DE69908499D1 - Polymerisierbare bis-sulfonylderivate und ihre verwendung in der herstellung von ionenaustauschermembranen - Google Patents

Polymerisierbare bis-sulfonylderivate und ihre verwendung in der herstellung von ionenaustauschermembranen

Info

Publication number
DE69908499D1
DE69908499D1 DE69908499T DE69908499T DE69908499D1 DE 69908499 D1 DE69908499 D1 DE 69908499D1 DE 69908499 T DE69908499 T DE 69908499T DE 69908499 T DE69908499 T DE 69908499T DE 69908499 D1 DE69908499 D1 DE 69908499D1
Authority
DE
Germany
Prior art keywords
manufacture
ion exchange
exchange membranes
sulfonyl derivatives
polymerizable bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69908499T
Other languages
English (en)
Other versions
DE69908499T2 (de
Inventor
Christophe Michot
Michel Armand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hydro Quebec
Original Assignee
Hydro Quebec
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CA002228466A external-priority patent/CA2228466A1/en
Priority claimed from CA002236196A external-priority patent/CA2236196A1/en
Application filed by Hydro Quebec filed Critical Hydro Quebec
Publication of DE69908499D1 publication Critical patent/DE69908499D1/de
Application granted granted Critical
Publication of DE69908499T2 publication Critical patent/DE69908499T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/48—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups having nitrogen atoms of sulfonamide groups further bound to another hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C317/18—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C317/22—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/32—Monomers containing two or more unsaturated aliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0289—Means for holding the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Metallurgy (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Fuel Cell (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyethers (AREA)
DE69908499T 1998-01-30 1999-01-29 Polymerisierbare bis-sulfonylderivate und ihre verwendung in der herstellung von ionenaustauschermembranen Expired - Lifetime DE69908499T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CA2228466 1998-01-30
CA002228466A CA2228466A1 (en) 1998-01-30 1998-01-30 New improved ion exchange membranes, their methods of preparation and their uses
CA002236196A CA2236196A1 (en) 1998-04-28 1998-04-28 New improved ion exchange membranes, their methods of preparation and their uses
CA2236196 1998-04-28
PCT/CA1999/000083 WO1999038842A1 (fr) 1998-01-30 1999-01-29 Derives bis-sulfonyles polymerisables et leur utilisation dans la preparation de membranes echangeuses d'ions

Publications (2)

Publication Number Publication Date
DE69908499D1 true DE69908499D1 (de) 2003-07-10
DE69908499T2 DE69908499T2 (de) 2004-05-13

Family

ID=25680016

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69908499T Expired - Lifetime DE69908499T2 (de) 1998-01-30 1999-01-29 Polymerisierbare bis-sulfonylderivate und ihre verwendung in der herstellung von ionenaustauschermembranen

Country Status (5)

Country Link
US (3) US20030023016A1 (de)
EP (2) EP1312603A1 (de)
JP (2) JP5073883B2 (de)
DE (1) DE69908499T2 (de)
WO (1) WO1999038842A1 (de)

