DE69836159D1 - Druckwechseladsorptionsverfahren zur Wasserstoffreinigung - Google Patents
Druckwechseladsorptionsverfahren zur WasserstoffreinigungInfo
- Publication number
- DE69836159D1 DE69836159D1 DE69836159T DE69836159T DE69836159D1 DE 69836159 D1 DE69836159 D1 DE 69836159D1 DE 69836159 T DE69836159 T DE 69836159T DE 69836159 T DE69836159 T DE 69836159T DE 69836159 D1 DE69836159 D1 DE 69836159D1
- Authority
- DE
- Germany
- Prior art keywords
- swing adsorption
- pressure swing
- adsorption process
- hydrogen purification
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
- B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/502—Carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S95/00—Gas separation: processes
- Y10S95/90—Solid sorbent
- Y10S95/902—Molecular sieve
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Of Gases By Adsorption (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9700784A FR2758739B1 (fr) | 1997-01-24 | 1997-01-24 | Perfectionnement dans les procedes psa de purification de l'hydrogene |
FR9700784 | 1997-01-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69836159D1 true DE69836159D1 (de) | 2006-11-30 |
DE69836159T2 DE69836159T2 (de) | 2007-11-29 |
Family
ID=9502956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69836159T Expired - Lifetime DE69836159T2 (de) | 1997-01-24 | 1998-01-16 | Druckwechseladsorptionsverfahren zur Wasserstoffreinigung |
Country Status (10)
Country | Link |
---|---|
US (1) | US6464756B1 (de) |
EP (1) | EP0855209B1 (de) |
JP (1) | JP4382885B2 (de) |
AT (1) | ATE342758T1 (de) |
CA (1) | CA2224945C (de) |
DE (1) | DE69836159T2 (de) |
DK (1) | DK0855209T3 (de) |
ES (1) | ES2276451T3 (de) |
FR (1) | FR2758739B1 (de) |
PT (1) | PT855209E (de) |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2782507B1 (fr) * | 1998-08-21 | 2000-09-29 | Air Liquide | Procede de fabrication de particules de zeolite x echangee par des cations metalliques |
FR2782460B1 (fr) * | 1998-08-21 | 2000-09-22 | Air Liquide | Procede psa utilisant un adsorbant agglomere constitue d'une phase zeolitique et d'un liant |
FR2782461B1 (fr) | 1998-08-21 | 2000-09-22 | Air Liquide | Procede psa utilisant une zeolithe faujasite contenant des cations metalliques en tant qu'adsorbant |
FR2783439B1 (fr) * | 1998-09-23 | 2000-10-20 | Air Liquide | Particules d'adsorbant ellipsoidales et leur utilisation dans un procede de production de gaz |
US6302943B1 (en) | 1999-11-02 | 2001-10-16 | Air Products And Chemicals, Inc. | Optimum adsorbents for H2 recovery by pressure and vacuum swing absorption |
JP2000202281A (ja) * | 2000-04-20 | 2000-07-25 | Air Water Inc | 選択的窒素吸着剤およびそれを用いた空気分離方法 |
DE60129626T2 (de) | 2000-04-20 | 2008-05-21 | Tosoh Corp., Shinnanyo | Verfahren zum Reinigen von einem Wasserstoff enthaltenden Gasgemisch |
FR2811241B1 (fr) * | 2000-07-07 | 2002-12-13 | Ceca Sa | Procede pour la purification de melanges gazeux a base d'hydrogene utilisant une zeolite x au calcium |
US6596256B1 (en) * | 2000-08-28 | 2003-07-22 | The Boc Group, Inc. | Synthesis of low silicon sodium X zeolite |
EP1354619B1 (de) * | 2000-12-25 | 2007-04-04 | Sumitomo Seika Chemicals Co., Ltd. | Verfahren zur abtrennung von wasserstoffgas |
