CN102368907B - 稳定化的杀生物组合物 - Google Patents

稳定化的杀生物组合物 Download PDF

Info

Publication number
CN102368907B
CN102368907B CN201080012502.6A CN201080012502A CN102368907B CN 102368907 B CN102368907 B CN 102368907B CN 201080012502 A CN201080012502 A CN 201080012502A CN 102368907 B CN102368907 B CN 102368907B
Authority
CN
China
Prior art keywords
stabilisation
purposes
phosphonium
waterborne compositions
arsenic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201080012502.6A
Other languages
English (en)
Other versions
CN102368907A (zh
Inventor
C·琼斯
S·埃德蒙斯
A·菲洛斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Energy Solutions (USA) LLC
Original Assignee
Rhodia Operations SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Operations SAS filed Critical Rhodia Operations SAS
Publication of CN102368907A publication Critical patent/CN102368907A/zh
Application granted granted Critical
Publication of CN102368907B publication Critical patent/CN102368907B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/34—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-halogen bonds; Phosphonium salts
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • C02F2103/365—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/04—Disinfection
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Processing Of Meat And Fish (AREA)

Abstract

本发明涉及用于稳定化含磷化合物水性组合物的方法，包括向所述组合物中添加有效砷稳定化量的选自氨、铵盐、有机氨基酸、肽和多肽的化合物的步骤；应用该稳定化的组合物以用于处理任选地包含或接触金属硫化物污垢的水性体系，该方法包括向所述体系中分开地或一起地添加有效防污垢量的稳定化的水性组合物，或者用于处理水体系以杀死或抑制微生物的生长，包括向水体系中施用或者就地形成有效抑制量的稳定化的水性组合物。

