EA020668B1 - Полимеры и способ для улучшения подвижности в почве слаборастворимых инсектицидов, способ борьбы с вредителями и инсектицидный состав - Google Patents

Info

Publication number

EA020668B1

EA020668B1 EA201101602A EA201101602A EA020668B1 EA 020668 B1 EA020668 B1 EA 020668B1 EA 201101602 A EA201101602 A EA 201101602A EA 201101602 A EA201101602 A EA 201101602A EA 020668 B1 EA020668 B1 EA 020668B1

Authority

EA

Eurasian Patent Office

Prior art keywords

solubilizer

group

polymer

soil

acid

Prior art date

2009-05-11

Links

• Espacenet
• Global Dossier
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• 239000000203 mixture Substances 0.000 title claims abstract description 123
• 239000002689 soil Substances 0.000 title claims abstract description 89
• 238000000034 method Methods 0.000 title claims abstract description 30
• 230000000749 insecticidal effect Effects 0.000 title claims abstract description 25
• 239000002917 insecticide Substances 0.000 title claims abstract description 23
• 241000607479 Yersinia pestis Species 0.000 title claims abstract description 15
• 229920000642 polymer Polymers 0.000 title claims description 144
• 238000009472 formulation Methods 0.000 title abstract description 3
• 239000002904 solvent Substances 0.000 claims abstract description 149
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 48
• 239000004480 active ingredient Substances 0.000 claims abstract description 18
• 239000007864 aqueous solution Substances 0.000 claims abstract description 16
• -1 1,2-propylene Chemical group 0.000 claims description 134
• 239000004417 polycarbonate Substances 0.000 claims description 74
• 229920000515 polycarbonate Polymers 0.000 claims description 74
• 239000000178 monomer Substances 0.000 claims description 60
• 229920001223 polyethylene glycol Polymers 0.000 claims description 59
• 239000002202 Polyethylene glycol Substances 0.000 claims description 57
• ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 claims description 55
• 239000005899 Fipronil Substances 0.000 claims description 54
• 229940013764 fipronil Drugs 0.000 claims description 54
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 50
• 239000002671 adjuvant Substances 0.000 claims description 37
• 229920001577 copolymer Polymers 0.000 claims description 36
• 150000001298 alcohols Chemical class 0.000 claims description 24
• RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
• 239000002253 acid Substances 0.000 claims description 19
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 18
• 125000001931 aliphatic group Chemical group 0.000 claims description 16
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 15
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
• 239000005892 Deltamethrin Substances 0.000 claims description 13
• 125000000217 alkyl group Chemical group 0.000 claims description 13
• 229960002483 decamethrin Drugs 0.000 claims description 13
• OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 13
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 12
• 241000256602 Isoptera Species 0.000 claims description 12
• 150000001735 carboxylic acids Chemical class 0.000 claims description 12
• 150000001991 dicarboxylic acids Chemical class 0.000 claims description 11
• 150000005690 diesters Chemical class 0.000 claims description 11
• YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 claims description 11
• HJUFTIJOISQSKQ-UHFFFAOYSA-N fenoxycarb Chemical compound C1=CC(OCCNC(=O)OCC)=CC=C1OC1=CC=CC=C1 HJUFTIJOISQSKQ-UHFFFAOYSA-N 0.000 claims description 11
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
• 239000005944 Chlorpyrifos Substances 0.000 claims description 9
• 239000005896 Etofenprox Substances 0.000 claims description 9
• SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 claims description 9
• 229950005085 etofenprox Drugs 0.000 claims description 9
• 239000000194 fatty acid Substances 0.000 claims description 9
• 239000002736 nonionic surfactant Substances 0.000 claims description 9
• 229920001296 polysiloxane Polymers 0.000 claims description 9
• 239000004094 surface-active agent Substances 0.000 claims description 9
• KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims description 8
• 239000005877 Alpha-Cypermethrin Substances 0.000 claims description 8
• 239000005946 Cypermethrin Substances 0.000 claims description 8
• 150000001408 amides Chemical class 0.000 claims description 8
• 125000003277 amino group Chemical group 0.000 claims description 8
• OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 claims description 8
• CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 claims description 8
• 239000012141 concentrate Substances 0.000 claims description 8
• KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 8
• 229960005424 cypermethrin Drugs 0.000 claims description 8
• 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
• 229930195729 fatty acid Natural products 0.000 claims description 8
• 150000004665 fatty acids Chemical class 0.000 claims description 8
• 229920000570 polyether Polymers 0.000 claims description 8
• 229920002554 vinyl polymer Polymers 0.000 claims description 8
• 239000005907 Indoxacarb Substances 0.000 claims description 7
• VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 claims description 7
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
• ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 claims description 6
• FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 claims description 6
• 229910019142 PO4 Inorganic materials 0.000 claims description 6
• QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 6
• 229940024113 allethrin Drugs 0.000 claims description 6
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 6
• 229960001591 cyfluthrin Drugs 0.000 claims description 6
• QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 claims description 6
• 150000002191 fatty alcohols Chemical class 0.000 claims description 6
• 235000021317 phosphate Nutrition 0.000 claims description 6
• 229920001567 vinyl ester resin Polymers 0.000 claims description 6
• 241000257303 Hymenoptera Species 0.000 claims description 5
• 150000001336 alkenes Chemical class 0.000 claims description 5
• RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 claims description 5
• RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 claims description 5
• 229960000490 permethrin Drugs 0.000 claims description 5
• NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 claims description 5
• 239000005884 Beta-Cyfluthrin Substances 0.000 claims description 4
• QQODLKZGRKWIFG-RUTXASTPSA-N [(R)-cyano-(4-fluoro-3-phenoxyphenyl)methyl] (1S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)Cl)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-RUTXASTPSA-N 0.000 claims description 4
• 239000003945 anionic surfactant Substances 0.000 claims description 4
• 239000012188 paraffin wax Substances 0.000 claims description 4
