DE69916834D1 - Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen - Google Patents

Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen

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Publication number
DE69916834D1
DE69916834D1 DE69916834T DE69916834T DE69916834D1 DE 69916834 D1 DE69916834 D1 DE 69916834D1 DE 69916834 T DE69916834 T DE 69916834T DE 69916834 T DE69916834 T DE 69916834T DE 69916834 D1 DE69916834 D1 DE 69916834D1
Authority
DE
Germany
Prior art keywords
lewis acid
acid base
base complexes
activated lewis
polymerizing olefines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69916834T
Other languages
English (en)
Other versions
DE69916834T2 (de
Inventor
W Holtcamp
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Univation Technologies LLC
Original Assignee
Univation Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Technologies LLC filed Critical Univation Technologies LLC
Application granted granted Critical
Publication of DE69916834D1 publication Critical patent/DE69916834D1/de
Publication of DE69916834T2 publication Critical patent/DE69916834T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69916834T 1998-06-12 1999-06-03 Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen Expired - Fee Related DE69916834T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US8902398P 1998-06-12 1998-06-12
US89023P 1998-06-12
PCT/US1999/012491 WO1999064476A1 (en) 1998-06-12 1999-06-03 Olefin polymerization process using activated lewis acid-base complexes

Publications (2)

Publication Number Publication Date
DE69916834D1 true DE69916834D1 (de) 2004-06-03
DE69916834T2 DE69916834T2 (de) 2004-09-30

Family

ID=22215054

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69916834T Expired - Fee Related DE69916834T2 (de) 1998-06-12 1999-06-03 Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen

Country Status (9)

Country Link
US (1) US6211312B1 (de)
EP (1) EP1090045B1 (de)
JP (1) JP2002517571A (de)
AU (1) AU743376B2 (de)
BR (1) BR9911158A (de)
CA (1) CA2330529A1 (de)
DE (1) DE69916834T2 (de)
ES (1) ES2216586T3 (de)
WO (1) WO1999064476A1 (de)

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US20040072975A1 (en) * 2000-03-17 2004-04-15 Jorg Schottek Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins
CN1250581C (zh) * 2000-09-26 2006-04-12 英国石油化学品有限公司 载体催化剂体系
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US6960634B2 (en) * 2001-10-31 2005-11-01 Univation Technologies, Llc Methods for adjusting melt properties of metallocene catalyzed olefin copolymers
US6703338B2 (en) * 2002-06-28 2004-03-09 Univation Technologies, Llc Polymerization catalyst activators, method of preparing, and their use in polymerization processes
US20030207757A1 (en) * 2002-04-30 2003-11-06 Daelim Industries Co., Ltd. Catalyst composition comprising metallocene compound having bulky cycloalkyl-substituted cyclopentadienyl ligand, and process for olefin polymerization using the same
JP2006508903A (ja) 2002-07-09 2006-03-16 バセル ポリオレフィン ジーエムビーエイチ オレフィン重合用触媒系
AU2003288399A1 (en) * 2002-12-17 2004-07-09 Bp Chemicals Limited Supported olefin polymerization catalyst
US7741417B2 (en) 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
EP2029790A1 (de) 2006-06-02 2009-03-04 L'AIR LIQUIDE, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren zur bildung von high-k-filmen auf basis von neuen titan-, zirconium- und hafniumvorläufern und ihre verwendung für die halbleiterfertigung
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TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
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BR112014010900B1 (pt) 2011-11-08 2020-02-18 Univation Technologies, Llc Método de preparar um sistema de catalisador, sistema catalisador e processo de polimerização
US9034998B2 (en) 2011-12-16 2015-05-19 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9156924B2 (en) 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9631038B2 (en) 2013-10-11 2017-04-25 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9771442B2 (en) 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10364259B2 (en) 2016-12-30 2019-07-30 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Zirconium, hafnium, titanium precursors and deposition of group 4 containing films using the same
US10337104B2 (en) 2016-12-30 2019-07-02 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Zirconium, hafnium, titanium precursors and deposition of group 4 containing films using the same
US10465289B2 (en) 2016-12-30 2019-11-05 L'Air Liquide, Société Anonyme pour l'Etude at l'Exploitation des Procédés Georges Claude Zirconium, hafnium, titanium precursors and deposition of group 4 containing films using the same
EP3589693B1 (de) 2017-02-28 2024-01-03 ExxonMobil Chemical Patents Inc. Mit ölgestrecktem, bimodalem metallocen-synthetisiertem epdm hergestelltes thermoplastisches vulkanisat
US10047174B1 (en) 2017-06-28 2018-08-14 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10167352B1 (en) 2017-06-28 2019-01-01 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10174138B1 (en) 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
WO2019152209A1 (en) * 2018-01-31 2019-08-08 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US10851187B2 (en) * 2018-01-31 2020-12-01 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US10865258B2 (en) 2018-01-31 2020-12-15 Exxonmobil Chemical Patents Inc. Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same
US10829573B1 (en) 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers
EP4176005A1 (de) 2020-07-02 2023-05-10 Celanese International Corporation Thermoplastische vulkanisatzusammensetzungen mit multimodalem metallocencopolymerkautschuk und herstellungsverfahren dafür

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Also Published As

Publication number Publication date
AU743376B2 (en) 2002-01-24
US6211312B1 (en) 2001-04-03
AU4333399A (en) 1999-12-30
DE69916834T2 (de) 2004-09-30
BR9911158A (pt) 2001-04-03
EP1090045A1 (de) 2001-04-11
WO1999064476A1 (en) 1999-12-16
ES2216586T3 (es) 2004-10-16
EP1090045B1 (de) 2004-04-28
CA2330529A1 (en) 1999-12-16
JP2002517571A (ja) 2002-06-18

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