DK2386203T3 - Anvendelse af dithiin-tetracarboximider til bekæmpelse af fytopatogene svampe - Google Patents

Anvendelse af dithiin-tetracarboximider til bekæmpelse af fytopatogene svampe Download PDF

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DK2386203T3
DK2386203T3 DK11175741.5T DK11175741T DK2386203T3 DK 2386203 T3 DK2386203 T3 DK 2386203T3 DK 11175741 T DK11175741 T DK 11175741T DK 2386203 T3 DK2386203 T3 DK 2386203T3
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dithiino
dipyrrole
tetron
species
bis
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Thomas Seitz
Ulrike Wachendorff-Neumann
Peter Dahmen
Arnd Voerste
Ralf Dunkel
Stefan Hillebrand
Stephane Brunet
Juergen Benting
Klaus-Guenther Tietjen
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Bayer Cropscience Ag
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains three hetero rings
    • C07D495/14—Ortho-condensed systems

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
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  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
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  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Claims (10)

1. Anvendelse af dithiin-tetracarboximider med den almene formel (I)
(I) hvor R1 og R2 er ens eller forskellige og står for hydrogen, for Ci-Cs-alkyl, i givet fald substitueret en eller flere gange med halogen, -OR3, -COR4, for C3-C7-cycloalkyl, i givet fald substitueret en eller flere gange med halogen, Ci-C4-alkyl eller Ci-C4-halogenalkyl, for aryl eller aryl-(Ci-C4-alkyl) , hver især i givet fald substitueret en eller flere gange med halogen, Ci-C4-alkyl, Ci-C4-halogenalkyl, -COR4 eller sulfony1amino, R3 står for hydrogen, Ci-C4-alkyl, Ci-C4-alkylcarbonyl eller for aryl, i givet fald substitueret en eller flere gange med halogen, Ci-C4-alkyl eller Ci-C4-halogenalkyl, R4 står for hydroxy, Ci-C4-alkyl eller Ci-C4-alkoxy, n står for 0 eller 1, til beskyttelse af høstede frugter eller grøntsager mod fytopatogene svampe.
2. Anvendelse ifølge krav 1, kendetegnet ved, at sygdommen fremkaldes af en af de følgende sygdomsfremkaldende faktorer: Colletotrichum-arter, f.eks. Colletotrichum gloeosporioides; Fusarium-arter, f.eks. Fusarium semitectum, Fusarium solani, Fusarium oxysporum; Verticillium-arter; Botrytis-arter, f.eks. Botrytis cinerea, Phomopsis-arter; Alternaria-arter; Phytophthora-arter, f.eks. Phytophthora cactorum; Septoria-arter; Monilinia-arter, f.eks. Monilinia laxa; Venturia-arter, f.eks. Venturia inaequalis; Glomerella-arter, f.eks. Glomerella cingulata, Sclerotinia-arter; Penicillium-arter, f.eks. Penicillium expansum; Gloeosporium-arter, Stemphyllium-arter; Thielaviopsis-arter; Aspergillus-arter, f.eks. Aspergillus niger; Nectria-arter, f.eks. Nectria galligena.
3. Anvendelse ifølge krav 1 eller 2, kendetegnet ved, at frugter og grøntsager er udvalgt af korn, f.eks. hvede, byg, rug, triticale, ris, hirse og havre; roer, f.eks. sukkerroe og foderroe; kernefrugter, stenfrugter og bærfrugter, f.eks. æble, pære, abrikoser, kirsebær, mandler og ferskner samt jordbær; bønne, ærter, soja; olieplanter, f.eks. raps, sennep, birkes, oliven, solsikke, kokosnød, kakao, jordnød; Cucurbitaceae, f.eks. agurk; bomuld, citroner, appelsiner og grapefrugt; Brassicaceae, f.eks. hvidkål, rødkål, broccoli, blomkål, rosenkål, pak choi, kålrabi, radise; grøntsager, f.eks. porre, tomat, løg, kartofler; eller maj s, tobak, kaffe, sukkerrør, vinstok.
