DK2408308T3 - Stabiliseret biocid sammensætning - Google Patents
Stabiliseret biocid sammensætning Download PDFInfo
- Publication number
- DK2408308T3 DK2408308T3 DK10702121.4T DK10702121T DK2408308T3 DK 2408308 T3 DK2408308 T3 DK 2408308T3 DK 10702121 T DK10702121 T DK 10702121T DK 2408308 T3 DK2408308 T3 DK 2408308T3
- Authority
- DK
- Denmark
- Prior art keywords
- phosphonium
- arsenic
- compound
- process according
- tetrakis
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 56
- 229910052785 arsenic Inorganic materials 0.000 claims description 49
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 49
- 150000001875 compounds Chemical class 0.000 claims description 45
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 24
- 229910052698 phosphorus Inorganic materials 0.000 claims description 24
- 239000011574 phosphorus Substances 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 23
- 230000000087 stabilizing effect Effects 0.000 claims description 21
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 18
- -1 phosphonium compound Chemical class 0.000 claims description 17
- 239000012535 impurity Substances 0.000 claims description 11
- 150000003863 ammonium salts Chemical class 0.000 claims description 10
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 9
- 229920001184 polypeptide Polymers 0.000 claims description 9
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- 229940024606 amino acid Drugs 0.000 claims description 8
- 235000001014 amino acid Nutrition 0.000 claims description 8
- 150000001413 amino acids Chemical class 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 8
- 150000004714 phosphonium salts Chemical class 0.000 claims description 7
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 6
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004471 Glycine Substances 0.000 claims description 4
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical group [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 claims description 4
- RWSXRVCMGQZWBV-WDSKDSINSA-N glutathione Chemical compound OC(=O)[C@@H](N)CCC(=O)N[C@@H](CS)C(=O)NCC(O)=O RWSXRVCMGQZWBV-WDSKDSINSA-N 0.000 claims description 4
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 claims description 4
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 4
- 150000003003 phosphines Chemical class 0.000 claims description 4
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical group [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical group [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Chemical group 0.000 claims description 3
- YTVQIZRDLKWECQ-UHFFFAOYSA-N 2-benzoylcyclohexan-1-one Chemical compound C=1C=CC=CC=1C(=O)C1CCCCC1=O YTVQIZRDLKWECQ-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 108010011485 Aspartame Proteins 0.000 claims description 2
- YPWSLBHSMIKTPR-UHFFFAOYSA-N Cystathionine Natural products OC(=O)C(N)CCSSCC(N)C(O)=O YPWSLBHSMIKTPR-UHFFFAOYSA-N 0.000 claims description 2
- ILRYLPWNYFXEMH-UHFFFAOYSA-N D-cystathionine Natural products OC(=O)C(N)CCSCC(N)C(O)=O ILRYLPWNYFXEMH-UHFFFAOYSA-N 0.000 claims description 2
- 108010024636 Glutathione Proteins 0.000 claims description 2
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- ILRYLPWNYFXEMH-WHFBIAKZSA-N L-cystathionine Chemical compound [O-]C(=O)[C@@H]([NH3+])CCSC[C@H]([NH3+])C([O-])=O ILRYLPWNYFXEMH-WHFBIAKZSA-N 0.000 claims description 2
- LEVWYRKDKASIDU-IMJSIDKUSA-N L-cystine Chemical compound [O-]C(=O)[C@@H]([NH3+])CSSC[C@H]([NH3+])C([O-])=O LEVWYRKDKASIDU-IMJSIDKUSA-N 0.000 claims description 2
- AGPKZVBTJJNPAG-WHFBIAKZSA-N L-isoleucine Chemical compound CC[C@H](C)[C@H](N)C(O)=O AGPKZVBTJJNPAG-WHFBIAKZSA-N 0.000 claims description 2
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- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 claims description 2
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 claims description 2
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 claims description 2
- ROHFNLRQFUQHCH-UHFFFAOYSA-N Leucine Natural products CC(C)CC(N)C(O)=O ROHFNLRQFUQHCH-UHFFFAOYSA-N 0.000 claims description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004472 Lysine Substances 0.000 claims description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical group OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 2