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EP1400539B1 (de) 1998-01-30 2008-12-03 Hydro Quebec Verfahren zur Herstellung von vernetzten sulfonierten Polymeren
WO1999038842A1 (fr) 1998-01-30 1999-08-05 Hydro-Quebec Derives bis-sulfonyles polymerisables et leur utilisation dans la preparation de membranes echangeuses d'ions
WO1999045048A1 (en) * 1998-03-03 1999-09-10 E.I. Du Pont De Nemours And Company Substantially fluorinated ionomers
US6090895A (en) * 1998-05-22 2000-07-18 3M Innovative Properties Co., Crosslinked ion conductive membranes
WO2001027167A1 (en) 1999-10-12 2001-04-19 Millipore Corporation Fluorocarbon polymeric compositions having hydrophilic functional groups and process
US6423784B1 (en) 1999-12-15 2002-07-23 3M Innovative Properties Company Acid functional fluoropolymer membranes and method of manufacture
CA2389977A1 (en) * 1999-12-23 2001-07-05 Hanne Anna Katherina Blau Method for preparing fluorosulfonyl imide monomer
US6646075B2 (en) 1999-12-23 2003-11-11 3M Innovative Properties Company High molecular weight perfluorocyclobutane polymers and method of making
JP2001302721A (ja) * 2000-04-24 2001-10-31 Toyota Central Res & Dev Lab Inc 高プロトン伝導性電解質
US6268532B1 (en) * 2000-06-05 2001-07-31 3M Innovative Properties Company Sulfonated perfluorovinyl functional monomers
US6559237B1 (en) 2000-06-05 2003-05-06 3M Innovative Properties Company Sulfonated perfluorocyclobutane ion-conducting membranes
JP4790105B2 (ja) * 2000-08-29 2011-10-12 富士フイルム株式会社 電解質組成物及びそれを用いた電気化学電池
WO2002018036A1 (en) * 2000-08-31 2002-03-07 Mykrolis Corporation Porous or non-porous substrate coated with an immobilized polymeric composition having sulfonyl groups and hydrophilic functional groups and process
EP1359142A4 (de) * 2001-02-01 2007-06-13 Asahi Chemical Ind Eine sulfonamid-gruppe enthaltendes perfluorvinyl-ether-monomer
US7094469B2 (en) 2001-08-28 2006-08-22 Mykrolis Corporation Porous or non-porous substrate coated with an immobilized polymeric composition having sulfonyl groups and hydrophilic functional groups and process
SE0103084D0 (sv) 2001-09-14 2001-09-14 Amersham Pharm Biotech Ab Generation of ion exchange media
US6727386B2 (en) * 2001-10-25 2004-04-27 3M Innovative Properties Company Aromatic imide and aromatic methylidynetrissulfonyl compounds and method of making
JP4176410B2 (ja) * 2002-07-31 2008-11-05 旭化成株式会社 ビススルホニルイミド基含有モノマーの製造方法
ITMI20030444A1 (it) * 2003-03-11 2004-09-12 Solvay Solexis Spa Processo per preparare (per)fluoroalogenoeteri.
WO2004097851A1 (ja) 2003-04-28 2004-11-11 Asahi Glass Company Limited 固体高分子電解質材料、製造方法及び固体高分子型燃料電池用膜電極接合体
TW200536868A (en) * 2004-05-07 2005-11-16 Du Pont Stable trifluorostyrene containing compounds, and their use in polymer electrolyte membranes
FR2876694B1 (fr) * 2004-10-19 2006-12-08 Commissariat Energie Atomique Polymeres fluores et membranes preparees a partir de tels polymeres, notamment pour piles a combustible et procede de synthese de tels polymeres
KR20070121762A (ko) * 2005-04-18 2007-12-27 아사히 가라스 가부시키가이샤 커플링 반응에 의한 플루오로술포닐기를 갖는 화합물의제조 방법
EP2554579B1 (de) * 2008-04-24 2016-03-30 3M Innovative Properties Company Protonenleitende materialen
JP2011241344A (ja) * 2010-05-20 2011-12-01 Toyota Central R&D Labs Inc 高分子電解質及びその製造方法、イミドモノマ、並びに、電池
US10253128B2 (en) 2013-08-07 2019-04-09 Nichias Corporation Crosslinking agent and fluorine-containing aromatic compound
EP3031798B1 (de) * 2014-12-10 2017-09-27 Belenos Clean Power Holding AG Neuartiger Vernetzer zur Herstellung einer neuen Familie einzelner Ionenleitungspolymere für elektrochemische Vorrichtungen und diese Polymere
KR102074551B1 (ko) * 2016-10-04 2020-02-06 주식회사 엘지화학 중합체 및 이를 포함하는 막
KR102487719B1 (ko) * 2016-10-28 2023-01-16 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 중합체의 가교 방법
US20180289383A1 (en) * 2017-04-07 2018-10-11 Gel-E, Inc. Means and method to stop bleeding from the nose
CN108878934B (zh) * 2018-07-02 2021-06-25 天津农学院 一种锂离子树脂离子导电膜的制备方法
CN113273006A (zh) * 2019-01-08 2021-08-17 Ａｇｃ株式会社 催化剂层、催化剂层形成用液体及膜电极接合体
GB202101153D0 (en) * 2021-01-28 2021-03-17 Fujifilm Mfg Europe Bv Polymer films

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US6025092A (en) * 1998-02-13 2000-02-15 E. I. Du Pont De Nemours And Company Fluorinated ionomers and their uses
US6228187B1 (en) * 1998-08-19 2001-05-08 Air Liquide America Corp. Apparatus and methods for generating an artificial atmosphere for the heat treating of materials

Also Published As

Publication number Publication date
JP2010248499A (ja) 2010-11-04
JP5073883B2 (ja) 2012-11-14
US20030023016A1 (en) 2003-01-30
US8697824B2 (en) 2014-04-15
US20050014917A1 (en) 2005-01-20
DE69908499T2 (de) 2004-05-13
JP2001522376A (ja) 2001-11-13
EP0973734A1 (de) 2000-01-26
EP0973734B1 (de) 2003-06-04
WO1999038842A1 (fr) 1999-08-05
EP1312603A1 (de) 2003-05-21
US20090076178A1 (en) 2009-03-19

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