FR2832077B1 (fr) * | 2001-11-12 | 2004-08-27 | Air Liquide | Adsorbant zeolitique au baryum et calcium pour la purification de gaz, en particulier de l'air |
FR2832141B1 (fr) * | 2001-11-14 | 2004-10-01 | Ceca Sa | Procede de purification de gaz de synthese |
FR2835445B1 (fr) | 2002-02-07 | 2004-11-19 | Air Liquide | Utilisation d'un adsorbant sous forme de mousse solide pour la purification ou la separation de gaz |
US6605136B1 (en) * | 2002-07-10 | 2003-08-12 | Air Products And Chemicals, Inc. | Pressure swing adsorption process operation and optimization |
US7175751B2 (en) * | 2003-05-01 | 2007-02-13 | Ovonic Fuel Cell Company Llc | Method and apparatus for electrorefining impure hydrogen |
CN1315563C (zh) * | 2003-06-06 | 2007-05-16 | 四川天一科技股份有限公司 | 从混合气体中脱除乙烯、二氧化碳的吸附分离法 |
US7404846B2 (en) | 2005-04-26 | 2008-07-29 | Air Products And Chemicals, Inc. | Adsorbents for rapid cycle pressure swing adsorption processes |
US20080011163A1 (en) * | 2006-07-17 | 2008-01-17 | Mcclain Michael S | Sorbent porous polymeric composite materials |
KR100896455B1 (ko) * | 2007-07-09 | 2009-05-14 | 한국에너지기술연구원 | 압력변동흡착장치 및 이를 이용한 수소 정제 방법 |
US8357432B2 (en) * | 2009-03-04 | 2013-01-22 | Xerox Corporation | Mixed solvent process for preparing structured organic films |
JP2011032128A (ja) * | 2009-07-31 | 2011-02-17 | Jx Nippon Oil & Energy Corp | 水素の精製方法、水素の出荷設備、及び水素ステーション |
US9567425B2 (en) | 2010-06-15 | 2017-02-14 | Xerox Corporation | Periodic structured organic films |
US8697322B2 (en) | 2010-07-28 | 2014-04-15 | Xerox Corporation | Imaging members comprising structured organic films |
US8318892B2 (en) | 2010-07-28 | 2012-11-27 | Xerox Corporation | Capped structured organic film compositions |
US8257889B2 (en) | 2010-07-28 | 2012-09-04 | Xerox Corporation | Imaging members comprising capped structured organic film compositions |
US8119315B1 (en) | 2010-08-12 | 2012-02-21 | Xerox Corporation | Imaging members for ink-based digital printing comprising structured organic films |
US8119314B1 (en) | 2010-08-12 | 2012-02-21 | Xerox Corporation | Imaging devices comprising structured organic films |
US8759473B2 (en) | 2011-03-08 | 2014-06-24 | Xerox Corporation | High mobility periodic structured organic films |
US8247142B1 (en) | 2011-06-30 | 2012-08-21 | Xerox Corporation | Fluorinated structured organic film compositions |
US8353574B1 (en) | 2011-06-30 | 2013-01-15 | Xerox Corporation | Ink jet faceplate coatings comprising structured organic films |
US8313560B1 (en) | 2011-07-13 | 2012-11-20 | Xerox Corporation | Application of porous structured organic films for gas separation |
US8410016B2 (en) | 2011-07-13 | 2013-04-02 | Xerox Corporation | Application of porous structured organic films for gas storage |
US8377999B2 (en) | 2011-07-13 | 2013-02-19 | Xerox Corporation | Porous structured organic film compositions |
US8460844B2 (en) | 2011-09-27 | 2013-06-11 | Xerox Corporation | Robust photoreceptor surface layer |
US8372566B1 (en) | 2011-09-27 | 2013-02-12 | Xerox Corporation | Fluorinated structured organic film photoreceptor layers |