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 claims description 2
- 108010077895 Sarcosine Proteins 0.000 claims description 2
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 claims description 2
- 235000004279 alanine Nutrition 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 150000001450 anions Chemical group 0.000 claims description 2
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 claims description 2
- 239000000605 aspartame Substances 0.000 claims description 2
- 229960003438 aspartame Drugs 0.000 claims description 2
- 235000010357 aspartame Nutrition 0.000 claims description 2
- 229940000635 beta-alanine Drugs 0.000 claims description 2
- 229960003067 cystine Drugs 0.000 claims description 2
- 229960003180 glutathione Drugs 0.000 claims description 2
- 229960000310 isoleucine Drugs 0.000 claims description 2
- AGPKZVBTJJNPAG-UHFFFAOYSA-N isoleucine Natural products CCC(C)C(N)C(O)=O AGPKZVBTJJNPAG-UHFFFAOYSA-N 0.000 claims description 2
- 229930182817 methionine Natural products 0.000 claims description 2
- 229940043230 sarcosine Drugs 0.000 claims description 2
- FAUOSXUSCVJWAY-UHFFFAOYSA-N tetrakis(hydroxymethyl)phosphanium Chemical class OC[P+](CO)(CO)CO FAUOSXUSCVJWAY-UHFFFAOYSA-N 0.000 claims description 2
- VELJAQNIUXJKSV-UHFFFAOYSA-M tetrakis(hydroxymethyl)phosphanium;acetate Chemical compound CC([O-])=O.OC[P+](CO)(CO)CO VELJAQNIUXJKSV-UHFFFAOYSA-M 0.000 claims description 2
- XAAGVNUUSJZVIC-UHFFFAOYSA-M tetrakis(hydroxymethyl)phosphanium;bromide Chemical compound [Br-].OC[P+](CO)(CO)CO XAAGVNUUSJZVIC-UHFFFAOYSA-M 0.000 claims description 2
- ZTBDCHNXDHUMCJ-UHFFFAOYSA-K tetrakis(hydroxymethyl)phosphanium;phosphate Chemical compound [O-]P([O-])([O-])=O.OC[P+](CO)(CO)CO.OC[P+](CO)(CO)CO.OC[P+](CO)(CO)CO ZTBDCHNXDHUMCJ-UHFFFAOYSA-K 0.000 claims description 2
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 claims description 2
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- 239000003139 biocide Substances 0.000 description 3
- JMXMXKRNIYCNRV-UHFFFAOYSA-N bis(hydroxymethyl)phosphanylmethanol Chemical compound OCP(CO)CO JMXMXKRNIYCNRV-UHFFFAOYSA-N 0.000 description 3
- 239000000498 cooling water Substances 0.000 description 3
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- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
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- YIEDHPBKGZGLIK-UHFFFAOYSA-L tetrakis(hydroxymethyl)phosphanium;sulfate Chemical compound [O-]S([O-])(=O)=O.OC[P+](CO)(CO)CO.OC[P+](CO)(CO)CO YIEDHPBKGZGLIK-UHFFFAOYSA-L 0.000 description 2
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- 150000001412 amines Chemical class 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
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- ZYNUSOWWGMTZHH-UHFFFAOYSA-L oxalate;tetrakis(hydroxymethyl)phosphanium Chemical compound [O-]C(=O)C([O-])=O.OC[P+](CO)(CO)CO.OC[P+](CO)(CO)CO ZYNUSOWWGMTZHH-UHFFFAOYSA-L 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/34—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-halogen bonds; Phosphonium salts
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
- C02F2103/365—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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- Dentistry (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Toxicology (AREA)
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Claims (12)
1. Fremgangsmåde til forebyggelse eller minimering af fældning af arsen eller arsenbaserede forbindelser som urenhed i en vandig sammensætning med en phosphorholdig forbindelse, hvor den phosphorholdige forbindelse er en phosphoniumforbindelse eller en alkylsubstitueret phosphin med arsen som urenhed, som omfatter trinet tilsætning til sammensætningen af en effektiv arsenstabiliserende mængde af en forbindelse udvalgt fra gruppen, der består af ammoniak, ammoniumsalt, organisk aminosyre, peptid og polypeptid, hvor den effektive arsenstabiliserende mængde er en koncentration på mellem 40 og 10.000 ppm i den vandige sammensætning.
