EA013086B1 - Способ получения оксидов олефинов и пероксидов, реактор и его применение - Google Patents
Способ получения оксидов олефинов и пероксидов, реактор и его применение Download PDFInfo
- Publication number
- EA013086B1 EA013086B1 EA200700873A EA200700873A EA013086B1 EA 013086 B1 EA013086 B1 EA 013086B1 EA 200700873 A EA200700873 A EA 200700873A EA 200700873 A EA200700873 A EA 200700873A EA 013086 B1 EA013086 B1 EA 013086B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- catalyst
- reactor
- reaction
- reaction zone
- oxide
- Prior art date
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- 150000001336 alkenes Chemical class 0.000 title claims description 27
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 14
- 150000002978 peroxides Chemical class 0.000 title description 11
- 238000004519 manufacturing process Methods 0.000 title description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 85
- -1 peroxide compounds Chemical class 0.000 claims abstract description 35
- 238000000034 method Methods 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 10
- 239000003054 catalyst Substances 0.000 claims description 58
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 34
- 238000006735 epoxidation reaction Methods 0.000 claims description 24
- 239000007789 gas Substances 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 16
- 229910052719 titanium Inorganic materials 0.000 claims description 15
- 239000010936 titanium Substances 0.000 claims description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 14
- 239000011521 glass Substances 0.000 claims description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 210000003298 dental enamel Anatomy 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 229910001936 tantalum oxide Inorganic materials 0.000 claims description 8
- 239000011787 zinc oxide Substances 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 6
- 238000012546 transfer Methods 0.000 claims description 6
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000002808 molecular sieve Substances 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 239000007769 metal material Substances 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052711 selenium Inorganic materials 0.000 claims description 2
- 239000011669 selenium Substances 0.000 claims description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 1
- 150000002902 organometallic compounds Chemical class 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 125000006850 spacer group Chemical group 0.000 claims 1
- 150000003609 titanium compounds Chemical class 0.000 claims 1
- 150000003658 tungsten compounds Chemical class 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 abstract description 3
- 239000012071 phase Substances 0.000 description 19
- 230000003197 catalytic effect Effects 0.000 description 8
- 239000007800 oxidant agent Substances 0.000 description 7
- 238000005192 partition Methods 0.000 description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 6
- 238000010574 gas phase reaction Methods 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
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- 238000001704 evaporation Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KSFOVUSSGSKXFI-GAQDCDSVSA-N CC1=C/2NC(\C=C3/N=C(/C=C4\N\C(=C/C5=N/C(=C\2)/C(C=C)=C5C)C(C=C)=C4C)C(C)=C3CCC(O)=O)=C1CCC(O)=O Chemical compound CC1=C/2NC(\C=C3/N=C(/C=C4\N\C(=C/C5=N/C(=C\2)/C(C=C)=C5C)C(C=C)=C4C)C(C)=C3CCC(O)=O)=C1CCC(O)=O KSFOVUSSGSKXFI-GAQDCDSVSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229950003776 protoporphyrin Drugs 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000218645 Cedrus Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- GXBYFVGCMPJVJX-UHFFFAOYSA-N Epoxybutene Chemical class C=CC1CO1 GXBYFVGCMPJVJX-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- GNKTZDSRQHMHLZ-UHFFFAOYSA-N [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] Chemical compound [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] GNKTZDSRQHMHLZ-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004836 hexamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/249—Plate-type reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00783—Laminate assemblies, i.e. the reactor comprising a stack of plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00819—Materials of construction
