DE69918451D1 - Verfahren zur herstellung von olefinen unter verwendung eines pentasil-zeolith enthaltenden katalysators - Google Patents
Verfahren zur herstellung von olefinen unter verwendung eines pentasil-zeolith enthaltenden katalysatorsInfo
- Publication number
- DE69918451D1 DE69918451D1 DE69918451T DE69918451T DE69918451D1 DE 69918451 D1 DE69918451 D1 DE 69918451D1 DE 69918451 T DE69918451 T DE 69918451T DE 69918451 T DE69918451 T DE 69918451T DE 69918451 D1 DE69918451 D1 DE 69918451D1
- Authority
- DE
- Germany
- Prior art keywords
- hydrocarbon
- passed
- catalyst
- naphtha
- pentasil zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16184598A | 1998-09-28 | 1998-09-28 | |
| US161845 | 1998-09-28 | ||
| US40558299A | 1999-09-27 | 1999-09-27 | |
| US405582 | 1999-09-27 | ||
| PCT/US1999/022460 WO2000018853A1 (en) | 1998-09-28 | 1999-09-28 | Process for manufacturing olefins using a pentasil zeolite based catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69918451D1 true DE69918451D1 (de) | 2004-08-05 |
| DE69918451T2 DE69918451T2 (de) | 2005-07-28 |
Family
ID=26858166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69918451T Expired - Fee Related DE69918451T2 (de) | 1998-09-28 | 1999-09-28 | Verfahren zur herstellung von olefinen unter verwendung eines pentasil-zeolith enthaltenden katalysators |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6548725B2 (de) |
| EP (1) | EP1117750B1 (de) |
| JP (1) | JP2002525380A (de) |
| CN (1) | CN1195714C (de) |
| AT (1) | ATE270318T1 (de) |
| AU (1) | AU6271299A (de) |
| CA (1) | CA2345308A1 (de) |
| DE (1) | DE69918451T2 (de) |
| ES (1) | ES2224702T3 (de) |
| ID (1) | ID29487A (de) |
| NO (1) | NO20011561D0 (de) |
| WO (1) | WO2000018853A1 (de) |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1195424A1 (de) * | 2000-10-05 | 2002-04-10 | ATOFINA Research | Verfahren zur Krackung von olefinreichen Kohlenwasserstoffeinsätzen |
| US7431821B2 (en) | 2003-01-31 | 2008-10-07 | Chevron U.S.A. Inc. | High purity olefinic naphthas for the production of ethylene and propylene |
| GB2399090B (en) * | 2003-01-31 | 2005-06-08 | Chevron Usa Inc | High purity olefinic naphthas for the production of ethylene and propylene |
| US7150821B2 (en) | 2003-01-31 | 2006-12-19 | Chevron U.S.A. Inc. | High purity olefinic naphthas for the production of ethylene and propylene |
| GB2408747B (en) * | 2003-01-31 | 2006-01-18 | Chevron Usa Inc | High purity olefinic naphthas for the production of ethylene and propylene |
| US7084318B2 (en) * | 2003-08-01 | 2006-08-01 | Saudi Basic Industries Corporation | Toluene methylation process |
| US7060864B2 (en) * | 2003-09-30 | 2006-06-13 | Saudi Basic Industries Corporation | Toluene methylation process |
| US7060644B2 (en) * | 2004-01-08 | 2006-06-13 | Saudi Basic Industries Corporation | Aromatic alkylation catalyst and method |
| US6943131B1 (en) | 2004-03-02 | 2005-09-13 | Saudi Basic Industries Corporation | Selective zeolite catalyst modification |
| CN1332756C (zh) * | 2004-07-14 | 2007-08-22 | 中国石油化工股份有限公司 | 一种含沸石的烃类转化催化剂 |
| US7399727B2 (en) * | 2004-04-23 | 2008-07-15 | Saudi Basic Industries Corporation | Zeolite catalyst and method |
