DE69929222T2 - Selektive oxidation und katalysator dafür - Google Patents
Selektive oxidation und katalysator dafür Download PDFInfo
- Publication number
- DE69929222T2 DE69929222T2 DE69929222T DE69929222T DE69929222T2 DE 69929222 T2 DE69929222 T2 DE 69929222T2 DE 69929222 T DE69929222 T DE 69929222T DE 69929222 T DE69929222 T DE 69929222T DE 69929222 T2 DE69929222 T2 DE 69929222T2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- net
- oxidation
- selective oxidation
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- 238000007254 oxidation reaction Methods 0.000 title claims description 57
- 230000003647 oxidation Effects 0.000 title claims description 56
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- 238000006243 chemical reaction Methods 0.000 claims description 32
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- 125000002947 alkylene group Chemical group 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
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- 239000001569 carbon dioxide Substances 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
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- 239000000654 additive Substances 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- 229910052792 caesium Inorganic materials 0.000 description 4
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 4
- 239000012018 catalyst precursor Substances 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 4
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
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- 239000011149 active material Substances 0.000 description 2
- -1 air Chemical compound 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
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- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 238000006735 epoxidation reaction Methods 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
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- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000000643 oven drying Methods 0.000 description 2
- OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- XNGYKPINNDWGGF-UHFFFAOYSA-L silver oxalate Chemical compound [Ag+].[Ag+].[O-]C(=O)C([O-])=O XNGYKPINNDWGGF-UHFFFAOYSA-L 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
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- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
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- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
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- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
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- 239000012043 crude product Substances 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
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- 239000000374 eutectic mixture Substances 0.000 description 1
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- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
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- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- WPFGFHJALYCVMO-UHFFFAOYSA-L rubidium carbonate Chemical compound [Rb+].[Rb+].[O-]C([O-])=O WPFGFHJALYCVMO-UHFFFAOYSA-L 0.000 description 1
- 229910000026 rubidium carbonate Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
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- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/58—Fabrics or filaments
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10371798P | 1998-10-09 | 1998-10-09 | |
| US103717P | 1998-10-09 | ||
| US09/407,436 US6417376B1 (en) | 1998-10-09 | 1999-09-29 | Selective oxidation process and catalyst therefor |
| US407436 | 1999-09-29 | ||
| PCT/US1999/023347 WO2000021944A2 (en) | 1998-10-09 | 1999-10-07 | Selective oxidation process and catalyst therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69929222D1 DE69929222D1 (de) | 2006-02-02 |
| DE69929222T2 true DE69929222T2 (de) | 2006-09-07 |
Family
ID=26800777
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69929222T Expired - Lifetime DE69929222T2 (de) | 1998-10-09 | 1999-10-07 | Selektive oxidation und katalysator dafür |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6417376B1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1119410B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5153034B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR100611443B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN1332764C (cg-RX-API-DMAC7.html) |
| AR (1) | AR020759A1 (cg-RX-API-DMAC7.html) |
| AT (1) | ATE314145T1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU760603B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BR9914121A (cg-RX-API-DMAC7.html) |
| DE (1) | DE69929222T2 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2257100T3 (cg-RX-API-DMAC7.html) |
| ID (1) | ID29043A (cg-RX-API-DMAC7.html) |
| MX (1) | MXPA01003318A (cg-RX-API-DMAC7.html) |
| MY (1) | MY119687A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2000021944A2 (cg-RX-API-DMAC7.html) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19931902A1 (de) * | 1999-07-08 | 2001-01-18 | Consortium Elektrochem Ind | Verfahren zur Herstellung von monolithischen Oxidationskatalysatoren und deren Verwendung bei der Gasphasenoxidation von Kohlenwasserstoffen |
| US6667017B2 (en) * | 1999-10-15 | 2003-12-23 | Abb Lummus Global, Inc. | Process for removing environmentally harmful compounds |
| JP4995373B2 (ja) * | 2001-02-20 | 2012-08-08 | 三菱レイヨン株式会社 | 反応管、触媒の製造方法、不飽和アルデヒドおよび不飽和カルボン酸の製造方法 |
| CN100393444C (zh) * | 2003-07-30 | 2008-06-11 | 康宁股份有限公司 | 用于化学用途和热学用途的金属蜂窝状基材 |
| US7067455B2 (en) * | 2003-11-21 | 2006-06-27 | Conocophillips Company | Copper modified catalysts for oxidative dehydrogenation |
| DE102008025843A1 (de) * | 2008-05-29 | 2009-12-03 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Phthalsäureanhydrid |
| CN102712850B (zh) * | 2009-10-27 | 2016-08-03 | 艾格耐特资源有限公司 | 从生物油和/或煤油制备烃产物的方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US218124A (en) * | 1879-08-05 | Improvement in seed-sower and fertilizer-distributer | ||
| US3713281A (en) | 1971-11-02 | 1973-01-30 | G Asker | Heat and moisture exchange packing |
| EP0061304A1 (en) | 1981-03-18 | 1982-09-29 | Johnson Matthey Public Limited Company | Three dimensional interstitial catalyst support, its manufacture and use |
| JPS58153538A (ja) | 1982-03-08 | 1983-09-12 | Matsushita Electric Ind Co Ltd | 酸化触媒体 |
| CH653917A5 (de) | 1982-04-07 | 1986-01-31 | Alusuisse | Katalysatortraeger und seine verwendung. |
| DE3513726A1 (de) | 1985-04-17 | 1986-10-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von katalysatoren fuer die abgasentgiftung |
| DE3533573A1 (de) | 1985-09-20 | 1987-03-26 | Basf Ag | Traegerkatalysator, verfahren zu seiner herstellung und seine verwendung |
| US5102745A (en) * | 1989-11-13 | 1992-04-07 | Auburn University | Mixed fiber composite structures |
| CN1048892A (zh) | 1989-05-24 | 1991-01-30 | 奥本大学 | 混合纤维复合材料结构及其制法和用途 |
| US5080963A (en) | 1989-05-24 | 1992-01-14 | Auburn University | Mixed fiber composite structures high surface area-high conductivity mixtures |
| CZ286616B6 (cs) * | 1989-10-16 | 2000-05-17 | Haldor Topsoe A/S | Katalyzátor pro výrobu aldehydů |
| US5096663A (en) | 1990-05-29 | 1992-03-17 | Auburn University | Method of optimizing composite preparation for electrical properties: maximum capacitance electrodes |
| US20020068026A1 (en) * | 1997-08-08 | 2002-06-06 | Lawrence L. Murrell | Reactor |
-
1999
- 1999-09-29 US US09/407,436 patent/US6417376B1/en not_active Expired - Lifetime
- 1999-10-07 EP EP99970388A patent/EP1119410B1/en not_active Expired - Lifetime
- 1999-10-07 WO PCT/US1999/023347 patent/WO2000021944A2/en not_active Ceased
- 1999-10-07 CN CNB998118486A patent/CN1332764C/zh not_active Expired - Lifetime
- 1999-10-07 KR KR20017004479A patent/KR100611443B1/ko not_active Expired - Fee Related
- 1999-10-07 AU AU12010/00A patent/AU760603B2/en not_active Ceased
- 1999-10-07 AT AT99970388T patent/ATE314145T1/de not_active IP Right Cessation
- 1999-10-07 MX MXPA01003318 patent/MXPA01003318A/es unknown
- 1999-10-07 ES ES99970388T patent/ES2257100T3/es not_active Expired - Lifetime
- 1999-10-07 ID IDW00200101026A patent/ID29043A/id unknown
- 1999-10-07 BR BR9914121-3A patent/BR9914121A/pt not_active IP Right Cessation
- 1999-10-07 DE DE69929222T patent/DE69929222T2/de not_active Expired - Lifetime
- 1999-10-07 JP JP2000575850A patent/JP5153034B2/ja not_active Expired - Lifetime
- 1999-10-08 AR ARP990105110A patent/AR020759A1/es active IP Right Grant
- 1999-10-08 MY MYPI99004362A patent/MY119687A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MY119687A (en) | 2005-06-30 |
| MXPA01003318A (es) | 2001-10-01 |
| AU1201000A (en) | 2000-05-01 |
| EP1119410B1 (en) | 2005-12-28 |
| ATE314145T1 (de) | 2006-01-15 |
| WO2000021944A2 (en) | 2000-04-20 |
| CN1332764C (zh) | 2007-08-22 |
| KR100611443B1 (ko) | 2006-08-09 |
| JP5153034B2 (ja) | 2013-02-27 |
| ID29043A (id) | 2001-07-26 |
| AR020759A1 (es) | 2002-05-29 |
| US6417376B1 (en) | 2002-07-09 |
| EP1119410A2 (en) | 2001-08-01 |
| AU760603B2 (en) | 2003-05-15 |
| KR20010080066A (ko) | 2001-08-22 |
| CN1322151A (zh) | 2001-11-14 |
| BR9914121A (pt) | 2001-06-19 |
| DE69929222D1 (de) | 2006-02-02 |
| JP2003522111A (ja) | 2003-07-22 |
| WO2000021944A3 (en) | 2000-07-06 |
| ES2257100T3 (es) | 2006-07-16 |
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| 8364 | No opposition during term of opposition |