DK1689790T3 - Fremgangsmåde til fremstilling af polymerer - Google Patents

Fremgangsmåde til fremstilling af polymerer Download PDF

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Publication number
DK1689790T3
DK1689790T3 DK04798045.3T DK04798045T DK1689790T3 DK 1689790 T3 DK1689790 T3 DK 1689790T3 DK 04798045 T DK04798045 T DK 04798045T DK 1689790 T3 DK1689790 T3 DK 1689790T3
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DK
Denmark
Prior art keywords
monomer
ethylenically unsaturated
biocatalyst
unsaturated monomer
polymer
Prior art date
Application number
DK04798045.3T
Other languages
English (en)
Inventor
Stuart Greenhalgh
Kenneth Charles Symes
Yvonne Armitage
Jonathan Hughes
Gary Richardson
Original Assignee
Ciba Spec Chem Water Treat Ltd
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Publication date
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Application filed by Ciba Spec Chem Water Treat Ltd filed Critical Ciba Spec Chem Water Treat Ltd
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Publication of DK1689790T3 publication Critical patent/DK1689790T3/da

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00—Preparation of nitrogen-containing organic compounds
    • C12P13/02—Amides, e.g. chloramphenicol or polyamides; Imides or polyimides; Urethanes, i.e. compounds comprising N-C=O structural element or polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00—Preparation of nitrogen-containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/44—Polycarboxylic acids
    • C12P7/46—Dicarboxylic acids having four or less carbon atoms, e.g. fumaric acid, maleic acid

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)

Claims (10)

1. Fremgangsmåde til fremstilling af en polymer af en ethylenisk umættet monomer, hvilken monomer er (meth)acrylamid, hvor monomeren er opnået fra en biokatalyseret reaktion, hvor den ethylenisk umættede monomer er fremstillet ved tilvejebringelse af et substrat, der kan omdannes til den ethylenisk umættede monomer, hvilket substrat er (meth)acrylnitril, etablering af kontakt mellem substratet og en biokatalysator, hvilken biokatalysator omfatter cellemateriale i form af hele celler eller nedbrudte celler og fermenteringssuppe, og derved omdannelse af substratet til den ethylenisk umættede monomer i nærvær af cellematerialet og fermenteringssuppen, hvilken biokatalysator omfatter et nitrilhydrataseenzym, dannelse af polymeren ved hjælp af polymerisering af den ethylenisk umættede monomer eller en monomerblanding, der omfatter den ethylenisk umættede monomer, hvor der ikke sker fjernelse af cellematerialet og fermenteringssuppen fra den ethylenisk umættede monomer.
2. Fremgangsmåde ifølge krav 1, hvor cellematerialet omfatter hele celler.
3. Fremgangsmåde ifølge krav 1 eller 2, hvor cellematerialet omfatter nedbrudt cellemateriale.
4. Fremgangsmåde ifølge krav 3, hvor det nedbrudte cellemateriale er udvalgt fra gruppen, der består af cellevægsmateriale, cellemembranmateriale, cellekernemateriale, cytoplasma og proteiner.
5. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 4, hvor polymeren er en vandopløselig polymer med høj molekylvægt, der fremviser en iboende viskositet (IV) på mindst 3 dl/g (målt ved anvendelse af et suspenderet niveau-viskosimeter i 1 M natriumchlorid ved 25 °C).
6. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 5, hvor polymeren er en homopolymer eller copolymer af (meth)acrylamid.
7. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 6, hvor substratet indføres i en beholder og bringes i kontakt med biokatalysatoren, og hvor substratet omdannes til den ethylenisk umættede monomer, eventuelt indførelse af andre monomerer i beholderen til frembringelse af en monomerblanding, udsættelse af den ethylenisk umættede monomer eller monomerblandingen for polymeriseringsbetingelser, eventuelt ved indførelse af initiatorer i beholderen, og derved dannelse af polymeren inde i beholderen.
8. Fremgangsmåde ifølge krav 7, hvor biokatalysatoren fremstilles i beholderen.
9. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 8, hvor biokatalysatoren omfatter mikroorganismer fra Rhodococcus-slæqten, fortrinsvis arten Rhodococcus rhodochrous.
10. Fremgangsmåde ifølge krav 9, hvor mikroorganismen er Rhodococcus rhodochrous NCIMB 41164.
DK04798045.3T 2003-12-02 2004-11-22 Fremgangsmåde til fremstilling af polymerer DK1689790T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0327901.5A GB0327901D0 (en) 2003-12-02 2003-12-02 Process for producing polymers
PCT/EP2004/013250 WO2005054488A2 (en) 2003-12-02 2004-11-22 Process for producing polymers

Publications (1)

Publication Number Publication Date
DK1689790T3 true DK1689790T3 (da) 2014-11-17

Family

ID=29764409

Family Applications (1)

Application Number Title Priority Date Filing Date
DK04798045.3T DK1689790T3 (da) 2003-12-02 2004-11-22 Fremgangsmåde til fremstilling af polymerer

Country Status (17)