4. Anvendelse ifølge krav 1, 2 eller 3, kendetegnet ved, at dithiin-tetracarboximider med den almene formel (I) er udvalgt af: (1) 2 , 6-dimethyl-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1, 3,5,7 (2H,6H)-tetron (2) 2,6-diethyl-lH,5H-[1,4]dithiino[2;3-c:5,6-c']dipyrrol-1, 3,5,7 (2H,6H)-tetron (3) 2,6-dipropyl-lH,5H-[1,4]dithiino[2,3-c:5,6-c'Jdipyrrol- 1.3.5.7 (2H,6H)-tetron (4) 2,6-di(propan-2-y1)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-l,3,5,7(2H,6H)-tetron (5) 2,6-dicyclopropyl-lH,5H-[l,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (6) 2,6-bis(2,2,2-trifluorethyl)-IH,5H-[1,4]dithiino [2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H]-tetron (7) 2,6-bi s[trifluormethyl)cylopropyl]-IH,5H- [1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (8) IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol- 1.3.5.7 (2H,6H)-tetron (9) 2,6-bis(3,5-dichlorphenyl)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (10) 2,6-diphenyl-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (11) 2,6-dibenzyl-lH,5H-[l,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tretron (12) 2,6-bis(2-methoxyethyl) -1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (13) 2,6-bis(2-hydroxybutyl)-1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (14) 2,6-bis(2-hydroxypropy1) -1H,5H-[1,4]dithiino [2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (15) 2,6-bis(2-phenoxyethyl)-1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (16) 2, 6-bis(2-ethoxyethyl)-1H,5H-[1,4]dithiino[13-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (17) 2,6-bis(2-phenylpropan-2-yl) -1H,5H-[1,4]dithiino [2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (18) 2,6-bis(1-phenylethyl) -1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (19) 2, 6-bis(2-methoxy-2-methylpropyl)-1H,5H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (20) 2,6-di-tert-butyl-lH,5H-[l,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (21) (l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrro-2,6-diyl)diethan-2,1-diyldiacetat (22) 4,4'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)di-ben zen suit on amid (23) 2,2'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)dieddi kesyre (24) 2,2'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino(2,3-c:5,6-c']dipyrrol-2,6-diyl)di-propansyre (25) 2,2'-(l,3,5,7-tetraoxo-l,3,5,7-tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)dibutansyre (26) 2,2'(1,3,5,7-tetraoxo-1,3,5,7-tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)dihexansyre (27) 2,2'(1,3,5,7-tetraoxo-1,3,5,7-tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)bis(3,3-dimethylbutansyre) (28) 3,3'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino[ 2 ,3-c:5,6-c ']dipyrrol-2,6-diyl) dibutansyre (29) 5,5'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H[1,4]dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)di- pentansyre (30) 2,6-bis[3-(trifluormethyl) cyclohexyl]-1H,5H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (31) 2,6-bis(3-(trifluormethyl) phenyl]-1H,5H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (32) 2,2'-(l,3,5,7-tetraoxo-l,3,5,7-tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)bis(3-phenylpropansyre) (33) 2,6-bis(2-hydroxyethyl)-1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (34) 2,6-bis(2-hydroxy-2-methylpropyl)-1H,5H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (35) (l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)dibutan-1,2-diyldiacetat (36) (l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)dipropan-1,2 -diyldiacetat (37) 2,6-bis(hydroxymethyl) -1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (3 8) 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6- c']dipyrrol-1,3,5,7(2H,6H)-tetron-4-oxid (39) 2-ethyl-lH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol- 1,3,5,7 (2H,6H)-tetron (40) diethyl-2,2'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-2,6- diyl)dihexanoat (4 1) 2-[2- (1-ethoxy-1-oxobutan-2-yl)-1,3,5,7-tetraoxo- 2,3,5,7-tetrahydro-lH,6H-[1,4]dithiino[2,3-c:5, 6-c']dipyrrol-6-yl]butansyre
5. Anvendelse ifølge krav 1, 2, 3 eller 4, kendetegnet ved, at frugter og grøntsager er udvalgt af kernefrugter, stenfrugter og bærfrugter, f.eks. æble, pære, abrikoser, kirsebær, mandler og ferskner samt jordbær; citroner, appelsiner og grapefrugt; vinstok.