Description

稳定化的杀生物组合物
技术领域
本发明涉及稳定化的杀生物组合物。更特别地，本发明涉及包含含磷化合物(尤其是 盐)的稳定化的杀生物组合物，制备这种含磷化合物尤其是三(羟甲基)膦的 盐的方法，及其用于处理水体系以杀死或抑制微生物的生长并且防止或减轻通常与金属硫化物如硫化铁的沉积物有关的问题的用途。
背景技术
因而已知的是，三(羟甲基)膦及其盐(在此统称为THP)能够通过形成有色的水溶性络合物来溶解硫化铁。基于THP的产品，尤其是硫酸盐类(THPS)，通常作为杀生物剂被添加到油井中。基于THP的产品在控制硫酸盐还原菌方面是高度有效的，该硫酸盐还原菌的活性可能是造成硫化铁沉积物初始形成的原因。
磷酸盐岩是在生产有机磷化合物时使用的主要磷源，并且典型地，磷酸盐岩包含杂质如砷。磷酸盐岩中的砷含量随地理位置不同而变化。在磷酸盐矿石中非常低的水平下，典型地在低于10ppm下，砷的存在不会引起下游配制的产品的“最终使用/应用(end-use/application)”问题或者任何工艺问题。取决于下游工艺，在成品磷化合物/产品中仍将存在可变量的砷。不过，在初始磷酸盐岩中较高含量的砷可被携带通过下游工艺，并且可导致产品的不稳定性和变色和/或沉淀。
正在成为磷矿石主要来源之一的中国来源的磷酸盐岩典型地包含20-60ppm的砷，并且在许多情况下，这足以导致无法接受的含磷水溶液的变色和/或成问题的包含单质砷或砷化合物的红/褐色固体的沉淀，这既是难看的也是商业上无法接受的。这类沉淀物会堵塞过滤器，在槽中堆积并且形成淤泥。在含磷化合物水性组合物中高于1ppm，典型地高于5ppm并且确定地高于15ppm砷的重量浓度可产生以上所述的问题，已知此重量浓度可能达到50ppm且甚至更高。
因而一直需要水性的稳定化的含磷化合物，更特别地是其中砷杂质已经被完全地或者部分地至少减轻或去除的组合物。
发明内容
本发明满足上述需要中的至少一种。
事实上，在进行了广泛的研究和开发工作之后，本申请人出人意料地发现并开发了一种解决方案，该解决方案能够防止或者至少最小化从水性的稳定化的 组合物的砷或砷基化合物的沉淀。
本发明涉及于稳定化含磷化合物(更特别地是 盐)水性组合物的方法，包括向所述组合物中添加有效砷稳定化量的选自氨、铵盐、有机氨基酸、肽(具有-CO-NH-单元的化合物)和多肽的化合物的步骤。
本发明还涉及稳定化的水性组合物，所述组合物包含含磷化合物，更特别地是包含砷的 盐，以及有效砷稳定化量的选自氨、铵盐、有机α-氨基酸、肽和多肽的化合物。
根据另一方面，本发明涉及用于处理水体系以杀死或抑制微生物生长的方法，包括向水体系中施用或者就地形成有效抑制量的本发明的稳定化的水性组合物。该水体系可以是例如油田采出水、注入水、钻井液或管道水压试验用水、造纸厂稀浆料或回水、工业处理或冷却水、地热或脱盐水或者供料流或者被消毒的表面。
根据又一方面，本发明涉及处理包含或接触金属硫化物污垢的水性体系的方法，该方法包括向所述体系中分开地或一起地添加有效防污垢量的本发明的稳定化的水性组合物，使所述污垢与所述水性组合物接触，由此将所述污垢的至少一部分溶解在所述水性组合物中并且将所述溶解的污垢从该体系中取出。
优选地，该含磷化合物是具有砷作为杂质的 化合物，尤其是四(羟基有机基) 盐或式(I)的化合物
[R′R″(CH2OH)2P+]n X- (I)
其中：
n为X的化合价；
R′和R″可以相同或不同，选自烷基、羟烷基、烯基或芳基结构部分(moiety)并且X为阴离子。
R′和R″优选具有1-20个碳原子。
X优选地选自氯根、硫酸根、磷酸根、醋酸根、草酸根和溴根。
最优选地，该 化合物为硫酸四(羟甲基) 以下称作THPS。一般而言，四(羟甲基) 盐在下文称作THP+。
可选地，该 化合物可例如是氯化四(羟甲基) 溴化四(羟甲基) 磷酸四(羟甲基) 醋酸四(羟甲基) 或草酸四(羟甲基)
可选地，该含磷化合物可以是烷基取代的膦，例如式(II)所示的三(羟甲基)膦：
(CH2OHR2)P (II)
其中：
每个R，可以相同或不同，选自优选具有1-20个碳原子的烷基、羟烷基、烯基或芳基结构部分。
典型地，该含磷化合物中的砷含量大于5ppm，这可导致在含磷化合物水性组合物中大于1ppm，典型地大于5ppm并且确定地大于15ppm的砷的重量浓度，并且可达到50ppm且甚至更高，正如前面所述的。平均地，包含含磷化合物的水性组合物具有1-100ppm的砷重量浓度，更特别地为5-50ppm，并且甚至更多。
典型地，要稳定化的水性组合物中的 化合物的重量浓度为5-75，优选15-70。
选自氨、铵盐、有机氨基酸、肽(具有-CO-NH-单元的化合物)和多肽的化合物的有效砷稳定化量通常为在所述水性组合物中40-10,000ppm，优选75-5000ppm，最优选100-1000ppm的砷稳定化化合物的浓度。
