DE69723986T2 - Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren - Google Patents
Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren Download PDFInfo
- Publication number
- DE69723986T2 DE69723986T2 DE69723986T DE69723986T DE69723986T2 DE 69723986 T2 DE69723986 T2 DE 69723986T2 DE 69723986 T DE69723986 T DE 69723986T DE 69723986 T DE69723986 T DE 69723986T DE 69723986 T2 DE69723986 T2 DE 69723986T2
- Authority
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- Germany
- Prior art keywords
- mixer
- agglomerates
- fluidized bed
- surfactant
- residence time
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 238000000034 method Methods 0.000 title claims description 99
- 239000003599 detergent Substances 0.000 title claims description 92
- 230000008569 process Effects 0.000 title claims description 53
- 239000000203 mixture Substances 0.000 title claims description 48
- 238000004519 manufacturing process Methods 0.000 title description 12
- 239000007788 liquid Substances 0.000 claims description 46
- 239000004094 surface-active agent Substances 0.000 claims description 45
- 239000000843 powder Substances 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 34
- 238000005054 agglomeration Methods 0.000 claims description 21
- 239000007921 spray Substances 0.000 claims description 21
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 20
- 230000002776 aggregation Effects 0.000 claims description 18
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 17
- 239000003945 anionic surfactant Substances 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 13
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000005243 fluidization Methods 0.000 claims description 11
- 150000004760 silicates Chemical class 0.000 claims description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 10
- 235000017550 sodium carbonate Nutrition 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 7
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 239000003093 cationic surfactant Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 claims description 3
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 3
- 235000021317 phosphate Nutrition 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- 150000001860 citric acid derivatives Chemical class 0.000 claims description 2
- 239000012530 fluid Substances 0.000 description 25
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- 239000002245 particle Substances 0.000 description 21
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 15
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 9
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
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- 239000011230 binding agent Substances 0.000 description 6
- 150000007942 carboxylates Chemical group 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 239000004115 Sodium Silicate Substances 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 125000002947 alkylene group Chemical group 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
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- 238000005469 granulation Methods 0.000 description 5
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 5
- 239000011976 maleic acid Substances 0.000 description 5
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- 229920000768 polyamine Polymers 0.000 description 5
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- 235000019351 sodium silicates Nutrition 0.000 description 5
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- 229930182556 Polyacetal Natural products 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
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- 229910052739 hydrogen Inorganic materials 0.000 description 4
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 229920006324 polyoxymethylene Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 159000000001 potassium salts Chemical class 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
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- 239000007858 starting material Substances 0.000 description 3
