NO20011561L - Fremgangsmåte ved fremstilling av olefiner ved å bruke en pentasil zeolitt-basert katalysator - Google Patents

Fremgangsmåte ved fremstilling av olefiner ved å bruke en pentasil zeolitt-basert katalysator

Info

Publication number
NO20011561L
NO20011561L NO20011561A NO20011561A NO20011561L NO 20011561 L NO20011561 L NO 20011561L NO 20011561 A NO20011561 A NO 20011561A NO 20011561 A NO20011561 A NO 20011561A NO 20011561 L NO20011561 L NO 20011561L
Authority
NO
Norway
Prior art keywords
hydrocarbon
passed
catalyst
naphtha
mixtures
Prior art date
Application number
NO20011561A
Other languages
English (en)
Other versions
NO20011561D0 (no
Inventor
Gilbert F A Froment
Wilfried J H Dehertog
Mark P Kaminsky
Original Assignee
Bp Amoco Corp Law Dept
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Amoco Corp Law Dept filed Critical Bp Amoco Corp Law Dept
Publication of NO20011561L publication Critical patent/NO20011561L/no
Publication of NO20011561D0 publication Critical patent/NO20011561D0/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

En katalysator og en forbedret prosess for fremstilling av olefiner ved katalytisk krakking av nafta er beskrevet. Prosessen frembringer relativt større utbytter over et kom-mersielt viktig område av naftaomdanning,mens det gir om-trent det samme eller lavere utbytter av aromater og metan over dette området. I prosessen blir et hydrokarbon nafta råstoff omfattende et hydrokarbon med fra ca tre til ca tyve karbonatomer pr. molekyl sendt inn i en reaktor som inneholder en pentasil zeolittkatalysator. Katalysatoren omfatter fra ca 0,1 til ca 10 vekt% fosfor og ca 0,1 til 10 vekt% av et promotormetall valgt fra gruppen som består av gallium, germanium eller tinn og blandinger av disse.yd-rokarbonet kan sendes inn i reaktoren sammen med et for-tynningsmiddel valgt fra gruppen som består av damp, nitro-gen, metan, og etan og blandinger av disse. Alternativt kan hydrokarbonet sendes inn i reaktoren sammen med ekstra pro-pan.
NO20011561A 1998-09-28 2001-03-27 Fremgangsmåte ved fremstilling av olefiner ved å bruke en pentasil zeolitt-basert katalysator NO20011561D0 (no)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16184598A 1998-09-28 1998-09-28
US40558299A 1999-09-27 1999-09-27
PCT/US1999/022460 WO2000018853A1 (en) 1998-09-28 1999-09-28 Process for manufacturing olefins using a pentasil zeolite based catalyst

Publications (2)

Publication Number Publication Date
NO20011561L true NO20011561L (no) 2001-03-27
NO20011561D0 NO20011561D0 (no) 2001-03-27

Family

ID=26858166

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20011561A NO20011561D0 (no) 1998-09-28 2001-03-27 Fremgangsmåte ved fremstilling av olefiner ved å bruke en pentasil zeolitt-basert katalysator

Country Status (12)

Country Link
US (1) US6548725B2 (no)
EP (1) EP1117750B1 (no)
JP (1) JP2002525380A (no)
CN (1) CN1195714C (no)
AT (1) ATE270318T1 (no)
AU (1) AU6271299A (no)
CA (1) CA2345308A1 (no)
DE (1) DE69918451T2 (no)
ES (1) ES2224702T3 (no)
ID (1) ID29487A (no)
NO (1) NO20011561D0 (no)
WO (1) WO2000018853A1 (no)

