EA199800022A1 - Получение привитых вулканизированных модифицированных сополимеров изомоноолефинов и параалкилстирола - Google Patents

Получение привитых вулканизированных модифицированных сополимеров изомоноолефинов и параалкилстирола

Info

Publication number
EA199800022A1
EA199800022A1 EA199800022A EA199800022A EA199800022A1 EA 199800022 A1 EA199800022 A1 EA 199800022A1 EA 199800022 A EA199800022 A EA 199800022A EA 199800022 A EA199800022 A EA 199800022A EA 199800022 A1 EA199800022 A1 EA 199800022A1
Authority
EA
Eurasian Patent Office
Prior art keywords
free radical
carbon atoms
mixture
compositions
radical polymerization
Prior art date
Application number
EA199800022A
Other languages
English (en)
Inventor
Гзин-Чанг Ванг
Эрвин Джером Гарднер
Джеймс Винсент Фаско
Original Assignee
Эксон Кемикэл Пейтентс Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Эксон Кемикэл Пейтентс Инк. filed Critical Эксон Кемикэл Пейтентс Инк.
Publication of EA199800022A1 publication Critical patent/EA199800022A1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/04—Polymers provided for in subclasses C08C or C08F
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/283—Halogenated homo- or copolymers of iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C08L71/123—Polyphenylene oxides not modified by chemical after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

В заявке описаны вулканизуемые и вулканизованные привитой сополимеризацией полимерные композиции, приготовленные из смеси, включающей: а) эластомерный сополимер, содержащий от примерно 0,01 до примерно 10 мол.% сложноэфирных групп Y, неупорядоченно распределенных вдоль и подвешенных на эластомерной полимерной цепи, причем эти сложноэфирные группы Y соответствуют формулегде Rи Rнезависимо друг от друга выбраны из группы, включающей водород и алкильную группу, содержащую от 1 до примерно 6 углеродных атомов, a Rвыбран из группы, включающей водород, алкильную группу, содержащую от 1 до примерно 28 углеродных атомов, арильную группу и алкенильную группу, содержащую от 2 до примерно 28 углеродных атомов, и б) по меньшей мере один мономер, способный к свободнорадикальной полимеризации. Описан также способ получения вулканизованных привитой сополимеризацией полимерных композиций, включающий приготовление такой смеси компонентов (а) и (б) и воздействие на эту смесь условиями свободнорадикальной полимеризации. Сложноэфирные группы Y, подвешенные на эластомерной полимерной цепи, например остатки эфира бензил(мет)акриловой кислоты, содержащиеся в изобутилен/параметилстирольных сополимерных цепях, способны принимать участие в инициируемых свободными радикалами взаимодействиях с монофункциональными или полифункциональными мономерами, способными к свободнорадикальной полимеризации, с получением вулканизованных привитой сополимеризацией композиций, обладающих необычным балансом физических свойств. Эти композиции можно формовать с получением профилированных материалов, таких как пленки, покрытия, клеевые прослойки, а также литые
EA199800022A 1995-06-06 1996-06-06 Получение привитых вулканизированных модифицированных сополимеров изомоноолефинов и параалкилстирола EA199800022A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/469,285 US5567775A (en) 1989-11-27 1995-06-06 Craft curing of modified isomonoolefin/para-alkylstyrene copolymers
PCT/US1996/009829 WO1996039452A1 (en) 1995-06-06 1996-06-06 Graft curing of modified isomonoolefin/para-alkylstyrene copolymers

Publications (1)

Publication Number Publication Date
EA199800022A1 true EA199800022A1 (ru) 1998-08-27

Family

ID=23863205

Family Applications (1)

Application Number Title Priority Date Filing Date
EA199800022A EA199800022A1 (ru) 1995-06-06 1996-06-06 Получение привитых вулканизированных модифицированных сополимеров изомоноолефинов и параалкилстирола

Country Status (14)