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- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 2
- 229910017090 AlO 2 Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229940091181 aconitic acid Drugs 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical group 0.000 description 2
- 125000004450 alkenylene group Chemical group 0.000 description 2
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- 125000003710 aryl alkyl group Chemical group 0.000 description 2
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- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 2
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- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 2
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- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical class OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 2
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- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 2
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- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
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- PIEBLDUKOUPLRJ-UHFFFAOYSA-N CN(C)C(CCCCC)S(=O)(=O)O Chemical compound CN(C)C(CCCCC)S(=O)(=O)O PIEBLDUKOUPLRJ-UHFFFAOYSA-N 0.000 description 1
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- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- DUCCPNVOQJMMAN-UHFFFAOYSA-N dimethylamino hexanoate Chemical compound CCCCCC(=O)ON(C)C DUCCPNVOQJMMAN-UHFFFAOYSA-N 0.000 description 1
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- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
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- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Chemical group 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical class CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000001205 polyphosphate Chemical class 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000010334 sieve classification Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1996/015881 WO1998014549A1 (en) | 1996-10-04 | 1996-10-04 | Process for making a low density detergent composition by non-tower process |
| WOPCT/US96/15881 | 1996-10-04 | ||
| PCT/US1997/009795 WO1998014557A1 (en) | 1996-10-04 | 1997-06-05 | Process for making a detergent composition by non-tower process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69723986D1 DE69723986D1 (de) | 2003-09-11 |
| DE69723986T2 true DE69723986T2 (de) | 2004-06-03 |
Family
ID=22255901
Family Applications (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69715224T Expired - Fee Related DE69715224T2 (de) | 1996-10-04 | 1997-06-05 | Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren |
| DE69726440T Expired - Fee Related DE69726440T2 (de) | 1996-10-04 | 1997-06-05 | Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne turm-verfahren |
| DE69726439T Expired - Fee Related DE69726439T2 (de) | 1996-10-04 | 1997-06-05 | Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren |
| DE69721287T Expired - Fee Related DE69721287T2 (de) | 1996-10-04 | 1997-06-05 | Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren |
| DE69723986T Expired - Fee Related DE69723986T2 (de) | 1996-10-04 | 1997-06-05 | Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren |
Family Applications Before (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69715224T Expired - Fee Related DE69715224T2 (de) | 1996-10-04 | 1997-06-05 | Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren |
| DE69726440T Expired - Fee Related DE69726440T2 (de) | 1996-10-04 | 1997-06-05 | Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne turm-verfahren |
| DE69726439T Expired - Fee Related DE69726439T2 (de) | 1996-10-04 | 1997-06-05 | Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren |
| DE69721287T Expired - Fee Related DE69721287T2 (de) | 1996-10-04 | 1997-06-05 | Verfahren zur herstellung von einer waschmittelzusammensetzung nach ohne-turm-verfahren |
