DK0935624T3 - Stive polyurethanskum - Google Patents
Stive polyurethanskumInfo
- Publication number
- DK0935624T3 DK0935624T3 DK97911214T DK97911214T DK0935624T3 DK 0935624 T3 DK0935624 T3 DK 0935624T3 DK 97911214 T DK97911214 T DK 97911214T DK 97911214 T DK97911214 T DK 97911214T DK 0935624 T3 DK0935624 T3 DK 0935624T3
- Authority
- DK
- Denmark
- Prior art keywords
- polyurethane foam
- rigid polyurethane
- rigid
- foam
- polyurethane
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/089—Reaction retarding agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96117643 | 1996-11-04 | ||
PCT/EP1997/005610 WO1998020058A1 (en) | 1996-11-04 | 1997-10-10 | Rigid polyurethane foams |
Publications (1)
Publication Number | Publication Date |
---|---|
DK0935624T3 true DK0935624T3 (da) | 2000-12-18 |
Family
ID=8223363
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK97911214T DK0935624T3 (da) | 1996-11-04 | 1997-10-10 | Stive polyurethanskum |
Country Status (23)
Country | Link |
---|---|
US (2) | US6403665B1 (de) |
EP (1) | EP0935624B1 (de) |
JP (1) | JP2001503461A (de) |
KR (1) | KR20000053019A (de) |
CN (1) | CN1134473C (de) |
AR (1) | AR010541A1 (de) |
AU (1) | AU723069B2 (de) |
BR (1) | BR9712860A (de) |
CA (1) | CA2268182A1 (de) |
CZ (1) | CZ156699A3 (de) |
DE (1) | DE69702926T2 (de) |
DK (1) | DK0935624T3 (de) |
ES (1) | ES2149580T3 (de) |
HU (1) | HUP9904499A3 (de) |
ID (1) | ID22277A (de) |
NZ (1) | NZ335208A (de) |
PL (1) | PL333050A1 (de) |
RU (1) | RU2189379C2 (de) |
SI (1) | SI0935624T1 (de) |
SK (1) | SK58299A3 (de) |
TR (1) | TR199900970T2 (de) |
TW (1) | TW399076B (de) |
WO (1) | WO1998020058A1 (de) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6803495B2 (en) * | 2000-06-28 | 2004-10-12 | World Properties, Inc. | Polyurethane foam composition and method of manufacture thereof |
US6387972B1 (en) * | 2001-02-15 | 2002-05-14 | Crompton Corporation | Process to enhance polyurethane foam performance |
US20030039226A1 (en) * | 2001-08-24 | 2003-02-27 | Kwak Joseph A. | Physical layer automatic repeat request (ARQ) |
AU2008209665B2 (en) * | 2001-08-30 | 2011-08-04 | Huntsman International Llc | Process for making rigid urethane-modified polyisocyanurate foams |
EP1288239A1 (de) | 2001-08-30 | 2003-03-05 | Huntsman International Llc | Verfahren zur Herstellung von urethanmodifizierten Polyisocyanurathartschäumen |
US6753357B2 (en) * | 2001-12-18 | 2004-06-22 | Foam Supplies, Inc. | Rigid foam compositions and method employing methyl formate as a blowing agent |
GB0222522D0 (en) | 2002-09-27 | 2002-11-06 | Controlled Therapeutics Sct | Water-swellable polymers |
AU2012200194B2 (en) * | 2004-08-04 | 2013-12-05 | Foam Supplies, Inc. | Reactivity drift and catalyst degradation in polyurethane foam |
MX2007001331A (es) * | 2004-08-04 | 2008-03-11 | Foam Supplies Inc | Variacion de la reactividad y degradacion del catalizador en espuma de poliuretano. |
GB0417401D0 (en) | 2004-08-05 | 2004-09-08 | Controlled Therapeutics Sct | Stabilised prostaglandin composition |
US8501828B2 (en) * | 2004-08-11 | 2013-08-06 | Huntsman Petrochemical Llc | Cure rebond binder |
US20060141239A1 (en) * | 2004-12-28 | 2006-06-29 | Gilder Stephen D | Method for making a bonded foam product suitable for use as an underlayment for floor coverings |
ES2942678T3 (es) | 2005-07-26 | 2023-06-05 | Knauf Insulation Gmbh | Aglutinantes y materiales fabricados con los mismos |
GB0613333D0 (en) | 2006-07-05 | 2006-08-16 | Controlled Therapeutics Sct | Hydrophilic polyurethane compositions |
GB0613638D0 (en) | 2006-07-08 | 2006-08-16 | Controlled Therapeutics Sct | Polyurethane elastomers |
