DK163790A - Fremgangsmaade til fremstilling af en alumoxanbaerer til en aktiv metallocenkatalysator under anvendelse af triethylaluminium - Google Patents
Fremgangsmaade til fremstilling af en alumoxanbaerer til en aktiv metallocenkatalysator under anvendelse af triethylaluminium Download PDFInfo
- Publication number
- DK163790A DK163790A DK163790A DK163790A DK163790A DK 163790 A DK163790 A DK 163790A DK 163790 A DK163790 A DK 163790A DK 163790 A DK163790 A DK 163790A DK 163790 A DK163790 A DK 163790A
- Authority
- DK
- Denmark
- Prior art keywords
- catalyst
- silica gel
- alumoxane
- preparing
- olefins
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000012968 metallocene catalyst Substances 0.000 title 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 239000000741 silica gel Substances 0.000 abstract 4
- 229910002027 silica gel Inorganic materials 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000012071 phase Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
- Unwinding Webs (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/268,834 US4925821A (en) | 1987-12-17 | 1988-11-08 | Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst |
PCT/US1989/005006 WO1990005149A1 (fr) | 1988-11-08 | 1989-11-07 | Procede d'utilisation de triethylaluminium pour preparer un support en alumoxane pour un catalyseur de metallocene actif |
Publications (2)
Publication Number | Publication Date |
---|---|
DK163790D0 DK163790D0 (da) | 1990-07-06 |
DK163790A true DK163790A (da) | 1990-08-23 |
Family
ID=23024690
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK163790A DK163790A (da) | 1988-11-08 | 1990-07-06 | Fremgangsmaade til fremstilling af en alumoxanbaerer til en aktiv metallocenkatalysator under anvendelse af triethylaluminium |
Country Status (17)
Country | Link |
---|---|
US (1) | US4925821A (fr) |
EP (1) | EP0368644B1 (fr) |
JP (1) | JPH03502210A (fr) |
KR (1) | KR900701857A (fr) |
AT (1) | ATE148893T1 (fr) |
AU (1) | AU621172B2 (fr) |
BR (1) | BR8907158A (fr) |
CA (1) | CA2002436A1 (fr) |
DE (1) | DE68927765T2 (fr) |
DK (1) | DK163790A (fr) |
ES (1) | ES2097743T3 (fr) |
FI (1) | FI903448A0 (fr) |
HU (1) | HUT55416A (fr) |
IL (1) | IL92242A0 (fr) |
PT (1) | PT92233A (fr) |
WO (1) | WO1990005149A1 (fr) |
YU (1) | YU213389A (fr) |
Families Citing this family (105)
Publication number | Priority date | Publication date | Assignee | Title |
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CA2058383A1 (fr) * | 1991-05-17 | 1992-11-18 | Ted M. Pettijohn | Polymerisation d'olefines |
CA2068939C (fr) * | 1991-05-20 | 1996-04-09 | Takashi Ueda | Polymerisation d'olefines et catalyseur utilise a cette fin |
FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
EP0578838A1 (fr) * | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation |
EP0567952B1 (fr) * | 1992-04-29 | 1997-12-03 | Hoechst Aktiengesellschaft | Catalyseur de polymérisation d'olefins, procédé pour sa préparation et son utilisation |
US5238892A (en) * | 1992-06-15 | 1993-08-24 | Exxon Chemical Patents Inc. | Supported catalyst for 1-olefin(s) (co)polymerization |
US5602067A (en) * | 1992-12-28 | 1997-02-11 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
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US5608019A (en) * | 1992-12-28 | 1997-03-04 | Mobil Oil Corporation | Temperature control of MW in olefin polymerization using supported metallocene catalyst |
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US5414180A (en) * | 1993-07-14 | 1995-05-09 | Phillips Petroleum Company | Organo-aluminoxy product and use |
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DE4344672C1 (de) * | 1993-12-27 | 1995-06-14 | Basf Ag | Verfahren zur Herstellung von Polymerisaten des Ethylens durch Suspensionspolymerisation |
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CN1047388C (zh) * | 1995-07-14 | 1999-12-15 | 中国石油化工总公司 | 负载型金属茂类化合物/铝氧烷催化剂的制备 |
ES2120868B1 (es) * | 1995-08-03 | 2000-09-16 | Repsol Quimica Sa | Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas. |
US6486089B1 (en) | 1995-11-09 | 2002-11-26 | Exxonmobil Oil Corporation | Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution |
US5756416A (en) * | 1995-11-28 | 1998-05-26 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition having improved comonomer reactivity |