| US7285511B2 (en) * | 2004-04-23 | 2007-10-23 | Saudi Basic Industries Corporation | Method of modifying zeolite catalyst |
| WO2005123251A1 (en) * | 2004-06-09 | 2005-12-29 | Saudi Basic Industries Corporation | Fluoride-modified zeolite catalyst and method |
| CN100351344C (zh) * | 2004-07-14 | 2007-11-28 | 中国石油化工股份有限公司 | 一种选择性制取小分子烯烃的催化转化方法 |
| EP1856230B1 (de) * | 2005-03-11 | 2010-02-24 | Uop Llc | Katalysator für das katalytische naphtha-cracken und verfahren |
| US7304194B2 (en) * | 2005-05-05 | 2007-12-04 | Saudi Basic Industries Corporation | Hydrothermal treatment of phosphorus-modified zeolite catalysts |
| KR100598988B1 (ko) * | 2005-05-18 | 2006-07-12 | 주식회사 하이닉스반도체 | 오버레이 버니어 및 이를 이용한 반도체소자의 제조방법 |
| US7368410B2 (en) * | 2005-08-03 | 2008-05-06 | Saudi Basic Industries Corporation | Zeolite catalyst and method of preparing and use of zeolite catalyst |
| EP1931750B1 (de) * | 2005-10-07 | 2017-01-18 | Sk Innovation Co., Ltd. | Verfahren zur herstellung von leichten olefinen aus einem kohlenwasserstoff-ausgangsstoff |
| CN1986505B (zh) * | 2005-12-23 | 2010-04-14 | 中国石油化工股份有限公司 | 一种增产低碳烯烃的催化转化方法 |
| KR100651418B1 (ko) * | 2006-03-17 | 2006-11-30 | 에스케이 주식회사 | 고속유동층을 이용하여 탄화수소 원료로부터 경질 올레핀을제조하는 접촉분해 공정 |
| US7498473B2 (en) * | 2006-07-27 | 2009-03-03 | Uop Llc | Process for dehydrocyclodimerization |
| US20080025885A1 (en) * | 2006-07-27 | 2008-01-31 | Lubo Zhou | Process for Dehydrocyclodimerization |
| CN101279287B (zh) * | 2007-04-04 | 2011-07-13 | 中国石油化工股份有限公司 | 用于催化裂解制烯烃的催化剂 |
| CN101279881B (zh) * | 2007-04-04 | 2010-08-18 | 中国石油化工股份有限公司 | 催化裂解石脑油生产乙烯和丙烯的方法 |
| EP2188051A4 (de) * | 2007-08-13 | 2011-11-02 | Agency Science Tech & Res | Modifizierte katalysatorzusammensetzung zur umwandlung von alkohol in alken |
| US8846559B2 (en) * | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
| WO2011001572A1 (ja) | 2009-06-30 | 2011-01-06 | 新日本石油株式会社 | 単環芳香族炭化水素製造用触媒および単環芳香族炭化水素の製造方法 |
| KR101633534B1 (ko) | 2009-07-29 | 2016-06-27 | 제이엑스 에네루기 가부시키가이샤 | 단환 방향족 탄화수소 제조용 촉매 및 단환 방향족 탄화수소의 제조 방법 |
| US8062987B2 (en) * | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
| US20110230333A1 (en) * | 2010-03-16 | 2011-09-22 | Uop Llc | Olefin Cracking Catalyst and Manufacturing Process |
| CA2795120C (en) | 2010-03-31 | 2019-10-08 | Indian Oil Corporation Ltd | A process for simulataneous cracking of lighter and heavier hydrocarbon feed and system for the same |
| JP5587761B2 (ja) | 2010-12-28 | 2014-09-10 | Jx日鉱日石エネルギー株式会社 | 単環芳香族炭化水素の製造方法 |
| JP2012139641A (ja) | 2010-12-28 | 2012-07-26 | Jx Nippon Oil & Energy Corp | 単環芳香族炭化水素製造用触媒および単環芳香族炭化水素の製造方法 |
| JP2012139640A (ja) | 2010-12-28 | 2012-07-26 | Jx Nippon Oil & Energy Corp | 単環芳香族炭化水素製造用触媒および単環芳香族炭化水素の製造方法 |
| DK2739390T3 (da) * | 2011-08-03 | 2021-03-29 | Total Res & Technology Feluy | Fremgangsmåde til omdannelse af mindst en alkohol til lette olefiner |
| US8772192B2 (en) | 2012-06-29 | 2014-07-08 | Saudi Basic Industries Corporation | Germanium silicalite catalyst and method of preparation and use |
| US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
| US10099210B2 (en) | 2013-04-29 | 2018-10-16 | Saudi Basic Industries Corporation | Catalytic methods for converting naphtha into olefins |