Country Status (12)
| Country | Link |
|---|---|
| EP (9) | EP0929645A1 (es) |
| JP (9) | JP3305327B2 (es) |
| CN (8) | CN1156560C (es) |
| AR (6) | AR010509A1 (es) |
| AT (5) | ATE223476T1 (es) |
| AU (9) | AU7388196A (es) |
| BR (7) | BR9612732A (es) |
| CA (9) | CA2267291C (es) |
| DE (5) | DE69715224T2 (es) |
| ES (5) | ES2212109T3 (es) |
| MX (2) | MX219076B (es) |
| WO (9) | WO1998014549A1 (es) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU711592B2 (en) * | 1995-04-03 | 1999-10-14 | Novartis Ag | Pyrazole derivatives and processes for the preparation thereof |
| GB9526097D0 (en) * | 1995-12-20 | 1996-02-21 | Unilever Plc | Process |
| GB9712580D0 (en) * | 1997-06-16 | 1997-08-20 | Unilever Plc | Production of detergent granulates |
| GB9712583D0 (en) | 1997-06-16 | 1997-08-20 | Unilever Plc | Production of detergent granulates |
| GB9713748D0 (en) * | 1997-06-27 | 1997-09-03 | Unilever Plc | Production of detergent granulates |
| JP2002507629A (ja) | 1997-07-14 | 2002-03-12 | ザ、プロクター、エンド、ギャンブル、カンパニー | 粒子サイズによって塊状化を制御することによる低密度の洗剤組成物の作製方法 |
| BR9810723A (pt) | 1997-07-14 | 2000-08-08 | Procter & Gamble | Processo para fabricação de uma composição de detergente de baixa densidade por meio da aglomeração controlada em uma secadora de leito fluido |
| DE69823668T2 (de) | 1997-07-15 | 2005-04-07 | The Procter & Gamble Company, Cincinnati | Verfahren zur herstellung hochkonzentrierter waschmittelagglomerate durch mehrstufige einspritzung von tensidpasten |
| US6440342B1 (en) | 1998-07-08 | 2002-08-27 | The Procter & Gamble Company | Process for making a low density detergent composition by controlling nozzle height in a fluid bed dryer |
| CN1179030C (zh) | 1998-08-20 | 2004-12-08 | 宝洁公司 | 包括中速混合器/密化器的制备高密度洗涤剂的方法 |
| US6794354B1 (en) * | 1998-09-18 | 2004-09-21 | The Procter & Gamble Company | Continuous process for making detergent composition |
| EP1124937B1 (en) * | 1998-10-26 | 2002-12-11 | The Procter & Gamble Company | Processes for making granular detergent composition having improved appearance and solubility |
| GB9825558D0 (en) * | 1998-11-20 | 1999-01-13 | Unilever Plc | Granular detergent components and particulate detergent compositions containing them |
| GB9913546D0 (en) | 1999-06-10 | 1999-08-11 | Unilever Plc | Granular detergent component containing zeolite map and laundry detergent compositions containing it |
| US6894018B1 (en) | 1999-06-21 | 2005-05-17 | The Procter & Gamble Company | Process for making granular detergent in a fluidized bed granulator having recycling of improperly sized particles |
| ATE273378T1 (de) * | 1999-06-21 | 2004-08-15 | Procter & Gamble | Verfahren zur herstellung granularer waschmittelzusammensetzungen |
| GB0009877D0 (en) † | 2000-04-20 | 2000-06-07 | Unilever Plc | Granular detergent component and process for its preparation |
| EP2123742A1 (en) | 2008-05-14 | 2009-11-25 | The Procter and Gamble Company | A solid laundry detergent composition comprising light density silicate salt |
| WO2011061045A1 (en) | 2009-11-20 | 2011-05-26 | Unilever Nv | Detergent granule and its manufacture |
| MX2016013263A (es) | 2014-04-10 | 2017-01-16 | Procter & Gamble | Granulos detergentes compuestos y composiciones para lavanderia que comprenden estos. |
| JP7485606B2 (ja) | 2018-01-26 | 2024-05-16 | エコラボ ユーエスエー インコーポレイティド | 液体アニオン性界面活性剤の固化 |
| WO2019148090A1 (en) | 2018-01-26 | 2019-08-01 | Ecolab Usa Inc. | Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a carrier |
| BR112020015170A2 (pt) | 2018-01-26 | 2021-01-26 | Ecolab Usa Inc. | composições de tensoativo líquido solidificado e de limpeza sólida, e, método para limpar uma superfície |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3625902A (en) * | 1968-10-11 | 1971-12-07 | Stauffer Chemical Co | Method of preparing agglomerated detergent composition |
| US4169806A (en) * | 1978-08-09 | 1979-10-02 | The Procter & Gamble Company | Agglomeration process for making granular detergents |
| US4992079A (en) * | 1986-11-07 | 1991-02-12 | Fmc Corporation | Process for preparing a nonphosphate laundry detergent |