- B01J2219/00835—Comprising catalytically active material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00873—Heat exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00891—Feeding or evacuation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2451—Geometry of the reactor
- B01J2219/2453—Plates arranged in parallel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2461—Heat exchange aspects
- B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2469—Feeding means
- B01J2219/247—Feeding means for the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2476—Construction materials
- B01J2219/2477—Construction materials of the catalysts
- B01J2219/2479—Catalysts coated on the surface of plates or inserts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004050506A DE102004050506A1 (de) | 2004-10-15 | 2004-10-15 | Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung |
| PCT/EP2005/009965 WO2006042598A1 (de) | 2004-10-15 | 2005-09-16 | Verfahren zur herstellung von olefinoxiden und peroxiden, reaktor und dessen verwendung |
Publications (2)
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| EA200700873A1 EA200700873A1 (ru) | 2007-08-31 |
| EA013086B1 true EA013086B1 (ru) | 2010-02-26 |
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| EA200700873A EA013086B1 (ru) | 2004-10-15 | 2005-09-16 | Способ получения оксидов олефинов и пероксидов, реактор и его применение |
Country Status (17)
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| US (1) | US20080306288A1 (enExample) |
| EP (1) | EP1802596A1 (enExample) |
| JP (1) | JP2008516900A (enExample) |
| KR (1) | KR20070063004A (enExample) |
| CN (1) | CN101044129A (enExample) |
| AU (1) | AU2005297530A1 (enExample) |
| BR (1) | BRPI0516517A (enExample) |
| CA (1) | CA2584049A1 (enExample) |
| DE (1) | DE102004050506A1 (enExample) |
| EA (1) | EA013086B1 (enExample) |
| EG (1) | EG24502A (enExample) |
| HR (1) | HRP20070150A2 (enExample) |
| MX (1) | MX2007004501A (enExample) |
| NO (1) | NO20072459L (enExample) |
| NZ (1) | NZ554394A (enExample) |
| WO (1) | WO2006042598A1 (enExample) |
| ZA (1) | ZA200702469B (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7750170B2 (en) | 2005-12-22 | 2010-07-06 | Shell Oil Company | Process for mixing an oxidant having explosive potential with a hydrocarbon |
| BE1017793A3 (fr) * | 2005-12-22 | 2009-07-07 | Shell Int Research | Procede de preparation d'un oxyde d'olefine ou d'un produit chimique pouvant provenir d'un oxyde d'olefine. |
| US7459589B2 (en) | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
| JP5163921B2 (ja) * | 2006-03-01 | 2013-03-13 | 荒川化学工業株式会社 | エポキシ化合物の製造方法 |
| DE202006020415U1 (de) | 2006-04-01 | 2008-07-03 | Cognis Ip Management Gmbh | Verwendung von Mikroreaktionssystemen |
| CN101279957B (zh) * | 2007-04-04 | 2012-07-04 | 中国石油化工股份有限公司 | 丙烯环氧化制备环氧丙烷的方法 |
| DE102009003466A1 (de) * | 2009-02-11 | 2010-08-19 | Karlsruher Institut für Technologie | Hexaalkylguanidiniumsalze |
| JP5757126B2 (ja) * | 2011-03-28 | 2015-07-29 | 日産化学工業株式会社 | フローリアクターを用いたシャープレス不斉エポキシ化反応 |
| US9481741B2 (en) | 2012-11-26 | 2016-11-01 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof |
| MY184843A (en) * | 2015-11-26 | 2021-04-26 | Evonik Operations Gmbh | Process for the epoxidation of an olefin |
| CN109999821B (zh) * | 2019-03-12 | 2021-11-16 | 内蒙古工业大学 | 一种表面处理的铝合金催化剂的制备及其应用 |
| CN112979587B (zh) * | 2019-12-12 | 2022-12-02 | 中国科学院大连化学物理研究所 | 一种微通道反应器合成环氧丙烷的方法 |
| EP3954743A1 (de) | 2020-08-12 | 2022-02-16 | Evonik Operations GmbH | Verwendung von siliziumdioxid zur verbesserung der leitfähigkeit von beschichtungen |
| CN113333029B (zh) * | 2021-06-29 | 2023-08-25 | 南京先进生物材料与过程装备研究院有限公司 | 金属改性bea与卟啉配位的复合催化剂及其在环己烯选择性环氧化反应中的应用 |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19841993A1 (de) * | 1998-09-04 | 2000-03-09 | Mannesmann Ag | Mikrostruktur-Reaktor |