• 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 4
• 239000004550 soluble concentrate Substances 0.000 claims description 4
• 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 3
• QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
• 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 claims description 3
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
• 239000005977 Ethylene Substances 0.000 claims description 3
• 239000005906 Imidacloprid Substances 0.000 claims description 3
• 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
• 235000021536 Sugar beet Nutrition 0.000 claims description 3
• 150000003863 ammonium salts Chemical class 0.000 claims description 3
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
• 150000002334 glycols Chemical class 0.000 claims description 3
• 229940056881 imidacloprid Drugs 0.000 claims description 3
• YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims description 3
• 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 3
• 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
• ORJDWQVKIMZEMX-UHFFFAOYSA-N (2-nonylphenyl) hydrogen sulfate Chemical compound CCCCCCCCCC1=CC=CC=C1OS(O)(=O)=O ORJDWQVKIMZEMX-UHFFFAOYSA-N 0.000 claims description 2
• IQVNEKKDSLOHHK-FNCQTZNRSA-N (E,E)-hydramethylnon Chemical compound N1CC(C)(C)CNC1=NN=C(/C=C/C=1C=CC(=CC=1)C(F)(F)F)\C=C\C1=CC=C(C(F)(F)F)C=C1 IQVNEKKDSLOHHK-FNCQTZNRSA-N 0.000 claims description 2
• JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 claims description 2
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
• 150000001242 acetic acid derivatives Chemical class 0.000 claims description 2
• 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
• 239000003599 detergent Substances 0.000 claims description 2
• 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
• 238000005187 foaming Methods 0.000 claims description 2
• 235000021588 free fatty acids Nutrition 0.000 claims description 2
• 239000002480 mineral oil Substances 0.000 claims description 2
• 235000010446 mineral oil Nutrition 0.000 claims description 2
• 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 2
• 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 2
• 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
• 239000004546 suspension concentrate Substances 0.000 claims description 2
• ZCVAOQKBXKSDMS-PVAVHDDUSA-N (+)-trans-(S)-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-PVAVHDDUSA-N 0.000 claims 2
• 239000005874 Bifenthrin Substances 0.000 claims 2
• 239000005898 Fenoxycarb Substances 0.000 claims 2
• 239000005927 Pyriproxyfen Substances 0.000 claims 2
• 239000005937 Tebufenozide Substances 0.000 claims 2
• 229960001901 bioallethrin Drugs 0.000 claims 2
• QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 claims 2
• 239000005886 Chlorantraniliprole Substances 0.000 claims 1
• 125000005907 alkyl ester group Chemical group 0.000 claims 1
• 125000005336 allyloxy group Chemical group 0.000 claims 1
• PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims 1
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
• ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims 1
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• 239000004615 ingredient Substances 0.000 abstract 1
• 239000000047 product Substances 0.000 description 59
• 238000006243 chemical reaction Methods 0.000 description 55
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 42
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 30
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• 150000001875 compounds Chemical class 0.000 description 27
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• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 26
• 238000002360 preparation method Methods 0.000 description 25
• BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 22
• PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 21
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 20
• 239000000243 solution Substances 0.000 description 20
• 239000000463 material Substances 0.000 description 19
• 125000004432 carbon atom Chemical group C* 0.000 description 18
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• 238000011068 loading method Methods 0.000 description 17
• 239000011541 reaction mixture Substances 0.000 description 17
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 16
• 239000003054 catalyst Substances 0.000 description 16
• 239000007859 condensation product Substances 0.000 description 16
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• 229910052757 nitrogen Inorganic materials 0.000 description 15
• FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 14
• DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 13
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• YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical class ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 13
• 125000002947 alkylene group Chemical group 0.000 description 13
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
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• 238000006068 polycondensation reaction Methods 0.000 description 12
• OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 11
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• 239000005914 Metaflumizone Substances 0.000 description 10
• MIFOMMKAVSCNKQ-HWIUFGAZSA-N Metaflumizone Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)N\N=C(C=1C=C(C=CC=1)C(F)(F)F)\CC1=CC=C(C#N)C=C1 MIFOMMKAVSCNKQ-HWIUFGAZSA-N 0.000 description 10
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• WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 9
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• 125000005442 diisocyanate group Chemical group 0.000 description 9
• 238000007306 functionalization reaction Methods 0.000 description 9
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• NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
• MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 8
• 238000004821 distillation Methods 0.000 description 8
• 229920001519 homopolymer Polymers 0.000 description 8
• 239000003999 initiator Substances 0.000 description 8
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• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
• 150000001412 amines Chemical class 0.000 description 7
• 125000005587 carbonate group Chemical group 0.000 description 7
• 238000001816 cooling Methods 0.000 description 7
• 125000000524 functional group Chemical group 0.000 description 7
• 238000006116 polymerization reaction Methods 0.000 description 7
• 235000011118 potassium hydroxide Nutrition 0.000 description 7
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• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
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• MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
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• XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 6
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