| GB2209172A (en) * | 1987-08-28 | 1989-05-04 | Unilever Plc | Preparation of solid particulate components for detergents |
| KR0170424B1 (ko) * | 1990-07-05 | 1999-01-15 | 호르스트 헤를레,요한 글라슬 | 세제 및 청정제용 표면 활성제 과립의 제조방법 |
| HUT64391A (en) * | 1990-11-14 | 1993-12-28 | Procter & Gamble | Nonphosphated dishwashing compositions with oxygen belach systems and method for producing them |
| CZ284883B6 (cs) * | 1992-06-15 | 1999-03-17 | The Procter & Gamble Company | Způsob výroby kompaktních detergentních prostředků |
| WO1995010595A1 (en) * | 1993-10-15 | 1995-04-20 | The Procter & Gamble Company | Continuous process for making high density detergent granules |
| GB9322530D0 (en) * | 1993-11-02 | 1993-12-22 | Unilever Plc | Process for the production of a detergent composition |
| DK0663439T3 (da) * | 1994-01-17 | 2000-09-18 | Procter & Gamble | Fremgangsmåde til fremstilling af detergentgranulat |
| US5489392A (en) * | 1994-09-20 | 1996-02-06 | The Procter & Gamble Company | Process for making a high density detergent composition in a single mixer/densifier with selected recycle streams for improved agglomerate properties |
| US5516448A (en) * | 1994-09-20 | 1996-05-14 | The Procter & Gamble Company | Process for making a high density detergent composition which includes selected recycle streams for improved agglomerate |
| US5554587A (en) * | 1995-08-15 | 1996-09-10 | The Procter & Gamble Company | Process for making high density detergent composition using conditioned air |
-
1996
- 1996-10-04 CA CA002267291A patent/CA2267291C/en not_active Expired - Fee Related
- 1996-10-04 BR BR9612732A patent/BR9612732A/pt not_active IP Right Cessation
- 1996-10-04 EP EP96936168A patent/EP0929645A1/en not_active Withdrawn
- 1996-10-04 MX MX9903193A patent/MX219076B/es not_active IP Right Cessation
- 1996-10-04 AU AU73881/96A patent/AU7388196A/en not_active Abandoned
- 1996-10-04 WO PCT/US1996/015881 patent/WO1998014549A1/en not_active Application Discontinuation
- 1996-10-04 JP JP53523397A patent/JP3305327B2/ja not_active Expired - Fee Related
- 1996-10-04 MX MX9903195A patent/MX219077B/es not_active IP Right Cessation
-
1997
- 1997-06-05 AT AT97928871T patent/ATE223476T1/de not_active IP Right Cessation
- 1997-06-05 DE DE69715224T patent/DE69715224T2/de not_active Expired - Fee Related
- 1997-06-05 CA CA002268055A patent/CA2268055C/en not_active Expired - Fee Related
- 1997-06-05 AU AU34785/97A patent/AU3478597A/en not_active Abandoned
- 1997-06-05 WO PCT/US1997/009794 patent/WO1998014556A1/en active IP Right Grant
- 1997-06-05 WO PCT/US1997/009793 patent/WO1998014555A1/en not_active Application Discontinuation
- 1997-06-05 DE DE69726440T patent/DE69726440T2/de not_active Expired - Fee Related
- 1997-06-05 AT AT97929815T patent/ATE246726T1/de not_active IP Right Cessation
- 1997-06-05 JP JP51649498A patent/JP3299985B2/ja not_active Expired - Fee Related
- 1997-06-05 AT AT97928872T patent/ATE255159T1/de not_active IP Right Cessation
- 1997-06-05 CN CNB971802793A patent/CN1156560C/zh not_active Expired - Fee Related
- 1997-06-05 CN CN97180294.7A patent/CN1239992A/zh active Pending
- 1997-06-05 BR BR9712490-7A patent/BR9712490A/pt not_active IP Right Cessation
- 1997-06-05 AU AU34783/97A patent/AU3478397A/en not_active Abandoned
- 1997-06-05 EP EP97929815A patent/EP0929650B1/en not_active Expired - Lifetime
- 1997-06-05 JP JP51649098A patent/JP3299982B2/ja not_active Expired - Fee Related
- 1997-06-05 DE DE69726439T patent/DE69726439T2/de not_active Expired - Fee Related
- 1997-06-05 AU AU34782/97A patent/AU3478297A/en not_active Abandoned
- 1997-06-05 BR BR9713249-7A patent/BR9713249A/pt not_active Application Discontinuation
- 1997-06-05 BR BR9711865A patent/BR9711865A/pt not_active IP Right Cessation
- 1997-06-05 CA CA002268063A patent/CA2268063C/en not_active Expired - Fee Related
- 1997-06-05 CA CA002267424A patent/CA2267424C/en not_active Expired - Fee Related
- 1997-06-05 ES ES97928872T patent/ES2212109T3/es not_active Expired - Lifetime