| US20010021784A1 (en) * | 2000-01-21 | 2001-09-13 | Rudiger Schutte | Method of producing expoxides in the gaseous phase |
| US20020028164A1 (en) * | 2000-08-31 | 2002-03-07 | Rudiger Schutte | Process and device for carrying out reactions in reactor with slot-shaped reaction spaces |
| DE10111747A1 (de) * | 2000-09-12 | 2002-09-19 | Penth Bernd | Mikrorektor mit Katalyse |
| US20040034111A1 (en) * | 2002-08-15 | 2004-02-19 | Tonkovich Anna Lee | Process for conducting an equilibrium limited chemical reaction in a single stage process channel |
| EP1415706A1 (en) * | 2002-10-29 | 2004-05-06 | Corning Incorporated | Coated microstructure and method of manufacture |
| US20040105812A1 (en) * | 1999-08-17 | 2004-06-03 | Tonkovich Anna Lee Y. | Chemical reactor and method for gas phase reactant catalytic reactions |
| WO2004091771A1 (de) * | 2003-04-16 | 2004-10-28 | Uhde Gmbh | Mikroreaktor in plattenbauweise mit einem katalysator |
| US20040220434A1 (en) * | 2003-05-02 | 2004-11-04 | Brophy John H. | Process for converting a hydrocarbon to an oxygenate or a nitrile |
| US20040229752A1 (en) * | 2003-05-16 | 2004-11-18 | Long Richard Q. | Oxidation process using microchannel technology and novel catalyst useful in same |
| US20050163701A1 (en) * | 2004-01-27 | 2005-07-28 | Tonkovich Anna L. | Process for producing hydrogen peroxide using microchannel technology |
| EP1568412A1 (en) * | 1999-08-17 | 2005-08-31 | Battelle Memorial Institute | A chemical reactor and method for gas phase reactant catalytic reactions |
| WO2005105665A2 (en) * | 2004-04-27 | 2005-11-10 | Velocys, Inc. | Hydrogen peroxide production in microchannel reactors |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4374260A (en) * | 1976-08-30 | 1983-02-15 | Texaco Inc. | Ethylene oxide production |
| NL8502144A (nl) * | 1985-07-27 | 1987-02-16 | Stamicarbon | Katalysator en werkwijze voor de katalytische heterogene gasfaseoxidatie van alkenen en cycloalkenen volgens de wacker-route. |
| DE4241942A1 (de) * | 1992-12-11 | 1994-06-16 | Basf Ag | Verfahren zur Herstellung von 3,4-Epoxy-1-buten |
| DE69426907T2 (de) * | 1993-08-11 | 2001-09-27 | Mitsubishi Gas Chemical Co., Inc. | Titanosilikate Katalysatorteilchen |
| DE19731627A1 (de) * | 1997-07-23 | 1999-01-28 | Degussa | Granulate, enthaltend Titansilikalit-l |
| DE19748481C2 (de) * | 1997-11-03 | 2003-09-25 | Inst Mikrotechnik Mainz Gmbh | Statischer Mikrovermischer |
| DE10248599A1 (de) * | 2002-10-17 | 2004-04-29 | Degussa Ag | Verfahren zur Gewinnung einer gasförmigen Phase aus einem flüssigen Medium und Vorrichtung zu seiner Durchführung |
-
2004
- 2004-10-15 DE DE102004050506A patent/DE102004050506A1/de not_active Withdrawn
-
2005
- 2005-09-16 WO PCT/EP2005/009965 patent/WO2006042598A1/de not_active Ceased
- 2005-09-16 NZ NZ554394A patent/NZ554394A/en not_active IP Right Cessation
- 2005-09-16 AU AU2005297530A patent/AU2005297530A1/en not_active Abandoned
- 2005-09-16 EP EP05787485A patent/EP1802596A1/de not_active Withdrawn
- 2005-09-16 JP JP2007536014A patent/JP2008516900A/ja not_active Withdrawn
- 2005-09-16 MX MX2007004501A patent/MX2007004501A/es unknown
- 2005-09-16 KR KR1020077008549A patent/KR20070063004A/ko not_active Withdrawn
- 2005-09-16 CA CA002584049A patent/CA2584049A1/en not_active Abandoned
- 2005-09-16 BR BRPI0516517-2A patent/BRPI0516517A/pt not_active IP Right Cessation
- 2005-09-16 EA EA200700873A patent/EA013086B1/ru not_active IP Right Cessation
- 2005-09-16 US US11/665,357 patent/US20080306288A1/en not_active Abandoned
- 2005-09-16 CN CNA2005800349897A patent/CN101044129A/zh active Pending
- 2005-09-16 HR HR20070150A patent/HRP20070150A2/xx not_active Application Discontinuation
-
2007
- 2007-03-26 ZA ZA200702469A patent/ZA200702469B/xx unknown
- 2007-04-15 EG EGNA2007000378 patent/EG24502A/xx active
- 2007-05-14 NO NO20072459A patent/NO20072459L/no not_active Application Discontinuation