US8529997B2 (en) | 2012-01-17 | 2013-09-10 | Xerox Corporation | Methods for preparing structured organic film micro-features by inkjet printing |
US8765340B2 (en) | 2012-08-10 | 2014-07-01 | Xerox Corporation | Fluorinated structured organic film photoreceptor layers containing fluorinated secondary components |
US8906462B2 (en) | 2013-03-14 | 2014-12-09 | Xerox Corporation | Melt formulation process for preparing structured organic films |
JP6331937B2 (ja) * | 2014-10-01 | 2018-05-30 | 日本ポリプロ株式会社 | オレフィン重合体の製造方法 |
CN107486146B (zh) * | 2017-09-06 | 2020-10-23 | 洛阳建龙微纳新材料股份有限公司 | 一种混合阳离子LiCa-LSX分子筛制法及应用 |
FR3076828A1 (fr) | 2018-01-15 | 2019-07-19 | Arkema France | Procede de preparation de zeolithes en continu au moyen d'ultrasons |
CN112758892B (zh) * | 2021-01-05 | 2021-12-17 | 西南化工研究设计院有限公司 | 一种变压吸附提纯氢气系统及其方法 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3839847A (en) * | 1972-07-05 | 1974-10-08 | Hydrocarbon Research Inc | Cryogenic hydrogen adsorption system |
DE2729558C3 (de) * | 1977-06-30 | 1983-12-08 | Bergwerksverband Gmbh, 4300 Essen | Adsorptions/Desorptionsverfahren zur Gewinnung von Wasserstoff |
USRE31014E (en) * | 1981-03-30 | 1982-08-17 | Air Products And Chemicals, Inc. | Separation of multicomponent gas mixtures |
DE3143993A1 (de) * | 1981-11-05 | 1983-05-11 | Bayer Ag, 5090 Leverkusen | Molekularsieb-zeolith fuer die gewinnung von wasserstoff mit der druckwechsel-adsorptions-technik |
JPS60103002A (ja) * | 1983-11-01 | 1985-06-07 | Kawasaki Steel Corp | 吸着法を使用して一酸化炭素、二酸化炭素、水素及び窒素ガスを含む混合ガス中の一酸化炭素及び水素を精製する方法 |
JPS60139337A (ja) * | 1983-12-27 | 1985-07-24 | Toyo Soda Mfg Co Ltd | 一酸化炭素吸着剤 |
JPS61247612A (ja) * | 1985-04-23 | 1986-11-04 | Mitsubishi Heavy Ind Ltd | Co吸着分離方法 |
US4859217A (en) * | 1987-06-30 | 1989-08-22 | Uop | Process for separating nitrogen from mixtures thereof with less polar substances |
JPH0779940B2 (ja) * | 1987-09-16 | 1995-08-30 | 日本酸素株式会社 | 吸着分離法 |
JPH07166B2 (ja) * | 1987-09-24 | 1995-01-11 | 三菱重工業株式会社 | Co吸着分離方法 |
US5234472A (en) * | 1987-11-16 | 1993-08-10 | The Boc Group Plc | Separation of gas mixtures including hydrogen |
US4943304A (en) * | 1989-04-06 | 1990-07-24 | Air Products And Chemicals, Inc. | Process for the purification of bulk gases using chabazite adsorbents |
US5174979A (en) * | 1989-10-06 | 1992-12-29 | Uop | Mixed ion-exchanged zeolites and processes for the use thereof in gas separations |
US5220797A (en) * | 1990-09-28 | 1993-06-22 | The Boc Group, Inc. | Argon recovery from argon-oxygen-decarburization process waste gases |
US5133785A (en) * | 1991-02-26 | 1992-07-28 | Air Products And Chemicals, Inc. | Separation of multicomponent gas mixtures by selective adsorption |
US5152813A (en) * | 1991-12-20 | 1992-10-06 | Air Products And Chemicals, Inc. | Nitrogen adsorption with a Ca and/or Sr exchanged lithium X-zeolite |
US5266102A (en) * | 1992-09-23 | 1993-11-30 | Air Products And Chemicals, Inc. | O2 VSA process with low O2 capacity adsorbents |
US5258060A (en) * | 1992-09-23 | 1993-11-02 | Air Products And Chemicals, Inc. | Adsorptive separation using diluted adsorptive phase |
