DK138951B - Fremgangsmåde til fremstilling af N-phosphonomethyl-glycin. - Google Patents

Fremgangsmåde til fremstilling af N-phosphonomethyl-glycin.

Info

Publication number
DK138951B
DK138951B DK299773AA DK299773A DK138951B DK 138951 B DK138951 B DK 138951B DK 299773A A DK299773A A DK 299773AA DK 299773 A DK299773 A DK 299773A DK 138951 B DK138951 B DK 138951B
Authority
DK
Denmark
Prior art keywords
phosphonomethyl
glycine
preparation
Prior art date
Application number
DK299773AA
Other languages
Danish (da)
English (en)
Other versions
DK138951C (fi
Inventor
John Edward Franz
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/258,281 external-priority patent/US3954848A/en
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of DK138951B publication Critical patent/DK138951B/da
Application granted granted Critical
Publication of DK138951C publication Critical patent/DK138951C/da

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Saccharide Compounds (AREA)
DK299773AA 1972-05-31 1973-05-30 Fremgangsmåde til fremstilling af N-phosphonomethyl-glycin. DK138951B (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/258,281 US3954848A (en) 1972-05-31 1972-05-31 Process for producing N-phosphonomethyl glycine
US05/333,414 US3950402A (en) 1972-05-31 1973-02-16 Process for producing N-phosphonomethyl glycine

Publications (2)

Publication Number Publication Date
DK138951B true DK138951B (da) 1978-11-20
DK138951C DK138951C (fi) 1979-06-05

Family

ID=26946544

Family Applications (1)

Application Number Title Priority Date Filing Date
DK299773AA DK138951B (da) 1972-05-31 1973-05-30 Fremgangsmåde til fremstilling af N-phosphonomethyl-glycin.

Country Status (25)

Country Link
US (1) US3950402A (fi)
JP (1) JPS5111093B2 (fi)
BE (1) BE800238A (fi)
BG (1) BG21212A3 (fi)
CA (1) CA992093A (fi)
CH (1) CH574968A5 (fi)
CS (1) CS177133B2 (fi)
DD (1) DD104303A5 (fi)
DE (1) DE2327680C3 (fi)
DK (1) DK138951B (fi)
EG (1) EG11140A (fi)
ES (2) ES415335A1 (fi)
FR (2) FR2186477B1 (fi)
GB (1) GB1432043A (fi)
HU (1) HU167343B (fi)
IE (1) IE37730B1 (fi)
IL (1) IL42393A (fi)
IT (1) IT988869B (fi)
NL (1) NL162656C (fi)
NO (2) NO140556C (fi)
PL (1) PL107856B1 (fi)
RO (2) RO62901A (fi)
SE (2) SE404019B (fi)
SU (1) SU623523A3 (fi)
YU (2) YU36977B (fi)