2. Fremgangsmåde ifølge krav 1, hvor den phosphorholdige forbindelse er et tetrakis(hydroxyorgano)-phosphoniumsalt eller en tetrakis(hydroxyorgano)-phosphoniumforbindelse med formel (I) [R' R" (CH2OH) 2P+] η X- (I) hvor: n er valensen af X; R' og R", der kan være ens eller forskellige, er udvalgt blandt en alkyl-, hydroxyalkyl-, alkenyl- eller aryldel, og X er en anion.
3. Fremgangsmåde ifølge krav 1 eller 2, hvor i formel (I) R' og R" har mellem 1 og 20 carbonatomer, og X er udvalgt fra gruppen, der består af chlorid, sulfat, phosphat, acetat, oxalat og bromid.
4. Fremgangsmåde ifølge et hvilket som helst af ovennævnte krav, hvor phosphoniumforbindelsen er et tetrakis(hydroxymethyl)-phosphoniumsalt.
5. Fremgangsmåde ifølge et hvilket som helst af ovennævnte krav, hvor phosphoniumforbindelsen er tetrakis(hydroxymethyl)-phosphoniumchlorid, tetrakis(hydroxymethyl)-phosphoniumbromid, tetrakis(hydroxymethyl)-phosphoniumphosphat, tetrakis(hydroxymethyl)-phosphoniumacetat, tetrakis(hydroxymethyl)-phosphoniumoxalat eller tetrakis(hydroxymethyl)-phosphoniumsulfat.
6. Fremgangsmåde ifølge et hvilket som helst af ovennævnte krav, hvor phosphoniumforbindelsen har en vægtkoncentration i den vandige sammensætning, der stabiliseres ved mellem 5 og 75 %.
7. Fremgangsmåde ifølge et hvilket som helst af ovennævnte krav, hvor den vandige sammensætning med den phosphorholdige forbindelse har en vægtkoncentration af arsen på mellem 1 og 100 ppm.
8. Fremgangsmåde ifølge et hvilket som helst af ovennævnte krav, hvor vægtkoncentrationen af phosphoniumforbindelsen i den vandige sammensætning stabiliseres ved mellem 5 og 75 %.
9. Fremgangsmåde ifølge et hvilket som helst af ovennævnte krav, hvor den effektive arsenstabiliserende forbindelse er udvalgt fra gruppen, der består af ammoniak, ammoniumsalt, organisk aminosyre, peptid og polypeptid og er til stede ved en koncentration på mellem 75 og 5.000 ppm i den vandige sammensætning.
10. Fremgangsmåde ifølge et hvilket som helst af ovennævnte krav, der yderligere omfatter trinet justering af pH i den vandige sammensætning, så den stabiliseres ved en værdi under 7 før tilsætning af den arsenstabiliserende forbindelse til sammensætningen.
11. Fremgangsmåde ifølge et hvilket som helst af ovennævnte krav, hvor den arsenstabiliserende forbindelse er ammoniumchlorid, ammoniumbromid, alanin, beta-alanin, cystathionin, cystin, histidin, glycin, leucin, isoleucin, histidin, lysin, methionin, prolin, sarcosin, serin, tyronin, tyrosin, valin, glutathion, aspartam eller alitam.
