ATE148893T1 - Verfahren zur anwendung von triethylaluminium beim herstellen eines alumoxans auf einem träger für einen aktiven metallocen-katalysator - Google Patents
Verfahren zur anwendung von triethylaluminium beim herstellen eines alumoxans auf einem träger für einen aktiven metallocen-katalysatorInfo
- Publication number
- ATE148893T1 ATE148893T1 AT89311571T AT89311571T ATE148893T1 AT E148893 T1 ATE148893 T1 AT E148893T1 AT 89311571 T AT89311571 T AT 89311571T AT 89311571 T AT89311571 T AT 89311571T AT E148893 T1 ATE148893 T1 AT E148893T1
- Authority
- AT
- Austria
- Prior art keywords
- catalyst
- alumoxane
- silica gel
- olefins
- supported
- Prior art date
Links
- 229910052782 aluminium Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title 1
- 239000012968 metallocene catalyst Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 239000000741 silica gel Substances 0.000 abstract 4
- 229910002027 silica gel Inorganic materials 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000012071 phase Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
- Unwinding Webs (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/268,834 US4925821A (en) | 1987-12-17 | 1988-11-08 | Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE148893T1 true ATE148893T1 (de) | 1997-02-15 |
Family
ID=23024690
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT89311571T ATE148893T1 (de) | 1988-11-08 | 1989-11-08 | Verfahren zur anwendung von triethylaluminium beim herstellen eines alumoxans auf einem träger für einen aktiven metallocen-katalysator |
Country Status (17)
Country | Link |
---|---|
US (1) | US4925821A (de) |
EP (1) | EP0368644B1 (de) |
JP (1) | JPH03502210A (de) |
KR (1) | KR900701857A (de) |
AT (1) | ATE148893T1 (de) |
AU (1) | AU621172B2 (de) |
BR (1) | BR8907158A (de) |
CA (1) | CA2002436A1 (de) |
DE (1) | DE68927765T2 (de) |
DK (1) | DK163790A (de) |
ES (1) | ES2097743T3 (de) |
FI (1) | FI903448A0 (de) |
HU (1) | HUT55416A (de) |
IL (1) | IL92242A0 (de) |
PT (1) | PT92233A (de) |
WO (1) | WO1990005149A1 (de) |
YU (1) | YU213389A (de) |
Families Citing this family (105)
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WO2018118155A1 (en) | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018147931A1 (en) | 2017-02-07 | 2018-08-16 | Exxonmobil Chemical Patents Inc. | Processes for reducing the loss of catalyst activity of a ziegler-natta catalyst |
WO2018191000A1 (en) | 2017-04-10 | 2018-10-18 | Exxonmobil Chemicl Patents Inc. | Methods for making polyolefin polymer compositions |
EP3621996B1 (de) | 2017-05-10 | 2023-01-18 | Univation Technologies, LLC | Katalysatorsysteme und verfahren zu ihrer verwendung |
US11591417B2 (en) | 2017-12-13 | 2023-02-28 | Exxonmobil Chemical Patents Inc. | Deactivation methods for active components from gas phase polyolefin polymerization processes |
WO2019173030A1 (en) | 2018-03-08 | 2019-09-12 | Exxonmobil Chemical Patents Inc. | Methods of preparing and monitoring a seed bed for polymerization reactor startup |
CN112055719B (zh) | 2018-05-02 | 2022-11-25 | 埃克森美孚化学专利公司 | 从中试装置放大到较大生产设施的方法 |
EP3788082A1 (de) | 2018-05-02 | 2021-03-10 | ExxonMobil Chemical Patents Inc. | Verfahren zur aufskalierung von einer pilotanlage zu einer grösseren produktionsanlage |
WO2022020025A1 (en) | 2020-07-22 | 2022-01-27 | Exxonmobil Chemical Patents Inc. | Polyolefin compositions and articles thereof |
EP4259669A1 (de) | 2020-12-08 | 2023-10-18 | ExxonMobil Chemical Patents Inc. | Hochdichte polyethylenzusammensetzungen mit langkettiger verzweigung |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3240382A1 (de) * | 1982-11-02 | 1984-05-03 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von gefuellten polyolefinen |
DE3424697C2 (de) * | 1984-07-05 | 1999-07-08 | Targor Gmbh | Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen |
US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
EP0250600B1 (de) * | 1985-12-24 | 1991-02-20 | Mitsui Petrochemical Industries, Ltd. | Verfahren zur polymerisation von alpha-olefinen |
EP0315234A1 (de) * | 1987-10-26 | 1989-05-10 | Texas Alkyls, Inc. | Verfahren zur Herstellung von Aluminoxanen |
US4912075A (en) * | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
US5008228A (en) * | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
US4935397A (en) * | 1988-09-28 | 1990-06-19 | Exxon Chemical Patents Inc. | Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same |
-
1988
- 1988-11-08 US US07/268,834 patent/US4925821A/en not_active Expired - Lifetime
-
1989
- 1989-11-07 AU AU46248/89A patent/AU621172B2/en not_active Ceased
- 1989-11-07 CA CA002002436A patent/CA2002436A1/en not_active Abandoned
- 1989-11-07 JP JP2500382A patent/JPH03502210A/ja active Pending
- 1989-11-07 IL IL92242A patent/IL92242A0/xx unknown
- 1989-11-07 HU HU896883A patent/HUT55416A/hu unknown
- 1989-11-07 BR BR898907158A patent/BR8907158A/pt unknown
- 1989-11-07 WO PCT/US1989/005006 patent/WO1990005149A1/en active Application Filing
- 1989-11-08 ES ES89311571T patent/ES2097743T3/es not_active Expired - Lifetime
- 1989-11-08 PT PT92233A patent/PT92233A/pt not_active Application Discontinuation
- 1989-11-08 AT AT89311571T patent/ATE148893T1/de active
- 1989-11-08 DE DE68927765T patent/DE68927765T2/de not_active Expired - Fee Related
- 1989-11-08 YU YU02133/89A patent/YU213389A/xx unknown
- 1989-11-08 EP EP89311571A patent/EP0368644B1/de not_active Expired - Lifetime
-
1990
- 1990-07-06 DK DK163790A patent/DK163790A/da not_active IP Right Cessation
- 1990-07-06 FI FI903448A patent/FI903448A0/fi not_active IP Right Cessation
- 1990-07-07 KR KR1019900701457A patent/KR900701857A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
PT92233A (pt) | 1990-05-31 |
DK163790D0 (da) | 1990-07-06 |
AU621172B2 (en) | 1992-03-05 |
JPH03502210A (ja) | 1991-05-23 |
CA2002436A1 (en) | 1990-05-08 |
HUT55416A (en) | 1991-05-28 |
DE68927765D1 (de) | 1997-03-27 |
KR900701857A (ko) | 1990-12-04 |
EP0368644B1 (de) | 1997-02-12 |
AU4624889A (en) | 1990-05-28 |
BR8907158A (pt) | 1991-02-26 |
IL92242A0 (en) | 1990-07-26 |
YU213389A (en) | 1991-02-28 |
FI903448A0 (fi) | 1990-07-06 |
HU896883D0 (en) | 1990-12-28 |
ES2097743T3 (es) | 1997-04-16 |
DK163790A (da) | 1990-08-23 |
DE68927765T2 (de) | 1997-05-28 |
WO1990005149A1 (en) | 1990-05-17 |
EP0368644A1 (de) | 1990-05-16 |
US4925821A (en) | 1990-05-15 |
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