US10/155,564 priority patent/US6843978B2/en
Publication of WO2001037629A8 publication Critical patent/WO2001037629A8/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B43/00—Formation or introduction of functional groups containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C07B45/04—Formation or introduction of functional groups containing sulfur of sulfonyl or sulfinyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/23—Ferrierite, e.g. SR-D ZSM-33

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La presente invención se refiere a un material microporoso formado por oxígeno, silicio, germanio, aluminio, boro, galio, zirconio y/o titanio en su composición, denominado TIQ-6, al procedimiento de su preparación y a sus aplicaciones catalíticas en reacciones de oxidación. El método de preparación del material TIQ-6 se basa en la síntesis de un gel con contenido en titanio y/o zirconio, su tratamiento hidrotermal en condiciones controladas, y el tratamiento del material laminar resultante con una solución de un compuesto orgánico, preferentemente de cadena hidrocarbonada larga, que contenga un grupo aceptor de protones. Este material hinchado es sometido a un tratamiento específico mediante agitación, ultrasonidos o por cualquier otro método conocido en el arte, para obtener un sólido deslaminado de elevada superficie externa. Asimismo, se reivindica un material con características similares al TIQ-6, pero que además posee grupos orgánicos anclados en su superficie denominado METIQ-6, al procedimiento de su preparación y a sus aplicaciones como catalizador en reacciones de oxidación. La incorporación de las especies orgánicas durante la síntesis del material denominado METIQ-6 se realiza mediante un proceso postsíntesis sobre el material TIQ-6.
PCT/ES2000/000456 1999-11-24 2000-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidación. tiq-6 y metiq-6 WO2001037629A2 (es)

Priority Applications (10)

Application Number Priority Date Filing Date Title
JP2001539268A JP2003514751A (ja) 1999-11-24 2000-11-24 酸化反応に活性を有する高表面積微多孔質物質（ｔｉｑ−６およびｍｅｔｉｑ−６）
ES00979683T ES2236000T3 (es) 1999-11-24 2000-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion tiq-6 y metiq-6.
DK00979683T DK1243333T3 (da) 1999-11-24 2000-11-24 Mikroporöse materialer med stor overflade, hvilke er aktive i oxidationsreaktioner. TIQ-6 og METIQ-6
AT00979683T ATE286432T1 (de) 1999-11-24 2000-11-24 Mikroporöse materialien grosser oberfläche, welche in den oxidationsreaktionen tiq-6 und metiq-6 aktiv sind
EP00979683A EP1243333B1 (en) 1999-11-24 2000-11-24 High surface microporous materials which are active in oxidation reactions. tiq-6 and metiq-6
CNB008186006A CN1191884C (zh) 1999-11-24 2000-11-24 在氧化反应中有活性的高表面积微孔材料(tiq－6和metiq－6)
EA200200583A EA004784B1 (ru) 1999-11-24 2000-11-24 Микропористые материалы (tiq-6 и metiq-6) с большой площадью поверхности, проявляющие активность в окислительных реакциях
DE60017286T DE60017286T2 (de) 1999-11-24 2000-11-24 Mikroporöse materialien grosser oberfläche, welche in den oxidationsreaktionen tiq-6 und metiq-6 aktiv sind
AU17085/01A AU782301B2 (en) 1999-11-24 2000-11-24 Microporous materials (TIQ-6 and METIQ-6) of high surface area active in oxidation reactions
US10/155,564 US6843978B2 (en) 1999-11-24 2002-05-24 Microporous materials (TIQ-6 and METIQ-6) of high surface area active in oxidation reactions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES009902655A ES2178910B1 (es) 1999-11-24 1999-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion. tiq-6 y metiq-6.
ESP9902655 1999-11-24

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/155,564 Continuation US6843978B2 (en) 1999-11-24 2002-05-24 Microporous materials (TIQ-6 and METIQ-6) of high surface area active in oxidation reactions

Publications (3)

Publication Number Publication Date
WO2001037629A2 WO2001037629A2 (es) 2001-05-31
WO2001037629A3 true WO2001037629A3 (es) 2002-03-14
WO2001037629A8 WO2001037629A8 (es) 2003-02-06

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US (1) US6843978B2 (es)
EP (1) EP1243333B1 (es)
JP (1) JP2003514751A (es)
CN (1) CN1191884C (es)
AT (1) ATE286432T1 (es)
AU (1) AU782301B2 (es)
DE (1) DE60017286T2 (es)
DK (1) DK1243333T3 (es)
EA (1) EA004784B1 (es)
ES (2) ES2178910B1 (es)
IN (1) IN2002KO00840A (es)
NZ (1) NZ519657A (es)
WO (1) WO2001037629A2 (es)

