EA199600033A3 - Способ получения метилмеркаптана и катализатор для его осуществления - Google Patents
Способ получения метилмеркаптана и катализатор для его осуществленияInfo
- Publication number
- EA199600033A3 EA199600033A3 EA199600033A EA199600033A EA199600033A3 EA 199600033 A3 EA199600033 A3 EA 199600033A3 EA 199600033 A EA199600033 A EA 199600033A EA 199600033 A EA199600033 A EA 199600033A EA 199600033 A3 EA199600033 A3 EA 199600033A3
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- methylmercaptan
- preparation
- pref
- catalyst
- degrees
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
- C07C319/08—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by replacement of hydroxy groups or etherified or esterified hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/232—Carbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Изобретение относится к способу получения метилмеркаптана путем взаимодействия метанола с сероводородом в паровой фазе при температуре ниже 350°С в присутствии катализатора, представляющего собой карбонат щелочного металла, нанесенный на оксид алюминия, а также к указанному катализатору, используемому при температуре ниже 350°С. Предлагаемый способ повышает селективность реакции в отношении метилмеркаптана, используемый катализатор более стабилен во времени.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9507571A FR2735773B1 (fr) | 1995-06-23 | 1995-06-23 | Procede de preparation de methylmercaptan |
Publications (3)
Publication Number | Publication Date |
---|---|
EA199600033A2 EA199600033A2 (ru) | 1996-12-30 |
EA199600033A3 true EA199600033A3 (ru) | 1997-03-31 |
EA000798B1 EA000798B1 (ru) | 2000-04-24 |
Family
ID=9480336
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA199600033A EA000798B1 (ru) | 1995-06-23 | 1996-06-21 | Способ получения метилмеркаптана |
Country Status (13)
Country | Link |
---|---|
US (1) | US5847223A (ru) |
EP (1) | EP0749961B1 (ru) |
JP (1) | JP2963396B2 (ru) |
CN (1) | CN1068874C (ru) |
AT (1) | ATE202085T1 (ru) |
DE (1) | DE69613276T2 (ru) |
DK (1) | DK0749961T3 (ru) |
EA (1) | EA000798B1 (ru) |
ES (1) | ES2158258T3 (ru) |
FR (1) | FR2735773B1 (ru) |
GR (1) | GR3036037T3 (ru) |
PT (1) | PT749961E (ru) |
SG (1) | SG40879A1 (ru) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2120822C1 (ru) * | 1997-09-18 | 1998-10-27 | Институт катализа им.Г.К.Борескова СО РАН | Катализатор синтеза метилмеркаптана |
CN1101253C (zh) * | 1998-08-25 | 2003-02-12 | 中国科学院长春应用化学研究所 | 多金属氧酸盐的单层和多层分子组装体系 |
DE10319739A1 (de) * | 2003-04-30 | 2004-11-18 | Basf Ag | Katalysator zur Herstellung von Methylmercaptan aus Methanol und Schwefelwasserstoff |
DE10338887A1 (de) * | 2003-08-23 | 2005-03-17 | Degussa Ag | Katalysator zur Synthese von Alkylmercaptan und Verfahren zu seiner Herstellung |
WO2005040082A2 (en) * | 2003-10-10 | 2005-05-06 | Degussa Ag | Process for the manufacture of methylmercaptan |
DE102004037739A1 (de) * | 2004-08-04 | 2006-03-16 | Degussa Ag | Wolframat enthaltende Katalysatoren zur Synthese von Alkylmercaptan und Verfahren zu ihrer Herstellung |
DE102006032635A1 (de) * | 2006-07-13 | 2008-01-17 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Alkylmercaptanen in einem Mehrzonenfestbettreaktor |
PE20121096A1 (es) | 2008-12-23 | 2012-08-05 | Basf Se | Metodo para comprimir gases que contienen sulfuro de hidrogeno |