6. Fremgangsmåde til bekæmpelse af sygdomme efter høst (post-harvest) og/eller under lagring ved hjælp af behandling af frugter og grøntsager med i det mindste et dithiin-tetracarboximid med den almene formel (I)
OD hvor R1 og R2 er ens eller forskellige og står for hydrogen, for Ci-Cg-alkyl, i givet fald substitueret en eller flere gange med halogen, -OR3, -COR4, for C3-C7-cycloalkyl, i givet fald substitueret en eller flere gange med halogen, Ci-C4-alkyl eller Ci-C4-halogenalkyl, for aryl eller aryl-(Ci-C4-alkyl) , hver især i givet fald substitueret en eller flere gange med halogen, Ci-C4-alkyl, Ci-C4-halogenalkyl, -COR4 eller sulfonylamino. R3 står for hydrogen, Ci-C4-alkyl Ci-C4-alkylcarbonyl eller for aryl, i givet fald substitueret en eller flere gange med halogen, Ci-C4-alkyl eller Ci-C4-halogenalkyl, R4 står for hydroxy, Ci-C4-alkyl eller Ci-C4-alkoxy, n står for 0 eller 1, til beskyttelse af høstede frugter eller grøntsager mod fytopatogene svampe.
7. Fremgangsmåde ifølge krav 1, kendetegnet ved, at sygdommen fremkaldes af en af de følgende sygdomsfremkaldende faktorer: Colletotrichum-arter, f.eks. Colletotrichum gloeosporioides; Fusarium-arter, f.eks. Fusarium semitectum, Fusarium solani, Fusarium oxysporum; Verticillium-arter; Botrytis-arter, f.eks. Botrytis cinerea; Phomopsis-arter; Alternaria-arter; Phytophthora-arter, f.eks. Phytophthora cactorum; Septoria-arter; Monilinia-arter, f.eks. Monilinia laxa; Venturia-arter, f.eks. Venturia inaequalis; Glomere 11a-arter, f.eks. Glomerella cingulata; Sclerotinia-arter; Penicillium-arter, f.eks. Penicillium expansum; Gloeosporium-arter; Stemphyllium-arter; Thielaviopsis-arter; Aspergillus-arter, f.eks. Aspergillus niger; Nectria-arter, f.eks. Nectria galligena.
8. Fremgangsmåde ifølge krav 6 eller 7, kendetegnet ved, at frugter og grøntsager er udvalgt af korn, f.eks. hvede, byg, rug, triticale, ris, hirse og havre; roer, f.eks. sukkerroe og foderroe; kernefrugter, stenfrugter og bærfrugter, f.eks. æble, pære, abrikoser, kirsebær, mandler og ferskner samt jordbær; bønne, ærter, soja; olieplanter, f.eks. raps, sennep, birkes, oliven, solsikke, kokosnød, kakao, jordnød; Cucurbitaceae, f.eks. agurk; bomuld, citroner, appelsiner og grapefrugt; Brassicaceae, f.eks. hvidkål, rødkål, broccoli, blomkål, rosenkål, pak choi, kålrabi, radisse; grøntsager, f.eks. porre, tomat, løg, kartofler; eller maj s, tobak, kaffe, sukkerrør, vinstok.