- 1997-06-05 AT AT97931058T patent/ATE238409T1/de not_active IP Right Cessation
- 1997-06-05 JP JP51648998A patent/JP3299981B2/ja not_active Expired - Fee Related
- 1997-06-05 CN CN97180298.XA patent/CN1239995A/zh active Pending
- 1997-06-05 BR BR9711861A patent/BR9711861A/pt not_active Application Discontinuation
- 1997-06-05 CN CNB971802807A patent/CN1156561C/zh not_active Expired - Fee Related
- 1997-06-05 WO PCT/US1997/009790 patent/WO1998014552A1/en active IP Right Grant
- 1997-06-05 EP EP97928872A patent/EP0929649B1/en not_active Expired - Lifetime
- 1997-06-05 WO PCT/US1997/009791 patent/WO1998014553A1/en active IP Right Grant
- 1997-06-05 CN CNB971802963A patent/CN1156562C/zh not_active Expired - Fee Related
- 1997-06-05 CN CNB971802785A patent/CN1133738C/zh not_active Expired - Fee Related
- 1997-06-05 AU AU33031/97A patent/AU3303197A/en not_active Abandoned
- 1997-06-05 JP JP51649398A patent/JP3299984B2/ja not_active Expired - Fee Related
- 1997-06-05 WO PCT/US1997/009789 patent/WO1998014551A1/en active IP Right Grant
- 1997-06-05 EP EP97931058A patent/EP0929653B1/en not_active Expired - Lifetime
- 1997-06-05 AU AU33030/97A patent/AU3303097A/en not_active Abandoned
- 1997-06-05 JP JP51649698A patent/JP3299987B2/ja not_active Expired - Fee Related
- 1997-06-05 CA CA002268067A patent/CA2268067C/en not_active Expired - Fee Related
- 1997-06-05 ES ES97931056T patent/ES2210544T3/es not_active Expired - Lifetime
- 1997-06-05 AU AU34784/97A patent/AU3478497A/en not_active Abandoned
- 1997-06-05 EP EP97932153A patent/EP0929655A1/en not_active Ceased
- 1997-06-05 BR BR9712492-3A patent/BR9712492A/pt not_active IP Right Cessation
- 1997-06-05 CN CNB971802939A patent/CN1133739C/zh not_active Expired - Fee Related
- 1997-06-05 JP JP51649298A patent/JP3345022B2/ja not_active Expired - Fee Related
- 1997-06-05 WO PCT/US1997/009792 patent/WO1998014554A1/en not_active Application Discontinuation
- 1997-06-05 CA CA002268062A patent/CA2268062C/en not_active Expired - Fee Related
- 1997-06-05 DE DE69721287T patent/DE69721287T2/de not_active Expired - Fee Related
- 1997-06-05 AU AU33785/97A patent/AU3378597A/en not_active Abandoned
- 1997-06-05 BR BR9713246-2A patent/BR9713246A/pt not_active IP Right Cessation
- 1997-06-05 WO PCT/US1997/009795 patent/WO1998014557A1/en active IP Right Grant
- 1997-06-05 ES ES97928871T patent/ES2178778T3/es not_active Expired - Lifetime
- 1997-06-05 CA CA002268068A patent/CA2268068C/en not_active Expired - Fee Related
- 1997-06-05 EP EP97928871A patent/EP0929648B1/en not_active Expired - Lifetime
- 1997-06-05 CA CA002268052A patent/CA2268052C/en not_active Expired - Fee Related
- 1997-06-05 JP JP51649598A patent/JP3299986B2/ja not_active Expired - Fee Related
- 1997-06-05 AT AT97931056T patent/ATE255160T1/de not_active IP Right Cessation
- 1997-06-05 WO PCT/US1997/009796 patent/WO1998014558A1/en active Application Filing
- 1997-06-05 CN CNB971802971A patent/CN1156563C/zh not_active Expired - Fee Related
- 1997-06-05 AU AU35683/97A patent/AU3568397A/en not_active Abandoned
- 1997-06-05 ES ES97931058T patent/ES2193386T3/es not_active Expired - Lifetime
- 1997-06-05 DE DE69723986T patent/DE69723986T2/de not_active Expired - Fee Related
- 1997-06-05 ES ES97929815T patent/ES2201305T3/es not_active Expired - Lifetime
- 1997-06-05 EP EP97931059A patent/EP0929654A1/en not_active Withdrawn
- 1997-06-05 JP JP51649198A patent/JP3299983B2/ja not_active Expired - Fee Related
- 1997-06-05 CA CA002268060A patent/CA2268060C/en not_active Expired - Fee Related
- 1997-06-05 EP EP97931057A patent/EP0929652A1/en not_active Ceased
- 1997-06-05 EP EP97931056A patent/EP0929651B1/en not_active Expired - Lifetime
- 1997-10-03 AR ARP970104576A patent/AR010509A1/es unknown
- 1997-10-03 AR ARP970104578A patent/AR010510A1/es unknown
- 1997-10-03 AR ARP970104577A patent/AR010729A1/es unknown
- 1997-10-03 AR ARP970104574A patent/AR010507A1/es unknown
- 1997-10-03 AR ARP970104579A patent/AR010511A1/es unknown
- 1997-10-03 AR ARP970104575A patent/AR010508A1/es unknown
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