JP2008074880A (ja) * | 2006-09-19 | 2008-04-03 | Nippon Polyurethane Ind Co Ltd | 硬質ポリウレタンスラブフォームの製造方法、硬質ポリウレタンスラブフォームおよび配管用断熱材 |
GB0620685D0 (en) | 2006-10-18 | 2006-11-29 | Controlled Therapeutics Sct | Bioresorbable polymers |
ES2574128T3 (es) * | 2007-01-19 | 2016-06-15 | Huntsman Petrochemical Llc | Aminas terciarias bloqueadas con ácidos poliméricos |
BRPI0721232B1 (pt) | 2007-01-25 | 2023-01-24 | Knauf Insulation Limited | Placa de madeira compósita |
EP2125650B1 (de) | 2007-01-25 | 2024-05-15 | Knauf Insulation | Mineralfaserplatte |
PL2108006T3 (pl) | 2007-01-25 | 2021-04-19 | Knauf Insulation Gmbh | Spoiwa i wytworzone z nich materiały |
WO2008127936A2 (en) | 2007-04-13 | 2008-10-23 | Knauf Insulation Gmbh | Composite maillard-resole binders |
GB0715100D0 (en) | 2007-08-03 | 2007-09-12 | Knauf Insulation Ltd | Binders |
US9453115B2 (en) * | 2007-10-12 | 2016-09-27 | Honeywell International Inc. | Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents |
JP5670321B2 (ja) * | 2008-06-12 | 2015-02-18 | 3A テヒノロギー ウント メーニッジメント リミテッド | 発泡ポリエステル類及びその製造方法 |
EP2462169B1 (de) | 2009-08-07 | 2019-02-27 | Knauf Insulation | Molassebindemittel |
BR112012028526B1 (pt) | 2010-05-07 | 2020-11-17 | Knauf Insulation | método de preparação de uma tábua de madeira compósita com um aglutinante polimérico, termorrígido, curado |
JP6223823B2 (ja) | 2010-05-07 | 2017-11-01 | ナフ インサレーション エセペーアールエル | 炭水化物ポリアミン結合剤およびそれを用いて作製される材料 |
EP2576882B1 (de) | 2010-06-07 | 2015-02-25 | Knauf Insulation | Faserprodukte mit temperaturregelungzusätzen |
WO2012152731A1 (en) | 2011-05-07 | 2012-11-15 | Knauf Insulation | Liquid high solids binder composition |
KR102049107B1 (ko) * | 2012-02-28 | 2019-11-27 | 바스프 에스이 | 경질 중합체 발포체의 제조 방법 |
GB201206193D0 (en) | 2012-04-05 | 2012-05-23 | Knauf Insulation Ltd | Binders and associated products |
US9598548B2 (en) * | 2012-08-09 | 2017-03-21 | Basf Se | Producing polymer foams comprising imide groups |
GB201214734D0 (en) | 2012-08-17 | 2012-10-03 | Knauf Insulation Ltd | Wood board and process for its production |
US10023681B2 (en) * | 2012-10-24 | 2018-07-17 | Evonik Degussa Gmbh | Delay action catalyst for improving the stability of polyurethane systems having halogen containing blowing agents |
ES2921601T3 (es) | 2012-12-05 | 2022-08-30 | Knauf Insulation Sprl | Aglutinante |
EP3102587B1 (de) | 2014-02-07 | 2018-07-04 | Knauf Insulation, LLC | Unvulkanisierte gegenstände mit verbesserter haltbarkeit |
GB201408909D0 (en) | 2014-05-20 | 2014-07-02 | Knauf Insulation Ltd | Binders |
EP3280751B1 (de) * | 2015-04-07 | 2021-03-17 | Covestro Intellectual Property GmbH & Co. KG | Polyolvormischungszusammensetzung für polyurethanhartschaumstoffe |
GB201517867D0 (en) | 2015-10-09 | 2015-11-25 | Knauf Insulation Ltd | Wood particle boards |
GB201610063D0 (en) | 2016-06-09 | 2016-07-27 | Knauf Insulation Ltd | Binders |
GB201701569D0 (en) | 2017-01-31 | 2017-03-15 | Knauf Insulation Ltd | Improved binder compositions and uses thereof |
CN107337778A (zh) * | 2017-08-07 | 2017-11-10 | 冯运成 | 聚氨酯泡沫组合物及由其制备的聚氨酯泡沫塑料 |
BR112020003914A2 (pt) * | 2017-09-05 | 2020-09-08 | Huntsman Petrochemical Llc | pré-mistura de poliol, métodos para formar uma pré-mistura de poliol e para formar uma espuma de poliuretano ou poliisocianurato, espuma, e, formulação de poliuretano |
GB201804908D0 (en) | 2018-03-27 | 2018-05-09 | Knauf Insulation Ltd | Binder compositions and uses thereof |
GB201804907D0 (en) | 2018-03-27 | 2018-05-09 | Knauf Insulation Ltd | Composite products |