| KR101600430B1 (ko) | 2015-01-08 | 2016-03-07 | 한국화학연구원 | 이산화탄소가 풍부한 합성가스로부터 단환 방향족 화합물 및 장쇄올레핀 화합물의 직접 합성방법 |
| EP3936588A1 (de) | 2015-12-22 | 2022-01-12 | SABIC Global Technologies B.V. | Verfahren zur herstellung von ethylen und propylen aus naphtha |
| FR3049954A1 (fr) | 2016-04-08 | 2017-10-13 | Ifp Energies Now | Utilisation de zeolithe nu-86 pour le procede de craquage catalytique de naphtha |
| US9981888B2 (en) | 2016-06-23 | 2018-05-29 | Saudi Arabian Oil Company | Processes for high severity fluid catalytic cracking systems |
| US11807816B2 (en) | 2016-12-19 | 2023-11-07 | Sabic Global Technologies B.V. | Process integration for cracking light paraffinic hydrocarbons |
| CN110603311A (zh) * | 2017-05-10 | 2019-12-20 | 沙特基础全球技术有限公司 | 使用径向流移动床反应器系统催化裂化石脑油的方法 |
| US10870802B2 (en) | 2017-05-31 | 2020-12-22 | Saudi Arabian Oil Company | High-severity fluidized catalytic cracking systems and processes having partial catalyst recycle |
| US10889768B2 (en) | 2018-01-25 | 2021-01-12 | Saudi Arabian Oil Company | High severity fluidized catalytic cracking systems and processes for producing olefins from petroleum feeds |
| WO2019211684A1 (en) * | 2018-04-30 | 2019-11-07 | Sabic Global Technologies B.V. | Process of producing light olefins from isomerized straight run naphtha |
| KR102096308B1 (ko) | 2018-05-30 | 2020-04-02 | 한국화학연구원 | 선형 장쇄올레핀 제조용 피셔―트롭쉬 합성반응 촉매 및 이를 이용한 선형 장쇄올레핀의 제조방법 |
| US10350585B1 (en) | 2018-08-14 | 2019-07-16 | Saudi Arabian Oil Company | Methods for synthesizing hierarchical zeolites for catalytic cracking |
| EP3620499A1 (de) | 2018-09-06 | 2020-03-11 | INDIAN OIL CORPORATION Ltd. | Verfahren zur selektiven herstellung von leichten olefinen und aromaten aus gecracktem leichtem naphtha |
| WO2020049372A1 (en) | 2018-09-06 | 2020-03-12 | Sabic Global Technologies B.V. | Process for catalytic cracking of naphtha using multi-stage radial flow moving bed reactor system |
| EP3902629A4 (de) * | 2018-12-26 | 2022-10-05 | PTT Global Chemical Public Company Limited | Katalysator zur herstellung von leichten olefinen aus c4-c7-kohlenwasserstoffen |
| CN114364770A (zh) * | 2019-08-05 | 2022-04-15 | 沙特基础工业全球技术公司 | 不用蒸汽作为稀释剂的烃的催化裂解以制备烯烃和芳香烃的方法 |
| KR102653716B1 (ko) | 2020-03-03 | 2024-04-03 | 한국화학연구원 | 이산화탄소가 포함된 합성가스로부터 선형 알파 올레핀을 제조하기 위한 촉매 및 이를 이용한 선형 알파 올레핀의 제조방법 |
| US11332680B2 (en) | 2020-09-01 | 2022-05-17 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of lesser and greater boiling point fractions with steam |
| US11352575B2 (en) | 2020-09-01 | 2022-06-07 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize hydrotreating of cycle oil |
| US11230673B1 (en) | 2020-09-01 | 2022-01-25 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of a lesser boiling point fraction with steam |
| US11505754B2 (en) | 2020-09-01 | 2022-11-22 | Saudi Arabian Oil Company | Processes for producing petrochemical products from atmospheric residues |
| US11242493B1 (en) | 2020-09-01 | 2022-02-08 | Saudi Arabian Oil Company | Methods for processing crude oils to form light olefins |
| US11230672B1 (en) | 2020-09-01 | 2022-01-25 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking |
| US11434432B2 (en) | 2020-09-01 | 2022-09-06 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of a greater boiling point fraction with steam |
| CA3194958A1 (en) * | 2020-11-06 | 2022-05-12 | Antti Ojala | A method for producing a cracking product fraction comprising propylene, c4 olefins, or both |
| US20240286977A1 (en) | 2023-02-10 | 2024-08-29 | Exelus Inc. | Multifunctional catalyst for naphtha cracking |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3972832A (en) * | 1974-09-23 | 1976-08-03 | Mobil Oil Corporation | Phosphorus-containing zeolite catalyst |
| US4112056A (en) * | 1977-05-02 | 1978-09-05 | Mobil Oil Corporation | Preparation of zeolites |
| US4356338A (en) * | 1979-07-27 | 1982-10-26 | Mobil Oil Corporation | Extending catalyst life by treating with phosphorus and/or steam |
| US4394300A (en) * | 1980-04-07 | 1983-07-19 | Mobil Oil Corporation | Zeolite catalyst modified with group IVB metal |
| US4801567A (en) * | 1981-06-19 | 1989-01-31 | Union Oil Company Of California | Oxidation catalyst |
| US4599477A (en) * | 1981-08-03 | 1986-07-08 | Union Oil Company Of California | Oxidative-dehydrogenation process |
| US4861930A (en) * | 1988-09-28 | 1989-08-29 | Uop | Combination process for the conversion of a C2 -C6 aliphatic hydrocarbon |
| US5166455A (en) * | 1992-01-16 | 1992-11-24 | Mobil Oil Corporation | Process for the production of tertiary alkytl ethers from FCC light naphtha |
| US5389232A (en) * | 1992-05-04 | 1995-02-14 | Mobil Oil Corporation | Riser cracking for maximum C3 and C4 olefin yields |
| US5476823A (en) * | 1993-05-28 | 1995-12-19 | Mobil Oil Corp. | Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof |
-
1999
- 1999-09-28 CA CA002345308A patent/CA2345308A1/en not_active Abandoned
- 1999-09-28 AT AT99949945T patent/ATE270318T1/de not_active IP Right Cessation
- 1999-09-28 CN CNB998114413A patent/CN1195714C/zh not_active Expired - Fee Related
- 1999-09-28 EP EP99949945A patent/EP1117750B1/de not_active Expired - Lifetime
- 1999-09-28 ID IDW20010946A patent/ID29487A/id unknown
- 1999-09-28 ES ES99949945T patent/ES2224702T3/es not_active Expired - Lifetime
- 1999-09-28 JP JP2000572303A patent/JP2002525380A/ja active Pending
- 1999-09-28 WO PCT/US1999/022460 patent/WO2000018853A1/en not_active Ceased
- 1999-09-28 DE DE69918451T patent/DE69918451T2/de not_active Expired - Fee Related
- 1999-09-28 AU AU62712/99A patent/AU6271299A/en not_active Abandoned
-
2001
- 2001-03-27 NO NO20011561A patent/NO20011561D0/no unknown
- 2001-07-31 US US09/918,925 patent/US6548725B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU6271299A (en) | 2000-04-17 |
| ATE270318T1 (de) | 2004-07-15 |
| JP2002525380A (ja) | 2002-08-13 |
| CN1320148A (zh) | 2001-10-31 |
| EP1117750A1 (de) | 2001-07-25 |
| NO20011561L (no) | 2001-03-27 |
| US20010056217A1 (en) | 2001-12-27 |
| ID29487A (id) | 2001-08-30 |
| NO20011561D0 (no) | 2001-03-27 |
| US6548725B2 (en) | 2003-04-15 |
| CN1195714C (zh) | 2005-04-06 |
| CA2345308A1 (en) | 2000-04-06 |
| ES2224702T3 (es) | 2005-03-01 |
| DE69918451T2 (de) | 2005-07-28 |
| WO2000018853A1 (en) | 2000-04-06 |
| EP1117750B1 (de) | 2004-06-30 |
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