CN102247873B (zh) * | 2011-08-04 | 2013-05-01 | 厦门大学 | 一种合成甲硫醇的含磷催化剂及其制备方法 |
EP2606967A1 (de) | 2011-12-19 | 2013-06-26 | Evonik Degussa GmbH | Katalysator zur Synthese von Alkylmercaptanen und Verfahren zu seiner Herstellung |
CN109195948B (zh) * | 2016-05-31 | 2021-05-11 | 诺华丝国际股份有限公司 | 由二甲基硫醚生产甲基硫醇的方法 |
CN112979516B (zh) * | 2021-04-20 | 2023-12-08 | 查都(海南)科技有限公司 | 一种节能的甲硫醇合成装置 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2820061A (en) * | 1954-07-28 | 1958-01-14 | Pure Oil Co | Preparation of organic thiols |
FR1161066A (fr) * | 1955-06-22 | 1958-08-20 | American Oil Co | Perfectionnements apportés aux procédés pour fabriquer du mercaptan méthylique |
US2822400A (en) * | 1955-06-22 | 1958-02-04 | American Oil Co | Methyl mercaptan production process |
FR2253013B1 (ru) * | 1973-11-30 | 1980-01-04 | Rhone Progil | |
FR2477538A2 (fr) * | 1980-03-06 | 1981-09-11 | Rhone Poulenc Ind | Procede de preparation de methylmercaptan a partir d'hydrogene sulfure et de methanol |
SU1145013A1 (ru) * | 1982-09-29 | 1985-03-15 | Предприятие П/Я В-8952 | Способ получени 3-метилпентена-2 |
US5021383A (en) * | 1989-06-16 | 1991-06-04 | Berty Reaction Engineers, Ltd. | Catalyst for the destruction of toxic organic chemicals |
US5283369A (en) * | 1992-03-24 | 1994-02-01 | Elf Atochem North America, Inc. | Selective synthesis of mercaptans and catalyst therefor |
-
1995
- 1995-06-23 FR FR9507571A patent/FR2735773B1/fr not_active Expired - Fee Related
-
1996
- 1996-06-19 PT PT96401326T patent/PT749961E/pt unknown
- 1996-06-19 DK DK96401326T patent/DK0749961T3/da active
- 1996-06-19 EP EP96401326A patent/EP0749961B1/fr not_active Expired - Lifetime
- 1996-06-19 AT AT96401326T patent/ATE202085T1/de not_active IP Right Cessation
- 1996-06-19 DE DE69613276T patent/DE69613276T2/de not_active Expired - Lifetime
- 1996-06-19 ES ES96401326T patent/ES2158258T3/es not_active Expired - Lifetime
- 1996-06-20 CN CN96108374A patent/CN1068874C/zh not_active Expired - Fee Related
- 1996-06-21 JP JP8179785A patent/JP2963396B2/ja not_active Expired - Fee Related
- 1996-06-21 SG SG1996010120A patent/SG40879A1/en unknown
- 1996-06-21 EA EA199600033A patent/EA000798B1/ru not_active IP Right Cessation
- 1996-06-21 US US08/667,545 patent/US5847223A/en not_active Expired - Lifetime
-
2001
- 2001-06-14 GR GR20010400059T patent/GR3036037T3/el not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EA199600033A2 (ru) | 1996-12-30 |
ES2158258T3 (es) | 2001-09-01 |
SG40879A1 (en) | 1997-06-14 |
GR3036037T3 (en) | 2001-09-28 |
JPH0912535A (ja) | 1997-01-14 |
PT749961E (pt) | 2001-10-31 |
DK0749961T3 (da) | 2001-09-03 |
EP0749961A1 (fr) | 1996-12-27 |
JP2963396B2 (ja) | 1999-10-18 |
FR2735773B1 (fr) | 1997-09-12 |
DE69613276D1 (de) | 2001-07-19 |
CN1141915A (zh) | 1997-02-05 |
DE69613276T2 (de) | 2001-09-20 |
CN1068874C (zh) | 2001-07-25 |
EP0749961B1 (fr) | 2001-06-13 |
FR2735773A1 (fr) | 1996-12-27 |
US5847223A (en) | 1998-12-08 |
ATE202085T1 (de) | 2001-06-15 |
EA000798B1 (ru) | 2000-04-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM |
|
TC4A | Change in name of a patent proprietor in a eurasian patent |
Designated state(s): AM AZ BY KZ KG MD TJ TM |
|
PC4A | Registration of transfer of a eurasian patent by assignment | ||
MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): RU |