DE69913932D1 - Metallocen-trägerkatalysator, seine herstellung sowie damit durchgeführte olefinpolymerisation - Google Patents

Metallocen-trägerkatalysator, seine herstellung sowie damit durchgeführte olefinpolymerisation

Info

Publication number
DE69913932D1
DE69913932D1 DE69913932T DE69913932T DE69913932D1 DE 69913932 D1 DE69913932 D1 DE 69913932D1 DE 69913932 T DE69913932 T DE 69913932T DE 69913932 T DE69913932 T DE 69913932T DE 69913932 D1 DE69913932 D1 DE 69913932D1
Authority
DE
Germany
Prior art keywords
metallocen
production
olefin polymerization
carrier catalyst
polymerization carried
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69913932T
Other languages
English (en)
Other versions
DE69913932T2 (de
Inventor
Hyun-Ki Youn
Sah-Mun Hong
Young-Jae Jun
Tae-Soo Hwang
Sung-Woo Kang
Young-Ju Kim
Tae-Gon Kim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DL Holdings Co Ltd
Original Assignee
Daelim Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daelim Industrial Co Ltd filed Critical Daelim Industrial Co Ltd
Application granted granted Critical
Publication of DE69913932D1 publication Critical patent/DE69913932D1/de
Publication of DE69913932T2 publication Critical patent/DE69913932T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE1999613932 1998-10-22 1999-10-22 Metallocen-trägerkatalysator, seine herstellung sowie damit durchgeführte olefinpolymerisation Expired - Lifetime DE69913932T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-1998-0044308A KR100430438B1 (ko) 1998-10-22 1998-10-22 담지메탈로센촉매,그제조방법및이를이용한폴리올레핀의중합방법
KR9844308 1998-10-22
PCT/KR1999/000635 WO2000023483A1 (en) 1998-10-22 1999-10-22 Supported metallocene catalyst, its preparation method and olefin polymerization therewith

Publications (2)

Publication Number Publication Date
DE69913932D1 true DE69913932D1 (de) 2004-02-05
DE69913932T2 DE69913932T2 (de) 2004-11-18

Family

ID=19554970

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1999613932 Expired - Lifetime DE69913932T2 (de) 1998-10-22 1999-10-22 Metallocen-trägerkatalysator, seine herstellung sowie damit durchgeführte olefinpolymerisation

Country Status (5)

Country Link
US (1) US6683016B1 (de)
EP (1) EP1042375B1 (de)
KR (1) KR100430438B1 (de)
DE (1) DE69913932T2 (de)
WO (1) WO2000023483A1 (de)

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KR100404780B1 (ko) * 2000-02-18 2003-11-07 대림산업 주식회사 메탈로센 화합물과 이로부터 제조되는 메탈로센 촉매 및이를 이용한 올레핀의 중합 방법
EP1201683A1 (de) * 2000-10-30 2002-05-02 SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme) Verfahren zur Polymerisation von Alpha-Olefinen
KR100447799B1 (ko) * 2001-01-03 2004-09-08 대림산업 주식회사 메탈로센 화합물 및 이를 포함하는 촉매 조성물
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7323526B2 (en) * 2005-07-29 2008-01-29 Univation Technologies, Llc Supported metallocene-alkyl catalyst composition
KR100681302B1 (ko) 2005-12-16 2007-02-09 대림산업 주식회사 올레핀 중합용 촉매 및 이를 이용한 올레핀의 중합방법
PT1999168E (pt) * 2006-03-30 2012-03-16 Total Petrochemicals Res Feluy Processo para a preparação de polímeros de etileno usando um número de reactores dispostos em série
US20070255028A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
KR101339550B1 (ko) * 2011-11-24 2013-12-10 삼성토탈 주식회사 올레핀 중합 및 공중합용 촉매 및 이를 사용하는 올레핀 중합 또는 공중합 방법
SG11202001743RA (en) * 2017-10-31 2020-05-28 Exxonmobil Chemical Patents Inc Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
KR102342780B1 (ko) 2018-02-08 2021-12-23 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조방법
RU2666736C1 (ru) * 2018-05-30 2018-09-12 Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") Способ получения синтетических высоковязких полиальфаолефиновых базовых масел
EP4370566A1 (de) 2021-07-15 2024-05-22 Braskem S.A. Kontinuierliches verfahren zur metallocenvorpolymerisation für gasphasenpolymerisationsverfahren
EP4448593A1 (de) 2021-12-16 2024-10-23 Chevron Phillips Chemical Company Lp Modifikationen von sulfatierten bentoniten und verwendungen davon in metallocenkatalysatorsystemen zur olefinpolymerisierung

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US4897455A (en) 1985-06-21 1990-01-30 Exxon Chemical Patents Inc. Polymerization process
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4730071A (en) 1986-08-15 1988-03-08 Shell Oil Company Process for preparing aluminoxanes
US4912075A (en) 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US4937217A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US4937301A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
JP2538969B2 (ja) * 1988-02-16 1996-10-02 昭和化学工業株式会社 珪藻土から高品位化した多孔質珪藻殻の製造方法
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Also Published As

Publication number Publication date
DE69913932T2 (de) 2004-11-18
WO2000023483A1 (en) 2000-04-27
KR20000026665A (ko) 2000-05-15
EP1042375A1 (de) 2000-10-11
US6683016B1 (en) 2004-01-27
KR100430438B1 (ko) 2004-07-19
EP1042375B1 (de) 2004-01-02

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