Families Citing this family (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1195424A1 (en) * 2000-10-05 2002-04-10 ATOFINA Research A process for cracking an olefin-rich hydrocarbon feedstock
US7150821B2 (en) 2003-01-31 2006-12-19 Chevron U.S.A. Inc. High purity olefinic naphthas for the production of ethylene and propylene
GB2408747B (en) * 2003-01-31 2006-01-18 Chevron Usa Inc High purity olefinic naphthas for the production of ethylene and propylene
US7431821B2 (en) 2003-01-31 2008-10-07 Chevron U.S.A. Inc. High purity olefinic naphthas for the production of ethylene and propylene
GB2399090B (en) * 2003-01-31 2005-06-08 Chevron Usa Inc High purity olefinic naphthas for the production of ethylene and propylene
US7084318B2 (en) * 2003-08-01 2006-08-01 Saudi Basic Industries Corporation Toluene methylation process
US7060864B2 (en) * 2003-09-30 2006-06-13 Saudi Basic Industries Corporation Toluene methylation process
US7060644B2 (en) * 2004-01-08 2006-06-13 Saudi Basic Industries Corporation Aromatic alkylation catalyst and method
US6943131B1 (en) * 2004-03-02 2005-09-13 Saudi Basic Industries Corporation Selective zeolite catalyst modification
CN1332756C (zh) * 2004-07-14 2007-08-22 中国石油化工股份有限公司 一种含沸石的烃类转化催化剂
US7285511B2 (en) 2004-04-23 2007-10-23 Saudi Basic Industries Corporation Method of modifying zeolite catalyst
US7399727B2 (en) * 2004-04-23 2008-07-15 Saudi Basic Industries Corporation Zeolite catalyst and method
US7105713B2 (en) * 2004-06-09 2006-09-12 Saudi Basic Industries Corporation Preparation of alkyl-aromatic products
CN100351344C (zh) * 2004-07-14 2007-11-28 中国石油化工股份有限公司 一种选择性制取小分子烯烃的催化转化方法
WO2006098712A1 (en) * 2005-03-11 2006-09-21 Uop Llc Catalytic naphtha cracking catalyst and process
US7304194B2 (en) * 2005-05-05 2007-12-04 Saudi Basic Industries Corporation Hydrothermal treatment of phosphorus-modified zeolite catalysts
KR100598988B1 (ko) * 2005-05-18 2006-07-12 주식회사 하이닉스반도체 오버레이 버니어 및 이를 이용한 반도체소자의 제조방법
US7368410B2 (en) * 2005-08-03 2008-05-06 Saudi Basic Industries Corporation Zeolite catalyst and method of preparing and use of zeolite catalyst
WO2007043741A1 (en) * 2005-10-07 2007-04-19 Sk Energy Co., Ltd. Process for production of light olefins from hydrocarbon feedstock
CN1986505B (zh) * 2005-12-23 2010-04-14 中国石油化工股份有限公司 一种增产低碳烯烃的催化转化方法
KR100651418B1 (ko) * 2006-03-17 2006-11-30 에스케이 주식회사 고속유동층을 이용하여 탄화수소 원료로부터 경질 올레핀을제조하는 접촉분해 공정
US20080025885A1 (en) * 2006-07-27 2008-01-31 Lubo Zhou Process for Dehydrocyclodimerization
US7498473B2 (en) * 2006-07-27 2009-03-03 Uop Llc Process for dehydrocyclodimerization
CN101279881B (zh) * 2007-04-04 2010-08-18 中国石油化工股份有限公司 催化裂解石脑油生产乙烯和丙烯的方法
CN101279287B (zh) * 2007-04-04 2011-07-13 中国石油化工股份有限公司 用于催化裂解制烯烃的催化剂
WO2009022990A1 (en) * 2007-08-13 2009-02-19 Agency For Science, Technology And Research Modified catalyst composition for conversion of alcohol to alkene
US8846559B2 (en) * 2008-11-03 2014-09-30 Saudi Basic Industries Corporation Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing
US20110270004A1 (en) * 2009-06-30 2011-11-03 Shinichiro Yanagawa Catalyst for producing monocyclic aromatic hydrocarbons, and method for producing monocyclic aromatic hydrocarbons
JP4917672B2 (ja) 2009-07-29 2012-04-18 Ｊｘ日鉱日石エネルギー株式会社 単環芳香族炭化水素製造用触媒および単環芳香族炭化水素の製造方法
US8062987B2 (en) * 2009-10-05 2011-11-22 Saudi Basic Industries Corporation Phosphorus-containing zeolite catalysts and their method of preparation
US20110230333A1 (en) * 2010-03-16 2011-09-22 Uop Llc Olefin Cracking Catalyst and Manufacturing Process
BR112012024901A2 (pt) 2010-03-31 2021-07-20 Indian Oil Corporation Limited processo para o craqueamento simultâneo de hidrocarbonetos mais leves e mais pesados e sistema para o mesmo
JP5587761B2 (ja) 2010-12-28 2014-09-10 Ｊｘ日鉱日石エネルギー株式会社 単環芳香族炭化水素の製造方法
JP2012139641A (ja) 2010-12-28 2012-07-26 Jx Nippon Oil & Energy Corp 単環芳香族炭化水素製造用触媒および単環芳香族炭化水素の製造方法
JP2012139640A (ja) 2010-12-28 2012-07-26 Jx Nippon Oil & Energy Corp 単環芳香族炭化水素製造用触媒および単環芳香族炭化水素の製造方法
WO2013017496A1 (en) * 2011-08-03 2013-02-07 Total Research & Technology Feluy Use of a catalyst comprising a phosphorus modified zeolite in an alcohol dehydration process
US8772192B2 (en) 2012-06-29 2014-07-08 Saudi Basic Industries Corporation Germanium silicalite catalyst and method of preparation and use
US9278342B2 (en) 2012-07-02 2016-03-08 Saudi Basic Industries Corporation Method of modifying a phosphorus-containing zeolite catalyst
CN112264086A (zh) 2013-04-29 2021-01-26 沙特基础工业公司 石脑油转化成烯烃的催化方法
KR101600430B1 (ko) 2015-01-08 2016-03-07 한국화학연구원 이산화탄소가 풍부한 합성가스로부터 단환 방향족 화합물 및 장쇄올레핀 화합물의 직접 합성방법
EP3936588A1 (en) 2015-12-22 2022-01-12 SABIC Global Technologies B.V. Methods for producing ethylene and propylene from naphtha
FR3049954A1 (fr) 2016-04-08 2017-10-13 Ifp Energies Now Utilisation de zeolithe nu-86 pour le procede de craquage catalytique de naphtha
US9981888B2 (en) 2016-06-23 2018-05-29 Saudi Arabian Oil Company Processes for high severity fluid catalytic cracking systems
US11807816B2 (en) 2016-12-19 2023-11-07 Sabic Global Technologies B.V. Process integration for cracking light paraffinic hydrocarbons
EP3622039A1 (en) * 2017-05-10 2020-03-18 SABIC Global Technologies B.V. Process for catalytic cracking of naphtha using radial flow moving bed reactor system
US10870802B2 (en) 2017-05-31 2020-12-22 Saudi Arabian Oil Company High-severity fluidized catalytic cracking systems and processes having partial catalyst recycle
US10889768B2 (en) 2018-01-25 2021-01-12 Saudi Arabian Oil Company High severity fluidized catalytic cracking systems and processes for producing olefins from petroleum feeds
CN112154132A (zh) * 2018-04-30 2020-12-29 沙特基础工业全球技术公司 由异构化的直馏石脑油制备低碳烯烃的方法
KR102096308B1 (ko) 2018-05-30 2020-04-02 한국화학연구원 선형 장쇄올레핀 제조용 피셔―트롭쉬 합성반응 촉매 및 이를 이용한 선형 장쇄올레핀의 제조방법
US10350585B1 (en) 2018-08-14 2019-07-16 Saudi Arabian Oil Company Methods for synthesizing hierarchical zeolites for catalytic cracking
EP3620499A1 (en) 2018-09-06 2020-03-11 INDIAN OIL CORPORATION Ltd. Process for selective production of light olefins and aromatics from cracked light naphtha
CN112654690A (zh) 2018-09-06 2021-04-13 沙特基础全球技术有限公司 使用多级径向流移动床反应器系统催化裂化石脑油的方法
JP7467475B2 (ja) * 2018-12-26 2024-04-15 ピーティーティー グローバル ケミカル パブリック カンパニー リミテッド Ｃ４－ｃ７炭化水素から軽質オレフィンを製造するための触媒
WO2021024120A1 (en) * 2019-08-05 2021-02-11 Sabic Global Technologies B.V. A method for catalytic cracking of hydrocarbons to produce olefins and aromatics without steam as diluent
KR102653716B1 (ko) 2020-03-03 2024-04-03 한국화학연구원 이산화탄소가 포함된 합성가스로부터 선형 알파 올레핀을 제조하기 위한 촉매 및 이를 이용한 선형 알파 올레핀의 제조방법
US11505754B2 (en) 2020-09-01 2022-11-22 Saudi Arabian Oil Company Processes for producing petrochemical products from atmospheric residues
US11434432B2 (en) 2020-09-01 2022-09-06 Saudi Arabian Oil Company Processes for producing petrochemical products that utilize fluid catalytic cracking of a greater boiling point fraction with steam
US11242493B1 (en) 2020-09-01 2022-02-08 Saudi Arabian Oil Company Methods for processing crude oils to form light olefins
US11230672B1 (en) 2020-09-01 2022-01-25 Saudi Arabian Oil Company Processes for producing petrochemical products that utilize fluid catalytic cracking
US11230673B1 (en) 2020-09-01 2022-01-25 Saudi Arabian Oil Company Processes for producing petrochemical products that utilize fluid catalytic cracking of a lesser boiling point fraction with steam
US11352575B2 (en) 2020-09-01 2022-06-07 Saudi Arabian Oil Company Processes for producing petrochemical products that utilize hydrotreating of cycle oil
US11332680B2 (en) 2020-09-01 2022-05-17 Saudi Arabian Oil Company Processes for producing petrochemical products that utilize fluid catalytic cracking of lesser and greater boiling point fractions with steam