US5551257A (en) * | 1992-10-01 | 1996-09-03 | The Boc Group, Inc. | Production of ultrahigh purity nitrogen |
US5268023A (en) * | 1992-10-05 | 1993-12-07 | Air Products And Chemicals, Inc. | Nitrogen adsorption with highly Li exchanged X-zeolites with low Si/Al ratio |
US5464467A (en) * | 1994-02-14 | 1995-11-07 | The Boc Group, Inc. | Adsorptive separation of nitrogen from other gases |
IL112027A (en) * | 1994-02-14 | 1999-03-12 | Boc Group Inc | A method for separating nitrogen from other gases |
JP3462560B2 (ja) * | 1994-03-04 | 2003-11-05 | 日本パイオニクス株式会社 | 水素ガスの精製方法 |
US5573745A (en) * | 1994-05-12 | 1996-11-12 | Air Products And Chemicals, Inc. | High micropore volume low silica EMT-containing metallosilicates |
US5616170A (en) * | 1995-08-11 | 1997-04-01 | The Boc Group, Inc. | Adsorptive separation of nitrogen from other gases |
US5674311A (en) * | 1995-10-20 | 1997-10-07 | Praxair Technology, Inc. | Adsorption process and system using multilayer adsorbent beds |
-
1997
- 1997-01-24 FR FR9700784A patent/FR2758739B1/fr not_active Expired - Fee Related
-
1998
- 1998-01-16 DE DE69836159T patent/DE69836159T2/de not_active Expired - Lifetime
- 1998-01-16 EP EP98400075A patent/EP0855209B1/de not_active Expired - Lifetime
- 1998-01-16 AT AT98400075T patent/ATE342758T1/de not_active IP Right Cessation
- 1998-01-16 PT PT98400075T patent/PT855209E/pt unknown
- 1998-01-16 ES ES98400075T patent/ES2276451T3/es not_active Expired - Lifetime
- 1998-01-16 DK DK98400075T patent/DK0855209T3/da active
- 1998-01-23 CA CA002224945A patent/CA2224945C/fr not_active Expired - Fee Related
- 1998-01-26 US US09/013,237 patent/US6464756B1/en not_active Expired - Fee Related
- 1998-01-26 JP JP02779398A patent/JP4382885B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US6464756B1 (en) | 2002-10-15 |
ES2276451T3 (es) | 2007-06-16 |
PT855209E (pt) | 2007-02-28 |
EP0855209B1 (de) | 2006-10-18 |
FR2758739A1 (fr) | 1998-07-31 |
DE69836159T2 (de) | 2007-11-29 |
CA2224945C (fr) | 2006-06-20 |
JPH10212103A (ja) | 1998-08-11 |
DK0855209T3 (da) | 2007-02-19 |
FR2758739B1 (fr) | 1999-02-26 |
CA2224945A1 (fr) | 1998-07-24 |
ATE342758T1 (de) | 2006-11-15 |
JP4382885B2 (ja) | 2009-12-16 |
EP0855209A1 (de) | 1998-07-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69836159D1 (de) | Druckwechseladsorptionsverfahren zur Wasserstoffreinigung | |
FI883102A (fi) | Foerfarande foer att separera kvaeve fraon dess mindre polaera aemnen innehaollande blandningar. | |
CA2061463A1 (en) | Separation of multicomponent gas mixtures by selective adsorption | |
KR960033518A (ko) | 가스 스트림으로부터 이산화탄소의 제거방법 | |
EP0391350A3 (de) | Die Reinigung von Gasen mit Chabazitadsorbentien | |
IE882154L (en) | Adsorbent for gas purification | |
IN166241B (de) | ||
MY111563A (en) | Purification of fluids by adsorption. | |
AU578375B2 (en) | Producing ammonia synthesis gas | |
BR9803765A (pt) | Granulometria e espessura de leito de uma unidade psa. | |
HUP0302754A2 (hu) | Eljárás kén-oxi-fluoridok visszanyerésére és elválasztására gázelegyekből | |
PL265427A1 (en) | Method of purifying gaseous mixtures by adsorption processes and adsorber therefor |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |