DK2370359T3 - Modificerede y-zeolitter med trimodal intrakrystallinsk struktur, fremgangsmåde til fremstilling heraf og anvendelse heraf - Google Patents

Modificerede y-zeolitter med trimodal intrakrystallinsk struktur, fremgangsmåde til fremstilling heraf og anvendelse heraf Download PDF

Info

Publication number
DK2370359T3
DK2370359T3 DK09805783.9T DK09805783T DK2370359T3 DK 2370359 T3 DK2370359 T3 DK 2370359T3 DK 09805783 T DK09805783 T DK 09805783T DK 2370359 T3 DK2370359 T3 DK 2370359T3
Authority
DK
Denmark
Prior art keywords
equal
zeolite
mesopores
modified
volume
Prior art date
Application number
DK09805783.9T
Other languages
English (en)
Other versions
DK2370359T4 (da
Inventor
Jean-Pierre Dath
Jong Krijn Pieter De
Jongh Petra Elisabeth De
Laak Adrianus Nicolaas Cornelis Van
Jovana Zecevic
Donk Sander Van
Régine Kenmogne-Gatchuissi
Maxime Lacroix
François Fajula
Métin Bulut
Original Assignee
Total Raffinage France
Centre Nat Rech Scient
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40887869&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DK2370359(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Total Raffinage France, Centre Nat Rech Scient filed Critical Total Raffinage France
Application granted granted Critical
Publication of DK2370359T3 publication Critical patent/DK2370359T3/da
Publication of DK2370359T4 publication Critical patent/DK2370359T4/da

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/24—Type Y
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/22—After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Claims (15)