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19841993A1 (de) * | 1998-09-04 | 2000-03-09 | Mannesmann Ag | Mikrostruktur-Reaktor |
| EP1568412A1 (en) * | 1999-08-17 | 2005-08-31 | Battelle Memorial Institute | A chemical reactor and method for gas phase reactant catalytic reactions |
| US20040105812A1 (en) * | 1999-08-17 | 2004-06-03 | Tonkovich Anna Lee Y. | Chemical reactor and method for gas phase reactant catalytic reactions |
| US20010021784A1 (en) * | 2000-01-21 | 2001-09-13 | Rudiger Schutte | Method of producing expoxides in the gaseous phase |
| US20020028164A1 (en) * | 2000-08-31 | 2002-03-07 | Rudiger Schutte | Process and device for carrying out reactions in reactor with slot-shaped reaction spaces |
| WO2002018042A1 (en) * | 2000-08-31 | 2002-03-07 | Degussa Ag | Process and device for carrying out reactions in a reactor with slot-shaped reaction spaces |
| DE10111747A1 (de) * | 2000-09-12 | 2002-09-19 | Penth Bernd | Mikrorektor mit Katalyse |
| US20040034111A1 (en) * | 2002-08-15 | 2004-02-19 | Tonkovich Anna Lee | Process for conducting an equilibrium limited chemical reaction in a single stage process channel |
| EP1415706A1 (en) * | 2002-10-29 | 2004-05-06 | Corning Incorporated | Coated microstructure and method of manufacture |
| WO2004091771A1 (de) * | 2003-04-16 | 2004-10-28 | Uhde Gmbh | Mikroreaktor in plattenbauweise mit einem katalysator |
| US20040220434A1 (en) * | 2003-05-02 | 2004-11-04 | Brophy John H. | Process for converting a hydrocarbon to an oxygenate or a nitrile |
| US20040229752A1 (en) * | 2003-05-16 | 2004-11-18 | Long Richard Q. | Oxidation process using microchannel technology and novel catalyst useful in same |
| US20040228781A1 (en) * | 2003-05-16 | 2004-11-18 | Tonkovich Anna Lee | Microchannel with internal fin support for catalyst or sorption medium |
| US20050163701A1 (en) * | 2004-01-27 | 2005-07-28 | Tonkovich Anna L. | Process for producing hydrogen peroxide using microchannel technology |
| WO2005105665A2 (en) * | 2004-04-27 | 2005-11-10 | Velocys, Inc. | Hydrogen peroxide production in microchannel reactors |
| US20050265915A1 (en) * | 2004-04-27 | 2005-12-01 | Tonkovich Anna Lee Y | Hydrogen peroxide production in microchannel reactors |
Non-Patent Citations (5)
| Title |
|---|
| ANONYMOUS: "Neuer Schub für die Mikroverfahrenstechnik", PROCESS, MAGAZIN FÜR CHEMIE- UND PHARMATECHNIK, 'Online! September 2004 (2004-09), XP002359913, Retrieved from the Internet: URL:http://www.process.de/fachartikel/druc k/pr_fachartikel_druck_1555250.html> 'retrieved on 2005-12-15!, the whole document * |
| GAVRIILIDIS ET AL.: "1-Pentene epoxidation in catalytic microfabricated reactors", JOURNAL OF CATALYSIS, vol. 223, 25 April 2004 (2004-04-25), pages 241-249, XP004500266, the whole document * |
| SCHAUER UWE: "Mikro meets Makro oder vom Labor in den Pilotmaßstab" , INTERNET ARTICLE, 'Online! 21 June 2005 (2005-06-21), XP002360103, Retrieved from the Internet: URL:http://www.tu-chemnitz.de/chemie/tech/ aktuell.php> 'retrieved on 2005-12-15!, the whole document * |
| YUAN ET AL.: "Propylene epoxidation in a microreactor with electric heating", CATALYSIS TODAY, vol. 105, 2005, pages 544-550, XP002359644, the whole document * |
| ZAPF ET AL.: "Nanoporoese Katalystaorschichten für Anwendungen im Mikroreaktor", CHEMIE INGENIEUR TECHNIK, vol. 76, no. 5, 28 April 2004 (2004-04-28), pages 513-514, XP002359643, the whole document * |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2007004501A (es) | 2007-05-09 |
| EG24502A (en) | 2009-08-18 |
| DE102004050506A1 (de) | 2006-04-20 |
| NZ554394A (en) | 2009-10-30 |
| AU2005297530A1 (en) | 2006-04-27 |
| WO2006042598A1 (de) | 2006-04-27 |
| CN101044129A (zh) | 2007-09-26 |
| US20080306288A1 (en) | 2008-12-11 |
| ZA200702469B (en) | 2008-12-31 |
| HRP20070150A2 (hr) | 2007-08-31 |
| EP1802596A1 (de) | 2007-07-04 |
| CA2584049A1 (en) | 2006-04-27 |
| EA200700873A1 (ru) | 2007-08-31 |
| KR20070063004A (ko) | 2007-06-18 |
| BRPI0516517A (pt) | 2008-09-16 |
| NO20072459L (no) | 2007-06-29 |
| JP2008516900A (ja) | 2008-05-22 |
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