12. Fremgangsmåde ifølge et hvilket som helst af ovennævnte krav, hvor den arsenstabiliserende forbindelse er glycin.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16054009P | 2009-03-16 | 2009-03-16 | |
| PCT/EP2010/051194 WO2010105872A2 (en) | 2009-03-16 | 2010-02-01 | Stabilized biocidal composition |
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| Publication Number | Publication Date |
|---|---|
| DK2408308T3 true DK2408308T3 (da) | 2017-08-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK10702121.4T DK2408308T3 (da) | 2009-03-16 | 2010-02-01 | Stabiliseret biocid sammensætning |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US9090494B2 (da) |
| EP (1) | EP2408308B1 (da) |
| JP (1) | JP2012520336A (da) |
| KR (1) | KR20110132377A (da) |
| CN (1) | CN102368907B (da) |
| AR (1) | AR075823A1 (da) |
| AU (1) | AU2010225088B2 (da) |
| BR (1) | BRPI1009402B1 (da) |
| CA (1) | CA2754126C (da) |
| CO (1) | CO6450671A2 (da) |
| DK (1) | DK2408308T3 (da) |
| EC (1) | ECSP11011351A (da) |
| MX (1) | MX2011009607A (da) |
| MY (1) | MY157152A (da) |
| RU (1) | RU2522137C2 (da) |
| UA (1) | UA106606C2 (da) |
| WO (1) | WO2010105872A2 (da) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| MX2012012089A (es) * | 2010-04-28 | 2012-11-29 | Alcon Res Ltd | Composiciones farmaceuticas con agentes antimicrobianos de fosfonio. |
| NZ591490A (en) * | 2010-09-30 | 2014-10-31 | Amsa Inc | Formulations for use in sulfur scale control in industrial water systems |
| PL2684598T3 (pl) * | 2011-03-09 | 2019-09-30 | Kurita Water Industries Ltd. | Sposób poprawiania współczynnika zatrzymania membrany do odwróconej osmozy oraz zastosowanie środka do obróbki do poprawiania współczynnika zatrzymania membrany do odwróconej osmozy |
| JP5914973B2 (ja) * | 2011-03-09 | 2016-05-11 | 栗田工業株式会社 | 透過膜の阻止率向上方法及び阻止率向上処理剤 |
| DK2758347T3 (da) * | 2011-09-23 | 2017-03-27 | Lonza Ag | Fremgangsmåde til fjernelse af hydrogensulfid fra industriprocesfluider |
| BR112014015253A2 (pt) * | 2011-12-21 | 2017-08-22 | Shell Internationale Res Maaschappij B V | Método para inibir a formação de espuma em uma mistura, composição, e, mistura inibida com espuma |
| CA2880283C (en) | 2012-08-21 | 2020-07-21 | Lonza, Inc. | Method of scavenging hydrogen sulfide and/or sulfhydryl compounds |
| EP3353117B1 (en) | 2015-09-23 | 2021-03-24 | Saudi Arabian Oil Company | Removal of kinetic hydrate inhibitors |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2768997A (en) * | 1956-10-30 | Phosphorus-containing polypeptides | ||
| US3734861A (en) * | 1970-07-13 | 1973-05-22 | Hooker Chemical Corp | Synergistic metal sequestrant |
| DE2647863A1 (de) * | 1975-11-07 | 1977-05-12 | American Cyanamid Co | Waessrige loesungen von tetrakis(hydroxymethyl)-phosphoniumsalzen |
| US4147757A (en) * | 1976-12-13 | 1979-04-03 | Olin Corporation | Method for producing ammonium phosphate which is substantially free of arsenic |
| RU2143889C1 (ru) * | 1993-02-23 | 2000-01-10 | Генентек, Инк. | Способ стабилизации полипептида, способы получения композиций полипептида и композиции |
| ATE226393T1 (de) * | 1997-12-23 | 2002-11-15 | Rhodia Cons Spec Ltd | Biozide zusammemsetzungen und behandlungen |