  1. MODIFICEREDE Y-ZEOLITTER MED TRIMODAL INTRAKRYSTALLINSK STRUKTUR, FREMGANGSMÅDE TIL FREMSTILLING HERAF OG ANVENDELSE HERAF
    1. Fremgangsmåde til fremstilling af modificeret Y-zeolit med faujasit-struktur eller kompositmateriale, der omfatter den modificerede Y-zeolit med faujasit-struktur, især mindst 20 vægt-% i forhold til den samlede vægt af kompositmaterialet, hvilken fremgangsmåde omfatter følgende trin: a) at bringe en Y-zeolit eller et kompositmateriale, der indeholder den, især i en mængde på mindst 20 vægt-% i forhold til den samlede vægt af materialet, i suspension med en basisk vandig opløsning, der omfatter mindst en stærk base, især NaOH eller KOH, og/eller en svag base, særligt natriumcarbonat, natriumcitrat, for eksempel i en koncentration på fra 0,001 til 0,5 M, ved stuetemperatur under magnetomrøring eller mekanisk omrøring, b) at filtrere den opnåede zeolit og vaske den med et opløsningsmiddel, især et polært opløsningsmiddel, for eksempel rent destilleret vand, c) eventuelt at tørre den vaskede zeolit, d) at bringe den vaskede og eventuelt tørrede zeolit i en opløsning, især en vandig opløsning, i kontakt under omrøring med NH4NO3, især i en koncentration på fra 0,01 til 0,5 M, e) at vaske zeolitten med destilleret vand indtil opnåelse af neutralt pH, f) at kalcinere den opnåede zeolit, og g) at indsamle zeolitten.
  2. 2. Fremstillingsfremgangsmåde ifølge krav 1, kendetegnet ved, at vægtforholdet mellem den vandige opløsning og Y-zeolitten i trin a) kan ligge på fra 20 til 100, især fra 30 til 80, særligt fra 40 til 60, eller endog være 50.
  3. 3. Fremstillingsfremgangsmåde ifølge krav 1 eller 2, kendetegnet ved, at vægtforholdet mellem opløsningen af NH4N03 og Y-zeolit i trin d) kan ligge på fra 5 til 75, især fra 10 til 50, særligt fra 20 til 30, eller endog være 25.
  4. 4. Fremstillingsfremgangsmåde ifølge et hvilket som helst af kravene 1 til 3, kendetegnet ved, at udgangsmaterialet er en Y-zeolit, de har gennemgået mindst en dealumineringsbehandling, særligt en delvis dealumineringsbehandling, for eksempel ved mindst en behandling med syre og/eller damp.
  5. 5. Fremstillingsfremgangsmåde ifølge et hvilket som helst af kravene 1 til 4, kendetegnet ved, at den endvidere omfatter et trin til neutralisering af opløsningen inden den første filtrering.
  6. 6. Fremstillingsfremgangsmåde ifølge et hvilket som helst af kravene 1 til 5, der endvidere omfatter et trin til binding af en katalysator, især ved imprægnering af et katalytisk metal.
  7. 7. Modificeret Y-zeolit med faujasit-struktur, som kan opnås ved fremstillingsfremgangsmåden ifølge et hvilket som helst af kravene 1 til 6, hvis intrakrystallinske struktur udviser mindst et net af mikroporer, mindst et net af små mesoporer med en middeldiameter på fra 2 til 5 nm, og mindst et net af store mesoporer med en middeldiameter på fra 10 til 50 nm, idet disse forskellige net er indbyrdes forbundet.
  8. 8. Modificeret zeolit ifølge krav 7, hvor forholdet Vs/VI mellem volumenet af de små mesoporer (Vs) og volumenet af de store mesoporer VI er større end eller lig med 1, især større end eller lig med 1,20, eller endog større end eller lig med 1,60, ganske særligt større end eller lig med 1,80, endnu mere særligt større end eller lig med 2.
  9. 9. Zeolit ifølge et hvilket som helst af kravene 7 eller 8, kendetegnet ved, at den udviser et samlet mesoporevolumen, der er større end eller lig med 0,20 ml/g, især større end eller lig med 0,25 ml/g, særligt større end eller lig med 0,35 ml/g, eller endog større end eller lig med 0,40 ml/g.
  10. 10. Zeolit ifølge et hvilket som helst af kravene 7 til 9, kendetegnet ved, at den udviser et mikroporevolumen, der er mindre end eller lig med 0,20 ml/g, især mindre end eller lig med 0,18 ml/g, særligt mindre end eller lig med 0,16 ml/g, eller endog mindre end eller lig med 0,125 ml/g, ganske særligt mindre end eller lig med 0,10 ml/g.
  11. 11. Zeolit ifølge et hvilket som helst af kravene 7 til 10, kendetegnet ved, at den udviser et forhold mellem det samlede mesoporevolumen og mikroporevolumenet, der er større end eller lig med 1, især større end eller lig med 1,5, særligt større end eller lig med 3, eller endog større end eller lig med 3,5, ganske særligt større end eller lig med 4, endnu mere særligt større end eller lig med 4,5, ja endog større end eller lig med 5.
  12. 12. Partikler, særligt katalytiske partikler, der omfatter zeolitten ifølge et hvilket som helst af kravene 7 til 11 og mindst et bindemiddel, såsom silica eller alumina.
  13. 13. Partikler ifølge krav 12, der omfatter mindst 20 vægt-% zeolitter i forhold til den samlede vægt af partiklerne.
  14. 14. Partikler ifølge krav 12 eller 13, der ligeledes omfatter et katalytisk metal.
  15. 15. Anvendelse af partikler ifølge et af kravene 12 til 14 i en fremgangsmåde til behandling af olie eller tunge rester, især som katalysator for hydrokonvertering ved FCC, for eksempel hydrokrakning eller hydroisomerisering.
DK09805783.9T 2008-12-22 2009-12-22 Modificerede y-zeolitter med trimodal intrakrystallinsk struktur, fremgangsmåde til fremstilling heraf og anvendelse heraf DK2370359T4 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0858952A FR2940265B1 (fr) 2008-12-22 2008-12-22 Zeolithes y modifiees, leur procede de fabrication et leur utilisation
PCT/FR2009/052668 WO2010072976A1 (fr) 2008-12-22 2009-12-22 Zeolites y modifiees a structure intracristalline trimodale, leur procede de fabrication et leur utilisation