Country Link
US (1) US8067215B2 (da)
EP (2) EP1689790B1 (da)
JP (2) JP4966666B2 (da)
KR (1) KR101175118B1 (da)
CN (1) CN1886429B (da)
AU (1) AU2004295407B2 (da)
BR (1) BRPI0417245B1 (da)
CA (1) CA2547550C (da)
DK (1) DK1689790T3 (da)
ES (1) ES2517816T3 (da)
GB (1) GB0327901D0 (da)
IN (1) IN2006CH01927A (da)
MX (1) MX281093B (da)
PL (1) PL1689790T3 (da)
RU (1) RU2425886C2 (da)
WO (1) WO2005054488A2 (da)
ZA (1) ZA200603782B (da)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI529181B (zh) * 2005-02-28 2016-04-11 贏創德固賽有限責任公司 以可更新原料為基之吸水聚合物結構及其生產的方法
AU2009224346B2 (en) * 2008-03-14 2014-04-24 Mitsubishi Chemical Corporation Method for stabilization of aqueous acrylamide solution
WO2016050818A1 (en) * 2014-09-30 2016-04-07 Basf Se Method for preparing an aqueous acrylamide solution having a low acrylic acid concentration
RU2751919C2 (ru) 2016-03-29 2021-07-20 Басф Се Способ получения раствора полиакриламида с увеличенной вязкостью
WO2017186685A1 (en) * 2016-04-26 2017-11-02 Basf Se Method for preparing an aqueous polyacrylamide solution
CA3019652A1 (en) * 2016-04-26 2017-11-02 Basf Se Method for preparing an aqueous polyacrylamide solution
AU2017257206A1 (en) * 2016-04-26 2018-11-15 Basf Se Method for preparing an aqueous polyacrylamide solution
WO2021089584A1 (en) 2019-11-05 2021-05-14 Basf Se Method of storing a biocatalyst

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3037009A1 (de) 1979-10-04 1981-04-23 Nitto Chemical Industry Co., Ltd., Tokyo Verfahren zur herstellung von acrylamid aus acrylnitril unter verwendung von mikroorganismen
US4506062A (en) * 1982-08-09 1985-03-19 Allied Colloids Limited Inverse suspension polymerization process
GB8309275D0 (en) * 1983-04-06 1983-05-11 Allied Colloids Ltd Dissolution of water soluble polymers in water
GB8401206D0 (en) * 1984-01-17 1984-02-22 Allied Colloids Ltd Polymers and aqueous solutions
MX169933B (es) 1987-09-18 1993-08-02 Hideaki Yamada Procedimiento para la produccion biologica de amidas
CZ280901B6 (cs) * 1988-10-06 1996-05-15 Hideaki Yamada Způsob kultivace bakterií
SU1731814A1 (ru) 1990-05-17 1992-05-07 Саратовский филиал Всесоюзного научно-исследовательского института генетики и селекции промышленныхмикроорганизмов Штамм бактерий RноDососсUS RноDоснRоUS - продуцент нитрилгидратазы
GB9020081D0 (en) 1990-09-14 1990-10-24 Allied Colloids Ltd Polymerisation processes
RU2053300C1 (ru) * 1993-12-17 1996-01-27 Государственный научно-исследовательский институт генетики и селекции промышленных микроорганизмов Штамм бактерий rhodococcus rhodochrous - продуцент нитрилгидратазы
EP0839190A1 (en) * 1995-08-09 1998-05-06 Ciba Specialty Chemicals Water Treatments Limited Processes for the production of amidase
US5698629A (en) * 1995-08-21 1997-12-16 Nitto Chemical Industry Co., Ltd. Process for the preparation of a water-in-oil type high-molecular-weight polymer emulsion
JPH09118704A (ja) * 1995-08-21 1997-05-06 Nitto Chem Ind Co Ltd 油中水型高分子量重合体エマルションの製造法
GB9525372D0 (en) * 1995-12-12 1996-02-14 Allied Colloids Ltd Enzymes, their preparation and their use in the production of ammonium acrylate
BR9612006A (pt) 1995-12-12 1999-02-17 Allied Colloids Ltd Processo para fabricar uma solução aquosa contendo pelo menos 30 por cento em peso de ácido (met) acrílico ou sal do mesmo e abaixo de 0,2% de (met) acrilonitrila
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JP4708677B2 (ja) * 2000-12-20 2011-06-22 ダイヤニトリックス株式会社 微生物触媒を用いたアミド化合物の製造方法
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JPWO2003033716A1 (ja) * 2001-10-12 2005-02-03 ダイヤニトリックス株式会社 微生物触媒によるアクリルアミド及び／又はメタクリルアミドの製造方法
US6670158B2 (en) 2002-02-05 2003-12-30 E. I. Du Pont De Nemours And Company Method for producing methacrylic acid acrylic acid with a combination of enzyme catalysts
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Also Published As

Publication number Publication date
GB0327901D0 (en) 2004-01-07
ES2517816T3 (es) 2014-11-04
MXPA06006233A (es) 2006-07-31
WO2005054488A3 (en) 2005-08-04
CA2547550C (en) 2012-11-06
EP1689790B1 (en) 2014-08-20
CN1886429B (zh) 2010-12-08
KR20060127398A (ko) 2006-12-12
WO2005054488A2 (en) 2005-06-16
KR101175118B1 (ko) 2012-08-21
BRPI0417245B1 (pt) 2016-07-26
JP2007512819A (ja) 2007-05-24
CA2547550A1 (en) 2005-06-16
EP2796475A1 (en) 2014-10-29
CN1886429A (zh) 2006-12-27
RU2425886C2 (ru) 2011-08-10
IN2006CH01927A (da) 2007-06-08
US8067215B2 (en) 2011-11-29
AU2004295407B2 (en) 2010-02-18
EP1689790A2 (en) 2006-08-16
RU2006123431A (ru) 2008-01-10
US20070184536A1 (en) 2007-08-09
JP4966666B2 (ja) 2012-07-04
AU2004295407A1 (en) 2005-06-16
ZA200603782B (en) 2007-08-29
MX281093B (en) 2010-11-19
PL1689790T3 (pl) 2015-02-27
JP2012050445A (ja) 2012-03-15
BRPI0417245A (pt) 2007-03-06

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