DE69835373D1 - Olefin-polymerisationskatalysatorzusammensetzung, die übergangsmetallverbindungen in niedriger oxidationsstufe enthält - Google Patents

Olefin-polymerisationskatalysatorzusammensetzung, die übergangsmetallverbindungen in niedriger oxidationsstufe enthält

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Publication number
DE69835373D1
DE69835373D1 DE69835373T DE69835373T DE69835373D1 DE 69835373 D1 DE69835373 D1 DE 69835373D1 DE 69835373 T DE69835373 T DE 69835373T DE 69835373 T DE69835373 T DE 69835373T DE 69835373 D1 DE69835373 D1 DE 69835373D1
Authority
DE
Germany
Prior art keywords
transition metal
composition containing
catalyst composition
polymerization catalyst
metal compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69835373T
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English (en)
Other versions
DE69835373T2 (de
Inventor
T Matsunaga
S Schiffino
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of DE69835373D1 publication Critical patent/DE69835373D1/de
Application granted granted Critical
Publication of DE69835373T2 publication Critical patent/DE69835373T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/62003—Refractory metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/62082—Tridentate ligand
    • C08F4/62086—Neutral ligand
    • C08F4/62089—NNN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/627—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/629—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6294—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Plural Heterocyclic Compounds (AREA)
DE69835373T 1997-12-11 1998-11-03 Olefin-polymerisationskatalysatorzusammensetzung, die übergangsmetallverbindungen in niedriger oxidationsstufe enthält Expired - Lifetime DE69835373T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US989295 1997-12-11
US08/989,295 US6362294B1 (en) 1997-12-11 1997-12-11 Reduced oxidation state transition metal compounds useful as olefin polymerization catalysts
PCT/US1998/023519 WO1999029739A1 (en) 1997-12-11 1998-11-03 Reduced oxidation state transition metal compounds useful as olefin polymerization catalysts

Publications (2)

Publication Number Publication Date
DE69835373D1 true DE69835373D1 (de) 2006-09-07
DE69835373T2 DE69835373T2 (de) 2007-08-02

Family

ID=25534975

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69835373T Expired - Lifetime DE69835373T2 (de) 1997-12-11 1998-11-03 Olefin-polymerisationskatalysatorzusammensetzung, die übergangsmetallverbindungen in niedriger oxidationsstufe enthält

Country Status (10)

Country Link
US (1) US6362294B1 (de)
EP (1) EP1037932B1 (de)
JP (1) JP2001525459A (de)
KR (1) KR100592623B1 (de)
CN (1) CN1128821C (de)
BR (1) BR9813537A (de)
CA (1) CA2304506C (de)
DE (1) DE69835373T2 (de)
ES (1) ES2264573T3 (de)
WO (1) WO1999029739A1 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9914200D0 (en) * 1999-06-17 1999-08-18 Borealis As Catalysts
IT1314262B1 (it) * 1999-12-03 2002-12-06 Enichem Spa Tris-(3,5-dimetilpirazolil) borato di cromo dicloruro quale componentedi sistemi catalitici per la polimerizzazione di olefine e processo di
GB2369590B (en) * 2000-09-29 2005-05-04 Tosoh Corp Catalyst for trimerization of ethylene and process for trimerizing ethylene using the catalyst
US6930070B2 (en) * 2002-01-28 2005-08-16 Univation Technologies, Llc Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
JP5213342B2 (ja) * 2007-03-20 2013-06-19 国立大学法人 岡山大学 オレフィン重合用触媒及びオレフィンの重合方法。
US8022005B2 (en) * 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62195110A (ja) 1986-02-21 1987-08-27 株式会社村田製作所 セラミツクコンデンサ
JP2502102B2 (ja) * 1987-10-08 1996-05-29 東燃株式会社 オレフイン重合用触媒
US5237069A (en) 1990-10-26 1993-08-17 The Dow Chemical Company Hydridotris(pyrazolyl)borate metal complexes and polymerization process
US5744677A (en) 1991-10-16 1998-04-28 Amoco Corporation Ethylene oligomerization
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
DE69326463T2 (de) 1992-07-01 2000-05-04 Exxon Chemical Patents Inc Olefinpolymerisationskatalysatoren auf basis von uebergangsmetallen
US5312794A (en) * 1992-12-29 1994-05-17 Shell Oil Company Catalyst system for olefin polymerization
DE69410668D1 (de) 1993-03-23 1998-07-09 Asahi Chemical Ind Olefinpolymerisationkatalysator mit mehrzähnigem Ligand
JPH08127610A (ja) 1994-10-28 1996-05-21 Ube Ind Ltd オレフィン重合用触媒
EP0789718B1 (de) 1994-10-31 1998-04-08 Dsm N.V. Katalytische zusammensetzung und verfahren zur olefinpolymerisation
US5519099A (en) 1995-06-07 1996-05-21 Industrial Technology Research Institute Organometallic catalysts containing hydrotris(pyrazolyl) borate and cyclopentadienyl groups, and processes of employing the same
GB9522859D0 (en) 1995-11-08 1996-01-10 Borealis As Compounds
DE19548146C1 (de) 1995-12-21 1997-11-20 Basf Ag Tris(pyrazolyl)boratmetallkomplex-Katalysatoren und deren Verwendung

Also Published As

Publication number Publication date
CN1336937A (zh) 2002-02-20
CN1128821C (zh) 2003-11-26
WO1999029739A1 (en) 1999-06-17
EP1037932B1 (de) 2006-07-26
JP2001525459A (ja) 2001-12-11
DE69835373T2 (de) 2007-08-02
EP1037932A1 (de) 2000-09-27
CA2304506C (en) 2009-01-06
BR9813537A (pt) 2000-10-10
US6362294B1 (en) 2002-03-26
KR20010024474A (ko) 2001-03-26
KR100592623B1 (ko) 2006-06-23
CA2304506A1 (en) 1999-06-17
ES2264573T3 (es) 2007-01-01

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