DE69929064D1 - Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren - Google Patents

Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren

Info

Publication number
DE69929064D1
DE69929064D1 DE69929064T DE69929064T DE69929064D1 DE 69929064 D1 DE69929064 D1 DE 69929064D1 DE 69929064 T DE69929064 T DE 69929064T DE 69929064 T DE69929064 T DE 69929064T DE 69929064 D1 DE69929064 D1 DE 69929064D1
Authority
DE
Germany
Prior art keywords
lockers
improved
ligand metallocene
metallocene catalysts
polymerization procedures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69929064T
Other languages
English (en)
Other versions
DE69929064T2 (de
Inventor
G Mccullough
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Univation Technologies LLC
Original Assignee
Univation Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Technologies LLC filed Critical Univation Technologies LLC
Publication of DE69929064D1 publication Critical patent/DE69929064D1/de
Application granted granted Critical
Publication of DE69929064T2 publication Critical patent/DE69929064T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
DE69929064T 1998-08-21 1999-08-12 Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren Expired - Lifetime DE69929064T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US9740198P 1998-08-21 1998-08-21
US97401P 1998-08-21
US09/191,916 US6632901B2 (en) 1998-08-21 1998-11-13 Polymerization process using an improved bulky ligand metallocene-type catalyst system
US191916 1998-11-13
PCT/US1999/018368 WO2000011047A1 (en) 1998-08-21 1999-08-12 Polymerization process using an improved bulky ligand metallocene-type catalyst system

Publications (2)

Publication Number Publication Date
DE69929064D1 true DE69929064D1 (de) 2006-01-26
DE69929064T2 DE69929064T2 (de) 2006-08-31

Family

ID=26793216

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69929064T Expired - Lifetime DE69929064T2 (de) 1998-08-21 1999-08-12 Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren

Country Status (10)

Country Link
US (1) US6632901B2 (de)
EP (1) EP1112293B1 (de)
JP (1) JP4234327B2 (de)
AT (1) ATE313567T1 (de)
AU (1) AU756665C (de)
BR (1) BR9913144B1 (de)
CA (1) CA2332045A1 (de)
DE (1) DE69929064T2 (de)
ES (1) ES2253909T3 (de)
WO (1) WO2000011047A1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6894131B2 (en) * 1998-08-21 2005-05-17 Univation Technologies, Llc Polymerization process using a metallocene catalyst system
US6303718B1 (en) 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes
CA2379019A1 (en) * 1999-07-14 2001-01-25 Bayer Aktiengesellschaft Catalyst system that is based on fluorine-containing metal complexes
GB0025195D0 (en) 2000-10-13 2000-11-29 Borealis Tech Oy Liquid container
US6841504B2 (en) * 2002-01-28 2005-01-11 Univation Technologies, Llc Polymerization catalyst activator and its use in a polymerization process
US6875828B2 (en) * 2002-09-04 2005-04-05 Univation Technologies, Llc Bimodal polyolefin production process and films therefrom
US6753390B2 (en) 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
US6884748B2 (en) * 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
WO2004037837A1 (en) * 2002-10-25 2004-05-06 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin oligomerizations
US6869903B2 (en) * 2002-11-07 2005-03-22 Univation Technologies, Llc Synthesis of polymerization catalyst components
US6890876B2 (en) * 2002-11-26 2005-05-10 Univation Technologies, Llc Processes for producing fluorided catalysts from nitrogenous metallocenes
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US6967184B2 (en) * 2004-02-17 2005-11-22 Univation Technologies, Llc Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts
US20070049711A1 (en) * 2005-09-01 2007-03-01 Chi-I Kuo Catalyst compositions comprising support materials having an improved particle-size distribution
RU2510404C2 (ru) * 2009-06-16 2014-03-27 Шеврон Филлипс Кемикал Компани Лп Олигомеризация альфа-олефинов с применением каталитических систем металлоцен-тск и применение полученных полиальфаолефинов для получения смазывающих смесей
US20110082323A1 (en) * 2009-10-06 2011-04-07 Chevron Phillips Chemical Company Lp Oligomerization of olefin waxes using metallocene-based catalyst systems
DE102013005049A1 (de) * 2013-03-22 2014-09-25 Unify Gmbh & Co. Kg Verfahren und Vorrichtung zur Steuerung einer Sprachkommunikation sowie Verwendung derselben
KR102355323B1 (ko) * 2014-04-17 2022-01-25 보레알리스 아게 고온 용액 중합 공정으로 폴리에틸렌 코폴리머를 제조하기 위한 개선된 촉매 시스템
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
KR102533626B1 (ko) * 2021-03-29 2023-05-16 디엘케미칼 주식회사 폴리올레핀 수지 및 이의 제조 방법