推荐使用稀无机酸(例如硫酸、磷酸、硝酸或氢卤酸)或有机酸(例如甲酸或乙酸)调节要稳定化的水性组合物的pH值至低于7的值，并且优选6-3的值。然后，将该砷稳定化化合物添加到所述组合物中。
作为铵盐，推荐使用氯化铵或溴化铵。
作为有机氨基酸，推荐使用丙氨酸、β-丙氨酸、胱硫醚、胱氨酸、组氨酸、甘氨酸、亮氨酸、异亮氨酸、组氨酸、赖氨酸、甲硫氨酸、脯氨酸、肌氨酸、丝氨酸、甲状腺原氨酸、酪氨酸和缬氨酸。
作为肽和多肽，推荐使用谷胱甘肽、阿斯巴甜和阿力甜。
本发明还涉及通过本发明方法的稳定化的水性组合物，包含含磷化合物，更特别地是包含砷的 盐，以及有效砷稳定化量的选自氨、铵盐、有机α-氨基酸、肽和多肽的化合物。
本发明的稳定化的水性组合物没有显示任何砷沉淀并且在例如以1000ppm浓度的甘氨酸稳定时在存储时稳定数月，甚至超过6个月。
本发明的稳定化的水性组合物可用于处理被微生物污染或者易于被微生物污染的需氧或厌氧水体系。例如，它们对成问题的生物体例如油田水体系、冷却水体系、工业处理水、纸处理体系、地热水、集中供热和空调体系中的普通异养菌有效，可用于控制工业水体系、湖、河流、沟渠和水库中的藻类，并且可用于处理发电站中的冷却水并可用于船用发动机。该稳定化的水性组合物特别可用于杀死上述体系中的硫酸盐还原菌，并且尤其是在油田采出水、注入水、钻井液或水压试验用水中的硫酸盐还原菌。它们还可用作水性基配制剂中的防腐剂，所述水性基配制剂例如是沥青和焦油乳液、纸张施胶剂、粘合剂、油漆、纤维素纸浆，包括纸浆稀浆料，以及反洗再循环液。该稳定化的水性组合物可用在消毒剂中，所述消毒剂包括农场、家用和外科消毒剂。它们可被用在谷粮仓、作物和作物存储区的熏蒸中。该稳定化的水性组合物通过施用于植物和或施用于植物正在生长或者将要种植植物的土壤而可用于保护植物免受真菌、细菌、病毒和其他微生物植物病原体的侵害，或者可用在拌种中。该稳定化的水性组合物以按重量浓度计约5至75％重量浓度的浓缩物的形式提供，并且可任选地与其他功能性添加剂如消泡剂、表面活性剂和辅助杀生物化合物如醛掺混。该稳定化的水性组合物可以根据需要连续地计量加入到水体系中或者分批地计量加入。可选地，它在应用之前可被稀释至按重量计0.001-10％，优选0.01至0.1％的浓度。
根据另一方面，本发明涉及处理包含或接触金属硫化物污垢的水性体系的方法，该方法包括向所述体系中分开地或一起地添加有效防污垢量的本发明的稳定化的水性组合物，使所述污垢与所述水性组合物接触，由此将所述污垢的至少一部分溶解在所述水性组合物中并且将所述溶解的污垢从该体系中取出。
在该特定的应用中，该 化合物的稳定化的水性组合物可根据需要以连续处理的方式用于水体系中或者分批计量加入。可选地，它在应用之前可被稀释至按重量计0.001-10％，优选0.01至0.1％的浓度。
硫化铁沉积物是石油工业中经济损失的主要原因。这些沉积物主要源于通常作为代谢副产物由硫酸盐还原菌产生的硫化氢与铁类金属油田设备和/或地层中的铁化合物之间的反应。它们阻碍了石油通过油井，在相邻岩层中以及在管道中以及在加工和精炼设备中的流动。硫化铁颗粒还倾向于使尤其在二次采油过程中常常形成的油-水乳液稳定化，并且给石油生产者带来重大问题。
在该特定应用中，本发明的稳定化的水性组合物还可包含其他水处理产品，例如阴离子、阳离子、两性和非离子型表面活性剂和润湿剂。该配制剂可另外包含杀生物剂(例如甲醛或戊二醛)、分散剂、破乳剂、消泡剂、溶剂、污垢抑制剂、腐蚀抑制剂、气体水合物抑制剂、沥青烯抑制剂、环烷酸盐抑制剂、去氧剂和/或絮凝剂。
该组合物还可包含非表面活性生物渗透剂，包括任何描述在WO99/33345中的那些。
具体实施方式
本发明通过下列实施例进行进一步说明。
实施例1-4和对比实施例5：
在所有的实施例中，同样的含磷化合物水性组合物通过不同的砷稳定化化合物进行稳定化，所述水性组合物的 化合物为硫酸四(羟甲基) (THPS)。
该水性组合物为50％重量的THPS浓度以及30ppm重量的砷浓度。
四个样品(实施例1-4)使用不同浓度的稳定化化合物进行稳定化，并且最后一个样品完全未进行稳定化。
该砷稳定化化合物的效力通过测定可看到砷化合物沉淀物的时间来确定。
该沉淀物是在环境温度(25℃)下通过随时间的目视观测进行评估的。
在不进行处理的情况下，50％THPS配制剂在5天内显现出红色沉淀物。
结果总结在下表1中：
表1
实施例 砷稳定化化合物 砷稳定化化合物的浓度％ 效力
1 甘氨酸 0.1 ＞6个月
2 甘氨酸 0.02 至少2个月
3 谷胱甘肽 0.2 至少5个月
4 氯化铵 0.1 至少5个月
5 无 0 少于5天
在不进行处理的情况下，50％THPS配制剂对比实施例5在5天内显现出红色沉淀物。