Families Citing this family (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4072706A (en) * 1976-01-02 1978-02-07 Monsanto Company Oxidation of phosphonomethylamines
MX4703E (es) * 1976-12-20 1982-08-04 Monsanto Co Procedimiento mejorado para la preparacion de mono y disales de n-fosfonometilglicina
US4454043A (en) * 1980-11-17 1984-06-12 Monsanto Company Column switching procedure
IL66824A0 (en) * 1982-06-25 1982-12-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
GB8726714D0 (en) * 1987-11-14 1987-12-16 Beecham Group Plc Compounds
US5187292A (en) * 1988-08-18 1993-02-16 Rhone-Poulenc Agrochimie N-sulfomethylglycinate, use in the preparation of herbicides of the glyphosate type
FR2635522B1 (fr) * 1988-08-18 1990-11-16 Rhone Poulenc Agrochimie N-sulfonomethylglycinate procede de preparation, utilisation dans la preparation d'herbicides de type glyphosate
US4898972A (en) * 1988-09-26 1990-02-06 Monsanto Company Process for producing N-phosphonomethylglycine
HU204533B (en) * 1988-11-02 1992-01-28 Nitrokemia Ipartelepek Process for producing n-phosphono-methyl-glycine
US4937376A (en) * 1989-05-25 1990-06-26 Monsanto Company Process for producing N-phosphonomethylglycine
US4952723A (en) * 1989-07-31 1990-08-28 Monsanto Company Process for producing N-phosphonomethylglycine
US5047579A (en) * 1990-01-26 1991-09-10 Monsanto Company Process for producing n-phosphonomethylglycine
ES2021229A6 (es) * 1990-03-12 1991-10-16 Ercros Sa Perfeccionamientos introducidos en un procedimiento de obtencion de n-fosfonometilglicina por oxidacion de n-fosfonometiliminodiacetico.
US5043475A (en) * 1990-06-25 1991-08-27 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5077430A (en) * 1990-06-25 1991-12-31 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5077431A (en) * 1990-06-25 1991-12-31 Monsanto Company Peroxide process for producing n-phosphonomethylglycine
US5095140A (en) * 1990-06-25 1992-03-10 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5023369A (en) * 1990-06-25 1991-06-11 Monsanto Company Process for producing N-phosphonomethylglycine
US5061820A (en) * 1990-10-22 1991-10-29 Monsanto Company Process for producing N-phosphonomethylgylcine
US5072033A (en) * 1990-12-11 1991-12-10 Monsanto Company Process for producing N-phosphonomethylglycine
GB9300641D0 (en) * 1993-01-14 1993-03-03 Zeneca Ltd Process
SI9400449A (en) * 1994-12-20 1996-06-30 Pinus D D Process for preparing N-phosphonomethyl glycin
US6365772B1 (en) 1995-05-30 2002-04-02 Hampshire Chemical Corp. Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
DK0833831T3 (da) * 1995-06-07 2002-03-18 Monsanto Technology Llc Fremgangsmåde til fremstilling af N-phosphonomethyliminodieddikesyre
US5986128A (en) * 1996-11-01 1999-11-16 Monsanto Company Use of monosodium iminodiacetic acid solutions in the preparation of N-phosphonomethyliminodiacetic acid
EP1062221B1 (en) * 1998-02-12 2006-05-10 Monsanto Technology LLC Process for making glyphosate by oxidizing n-substituted glyphosates
US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
US6417133B1 (en) * 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
US5962729A (en) * 1998-05-14 1999-10-05 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon
DE69905894T2 (de) * 1998-07-06 2003-12-04 Syngenta Participations Ag, Basel Herstellung von n-phosphonomethylglycin salzen
IES980552A2 (en) * 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
BR9907000A (pt) * 1998-09-08 2000-09-26 Hampshire Chemical Corp Sìntese de ácido fosfonometiliminodiacético com efluente reduzido
NZ516546A (en) 1999-07-23 2003-08-29 Basf Ag Method of producing glyphosate or a salt thereof
WO2001012640A1 (de) 1999-08-11 2001-02-22 Basf Aktiengesellschaft Verfahren zur herstellung von phosphonomethylglycin
CA2395206A1 (en) * 1999-12-21 2001-06-28 Monsanto Technology Llc Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal-containing catalyst in liquid phase oxidation reactions
PT102419A (pt) * 2000-02-09 2001-08-30 Pedro Manuel Brito Da Silva Co N-fosfonoalquil)glicina n-(fosfonobenzil)glicina e n-(fosfonofenetil)glicina e seu processo de fabrico e a sua aplicacao como herbicida
AU2001264605C1 (en) 2000-05-15 2005-10-06 Monsanto Technology Llc Preparation of iminodiacetic acid compounds from monoethanolamine substrates
US7015351B2 (en) * 2000-05-22 2006-03-21 Monsanto Technology Llc Reaction systems for making N-(phosphonomethyl) glycine compounds
US6927304B2 (en) 2000-05-22 2005-08-09 Monsanto Technology Llc De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions
US6818450B2 (en) 2001-05-22 2004-11-16 Monsanto Technology Llc Use of infrared spectroscopy for on-line process control and endpoint detection
DE10130136A1 (de) * 2001-06-22 2003-01-02 Basf Ag Verfahren zur Gewinnung von N-Phosphonomethylglycin
CA2463776A1 (en) 2001-10-18 2003-04-24 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
CA2476255C (en) * 2002-02-14 2012-07-31 Monsanto Technology Llc Oxidation catalyst and process for its preparation and process for oxidation using it
US6921834B2 (en) 2002-05-22 2005-07-26 Dow Agrosciences Llc Continuous process for preparing N-phosphonomethyl glycine
JP4202047B2 (ja) * 2002-05-24 2008-12-24 富士通株式会社 ヘッド位置制御方法及びデイスク記憶装置
AR040319A1 (es) * 2002-06-28 2005-03-23 Monsanto Technology Llc Uso de telurio en catalizadores con contenido de metales nobles y con soporte de carbon para reacciones de oxidacion en fase liquida
ES2407031T3 (es) * 2003-08-14 2013-06-11 Monsanto Technology Llc Procedimiento para la oxidación del ácido N-(fosfonometil)iminodiacético o de una de sus sales
US7179936B2 (en) * 2003-09-17 2007-02-20 Monsanto Technology Llc Process for recovering a crystalline product from solution
WO2006031938A2 (en) * 2004-09-15 2006-03-23 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
TW200624151A (en) * 2004-11-12 2006-07-16 Monsanto Technology Llc Recovery of noble metals from aqueous process streams
AU2006214086B2 (en) 2005-02-17 2012-01-19 Monsanto Technology Llc Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
AU2006241162A1 (en) * 2005-04-25 2006-11-02 Monsanto Technology Llc Altering the crystal size distribution of N-(phosphonomethyl) iminodiacetic acid for improved filtration and product quality
AR059585A1 (es) * 2006-02-17 2008-04-16 Monsanto Technology Llc Catalizadores que contienen metales de transicion y procesos para su preparacion y uso como catalizadores para celdas de combustible
US7771494B2 (en) * 2007-01-31 2010-08-10 Monsanto Technology Llc Process for selective removal of water and impurities from N-(phosphonomethyl)glycine
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
CN101353358B (zh) * 2008-09-05 2011-01-19 江苏好收成韦恩农化股份有限公司 用改进反应系统制备n-(膦酰基甲基)甘氨酸的方法
CN103044486A (zh) * 2013-01-02 2013-04-17 北京化工大学 一种直接氧化双甘膦制备草甘膦的方法
CN110997561A (zh) 2017-06-26 2020-04-10 孟山都技术公司 来自草甘膦制造工艺的废物流的磷控制
CN109796491A (zh) * 2018-12-24 2019-05-24 荆州鸿翔化工有限公司 一种制备草甘膦的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL285361A (fi) * 1961-11-13 1900-01-01
US3429914A (en) * 1964-09-03 1969-02-25 Monsanto Co Organo-phosphono-amine oxides
DE2132511C3 (de) * 1971-06-30 1974-06-27 Joh. A. Benckiser Gmbh, 6700 Ludwigshafen Verfahren zur Herstellung von Aminomethylenphosphonsäuren