Country Link
US (1) US5567775A (ru)
EP (1) EP0830401A1 (ru)
JP (1) JPH11502254A (ru)
KR (1) KR19990022428A (ru)
CN (1) CN1190976A (ru)
BR (1) BR9608952A (ru)
CA (1) CA2220666A1 (ru)
CZ (1) CZ385297A3 (ru)
EA (1) EA199800022A1 (ru)
HU (1) HUP9901100A3 (ru)
MX (1) MX9709603A (ru)
PL (1) PL323734A1 (ru)
TW (1) TW332819B (ru)
WO (1) WO1996039452A1 (ru)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100281851B1 (ko) * 1997-01-27 2001-02-15 나까니시 히로유끼 접착성 수지조성물 및 그 조성물을 접착층용으로 사용한 적층체
KR20010032104A (ko) * 1997-12-15 2001-04-16 엑손 케미칼 패턴츠 인코포레이티드 투명하고 착색가능한 탄성중합체성 조성물
DE60230358D1 (de) * 2001-06-15 2009-01-29 Jsr Corp (Meth)acryloylgruppen enthaltende Ethylen-Alpha-Olefin Copolymere, Verfahren zu deren Herstellung und Kautschukzusammensetzung
US7509913B1 (en) * 2003-05-14 2009-03-31 Franklin Eagle Table bridge
US8597784B2 (en) 2010-09-30 2013-12-03 3M Innovative Properties Company Radiation curable poly(isobutylene) adhesive copolymers
KR101909760B1 (ko) 2010-11-16 2018-10-18 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Ｕｖ 경화성 무수물-개질 폴리(아이소부틸렌)
US8663407B2 (en) 2010-11-17 2014-03-04 3M Innovative Properties Company Isobutylene (Co)polymeric adhesive composition
TW201235359A (en) * 2010-11-24 2012-09-01 Lanxess Inc Ionomers comprising pendant vinyl groups and processes for preparing same
US8629209B2 (en) 2010-12-02 2014-01-14 3M Innovative Properties Company Moisture curable isobutylene adhesive copolymers
US8673995B2 (en) 2011-06-20 2014-03-18 3M Innovative Properties Company Radiation curable poly(isobutylene) adhesive copolymers having pendent amine groups
EP3305822B1 (en) 2015-05-26 2020-08-12 Kaneka Corporation Process for producing thermoplastic elastomer, and thermoplastic elastomer
EP3356427A4 (en) * 2015-09-30 2019-09-25 ExxonMobil Chemical Patents Inc. COMBINED COPOLYMERS OF AN ISOBUTYLENE COPOLYMER BACKBONE WITH POLYMER COMBINES
CN109219642A (zh) * 2016-06-03 2019-01-15 赛鲁斯股份有限公司 用末端1,1-二取代烯烃单体官能化的聚合物和其他化合物及其方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3489822A (en) * 1962-08-31 1970-01-13 Uniroyal Inc Grafted terpolymer of ethylene,propylene and a non-conjugated diene
US3968185A (en) * 1974-12-09 1976-07-06 Baldwin Francis P Preparation of modified elastomers
JPS59199785A (ja) * 1983-04-27 1984-11-12 Showa Highpolymer Co Ltd 嫌気硬化性を有する粘着材
JPS62153340A (ja) * 1985-12-27 1987-07-08 Showa Highpolymer Co Ltd 硬化性組成物
US5162445A (en) * 1988-05-27 1992-11-10 Exxon Chemical Patents Inc. Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof
EP0353471B1 (en) * 1988-08-05 1994-01-05 Edison Polymer Innovation Corporation ( Epic) UV curable polymer formulation
US5206303A (en) * 1990-12-27 1993-04-27 Exxon Chemical Patents Inc. Entanglement-inhibited macromolecules
EP0609397B1 (en) * 1991-10-17 1998-05-13 Exxon Chemical Patents Inc. Radiation curable isoolefin copolymers
DE69424423T2 (de) * 1993-07-08 2001-01-25 Avery Dennison Corp., Pasadena Druckempfindliche mischklebstoffe auf der basis von acrylat gesättigten kautschuken

Also Published As

Publication number Publication date
HUP9901100A2 (hu) 1999-07-28
PL323734A1 (en) 1998-04-14
CN1190976A (zh) 1998-08-19
WO1996039452A1 (en) 1996-12-12
CA2220666A1 (en) 1996-12-12
JPH11502254A (ja) 1999-02-23
CZ385297A3 (cs) 1998-05-13
HUP9901100A3 (en) 2000-02-28
TW332819B (en) 1998-06-01
EP0830401A1 (en) 1998-03-25
KR19990022428A (ko) 1999-03-25
BR9608952A (pt) 1999-03-02
US5567775A (en) 1996-10-22
MX9709603A (es) 1998-04-30

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