Claims (13)

1.有效砷稳定化量的选自氨、铵盐、有机氨基酸和肽的化合物通过添加到鏻化合物水性组合物中来用于防止或者至少最小化所述鏻化合物水性组合物中作为杂质含有的砷的沉淀的用途。
2.根据权利要求1的用途，其中所述肽是多肽。
3.根据权利要求1的用途，其中该鏻化合物是四(羟基有机基)鏻盐或式(I)的化合物
[R′R″(CH2OH)2P+]nXn- (I)
其中：
n为X的化合价；
R′和R″可以相同或不同，选自烷基、羟烷基、烯基或芳基结构部分并且X为阴离子。
4.根据权利要求1～3之任一项的用途，其中在式(I)中，R′和R″具有1～20个碳原子，并且
X选自氯根、硫酸根、磷酸根、醋酸根、草酸根和溴根。
5.根据权利要求1～3之任一项的用途，其中该鏻化合物为四(羟甲基)鏻盐。
6.根据权利要求1～3之任一项的用途，其中该鏻化合物是氯化四(羟甲基)鏻、溴化四(羟甲基)鏻、磷酸四(羟甲基)鏻、醋酸四(羟甲基)鏻、草酸四(羟甲基)鏻或硫酸四(羟甲基)鏻。
7.根据权利要求1～3之任一项的用途，其中该鏻化合物在要稳定化的水性组合物中的重量浓度为5～75％。
8.根据权利要求1～3之任一项的用途，其中该鏻化合物水性组合物具有的砷重量浓度为1～100ppm。
9.根据权利要求1～3之任一项的用途，其中要稳定化的水性组合物中的鏻化合物的重量浓度为5～75％。
10.根据权利要求1～3之任一项的用途，其中该有效砷稳定化化合物选自氨、铵盐、有机氨基酸、肽和多肽，并且在所述水性组合物中以40～10000ppm的浓度存在。
11.根据权利要求1～3之任一项的用途，进一步包括在将该砷稳定化化合物添加到所述组合物中之前调节要稳定化的水性组合物的pH值至低于7的值的步骤。
12.根据权利要求11的用途，其中该砷稳定化化合物为氯化铵、溴化铵、丙氨酸、β-丙氨酸、胱硫醚、胱氨酸、组氨酸、甘氨酸、亮氨酸、异亮氨酸、组氨酸、赖氨酸、甲硫氨酸、脯氨酸、肌氨酸、丝氨酸、甲状腺原氨酸、酪氨酸、缬氨酸、谷胱甘肽、阿斯巴甜或阿力甜。
13.根据权利要求11的用途，其中该砷稳定化化合物为甘氨酸。
CN201080012502.6A 2009-03-16 2010-02-01 稳定化的杀生物组合物 Active CN102368907B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16054009P 2009-03-16 2009-03-16
US61/160,540 2009-03-16
PCT/EP2010/051194 WO2010105872A2 (en) 2009-03-16 2010-02-01 Stabilized biocidal composition

Publications (2)

Publication Number Publication Date
CN102368907A CN102368907A (zh) 2012-03-07
CN102368907B true CN102368907B (zh) 2016-03-23

Family

ID=42740046

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080012502.6A Active CN102368907B (zh) 2009-03-16 2010-02-01 稳定化的杀生物组合物

Country Status (17)