Also Published As

Publication number Publication date
CS177133B2 (fi) 1977-07-29
NO783636L (no) 1973-12-03
FR2186477B1 (fi) 1977-12-30
JPS5111093B2 (fi) 1976-04-08
YU42985B (en) 1989-02-28
BE800238A (fr) 1973-11-30
SE7600415L (sv) 1976-01-16
IT988869B (it) 1975-04-30
FR2186477A1 (fi) 1974-01-11
YU36977B (en) 1984-08-31
IE37730B1 (en) 1977-09-28
SE404019B (sv) 1978-09-18
FR2193831A1 (fi) 1974-02-22
DE2327680C3 (de) 1979-01-04
RO66031A (ro) 1980-07-15
NO140556C (no) 1979-09-26
ES415335A1 (es) 1976-05-01
US3950402A (en) 1976-04-13
FR2193831B1 (fi) 1978-01-06
IL42393A0 (en) 1973-07-30
RO62901A (fi) 1977-08-15
NL162656B (nl) 1980-01-15
CA992093A (en) 1976-06-29
DD104303A5 (fi) 1974-03-05
BG21212A3 (bg) 1976-03-20
CH574968A5 (fi) 1976-04-30
HU167343B (fi) 1975-09-27
ES440610A1 (es) 1977-03-01
SE407579B (sv) 1979-04-02
NO149176B (no) 1983-11-21
YU142773A (en) 1982-06-18
NO149176C (no) 1984-02-29
YU262880A (en) 1983-06-30
DK138951C (fi) 1979-06-05
PL107856B1 (pl) 1980-03-31
NL162656C (nl) 1980-06-16
JPS4948620A (fi) 1974-05-11
EG11140A (en) 1977-08-15
IL42393A (en) 1975-12-31
DE2327680B2 (de) 1978-05-11
DE2327680A1 (de) 1973-12-13
SU623523A3 (ru) 1978-09-05
NL7307449A (fi) 1973-12-04
IE37730L (en) 1973-11-30
GB1432043A (en) 1976-04-14
NO140556B (no) 1979-06-18
AU5627773A (en) 1974-12-05

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Legal Events

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PUP Patent expired