BR112022019500A2 (pt) * | 2020-03-27 | 2022-12-06 | Huntsman Petrochemical Llc | Catalisadores de alquilaminopiridina bloqueados com ácido para espuma de poliuretano |
CN115572361A (zh) * | 2021-06-21 | 2023-01-06 | 万华化学(宁波)容威聚氨酯有限公司 | 一种酸性聚氨酯硬质泡沫及其制备方法 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL104983C (de) | 1955-03-04 | |||
NL103386C (de) * | 1958-03-12 | |||
US3645925A (en) | 1970-07-31 | 1972-02-29 | Jefferson Chem Co Inc | 4 4'-dimorpholinodiethyl ether catalyst for polyurethane preparation |
US3661808A (en) | 1970-07-31 | 1972-05-09 | Jefferson Chem Co Inc | Catalyst combination for polyurethanes |
US3980594A (en) | 1975-04-23 | 1976-09-14 | The General Tire & Rubber Company | Trimerization of aromatic isocyanates catalyzed by certain ammonium salts |
DE2607999C2 (de) | 1976-02-27 | 1983-02-03 | Bayer Ag, 5090 Leverkusen | Urethan- und Isocyanuratgruppen aufweisende Schaumstoffe und ein Verfahren zu ihrer Herstellung |
US4228248A (en) | 1979-02-12 | 1980-10-14 | Texaco Development Corp. | Morpholine derivatives and use as polyurethane catalyst |
US5688834A (en) * | 1991-08-30 | 1997-11-18 | Alliedsignal, Inc. | Catalysts which stabilize hydrohalocarbon blowing agent in polyurethane foam formulations |
US4760101A (en) | 1986-08-25 | 1988-07-26 | Ashland Oil, Inc. | Polyurethane-forming binder compositions containing certain carboxylic acids as bench life extenders |
US4758605A (en) * | 1987-03-12 | 1988-07-19 | The Dow Chemical Company | Stabilization of reactivity of polyester polyol based polyurethane foam components |
DE3824354A1 (de) | 1988-07-19 | 1990-01-25 | Basf Ag, 67063 Ludwigshafen | Verfahren zur herstellung von zellhaltigen kunststoffen nach dem polyisocyanat-polyadditionsverfahren mittels lagerstabiler, treibmittelhaltiger emulsionen und diese emulsionen |
US4983320A (en) | 1989-05-18 | 1991-01-08 | Akzo N.V. | Dialkyl dicarbonates as blowing agents for polymers |
KR0177154B1 (ko) | 1989-06-06 | 1999-05-15 | 야마구찌 도시아끼 | 경질 폴리우레탄포움의 제조방법 |
ATE129265T1 (de) | 1989-06-28 | 1995-11-15 | Bosch Siemens Hausgeraete | Hartschaumstoff sowie verfahren zur herstellung desselben. |
US4981879A (en) | 1989-08-28 | 1991-01-01 | Jim Walter Research Corp. | Rigid foam with improved "K" factor from perfluorinated hydrocarbons |
JPH03160015A (ja) | 1989-11-16 | 1991-07-10 | Bridgestone Corp | 硬質ポリウレタンフォームの製造方法 |
GB9102362D0 (en) | 1991-02-04 | 1991-03-20 | Ici Plc | Polymeric foams |
AU652034B2 (en) | 1991-04-03 | 1994-08-11 | Imperial Chemical Industries Plc | Manufacture of rigid foams and compositions therefor |
US5395859A (en) | 1991-06-21 | 1995-03-07 | Alliedsignal Inc. | Catalysts which stabilize hydrohalocarbon blowing agent in polyisocyanurate foam formulations during polymerization |
JP3160015B2 (ja) | 1991-07-12 | 2001-04-23 | 株式会社ガスター | 浴槽洗浄方法 |
WO1993015121A1 (de) | 1992-01-31 | 1993-08-05 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur herstellung von kunststoffen mit amid-gruppen |
JPH05222146A (ja) | 1992-02-14 | 1993-08-31 | Daikin Ind Ltd | 硬質ポリウレタンフォームの製造法 |
US5591781A (en) | 1993-10-27 | 1997-01-07 | Tosoh Corporation | Process for producing polyurethane foam with high curing rate |
US5489618A (en) * | 1993-11-29 | 1996-02-06 | Osi Specialties, Inc. | Process for preparing polyurethane foam |
JP3061717B2 (ja) | 1993-12-03 | 2000-07-10 | 日清紡績株式会社 | 変性ポリイソシアヌレート発泡体の製造法 |
US5539008A (en) | 1993-12-29 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Foamable composition containing unsaturated perfluorochemical blowing agent |
US5559161A (en) | 1994-02-18 | 1996-09-24 | Air Products And Chemicals, Inc. | Hydroxy-functional triamine catalyst compositions for the production of polyurethanes |