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
DE3678024D1 (de) 1985-03-26 1991-04-18 Mitsui Petrochemical Ind Fluessiges statisches ethylencopolymer, verfahren zur herstellung und anwendung desselben.
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4874880A (en) 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
EP0519746A1 (de) 1991-06-20 1992-12-23 Mitsui Petrochemical Industries, Ltd. Katalysator zur Olefinpolymerisation, Verfahren zur Polymerisation von Olefin und Übergangsmetallverbindung, verwendbar als Katalysator
RU2120947C1 (ru) * 1993-04-26 1998-10-27 Эксон Кемикэл Пейтентс Инк. Способ газофазной полимеризации в псевдоожиженном слое
DE69426648T3 (de) 1993-06-15 2005-02-03 Idemitsu Kosan Co. Ltd. Verfahren zur herstellung von olefinpolymeren und katalysator zur olefinpolymerisation
DE4332009A1 (de) 1993-09-21 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Organometallfluoriden
US5763543A (en) * 1994-09-14 1998-06-09 Exxon Chemical Patents Inc. Olefin polymerization process with little or no scavenger present
EP0857179A1 (de) 1995-08-18 1998-08-12 Basell Polyolefine GmbH Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren
AU6495998A (en) 1997-02-17 1998-09-08 Bayer Aktiengesellschaft Novel catalyst system, the use thereof in the polymerization of dienes in a solution, suspension and vapour phase and the use of diene rubbers produced therewith
DE19706027A1 (de) 1997-02-17 1998-08-20 Bayer Ag Titanocene für Lösungspolymerisation
US6303718B1 (en) 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes

Also Published As

Publication number Publication date
AU5774199A (en) 2000-03-14
US6632901B2 (en) 2003-10-14
AU756665C (en) 2004-01-08
ATE313567T1 (de) 2006-01-15
ES2253909T3 (es) 2006-06-01
WO2000011047A1 (en) 2000-03-02
EP1112293A1 (de) 2001-07-04
CA2332045A1 (en) 2000-03-02
JP2002523530A (ja) 2002-07-30
JP4234327B2 (ja) 2009-03-04
EP1112293B1 (de) 2005-12-21
BR9913144B1 (pt) 2009-08-11
AU756665B2 (en) 2003-01-23
US20020032287A1 (en) 2002-03-14
BR9913144A (pt) 2001-10-02
DE69929064T2 (de) 2006-08-31

Similar Documents

Publication Publication Date Title
DE69929064D1 (de) Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren
BR0016197A (pt) Sistema catalisador múltiplo
BR0016725A (pt) Sistema catalisador, uso do mesmo, e, processo para preparar poliolefinas
ATE434631T1 (de) Metallocenverbindungen, verfahren zur herstellung und verwendung als olefinpolymerisationskatalysatoren
DE69903849D1 (de) Polymerisationskatalysator
FI963759A (fi) Metalloseeniyhdisteitä, menetelmä niiden valmistamiseksi ja niiden käyttö olefiinien polymerointiin tarkoitetuissa katalyyteissä
TR200201083T2 (tr) Katalizör sistemleri ve bu sistemlerin bir polimerizasyon işleminde kullanımları.
DK0918818T3 (da) Oxygenindfangende flerkomponentsammensætning
ES2175066T3 (es) Antagonistas triciclicos de la vasopresina.
DE69016876D1 (de) Produktion von alpha-Olefinpolymeren.
ATE256136T1 (de) Metallocene
TR970073A2 (tr) Alfa adrenerjik resentör antagonistleri olarak pirimidindion pirimidintrion,triazindion, tetrahidrokinazolindion türevleri.
ATE277092T1 (de) Katalysatorbestandteil für olefinpolymerisation und katalysatorsystem und polymerisationsverfahren unter verwendung eines solchen katalysatorsystems
WO2003064433A8 (en) Polymerization catalyst activator and its use in a polymerization process
DE69609186D1 (de) Verbrückte metallocenverbindungen, verfahren zu deren herstellung und deren verwendung als olefinpolymerisationskatalysator
DE69927876T2 (de) Metallocenverbindung, und Verfahren zur Herstellung von Polyolefine unter Verwendung dieser
DE69903399D1 (de) Prepolymerisierte katalysatorkomponente für die polymerisierung von olefinen
DE69926339D1 (de) Verbrückte metallocene, herstellung und verwendung als olefinpolymerisationskatalysator
DE69708848D1 (de) Mischung von erdalkalialkylarylsulfonaten, ihre verwendung als schmierölzusatz und herstellungsmethode
DE69904521D1 (de) Verbrückte Zirconocene, deren Herstellung und deren Verwendung als Katalysatorkomponente für die Polymerisation von Olefinen
ATE466033T1 (de) Katalysatorsystem aus einer mischung von katalysatorbestandteilen zur herstellung einer polyolefinmischung
IT1299068B1 (it) Legandi fosforati chirali e loro complessi organometallici, utili come catalizzatori in sintesi stereoselettive
DE69905997D1 (de) Verfahren zur herstellung von geträgertem metallocen-katalysator und olefin-polymerisationsverfahren unter dessen verwendung
EP0970974A4 (de) Verfahren zur herstellung von olefinpolymeren
DE19981705T1 (de) y-Oxo-Bis-Metallocen-Komplexvrbindungen und Katalysatoren, die dieselben für die Polymerisation von Olefinen verwenden, sowie Polymerisationsverfahren

Legal Events

Date Code Title Description
8364 No opposition during term of opposition