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ES2179753B1 (es) 2000-10-11 2005-02-16 Universidad Politecnica De Valencia Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion gasolina.
ES2183710B1 (es) * 2001-04-12 2004-01-16 Univ Valencia Politecnica Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.
WO2005012458A1 (en) * 2003-08-01 2005-02-10 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
US7491316B2 (en) * 2004-07-29 2009-02-17 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
ES2281299B1 (es) * 2006-03-15 2008-12-16 Universidad Politecnica De Valencia Un procecimiento para la sintesis de esteres.
GB0702327D0 (en) * 2007-02-07 2007-03-21 Leuven K U Res & Dev Zeolite materials and synthesis method thereof
CN101602012B (zh) * 2008-06-12 2012-04-18 中国石油化工股份有限公司 含有芳烃磺酸基团的介孔材料及其制备方法和应用
TWI399242B (zh) * 2009-12-11 2013-06-21 China Petrochemical Dev Corp Taipei Taiwan Method for preparing large-diameter titanium-silicon molecular sieve and method for producing cyclohexanone oxime using the molecular sieve
US9522390B2 (en) * 2010-12-10 2016-12-20 The Regents Of The University Of California Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation
US8735614B2 (en) 2011-01-27 2014-05-27 Solvay Sa Process for the manufacture of 1,2-epoxy-3-chloropropane
CN102442683A (zh) * 2011-09-27 2012-05-09 华东理工大学 一种制备多级孔道含钛沸石的溶剂挥发法
KR101394133B1 (ko) * 2012-08-22 2014-05-15 주식회사 이엔에프테크놀로지 몰리브덴 합금막 및 인듐 산화막 식각액 조성물
US20160122296A1 (en) * 2013-05-29 2016-05-05 Basf Se Process for the oxidation of sulfoxides
FR3007405B1 (fr) * 2013-06-21 2016-07-29 Centre Nat De La Rech Scient (C N R S ) Procede de preparation d'une composition comprenant des particules silico/germano-metalliques fonctionnalisees et composition obtenue
US20210370277A1 (en) * 2017-10-30 2021-12-02 Basf Se Process for the preparation of zeolites encapsulating transition metal nanoparticles from layered silicate precursors
CN108947939B (zh) * 2018-08-16 2022-03-11 福州大学 一种异松油烯4,8-环氧化物的合成方法
CN111924852B (zh) * 2019-04-26 2023-11-03 中国石油大学(华东) 一种钛硅分子筛的制备方法
CN110902691B (zh) * 2019-11-25 2021-07-20 北京化工大学 一种y型分子筛疏水改性的方法
CN111167471B (zh) * 2020-01-17 2020-10-02 浙江新和成股份有限公司 一种金属氧化物涂覆的陶瓷波纹板催化剂、制备及其在制备柠檬醛关键中间体中的应用
TW202346272A (zh) * 2022-04-25 2023-12-01 日商住友化學股份有限公司 含鈦氧化矽之製造方法、環氧化物之製造方法、及含鈦氧化矽
CN118620617A (zh) * 2024-08-09 2024-09-10 电子科技大学长三角研究院(湖州) 一种晶态GaTiS-AEP有机开放骨架绿色光致发光源及其制备方法

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EA200200583A1 (ru) 2003-04-24
ES2178910B1 (es) 2003-12-16
EP1243333A2 (en) 2002-09-25
AU782301B2 (en) 2005-07-14
IN2002KO00840A (es) 2006-03-10
WO2001037629A2 (es) 2001-05-31
DK1243333T3 (da) 2005-04-25
CN1424938A (zh) 2003-06-18
CN1191884C (zh) 2005-03-09
WO2001037629A8 (es) 2003-02-06
EA004784B1 (ru) 2004-08-26
US6843978B2 (en) 2005-01-18
JP2003514751A (ja) 2003-04-22
NZ519657A (en) 2004-01-30
US20020193239A1 (en) 2002-12-19
DE60017286D1 (de) 2005-02-10
EP1243333B1 (en) 2005-01-05
ATE286432T1 (de) 2005-01-15
ES2236000T3 (es) 2005-07-16
ES2178910A1 (es) 2003-01-01
AU1708501A (en) 2001-06-04
DE60017286T2 (de) 2005-12-08

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