Country Link
US (1) US9090494B2 (zh)
EP (1) EP2408308B1 (zh)
JP (1) JP2012520336A (zh)
KR (1) KR20110132377A (zh)
CN (1) CN102368907B (zh)
AR (1) AR075823A1 (zh)
AU (1) AU2010225088B2 (zh)
BR (1) BRPI1009402B1 (zh)
CA (1) CA2754126C (zh)
CO (1) CO6450671A2 (zh)
DK (1) DK2408308T3 (zh)
EC (1) ECSP11011351A (zh)
MX (1) MX2011009607A (zh)
MY (1) MY157152A (zh)
RU (1) RU2522137C2 (zh)
UA (1) UA106606C2 (zh)
WO (1) WO2010105872A2 (zh)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK2563375T3 (da) * 2010-04-28 2014-08-18 Alcon Res Ltd Farmaceutiske sammensætninger med phosphonium-antimikrobielle midler
SG178819A1 (en) * 2010-09-30 2012-05-30 Amsa Inc Formulations for use in sulfur scale control in industrial water systems
MY164964A (en) * 2011-03-09 2018-02-28 Kurita Water Ind Ltd Method for improving rejection of reverse osmosis membrane, treatment agent for improving rejection, and reverse osmosis membrane
JP5914973B2 (ja) * 2011-03-09 2016-05-11 栗田工業株式会社 透過膜の阻止率向上方法及び阻止率向上処理剤
DK2758347T3 (en) * 2011-09-23 2017-03-27 Lonza Ag PROCEDURE FOR REMOVING HYDROGEN SULFIDE FROM INDUSTRIAL PROCESS FLUIDS
CN104011166A (zh) * 2011-12-21 2014-08-27 国际壳牌研究有限公司 抑制烃混合物中发泡的方法和组合物
WO2014031537A2 (en) 2012-08-21 2014-02-27 Lonza, Inc. Method of scavenging hydrogen sulfide and/or sulfhydryl compounds
US11000778B2 (en) 2015-09-23 2021-05-11 Saudi Arabian Oil Company Removal of kinetic hydrate inhibitors

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999033345A1 (en) * 1997-12-23 1999-07-08 Albright & Wilson Uk Limited Biocidal compositions and treatments
WO2000021892A1 (en) * 1998-10-14 2000-04-20 Albright & Wilson Uk Limited Leaching divalent metal salts
CN1311756A (zh) * 1998-06-05 2001-09-05 Fmc有限公司 从元素磷中去除砷的方法
WO2002008127A1 (en) * 2000-07-20 2002-01-31 Rhodia Consumer Specialties Limited Treatment of iron sulphide deposits
WO2003016432A1 (en) * 2001-08-15 2003-02-27 Synergy Chemical, Inc. Method and composition to decrease iron sulfide deposits in pipe lines
WO2004083131A1 (en) * 2003-03-21 2004-09-30 Rhodia Consumer Specialities Limited Formulation for corrosion and scale inhibition
WO2005026065A1 (en) * 2003-09-11 2005-03-24 Rhodia Uk Limited Treatment of iron sulphide deposits
WO2007038403A3 (en) * 2005-09-22 2007-08-02 Chem Technologies Iron sulfide cleaning formulation and methods of use thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2768997A (en) * 1956-10-30 Phosphorus-containing polypeptides
US3734861A (en) * 1970-07-13 1973-05-22 Hooker Chemical Corp Synergistic metal sequestrant
DE2647863A1 (de) * 1975-11-07 1977-05-12 American Cyanamid Co Waessrige loesungen von tetrakis(hydroxymethyl)-phosphoniumsalzen
US4147757A (en) * 1976-12-13 1979-04-03 Olin Corporation Method for producing ammonium phosphate which is substantially free of arsenic
RU2143889C1 (ru) * 1993-02-23 2000-01-10 Генентек, Инк. Способ стабилизации полипептида, способы получения композиций полипептида и композиции
CN1247835A (zh) * 1999-09-21 2000-03-22 重庆理想科技有限公司 一种含砷黄磷的脱砷方法及分级处理的方法
AU2001268512A1 (en) * 2000-06-16 2002-01-02 Hercules Incorporated Chemically-modified peptides, compositions, and methods of production and use

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999033345A1 (en) * 1997-12-23 1999-07-08 Albright & Wilson Uk Limited Biocidal compositions and treatments
CN1311756A (zh) * 1998-06-05 2001-09-05 Fmc有限公司 从元素磷中去除砷的方法
WO2000021892A1 (en) * 1998-10-14 2000-04-20 Albright & Wilson Uk Limited Leaching divalent metal salts
WO2002008127A1 (en) * 2000-07-20 2002-01-31 Rhodia Consumer Specialties Limited Treatment of iron sulphide deposits
WO2003016432A1 (en) * 2001-08-15 2003-02-27 Synergy Chemical, Inc. Method and composition to decrease iron sulfide deposits in pipe lines
WO2004083131A1 (en) * 2003-03-21 2004-09-30 Rhodia Consumer Specialities Limited Formulation for corrosion and scale inhibition
WO2005026065A1 (en) * 2003-09-11 2005-03-24 Rhodia Uk Limited Treatment of iron sulphide deposits
WO2007038403A3 (en) * 2005-09-22 2007-08-02 Chem Technologies Iron sulfide cleaning formulation and methods of use thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
四羟甲基季?l盐:一种新型多功能油田化学剂;魏斌等;《油田化学》;20060625;第23卷(第02期);184-187,115 *

Also Published As

Publication number Publication date
RU2522137C2 (ru) 2014-07-10
WO2010105872A3 (en) 2011-11-24
MY157152A (en) 2016-05-13
ECSP11011351A (es) 2011-11-30
AU2010225088A1 (en) 2011-09-22
US20120046248A1 (en) 2012-02-23
MX2011009607A (es) 2011-10-04
BRPI1009402A2 (pt) 2017-05-16
CN102368907A (zh) 2012-03-07
AU2010225088B2 (en) 2014-09-11
JP2012520336A (ja) 2012-09-06
EP2408308A2 (en) 2012-01-25
AR075823A1 (es) 2011-04-27
BRPI1009402A8 (pt) 2017-10-10
CA2754126C (en) 2017-08-08
CO6450671A2 (es) 2012-05-31
WO2010105872A2 (en) 2010-09-23
CA2754126A1 (en) 2010-09-23
BRPI1009402B1 (pt) 2018-02-06
KR20110132377A (ko) 2011-12-07
RU2011141868A (ru) 2013-04-27
UA106606C2 (uk) 2014-09-25
US9090494B2 (en) 2015-07-28
EP2408308B1 (en) 2017-04-26
DK2408308T3 (en) 2017-08-14

Similar Documents

Publication Publication Date Title
CN102368907B (zh) 稳定化的杀生物组合物
AU597894B2 (en) Biocidal mixtures of organophosphines and surfactants
AU2010361425B2 (en) Formulations for use in Sulfur Scale Control in Industrial Water Systems
Fattah Assessing struvite formation potential at wastewater treatment plants
JP2010534666A (ja) 水系流体及び水系流体と共に用いられるシステム中の微生物濃度の増大を低減及び抑制するための方法及び配合物
JP5892136B2 (ja) 冷却水系の殺藻方法
RU2006101563A (ru) Разобщающие агенты
Miyamoto Use of Acids and Aciduiants on Alkali Soils and Water
CN102448294B (zh) 戊二醛基杀生物组合物和使用方法
AU2002214357B2 (en) Multifunctional water-treating composition and method of water-treating using the same
AU2002214357A1 (en) Multifunctional water-treating composition and method of water-treating using the same
CA2061249C (en) Use of cationic alkyl-phosphonium salts as corrosion inhibitors in open recirculating systems
Dosoretz et al. Fouling in microirrigation systems applying treated wastewater effluents
Schwankl Maintaining microirrigation systems
KR101284801B1 (ko) 미생물 살균기능을 가진 수처리 조성물 및 이를 이용한수처리 방법
CN103763920B (zh) 杀生物组合物及使用方法
US9750258B2 (en) Stable composition for controlling biological growth and method for using same in oil field applications
US6066260A (en) Means of and process for regulating the hardness and pH value of water in freshwater aquaria
WO2006001667A1 (en) Multifunctional water treating composition and water-treating method using the same
CN103841830B (zh) 杀生物组合物及使用方法
Saodat et al. Section 4. Chemistry
CN105084562A (zh) 一种海水作为煤气化冷却水的处理方法
CN106212498A (zh) 一种专用于油田水处理的专用杀菌剂
KR20030079187A (ko) 다기능성 일액형 냉각수처리제 조성물 및 이를 이용한수처리 방법

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20230807

Address after: new jersey

Patentee after: Energy Solutions (USA) LLC

Address before: France

Patentee before: RHODIA OPERATIONS

TR01 Transfer of patent right