DE69810101T2 - Mischung für reifenwände und andere gummikonstruktionen - Google Patents
Mischung für reifenwände und andere gummikonstruktionenInfo
- Publication number
- DE69810101T2 DE69810101T2 DE69810101T DE69810101T DE69810101T2 DE 69810101 T2 DE69810101 T2 DE 69810101T2 DE 69810101 T DE69810101 T DE 69810101T DE 69810101 T DE69810101 T DE 69810101T DE 69810101 T2 DE69810101 T2 DE 69810101T2
- Authority
- DE
- Germany
- Prior art keywords
- para
- rubber
- alkylstyrene
- copolymer
- methylstyrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001971 elastomer Polymers 0.000 title claims description 51
- 239000005060 rubber Substances 0.000 title claims description 51
- 239000000203 mixture Substances 0.000 claims description 110
- 229920001577 copolymer Polymers 0.000 claims description 88
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 26
- 229920002857 polybutadiene Polymers 0.000 claims description 20
- 244000043261 Hevea brasiliensis Species 0.000 claims description 15
- 229920003052 natural elastomer Polymers 0.000 claims description 15
- 229920001194 natural rubber Polymers 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 11
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 9
- 239000005062 Polybutadiene Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- -1 aromatic styrene compounds Chemical class 0.000 claims description 6
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 6
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 5
- 229920001195 polyisoprene Polymers 0.000 claims description 4
- 150000003440 styrenes Chemical class 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 37
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 21
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 16
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 16
- 229910052794 bromium Inorganic materials 0.000 description 16
- 150000002367 halogens Chemical class 0.000 description 16
- 238000002156 mixing Methods 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 15
- 229910052736 halogen Inorganic materials 0.000 description 15
- 230000026030 halogenation Effects 0.000 description 13
- 238000005658 halogenation reaction Methods 0.000 description 13
- 238000004132 cross linking Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- 150000003254 radicals Chemical class 0.000 description 11
- 239000000306 component Substances 0.000 description 10
- 238000005336 cracking Methods 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 238000005893 bromination reaction Methods 0.000 description 9
- 239000000945 filler Substances 0.000 description 9
- 239000003999 initiator Substances 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 239000003085 diluting agent Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229920002943 EPDM rubber Polymers 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 230000031709 bromination Effects 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000007086 side reaction Methods 0.000 description 6
- 229920001897 terpolymer Polymers 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000001246 bromo group Chemical group Br* 0.000 description 3
- 229920005549 butyl rubber Polymers 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 235000019241 carbon black Nutrition 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 125000004970 halomethyl group Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000001743 benzylic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 2
- 238000009661 fatigue test Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 125000001188 haloalkyl group Chemical group 0.000 description 2
- 230000002140 halogenating effect Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229920003049 isoprene rubber Polymers 0.000 description 2
- 239000011968 lewis acid catalyst Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- MMMNTDFSPSQXJP-UHFFFAOYSA-N orphenadrine citrate Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O.C=1C=CC=C(C)C=1C(OCCN(C)C)C1=CC=CC=C1 MMMNTDFSPSQXJP-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- OGJJVYFQXFXJKU-UHFFFAOYSA-N 3-methylbicyclo[2.2.1]hepta-2,5-diene Chemical compound C1C2C(C)=CC1C=C2 OGJJVYFQXFXJKU-UHFFFAOYSA-N 0.000 description 1
- FYZHLRMYDRUDES-UHFFFAOYSA-N 5,7-dimethylocta-1,6-diene Chemical compound CC(C)=CC(C)CCC=C FYZHLRMYDRUDES-UHFFFAOYSA-N 0.000 description 1