Publications (2)

Publication Number Publication Date
DK2370359T3 true DK2370359T3 (da) 2018-05-14
DK2370359T4 DK2370359T4 (da) 2022-07-25

Family

ID=40887869

Family Applications (1)

Application Number Title Priority Date Filing Date
DK09805783.9T DK2370359T4 (da) 2008-12-22 2009-12-22 Modificerede y-zeolitter med trimodal intrakrystallinsk struktur, fremgangsmåde til fremstilling heraf og anvendelse heraf

Country Status (10)

Country Link
US (1) US9126183B2 (da)
EP (1) EP2370359B2 (da)
JP (1) JP5783906B2 (da)
CN (1) CN102264643B (da)
CA (1) CA2748018C (da)
DK (1) DK2370359T4 (da)
ES (1) ES2665021T5 (da)
FR (1) FR2940265B1 (da)
RU (1) RU2510293C2 (da)
WO (1) WO2010072976A1 (da)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5492431B2 (ja) * 2009-03-13 2014-05-14 出光興産株式会社 水素化分解触媒、水素化分解する方法及び水素化分解触媒の製造方法
WO2012068645A2 (en) 2010-11-25 2012-05-31 Katholieke Universiteit Leuven Method for the production of conjugated polyunsaturated fatty acids with heterogenous catalysts
FR2969510B1 (fr) 2010-12-23 2014-06-13 Total Raffinage Marketing Procede de preparation d'un catalyseur industriel d'hydroconversion, catalyseur ainsi obtenu et son utilisation dans un procede d'hydroconversion
EP2694438A4 (en) * 2011-04-08 2014-11-05 Rive Technology Inc MESOPOROUS ZEOLITE WITH MODIFIED FRAME
US9821298B2 (en) 2011-10-24 2017-11-21 Total Raffinage France Process for preparing a hydroconversion catalyst, catalyst thus obtained and use thereof in a hydroconversion process
FR2981583B1 (fr) * 2011-10-24 2019-05-17 Total Raffinage France Procede de preparation d'un catalyseur contenant des mesopores, catalyseur ainsi obtenu et son utilisation dasn un procede d'hydroconversion
FR2981584B1 (fr) * 2011-10-24 2019-09-20 Total Raffinage France Procede de preparation d'un catalyseur d'hydroconversion, catalyseur ainsi obtenu et son utilisation dans un procede d'hydroconversion
CN103889572B (zh) * 2011-10-24 2017-02-15 道达尔炼油法国 用于制备介孔化催化剂的方法、由此获得的催化剂及其在催化工艺中的用途
FR2981582B1 (fr) * 2011-10-24 2013-11-29 Total Raffinage Marketing Procede de preparation d'un catalyseur d'hydroconversion, catalyseur ainsi obtenu et son utilisation dans un procede d'hydroconversion
CA2848344C (en) * 2011-10-24 2019-12-03 Total Raffinage France Process for preparing a mesopores-containing catalyst, catalyst thus obtained and use thereof in a hydroconversion process
ES2440816B1 (es) * 2012-06-29 2014-11-04 Consejo Superior De Investigaciones Científicas (Csic) Craqueo catalítico de compuestos orgánicos utilizando una zeolita y modificada
KR102068312B1 (ko) * 2013-10-18 2020-01-20 에스케이이노베이션 주식회사 활성화된 eu-2 제올라이트 및 이의 용도
DE102014205783A1 (de) * 2014-03-27 2015-10-01 Johnson Matthey Public Limited Company Katalysator sowie Verfahren zum Herstellen eines Katalysator
KR101767658B1 (ko) * 2014-10-20 2017-08-14 주식회사 엘지화학 다공성 알루미노실리케이트를 포함하는 진공 단열재용 심재와 이를 구비한 진공 단열재
RU2650897C1 (ru) * 2016-10-13 2018-04-18 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Способ получения микро-мезопористого цеолита y и цеолит, полученный этим способом
CN107970972B (zh) * 2016-10-21 2019-11-15 中国石油化工股份有限公司 一种催化裂化催化剂及其制备方法
CN107970973B (zh) * 2016-10-21 2019-11-15 中国石油化工股份有限公司 一种催化裂化催化剂及其制备方法
CN107970971B (zh) * 2016-10-21 2019-11-15 中国石油化工股份有限公司 一种催化裂化催化剂及其制备方法
CN107970974B (zh) * 2016-10-21 2019-11-15 中国石油化工股份有限公司 一种催化裂化催化剂及其制备方法
CN107970976B (zh) * 2016-10-21 2019-11-15 中国石油化工股份有限公司 一种催化裂化催化剂及其制备方法
CN107970970B (zh) * 2016-10-21 2019-11-15 中国石油化工股份有限公司 一种催化裂化催化剂及其制备方法
JP2018154538A (ja) * 2017-03-21 2018-10-04 東ソー株式会社 銀含有ゼオライト
TWI831784B (zh) 2018-05-28 2024-02-11 大陸商中國石油化工科技開發有限公司 表面富鋁的NaY分子篩及其製備方法
CN109368653B (zh) * 2018-10-24 2021-07-20 深圳大学 一种双介孔Co-TUD-1分子筛及其制备方法
RU2751336C1 (ru) * 2020-10-02 2021-07-13 Общество с ограниченной ответственностью "Газпром нефтехим Салават" (ООО "Газпром нефтехим Салават") Катализатор, способ его получения и способ трансалкилирования бензола диэтилбензолами с его использованием
CN114433176B (zh) * 2020-10-20 2024-02-13 中国石油化工股份有限公司 多级孔y分子筛及其制备方法和应用以及脱烯烃催化剂及其制备方法和应用