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3972832A (en) * 1974-09-23 1976-08-03 Mobil Oil Corporation Phosphorus-containing zeolite catalyst
US4112056A (en) * 1977-05-02 1978-09-05 Mobil Oil Corporation Preparation of zeolites
US4356338A (en) * 1979-07-27 1982-10-26 Mobil Oil Corporation Extending catalyst life by treating with phosphorus and/or steam
US4394300A (en) * 1980-04-07 1983-07-19 Mobil Oil Corporation Zeolite catalyst modified with group IVB metal
US4801567A (en) * 1981-06-19 1989-01-31 Union Oil Company Of California Oxidation catalyst
US4599477A (en) * 1981-08-03 1986-07-08 Union Oil Company Of California Oxidative-dehydrogenation process
US4861930A (en) * 1988-09-28 1989-08-29 Uop Combination process for the conversion of a C2 -C6 aliphatic hydrocarbon
US5166455A (en) * 1992-01-16 1992-11-24 Mobil Oil Corporation Process for the production of tertiary alkytl ethers from FCC light naphtha
US5389232A (en) * 1992-05-04 1995-02-14 Mobil Oil Corporation Riser cracking for maximum C3 and C4 olefin yields
US5476823A (en) * 1993-05-28 1995-12-19 Mobil Oil Corp. Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof

Also Published As

Publication number Publication date
CA2345308A1 (en) 2000-04-06
JP2002525380A (ja) 2002-08-13
EP1117750A1 (en) 2001-07-25
CN1195714C (zh) 2005-04-06
DE69918451D1 (de) 2004-08-05
AU6271299A (en) 2000-04-17
US6548725B2 (en) 2003-04-15
ID29487A (id) 2001-08-30
DE69918451T2 (de) 2005-07-28
ES2224702T3 (es) 2005-03-01
CN1320148A (zh) 2001-10-31
WO2000018853A1 (en) 2000-04-06
EP1117750B1 (en) 2004-06-30
ATE270318T1 (de) 2004-07-15
US20010056217A1 (en) 2001-12-27
NO20011561D0 (no) 2001-03-27

Similar Documents

Publication Publication Date Title
NO20011561L (no) Fremgangsmåte ved fremstilling av olefiner ved å bruke en pentasil zeolitt-basert katalysator
AU744826B2 (en) Hydrocarbon conversion to propylene with high silica medium pore zeolite catalysts
Shertukde et al. Study of the mechanism of the cracking of small alkane molecules on HY Zeolites
CN105102407B (zh) 链烷烃转化成烯烃的方法和其中使用的催化剂
Ono et al. Transformation of but-1-ene into aromatic hydrocarbons over ZSM-5 zeolites
Wakui et al. Cracking of n-butane over alkaline earth-containing HZSM-5 catalysts
AU5532400A (en) Production of olefins
EP0168185A2 (en) Improving zeolite catalyst life
Lücke et al. CMHC: coupled methanol hydrocarbon cracking: Formation of lower olefins from methanol and hydrocarbons over modified zeolites
NZ207523A (en) Catalytic production of olefin mixtures from alcohols and/or ethers
BRPI0805207B1 (pt) processo de craqueamento catalítico de uma corrente de hidrocarbonetos para maximização de olefinas leves
CN103121894A (zh) 生产低碳烯烃的组合方法
Campelo et al. Comparison of the activity and selectivity of Pt/SAPO-5 and Pt/SAPO-11 in n-hexane and n-heptane hydroconversion
Montes et al. A new way to obtain acid or bifunctional catalysts: V. Considerations on bifunctionality of the propane aromatization reaction over [Ga, Al]-ZSM-5 catalysts
Song et al. Influence of reaction conditions on the aromatization of cofeeding n-butane with methanol over the Zn loaded ZSM-5/ZSM-11 zeolite catalyst
Domokos et al. Isomerization of linear butenes to iso-butene over medium pore zeolites: I. Kinetic aspects of the reaction over H-FER
US20070246400A1 (en) Zeolite Catalysts
Komatsu et al. Aromatization of butane on Pt–Ge intermetallic compounds supported on HZSM-5
US7884257B2 (en) Method for producing ethylene and propylene
Wakui et al. Dehydrogenative cracking of n-butane using double-stage reaction
WO2011054203A1 (zh) 对甲醇或二甲醚制低碳烯烃用的催化剂进行预处理的方法
JPH01113493A (ja) 変性モルデナイトをベースとする触媒を用いたオレフィンオリゴマーの製造方法
US5059735A (en) Process for the production of light olefins from C5 + hydrocarbons
Anunziata et al. Methane transformation using light gasoline as co-reactant over Zn/H-ZSM11
Yarlagadda et al. Oligomerization of ethene and propene over composite zeolite catalysts