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000012668 chain scission Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- 229920005556 chlorobutyl Polymers 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 125000000950 dibromo group Chemical group Br* 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 125000004968 halobutyl group Chemical group 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000003518 norbornenyl group Chemical class C12(C=CC(CC1)C2)* 0.000 description 1
- 239000012434 nucleophilic reagent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000005375 primary alkyl halides Chemical class 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000005376 secondary alkyl halides Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical class [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/283—Iso-olefin halogenated homopolymers or copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10495—Pneumatic tire or inner tube
- Y10T152/10765—Characterized by belt or breaker structure
- Y10T152/1081—Breaker or belt characterized by the chemical composition or physical properties of elastomer or the like
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4563297P | 1997-05-05 | 1997-05-05 | |
| US6259197P | 1997-10-20 | 1997-10-20 | |
| PCT/US1998/008863 WO1998050464A1 (en) | 1997-05-05 | 1998-05-01 | Composition for tire sidewalls and other rubber constructions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69810101D1 DE69810101D1 (de) | 2003-01-23 |
| DE69810101T2 true DE69810101T2 (de) | 2003-09-25 |
Family
ID=26723027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69810101T Expired - Fee Related DE69810101T2 (de) | 1997-05-05 | 1998-05-01 | Mischung für reifenwände und andere gummikonstruktionen |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US6374889B1 (enExample) |
| EP (1) | EP0981581B1 (enExample) |
| JP (1) | JP2002512652A (enExample) |
| KR (1) | KR20010012239A (enExample) |
| CN (1) | CN1255150A (enExample) |
| BR (1) | BR9808741A (enExample) |
| CA (1) | CA2286725A1 (enExample) |
| DE (1) | DE69810101T2 (enExample) |
| ES (1) | ES2186155T3 (enExample) |
| PL (1) | PL336595A1 (enExample) |
| TW (1) | TW434151B (enExample) |
| WO (1) | WO1998050464A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6223796B1 (en) * | 1999-08-17 | 2001-05-01 | The Goodyear Tire & Rubber Company | Pneumatic tire having an outer layer of veneer covering the sidewall |
| US6255397B1 (en) * | 1999-09-10 | 2001-07-03 | The Goodyear Tire & Rubber Company | Rubber composition containing hydroxyl terminated liquid polymer and tire with sidewall thereof |
| JP4988084B2 (ja) * | 2000-08-08 | 2012-08-01 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| US7714043B2 (en) * | 2000-10-18 | 2010-05-11 | Exxonmobil Chemical Patents Inc. | Tire innerliners having improved cold temperature properties |
| KR20030087645A (ko) * | 2001-03-19 | 2003-11-14 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 높은 견인력 및 내마모성 탄성중합체 조성물 |
| CA2449072A1 (en) * | 2001-06-07 | 2002-12-19 | Exxonmobil Chemical Patents Inc. | Halogenated isobutylene-based copolymers having enhanced viscosity and thermoplastic compositions thereof |
| US6939921B2 (en) * | 2001-10-16 | 2005-09-06 | Exxonmobil Chemical Patents Inc. | Colorable elastomeric composition |
| US20040069385A1 (en) * | 2002-07-01 | 2004-04-15 | Sean Timoney | Wheel |
| US6834697B2 (en) * | 2002-09-17 | 2004-12-28 | The Goodyear Tire & Rubber Company | Tire having sidewall of rubber composition containing functional liquid polymer, polybutadiene, and brominated copolymer of isobutylene and para-methylstyrene |
| US7060757B2 (en) * | 2003-02-06 | 2006-06-13 | Bridgestone Corporation | Rubber composition and pneumatic tire using the same |
| US7091282B2 (en) * | 2003-05-15 | 2006-08-15 | Bridgestone Corporation | Composition containing ethylene/propylene/diene copolymer and polyalkylene/olefin copolymer |
| CA2592498C (en) | 2004-12-29 | 2011-09-13 | Exxonmobil Chemical Patents Inc. | Select elastomeric blends and their use in articles |
| US7906600B2 (en) * | 2004-12-29 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
| US20070256771A1 (en) * | 2006-05-08 | 2007-11-08 | Balogh George F | Tire having sidewall with integral colored marking composite |
| BRPI0718823A2 (pt) | 2006-11-07 | 2014-10-07 | Cabot Corp | Negros de carbono com baixas quantidades de pah e métodos para produzir os mesmos |
| MX2010007178A (es) * | 2007-12-28 | 2011-02-22 | Bridgestone Americas Tire | Compuestos de pared lateral negra que contienen silice y neumaticos que comprenden los mismos. |
| CN102575052A (zh) * | 2009-09-10 | 2012-07-11 | 埃克森美孚化学专利公司 | 弹性体共聚物、共聚物组合物和它们在制品中的用途 |