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59193137A (ja) * 1983-03-31 1984-11-01 Res Assoc Residual Oil Process<Rarop> ゼオライト含有組成物及びそれを用いた水素化分解用触媒
US4663025A (en) * 1986-08-14 1987-05-05 Phillips Petroleum Company Catalytic cracking processes
US5227352A (en) 1990-06-29 1993-07-13 Petroleum Energy Center Catalyst composition for catalytic cracking of hydrocarbon oil and process for producing the same
JP2544317B2 (ja) * 1990-06-29 1996-10-16 財団法人石油産業活性化センター 流動接触分解触媒組成物およびその製法ならびにそれを用いる炭化水素油の流動接触分解法
JP2651472B2 (ja) * 1991-03-31 1997-09-10 財団法人石油産業活性化センター 新規な接触分解用触媒組成物ならびにそれを用いる接触分解法
US5601798A (en) * 1993-09-07 1997-02-11 Pq Corporation Process for preparing zeolite Y with increased mesopore volume
AU717421B2 (en) 1993-09-07 2000-03-23 Pq Holding, Inc. Process for preparing zeolite Y with increased mesopore volume
BR9400475A (pt) * 1994-02-09 1995-09-19 Petroleo Brasileiro Sa Processo de preparação de zeólita modificada e zeólita modificada
KR19980702741A (ko) * 1995-03-03 1998-08-05 반주트펜조한스아아르트 촉매 조성물, 및 탄화수소 전환 방법에서의 그것의 용도
JP3684265B2 (ja) * 1996-03-26 2005-08-17 触媒化成工業株式会社 均一なミクロポアと均一なメソポアの２種類の細孔を有するフォージャサイト型ゼオライトおよびその製造方法
EP1250287B1 (en) * 2000-01-05 2007-03-07 ExxonMobil Chemical Patents Inc. Porous inorganic macrostructure materials and process for their preparation
US6673235B2 (en) * 2000-09-22 2004-01-06 Engelhard Corporation FCC catalysts for feeds containing nickel and vanadium
US6635168B2 (en) * 2001-04-13 2003-10-21 W. R. Grace & Co.-Conn Gasoline sulfur reduction catalyst for fluid catalytic cracking process
JP2003277046A (ja) * 2002-03-19 2003-10-02 Nippon Oil Corp Ｙ型ゼオライトおよびその製造方法
US6723862B2 (en) * 2002-04-02 2004-04-20 Akzo Nobel N.V. Fatty acid isomerization with mesoporous zeolites
CN1230496C (zh) * 2002-10-28 2005-12-07 中国石油化工股份有限公司 一种含稀土y型沸石的石油烃裂化催化剂及其制备方法
US7589041B2 (en) 2004-04-23 2009-09-15 Massachusetts Institute Of Technology Mesostructured zeolitic materials, and methods of making and using the same
CN1789127A (zh) * 2004-12-15 2006-06-21 中国石油化工股份有限公司 一种富含介孔的y型分子筛的制备方法
EP1938898B1 (en) 2005-09-12 2019-06-12 Petroleum Energy Center Catalyst composition for hydrogenation treatment of hydrocarbon and hydrogenation treatment method
CN101108736B (zh) * 2006-07-21 2010-09-29 中国石油天然气集团公司 一类同时具有微孔和介孔的y型分子筛的制备方法
RU2320631C1 (ru) * 2006-11-10 2008-03-27 Ирина Игоревна Иванова Способ диспропорционирования изопропилбензола с использованием катализатора с микромезопористой структурой
WO2009062742A2 (en) 2007-11-16 2009-05-22 Grace Gmbh & Co. Kg Porous solid acid catalysts, methods of manufacturing the same, and methods of manufacturing organics molecules using the same
US8361434B2 (en) * 2008-09-18 2013-01-29 Exxonmobil Research And Engineering Company Extra mesoporous Y zeolite