| US6146610A (en) * | 1998-06-05 | 2000-11-14 | Fmc Corporation | Process for removal of arsenic from elemental phosphorus |
| AU6217499A (en) * | 1998-10-14 | 2000-05-01 | Albright & Wilson Uk Limited | Leaching divalent metal salts |
| CN1247835A (zh) * | 1999-09-21 | 2000-03-22 | 重庆理想科技有限公司 | 一种含砷黄磷的脱砷方法及分级处理的方法 |
| JP2004501166A (ja) * | 2000-06-16 | 2004-01-15 | ハーキュリーズ・インコーポレーテッド | 化学修飾ペプチド、組成物、並びに製造方法および使用 |
| GB0017675D0 (en) * | 2000-07-20 | 2000-09-06 | Rhodia Cons Spec Ltd | Treatment of iron sulphide deposits |
| EP1423491A4 (en) * | 2001-08-15 | 2011-11-02 | Mamre Llc | PROCESS AND COMPOSITION FOR REDUCING IRON SULFIDE DEPOSITS IN PIPES |
| GB0306531D0 (en) * | 2003-03-21 | 2003-04-23 | Rhodia Cons Spec Ltd | Formulation for corrosion and scale inhibition |
| GB0321276D0 (en) * | 2003-09-11 | 2003-10-08 | Rhodia Consumer Specialities L | Treatment of iron sulphide deposits |
| WO2007038403A2 (en) * | 2005-09-22 | 2007-04-05 | Chem Technologies | Iron sulfide cleaning formulation and methods of use thereof |
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2010
- 2010-01-02 UA UAA201111013A patent/UA106606C2/uk unknown
- 2010-02-01 MY MYPI2011004344A patent/MY157152A/en unknown
- 2010-02-01 WO PCT/EP2010/051194 patent/WO2010105872A2/en active Application Filing
- 2010-02-01 BR BRPI1009402-4A patent/BRPI1009402B1/pt active IP Right Grant
- 2010-02-01 CN CN201080012502.6A patent/CN102368907B/zh active Active
- 2010-02-01 US US13/257,174 patent/US9090494B2/en active Active
- 2010-02-01 JP JP2012500162A patent/JP2012520336A/ja not_active Ceased
- 2010-02-01 MX MX2011009607A patent/MX2011009607A/es active IP Right Grant
- 2010-02-01 DK DK10702121.4T patent/DK2408308T3/da active
- 2010-02-01 AU AU2010225088A patent/AU2010225088B2/en active Active
- 2010-02-01 EP EP10702121.4A patent/EP2408308B1/en active Active
- 2010-02-01 KR KR1020117021504A patent/KR20110132377A/ko not_active Application Discontinuation
- 2010-02-01 RU RU2011141868/13A patent/RU2522137C2/ru active
- 2010-02-01 CA CA2754126A patent/CA2754126C/en active Active
- 2010-03-12 AR ARP100100772A patent/AR075823A1/es active IP Right Grant
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2011
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- 2011-09-23 EC EC2011011351A patent/ECSP11011351A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2754126C (en) | 2017-08-08 |
| WO2010105872A2 (en) | 2010-09-23 |
| KR20110132377A (ko) | 2011-12-07 |
| MY157152A (en) | 2016-05-13 |
| EP2408308B1 (en) | 2017-04-26 |
| EP2408308A2 (en) | 2012-01-25 |
| ECSP11011351A (es) | 2011-11-30 |
| CA2754126A1 (en) | 2010-09-23 |
| CO6450671A2 (es) | 2012-05-31 |
| AR075823A1 (es) | 2011-04-27 |
| CN102368907B (zh) | 2016-03-23 |
| CN102368907A (zh) | 2012-03-07 |
| BRPI1009402A2 (pt) | 2017-05-16 |
| RU2522137C2 (ru) | 2014-07-10 |
| UA106606C2 (uk) | 2014-09-25 |
| RU2011141868A (ru) | 2013-04-27 |
| JP2012520336A (ja) | 2012-09-06 |
| US9090494B2 (en) | 2015-07-28 |
| AU2010225088A1 (en) | 2011-09-22 |
| WO2010105872A3 (en) | 2011-11-24 |
| BRPI1009402A8 (pt) | 2017-10-10 |
| AU2010225088B2 (en) | 2014-09-11 |
| MX2011009607A (es) | 2011-10-04 |
| US20120046248A1 (en) | 2012-02-23 |
| BRPI1009402B1 (pt) | 2018-02-06 |
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