DK2865731T3 - Fremgangsmåde til Fischer-Tropsch-syntese og til anvendelse af udstødningsgas - Google Patents

Fremgangsmåde til Fischer-Tropsch-syntese og til anvendelse af udstødningsgas Download PDF

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DK2865731T3
DK2865731T3 DK13810561.4T DK13810561T DK2865731T3 DK 2865731 T3 DK2865731 T3 DK 2865731T3 DK 13810561 T DK13810561 T DK 13810561T DK 2865731 T3 DK2865731 T3 DK 2865731T3
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fischer
hydrogen
tropsch synthesis
methane
syngas
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DK13810561.4T
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Yilong Chen
Kan Song
Pingyu Kuai
Yanfeng Zhang
Jiaqi Jin
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Wuhan Kaidi Eng Tech Res Inst
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/40—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with water vapor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/108—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B01D2257/7025—Methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • Y02P20/156—Methane [CH4]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Claims (10)

1. Fremgangsmåde til forbedring af Fischer-Tropsch-syntese og genanvendelse af udstødningsgasser derfra, hvor råmaterialet af syngassen er biomasse, hvor fremgangsmåden omfatter: 1) at omdanne rågas til Fischer-Tropsch-syntese ved anvendelse af en vandgasproces, at transportere den omdannede rågas til en Fischer-Tropsch-synteseindretning til Fischer-Tropsch-syntese i nærvær af en Fe-baseret eller Co-baseret katalysator, at styre en reaktionstemperatur i Fischer-Tropsch-syntesen ved mellem 150° og 300°C og et reaktionstryk på mellem 2 og 4 Mpa (A), at opnå et flydende carbonhydridprodukt og vand, der ledes ud fra Fischer-Tropsch-synteseindretningen; 2) at indføre udstødningsgasser fra Fischer-Tropsch-synteseindretningen i en første pressure swing adsorptionsindretning til hydrogengenvinding og at styre en renhed af hydrogenen ved 80-99 vol-%; 3) at indføre udstødningsgasserne fra trin 2) i en anden pressure swing adsorptionsindretning til methangenvinding og at styre en renhed af metha-nen ved 80-95 vol-%; 4) at føre en del af hydrogenen opnået i trin 2) tilbage til trin 1) for blanding med rågassen og at omdanne en resulterende blandet gas for at justere et hydrogen/carbonforhold af rågassen til Fischer-Tropsch-syntesen; og 5) at indføre methanen i trin 3) i en methanomdannelsesindretning til omdannelse for at opnå syngas med højt hydrogen/carbonforhold, at transportere syngassen til trin 1) til blanding med rågassen og at omdanne en resulterende blandet gas for at justere et hydrogen/carbonforhold af rågassen.
2. Fremgangsmåde ifølge krav 1, kendetegnet ved, at 30-60 vol.-% af den genanvendte hydrogen i trin 2) føres tilbage til trin 1) for at justere hydrogen/car- bonforholdet af rågassen, 2-8 vol.-% af den genanvendte hydrogen i trin 2) anvendes til at aktivere og reducere katalysatoren, og resthydrogenen anvendes til at behandle det flydende carbonhydridprodukt.
3. Fremgangsmåde ifølge krav 1 eller 2, kendetegnet ved, at udstødningsgasserne befriet for metan i trin 3) indføres i en carbonhydridomdannelsesindretning for at fungere som et brændstof eller anvendes direkte til forbrænding for at levere varme eller for at frembringe strøm.
4. Fremgangsmåde ifølge krav 1 eller 2, kendetegnet ved, at i trin 2) er renheden af hydrogenen 85-95 vol.-%.
5. Fremgangsmåde ifølge krav 1 eller 2, kendetegnet ved, at i trin 3) er renheden af methanen 90-95 vol.-%.
6. Fremgangsmåde ifølge krav 1 eller 2, kendetegnet ved, at i trin 5) er et volumenforhold mellem hydrogen og carbonmonoxid i syngassen efter en methanomdannelsesreaktion mellem 2 og 5.
7. Fremgangsmåde ifølge krav 1 eller 2, kendetegnet ved, at i trin 5) er et volumenforhold mellem hydrogen og carbonmonoxid i syngassen efter en methanomdannelsesreaktion mellem 3 og 4.
8. Fremgangsmåde ifølge krav 4, kendetegnet ved, at i trin 3) ligger renheden af methanen ved 90-95 vol.-%.
9. Fremgangsmåde ifølge krav 4, kendetegnet ved, at i trin 5) er et volumenforhold mellem hydrogen og carbonmonoxid i syngassen efter en methanomdannelsesreaktion mellem 3 og 4.
10. Fremgangsmåde ifølge krav 5, kendetegnet ved, at i trin 5) er et volumenforhold mellem hydrogen og carbonmonoxid i syngassen efter en methanomdan-nelsesreaktion mellem 3 og 4.
DK13810561.4T 2012-06-26 2013-04-25 Fremgangsmåde til Fischer-Tropsch-syntese og til anvendelse af udstødningsgas DK2865731T3 (da)

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CN201210213566.3A CN102703108B (zh) 2012-06-26 2012-06-26 一种费托合成及尾气利用的工艺方法
PCT/CN2013/074719 WO2014000502A1 (zh) 2012-06-26 2013-04-25 一种费托合成及尾气利用的工艺方法

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EP (1) EP2865731B1 (da)
JP (1) JP6040309B2 (da)
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EP2865731A1 (en) 2015-04-29
RU2015102091A (ru) 2016-08-10
US20150099813A1 (en) 2015-04-09
EP2865731A4 (en) 2016-03-09
EP2865731B1 (en) 2017-10-04
RU2594723C2 (ru) 2016-08-20
JP2015522674A (ja) 2015-08-06
JP6040309B2 (ja) 2016-12-07
WO2014000502A1 (zh) 2014-01-03
US9255226B2 (en) 2016-02-09
CN102703108A (zh) 2012-10-03
CN102703108B (zh) 2014-12-03

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