| US9175150B2 (en) | 2012-03-02 | 2015-11-03 | Cabot Corporation | Modified carbon blacks having low PAH amounts and elastomers containing the same |
| JP5502121B2 (ja) * | 2012-03-13 | 2014-05-28 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| US10012197B2 (en) | 2013-10-18 | 2018-07-03 | Holley Performance Products, Inc. | Fuel injection throttle body |
| US10286729B2 (en) | 2015-04-07 | 2019-05-14 | Lehigh Technologies, Inc. | Tire having crack resistant sidewalls |
| JPWO2017099202A1 (ja) * | 2015-12-11 | 2018-10-04 | 株式会社ブリヂストン | タイヤ及びタイヤの製造方法 |
| US9376997B1 (en) | 2016-01-13 | 2016-06-28 | Fuel Injection Technology Inc. | EFI throttle body with side fuel injectors |
| FR3081875B1 (fr) * | 2018-05-31 | 2020-05-22 | Compagnie Generale Des Etablissements Michelin | Pneumatique pourvu d'un flanc externe comportant un ou plusieurs elastomeres thermoplastiques et un ou plusieurs elastomeres dieniques synthetiques |
| FR3081873B1 (fr) * | 2018-05-31 | 2020-05-22 | Compagnie Generale Des Etablissements Michelin | Pneumatique pourvu d'un flanc externe comportant un ou plusieurs elastomeres thermoplastiques et un ou plusieurs elastomeres dieniques synthetiques |
| CN112250956A (zh) * | 2020-09-28 | 2021-01-22 | 赛轮集团股份有限公司 | 一种自清洁的浅色胎侧橡胶组合物 |
| JP7714167B2 (ja) * | 2021-11-05 | 2025-07-29 | 住友ゴム工業株式会社 | 空気入りタイヤ |
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|---|---|---|---|---|
| AU6924081A (en) * | 1981-03-13 | 1982-10-06 | Ventive A.B. | An arrangement in an eccentric press |
| US4548995A (en) | 1983-04-01 | 1985-10-22 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| US5162445A (en) | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
| US5654379A (en) | 1987-11-27 | 1997-08-05 | Exxon Chemicals Patent, Inc. | Process for selective bromination of para-alkylstyrene/isoolefin copolymers |
| DE3914540A1 (de) | 1988-05-02 | 1989-11-16 | Toyo Tire & Rubber Co | Pneumatischer reifen |
| WO1991005666A1 (de) | 1989-10-10 | 1991-05-02 | Siemens Aktiengesellschaft | Vorrichtung zum trocknen von aufzeichnungsträgern in tintendruckeinrichtungen |
| US5532312A (en) * | 1990-08-15 | 1996-07-02 | Exxon Chemical Patents, Inc. | Tire sidewall composition |
| DE69123849T2 (de) * | 1990-08-15 | 1997-04-10 | Exxon Chemical Patents Inc | Mischung für reifenseitenwand |
| US5376438A (en) * | 1993-02-08 | 1994-12-27 | Exxon Chemical Patents Inc. | Multilayer tire sidewall |
| JPH06240050A (ja) * | 1993-02-18 | 1994-08-30 | Yokohama Rubber Co Ltd:The | サイドウオール用ゴム組成物 |
| US5504164A (en) * | 1994-05-03 | 1996-04-02 | Exxon Chemical Patents Inc. | Curing systems for compositions containing halogenated copolymers of isobutylene and para-methylstrene |
| JP3329619B2 (ja) * | 1995-04-17 | 2002-09-30 | 株式会社ブリヂストン | ゴム組成物 |
| US5656694A (en) | 1995-05-03 | 1997-08-12 | Exxon Chemical Patents Inc. | Interpolymer cures of blends comprising halogenated isoolefin/para-alkylstyrene elastomers and unsaturated elastomers |
| CA2180912A1 (en) | 1996-04-12 | 1997-10-13 | Terry Russell Phillips | Tire with rubber sidewall |
-
1998
- 1998-05-01 CN CN98804856A patent/CN1255150A/zh active Pending
- 1998-05-01 ES ES98920115T patent/ES2186155T3/es not_active Expired - Lifetime
- 1998-05-01 US US09/071,105 patent/US6374889B1/en not_active Expired - Fee Related
- 1998-05-01 WO PCT/US1998/008863 patent/WO1998050464A1/en not_active Ceased
- 1998-05-01 PL PL98336595A patent/PL336595A1/xx unknown
- 1998-05-01 KR KR1019997010189A patent/KR20010012239A/ko not_active Withdrawn
- 1998-05-01 JP JP54825498A patent/JP2002512652A/ja not_active Ceased
- 1998-05-01 BR BR9808741-0A patent/BR9808741A/pt not_active Application Discontinuation
- 1998-05-01 CA CA002286725A patent/CA2286725A1/en not_active Abandoned
- 1998-05-01 EP EP98920115A patent/EP0981581B1/en not_active Expired - Lifetime
- 1998-05-01 DE DE69810101T patent/DE69810101T2/de not_active Expired - Fee Related
- 1998-05-04 TW TW087106858A patent/TW434151B/zh active
-
2002
- 2002-01-02 US US10/040,778 patent/US6837288B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0981581B1 (en) | 2002-12-11 |
| KR20010012239A (ko) | 2001-02-15 |
| CA2286725A1 (en) | 1998-11-12 |
| US20020100530A1 (en) | 2002-08-01 |
| BR9808741A (pt) | 2000-07-11 |
| US6374889B1 (en) | 2002-04-23 |
| ES2186155T3 (es) | 2003-05-01 |
| CN1255150A (zh) | 2000-05-31 |
| US6837288B2 (en) | 2005-01-04 |
| EP0981581A1 (en) | 2000-03-01 |
| JP2002512652A (ja) | 2002-04-23 |
| PL336595A1 (en) | 2000-07-03 |
| TW434151B (en) | 2001-05-16 |
| DE69810101D1 (de) | 2003-01-23 |
| WO1998050464A1 (en) | 1998-11-12 |
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