EP0672696B1 (de) | 1994-03-18 | 1999-05-19 | Air Products And Chemicals, Inc. | Amin-Katalysatoren mit niedrigem Geruch für auf Polyester-Polyole basierte Polyurethan-Blockweichschaumstoffe |
CA2144490A1 (en) | 1994-03-28 | 1995-09-29 | Michael J. Skowronski | Catalyst for polyisocyanurate foams made with alternative blowing agents |
US5430071A (en) | 1994-07-08 | 1995-07-04 | Basf Corporation | Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture |
DE4444249C2 (de) * | 1994-12-13 | 2003-12-24 | Basf Schwarzheide Gmbh | Katalysatorzusammensetzung für die Herstellung von nichtzelligen Polyurethanen nach dem Polyisocyanat-Polyadditionsverfahren |
US5464562A (en) | 1995-04-24 | 1995-11-07 | Basf Corporation | Polyoxyalkylene polyether monool polyurethane foam additive |
-
1997
- 1997-10-10 ID IDW990264D patent/ID22277A/id unknown
- 1997-10-10 DK DK97911214T patent/DK0935624T3/da active
- 1997-10-10 TR TR1999/00970T patent/TR199900970T2/xx unknown
- 1997-10-10 CN CNB971993998A patent/CN1134473C/zh not_active Expired - Fee Related
- 1997-10-10 WO PCT/EP1997/005610 patent/WO1998020058A1/en not_active Application Discontinuation
- 1997-10-10 BR BR9712860-0A patent/BR9712860A/pt active Search and Examination
- 1997-10-10 SK SK582-99A patent/SK58299A3/sk unknown
- 1997-10-10 RU RU99111765/04A patent/RU2189379C2/ru not_active IP Right Cessation
- 1997-10-10 EP EP97911214A patent/EP0935624B1/de not_active Expired - Lifetime
- 1997-10-10 SI SI9730089T patent/SI0935624T1/xx unknown
- 1997-10-10 ES ES97911214T patent/ES2149580T3/es not_active Expired - Lifetime
- 1997-10-10 JP JP52098898A patent/JP2001503461A/ja active Pending
- 1997-10-10 CA CA002268182A patent/CA2268182A1/en not_active Abandoned
- 1997-10-10 NZ NZ335208A patent/NZ335208A/xx unknown
- 1997-10-10 AU AU48668/97A patent/AU723069B2/en not_active Ceased
- 1997-10-10 KR KR1019990703907A patent/KR20000053019A/ko not_active Application Discontinuation
- 1997-10-10 DE DE69702926T patent/DE69702926T2/de not_active Expired - Lifetime
- 1997-10-10 CZ CZ991566A patent/CZ156699A3/cs unknown
- 1997-10-10 HU HU9904499A patent/HUP9904499A3/hu unknown
- 1997-10-10 PL PL97333050A patent/PL333050A1/xx unknown
- 1997-10-16 TW TW086115257A patent/TW399076B/zh not_active IP Right Cessation
- 1997-10-17 US US08/953,363 patent/US6403665B1/en not_active Expired - Lifetime
- 1997-11-04 AR ARP970105132A patent/AR010541A1/es not_active Application Discontinuation
-
2002
- 2002-03-06 US US10/090,783 patent/US6528549B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
HUP9904499A3 (en) | 2000-12-28 |
WO1998020058A1 (en) | 1998-05-14 |
US6403665B1 (en) | 2002-06-11 |
CA2268182A1 (en) | 1998-05-14 |
AR010541A1 (es) | 2000-06-28 |
HUP9904499A2 (hu) | 2000-05-28 |
TR199900970T2 (en) | 1999-07-21 |
TW399076B (en) | 2000-07-21 |
SK58299A3 (en) | 2000-02-14 |
US6528549B2 (en) | 2003-03-04 |
KR20000053019A (ko) | 2000-08-25 |
US20020123598A1 (en) | 2002-09-05 |
DE69702926D1 (en) | 2000-09-28 |
AU4866897A (en) | 1998-05-29 |
NZ335208A (en) | 2000-11-24 |
JP2001503461A (ja) | 2001-03-13 |
AU723069B2 (en) | 2000-08-17 |
DE69702926T2 (de) | 2001-02-22 |
EP0935624B1 (de) | 2000-08-23 |
BR9712860A (pt) | 1999-12-07 |
CZ156699A3 (cs) | 1999-08-11 |
CN1235617A (zh) | 1999-11-17 |
SI0935624T1 (en) | 2001-02-28 |
ID22277A (id) | 1999-09-30 |
PL333050A1 (en) | 1999-11-08 |
CN1134473C (zh) | 2004-01-14 |
RU2189379C2 (ru) | 2002-09-20 |
EP0935624A1 (de) | 1999-08-18 |
ES2149580T3 (es) | 2000-11-01 |
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