DE602004010642D1 - Verfahren zur polymerisation von olefinmonomeren mit mischkatalysatorsystemen - Google Patents

Verfahren zur polymerisation von olefinmonomeren mit mischkatalysatorsystemen

Info

Publication number
DE602004010642D1
DE602004010642D1 DE602004010642T DE602004010642T DE602004010642D1 DE 602004010642 D1 DE602004010642 D1 DE 602004010642D1 DE 602004010642 T DE602004010642 T DE 602004010642T DE 602004010642 T DE602004010642 T DE 602004010642T DE 602004010642 D1 DE602004010642 D1 DE 602004010642D1
Authority
DE
Germany
Prior art keywords
olefinmonomers
polymerizing
catalyst systems
compound catalyst
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE602004010642T
Other languages
English (en)
Other versions
DE602004010642T2 (de
Inventor
Michael A Kinnan
Fred D Ehrman
Pradeep P Shirodkar
Mark B Davis
Michele L Grief-Rust
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Univation Technologies LLC
Original Assignee
Univation Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Technologies LLC filed Critical Univation Technologies LLC
Publication of DE602004010642D1 publication Critical patent/DE602004010642D1/de
Application granted granted Critical
Publication of DE602004010642T2 publication Critical patent/DE602004010642T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/08—Presence of a deactivator
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE602004010642T 2003-03-21 2004-03-03 Verfahren zur polymerisation von olefinmonomeren mit mischkatalysatorsystemen Expired - Lifetime DE602004010642T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US45644403P 2003-03-21 2003-03-21
US456444P 2003-03-21
US10/788,631 US6833416B2 (en) 2003-03-21 2004-02-27 Methods of polymerizing olefin monomers with mixed catalyst systems
US788631 2004-02-27
PCT/US2004/006323 WO2004085488A2 (en) 2003-03-21 2004-03-03 Methods of polymerizing olefin monomers with mixed catalyst systems

Publications (2)

Publication Number Publication Date
DE602004010642D1 true DE602004010642D1 (de) 2008-01-24
DE602004010642T2 DE602004010642T2 (de) 2008-12-11

Family

ID=32994736

Family Applications (1)

Application Number Title Priority Date Filing Date
DE602004010642T Expired - Lifetime DE602004010642T2 (de) 2003-03-21 2004-03-03 Verfahren zur polymerisation von olefinmonomeren mit mischkatalysatorsystemen

Country Status (8)

Country Link
US (1) US6833416B2 (de)
EP (1) EP1620472B1 (de)
AR (1) AR043611A1 (de)
BR (1) BRPI0408550B1 (de)
CA (1) CA2518600A1 (de)
DE (1) DE602004010642T2 (de)
TW (1) TW200500379A (de)
WO (1) WO2004085488A2 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2487922A1 (en) * 2002-06-06 2003-12-18 Exxonmobil Chemical Patents Inc. Catalyst system and olefin polymerisation process
US7381778B2 (en) * 2002-06-06 2008-06-03 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
US7223823B2 (en) * 2002-06-06 2007-05-29 Exxon Mobil Chemical Patents Inc. Catalyst system and process
US7172987B2 (en) 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
US7238756B2 (en) * 2003-10-15 2007-07-03 Univation Technologies, Llc Polymerization process and control of polymer composition properties
DE102005035477A1 (de) * 2005-07-26 2007-02-01 Basell Polyolefine Gmbh Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren
DE102006004429A1 (de) * 2006-01-31 2007-08-02 Advanced Micro Devices, Inc., Sunnyvale Halbleiterbauelement mit einem Metallisierungsschichtstapel mit einem porösen Material mit kleinem ε mit einer erhöhten Integrität
EP2003150A1 (de) * 2007-06-13 2008-12-17 Petrochina Company Limited Verfahren zur Herstellung einer Polyolefinlegierung
EP2303937B1 (de) * 2008-07-23 2012-08-29 Basell Polyolefine GmbH Übergangsverfahren zwischen inkompatiblen olefinpolymerisations- und katalysatorsystemen
JP2012513506A (ja) * 2008-12-23 2012-06-14 バーゼル・ポリオレフィン・ゲーエムベーハー 非適合性のオレフィン重合触媒系の間の移行を行う方法
KR101522080B1 (ko) * 2009-12-18 2015-05-20 토탈 리서치 앤드 테크놀로지 펠루이 비호환성 에틸렌 중합 촉매 대체 방법
EP2447288B1 (de) * 2010-10-29 2016-06-22 Linde Aktiengesellschaft Verfahren zur Reaktionskontrolle einer exothermen Reaktion und Vorrichtung dafür
CA2824771A1 (en) 2011-01-14 2012-07-19 W.R. Grace & Co.-Conn. Process of making modified metallocene catalyst, catalyst produced and use thereof
JP6271807B2 (ja) * 2014-04-28 2018-01-31 バーゼル・ポリオレフィン・ゲーエムベーハー スラリー重合プロセスでアルミニウムアルキル供給を調節するための方法
EA032875B1 (ru) * 2014-12-22 2019-07-31 Сабик Глоубл Текнолоджиз Б.В. Способ перехода между несовместимыми катализаторами
US10822433B2 (en) * 2015-12-22 2020-11-03 Sabic Global Technologies B.V. Process for transitioning between incompatible catalysts
CN109957056B (zh) * 2017-12-14 2021-07-02 中国石油化工股份有限公司 卤化单烯烃-共轭二烯烃共聚物的制备方法
US11046793B2 (en) 2018-02-22 2021-06-29 Exxonmobil Chemical Patents Inc. Silica quenching agents for use in polymerization process
KR102060531B1 (ko) * 2018-07-20 2020-02-11 금호석유화학 주식회사 고무 조성물의 제조방법
US11976140B2 (en) * 2018-11-01 2024-05-07 Exxonmobil Chemical Patents Inc. In-line trimming of dry catalyst feed
WO2022268960A1 (en) * 2021-06-24 2022-12-29 Borealis Ag Utilization of 1-hexene in multi-stage polyolefin production
EP4389783A1 (de) 2022-12-20 2024-06-26 Borealis AG Katalysatorübergangsverfahren