9. Fremgangsmåde ifølge krav 6, 7 eller 8, kendetegnet ved, at dithiin-tetracarboximiderne med den almene formel (I) er udvalgt af: (1) 2,6-dimethyl-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1, 3,5,7 (2H,6H)-tetron (2) 2,6-diethyl-lH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1, 3,5,7 (2H,6H)-tetron (3) 2,6-dipropyl-lH,5H-[1,4]dithiino[2,3-c:5,6-c'Jdipyrrol- 1.3.5.7 (2H,6H)-tetron (4) 2,6-di(propan-2-yl)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (5) 2,6-dicyclopropyl-lH-45-[l,4]dithiino[2,3-c:5,6-c']dipyrrol-l,3,5,7(2H,6H)-tetron (6) 2,6-bis(2,2,2-trifluorethyl)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (7) 2,6-bis[1-(tri fluormethyl)cyclopropyl]-IH,5H- [1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7 (2H,6H)-tetron (8) IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol- 1.3.5.7 (2H,6H)-tetron (9) 2,6-bis(3,5-dichlorphenyl)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (1 O ) 2 , 6-diphenyl-IH,5H-[1,4]dithiino[2, 3-c:5,6- c']dipyrrol-l,3,5,7(2H,6H)-tetron (11) 2,6-dibenzyl-lH,5H-[l,4]dithiino[2,3-c:5,6-c']dipyrrol-l,3,5,7(2H,6H)-tetron (12) 2,6-bis(2-methoxyethyl)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (13) 2,6-bis(2-hydroxybutyl)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (14) 2,6-bi s(2-hydroxypropy1)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (15) 2, 6-bis(2-phenoxyethyl)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (16) 2,6-bi s(2-ethoxyethyhyl)-IH,5H-[1,4]dithi ino [ 2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (17) 2,6-bi s(2-phenylpropan-2-yl)-IH,5H-[1,4]dithiino [2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (18) 2,6-bis(1-phenylethyl)-IH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (19) 2, 6-bis(2-methoxy-2-methylpropylpopyl)-IH,5H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H, 6H)-tetron (20) 2,6-di-tert-butyl-lH,5H-[l,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (21) (l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)diethan-2,1-diyldiacetat (22) 4,4'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H-[14]dithiino[2,3-c:5,6-c']dipyrrol-2,6- diyl)dibenzensulfenamid (23) 2,2-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,b-c']dipyrrol-2,6-diyl)dieddi kesyre (24) 2,2'-(l,3,5,7-tetraoxo-l,3,5,7-tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)dipropansyre (25) 2,2'(1,3,5,7-tetraoxo-1,3,5,7-tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)dibutansyre (26) 2,2'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino(2,3-c:5,6-c']dipyrrol-2,6-diyl)dihexansyre (27) 2.2'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino(2,3-c:5,6-c']dipyrrol-2,6-diyl)bis(3,3- dimethylbutansyre) (28) 3,3'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl) dibutansyre (29) 5,5'-(l,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H- [1.4] dithiino(2,3-c:5,6-c']dipyrrol-2,6-diyl)dipentansyre (30) 2,6-bis[3-(tri fluormethyl)yclohexyl]-1H,5H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (31) 2,6-bis[3-(trifluormethyl) phenyl]-1H,5H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (32) 2,2'(1,3,5,7-tetraoxo-1,3,5,7-tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)bis(3-phenylpropansyre) (33) 2,6-bis(2-hydroxyethyl)-1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (34) 2,6-bis(2-hydroxy-2-methylpropyl)-1H,5H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7 (2H,6H)-tetron (35) (1.3,7-tetraoxo-l,3,5,7-tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)dibutan-1,2 -diyldiacetat (36) (l,3,5,7-tetraoxo-l,3,5,7-tetrahydro-2H,6H- [1.4] dithiino[2,3-c:5,6-c']dipyrrol-2,6-diyl)dipropan-1,2 -diyldiacetat (37) 2,6-bis(hydroxymethyl) -1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron (3 8) 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6- c']dipyrrol-1,3,5,7(2H,6H)-tetron-4-oxid (39) 2-ethyl-lH,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol- 1,3,5,7 (2H,6H)-tetron (40) diethyl-2,2'-(1,3,5,7-tetraoxo-l,3,5,7 -tetrahydro-2H,6H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-2,6- diyl)dihexanoat (4 1) 2-[2- (1-ethoxy-1-oxobutan-2-yl)-1,3,5,7-tetraoxo- 2,3,5,7-tetrahydro-lH,6H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-6-yl]butansyre
10. Fremgangsmåde ifølge krav 6, 7, 8 eller 9, kendetegnet ved, at frugter og grøntsager er udvalgt af kernefrugter, stenfrugter og bærfrugter, f.eks. æble, pære, abrikoser, kirsebær, mandler og ferskner samt jordbær, citroner, appelsiner og grapefrugt; vinstok.
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