Also Published As

Publication number Publication date
EP2370359B1 (fr) 2018-02-07
WO2010072976A1 (fr) 2010-07-01
RU2510293C2 (ru) 2014-03-27
US20120018349A1 (en) 2012-01-26
ES2665021T5 (es) 2022-10-11
EP2370359A1 (fr) 2011-10-05
EP2370359B2 (fr) 2022-05-18
JP5783906B2 (ja) 2015-09-24
RU2011130524A (ru) 2013-01-27
DK2370359T4 (da) 2022-07-25
JP2012513359A (ja) 2012-06-14
US9126183B2 (en) 2015-09-08
CN102264643B (zh) 2015-05-20
ES2665021T3 (es) 2018-04-24
CN102264643A (zh) 2011-11-30
FR2940265A1 (fr) 2010-06-25
CA2748018A1 (fr) 2010-07-01
CA2748018C (fr) 2017-08-08
FR2940265B1 (fr) 2011-06-10

Similar Documents

Publication Publication Date Title
DK2370359T3 (da) Modificerede y-zeolitter med trimodal intrakrystallinsk struktur, fremgangsmåde til fremstilling heraf og anvendelse heraf
JP6064112B2 (ja) 産業用の水素化転換触媒、例えば、水素化分解触媒の製造方法、それによって得られた触媒、及び、水素化転換におけるその触媒の使用
US9821298B2 (en) Process for preparing a hydroconversion catalyst, catalyst thus obtained and use thereof in a hydroconversion process
US20190262810A1 (en) Process for preparing a mesoporized catalyst, catalyst thus obtained and use thereof in a catalytic process
WO2017148852A1 (en) Controlled alkaline treatments on molecular sieves
CA2848344C (en) Process for preparing a mesopores-containing catalyst, catalyst thus obtained and use thereof in a hydroconversion process
Zheng et al. Synthesis and catalytic performance of a bi-phase core-shell zeolite composite
US9242234B2 (en) Modified Y-type zeolites having a trimodal intracrystalline structure, method for making same, and use thereof