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4460755A (en) * 1982-09-30 1984-07-17 Union Carbide Corporation Direct conversion of a polymerization reaction catalyzed by a Ziegler-type catalyst into one catalyzed by a chromium-based catalyst
US5106923A (en) * 1985-01-11 1992-04-21 The Dow Chemical Company Substituted phenol-formaldehyde novolac resins containing reduced quantities of 2-functional components and epoxy novolac resins prepared therefrom
JPH075663B2 (ja) 1986-04-01 1995-01-25 三井東圧化学株式会社 エチレンまたはα−オレフインの重合方法
US5106926A (en) 1990-12-11 1992-04-21 Union Carbide Chemicals & Plastics Technology Corporation Preparation of ethylene/1-octene copolymers of very low density in a fluidized bed reactor
US5391657A (en) 1993-09-27 1995-02-21 Union Carbide Chemicals & Plastics Technology Corporaton Method for reducing sheeting and static charges during polymerization of ethylene polymers
AU692192B2 (en) 1993-10-21 1998-06-04 Mobil Oil Corporation Improved in situ resins of bimodal molecular weight distribution
US5442019A (en) 1994-03-25 1995-08-15 Exxon Chemical Company Process for transitioning between incompatible polymerization catalysts
US5763543A (en) 1994-09-14 1998-06-09 Exxon Chemical Patents Inc. Olefin polymerization process with little or no scavenger present
IT1270125B (it) 1994-10-05 1997-04-28 Spherilene Srl Processo per la ( co) polimerizzazione di olefine
US5672666A (en) 1995-06-05 1997-09-30 Exxon Chemical Patents Inc. Process for transitioning between incompatible polymerization catalysts
JPH0995509A (ja) 1995-09-30 1997-04-08 Nippon Petrochem Co Ltd オレフィンの定常的気相重合における触媒切替え法
NO301331B1 (no) * 1996-03-05 1997-10-13 Borealis As Fremgangsmåte for skifting av katalysator ved suspensjonspolymerisasjon av olefiner
US6022933A (en) 1997-08-14 2000-02-08 Union Carbide Chemicals & Plastics Technology Corporation Process for the preparation of polyethylene

Also Published As

Publication number Publication date
WO2004085488A2 (en) 2004-10-07
EP1620472A4 (de) 2006-07-05
US20040186250A1 (en) 2004-09-23
BRPI0408550B1 (pt) 2014-03-04
WO2004085488A3 (en) 2004-11-25
DE602004010642T2 (de) 2008-12-11
EP1620472A2 (de) 2006-02-01
EP1620472B1 (de) 2007-12-12
BRPI0408550A (pt) 2006-03-07
CA2518600A1 (en) 2004-10-07
TW200500379A (en) 2005-01-01
US6833416B2 (en) 2004-12-21
AR043611A1 (es) 2005-08-03

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