US5976682A (en) * | 1996-03-12 | 1999-11-02 | Tenneco Packaging | Stretch wrap films |
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USRE38429E1 (en) * | 1996-03-12 | 2004-02-17 | Tyco Plastics Services Ag | Stretch wrap films |
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US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
ES2129323B1 (es) | 1996-04-18 | 2000-09-16 | Repsol Quimica Sa | Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas |
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KR102009103B1 (ko) | 2010-02-22 | 2019-08-08 | 유니베이션 테크놀로지즈, 엘엘씨 | 폴리올레핀 생산물을 생산하기 위한 촉매 시스템 및 이의 사용 방법 |
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CN107107433B (zh) | 2015-01-21 | 2019-09-13 | 尤尼威蒂恩技术有限责任公司 | 用于聚烯烃中的凝胶减少的方法 |
CN107660216B (zh) | 2015-05-08 | 2021-05-14 | 埃克森美孚化学专利公司 | 聚合方法 |
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CA3052770C (fr) | 2017-02-07 | 2021-09-07 | Exxonmobil Chemical Patents Inc. | Procedes de reduction de perte d'activite catalytique d'un catalyseur ziegler-natta |
WO2018191000A1 (fr) | 2017-04-10 | 2018-10-18 | Exxonmobil Chemicl Patents Inc. | Procédés de fabrication de compositions polymères de polyoléfine |
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DE3240382A1 (de) * | 1982-11-02 | 1984-05-03 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von gefuellten polyolefinen |
DE3424697C2 (de) * | 1984-07-05 | 1999-07-08 | Targor Gmbh | Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen |
US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
WO1987003889A1 (fr) * | 1985-12-24 | 1987-07-02 | Mitsui Petrochemical Industries, Ltd. | Procede de polymerisation d'alpha-olefines |
EP0315234A1 (fr) * | 1987-10-26 | 1989-05-10 | Texas Alkyls, Inc. | Procédé de préparation d'aluminoxanes |
US4912075A (en) * | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
US5008228A (en) * | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
US4935397A (en) * | 1988-09-28 | 1990-06-19 | Exxon Chemical Patents Inc. | Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same |
-
1988
- 1988-11-08 US US07/268,834 patent/US4925821A/en not_active Expired - Lifetime
-
1989
- 1989-11-07 WO PCT/US1989/005006 patent/WO1990005149A1/fr active Application Filing
- 1989-11-07 BR BR898907158A patent/BR8907158A/pt unknown
- 1989-11-07 JP JP2500382A patent/JPH03502210A/ja active Pending
- 1989-11-07 CA CA002002436A patent/CA2002436A1/fr not_active Abandoned
- 1989-11-07 HU HU896883A patent/HUT55416A/hu unknown
- 1989-11-07 IL IL92242A patent/IL92242A0/xx unknown
- 1989-11-07 AU AU46248/89A patent/AU621172B2/en not_active Ceased
- 1989-11-08 YU YU02133/89A patent/YU213389A/xx unknown
- 1989-11-08 AT AT89311571T patent/ATE148893T1/de active
- 1989-11-08 PT PT92233A patent/PT92233A/pt not_active Application Discontinuation
- 1989-11-08 ES ES89311571T patent/ES2097743T3/es not_active Expired - Lifetime
- 1989-11-08 DE DE68927765T patent/DE68927765T2/de not_active Expired - Fee Related
- 1989-11-08 EP EP89311571A patent/EP0368644B1/fr not_active Expired - Lifetime
-
1990
- 1990-07-06 FI FI903448A patent/FI903448A0/fi not_active IP Right Cessation
- 1990-07-06 DK DK163790A patent/DK163790A/da not_active IP Right Cessation
- 1990-07-07 KR KR1019900701457A patent/KR900701857A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
DK163790D0 (da) | 1990-07-06 |
AU621172B2 (en) | 1992-03-05 |
ES2097743T3 (es) | 1997-04-16 |
HUT55416A (en) | 1991-05-28 |
FI903448A0 (fi) | 1990-07-06 |
HU896883D0 (en) | 1990-12-28 |
US4925821A (en) | 1990-05-15 |
AU4624889A (en) | 1990-05-28 |
EP0368644A1 (fr) | 1990-05-16 |
YU213389A (en) | 1991-02-28 |
IL92242A0 (en) | 1990-07-26 |
KR900701857A (ko) | 1990-12-04 |
PT92233A (pt) | 1990-05-31 |
CA2002436A1 (fr) | 1990-05-08 |
BR8907158A (pt) | 1991-02-26 |
JPH03502210A (ja) | 1991-05-23 |
DE68927765T2 (de) | 1997-05-28 |
WO1990005149A1 (fr) | 1990-05-17 |
DE68927765D1 (de) | 1997-03-27 |
EP0368644B1 (fr) | 1997-02-12 |
ATE148893T1 (de) | 1997-02-15 |
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Legal Events
Date | Code | Title | Description |
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AHB | Application shelved due to non-payment | ||
PBP | Patent lapsed |