DE69713343T2 - Verbesserte propylenpolymere für orientierte filme - Google Patents
Verbesserte propylenpolymere für orientierte filmeInfo
- Publication number
- DE69713343T2 DE69713343T2 DE69713343T DE69713343T DE69713343T2 DE 69713343 T2 DE69713343 T2 DE 69713343T2 DE 69713343 T DE69713343 T DE 69713343T DE 69713343 T DE69713343 T DE 69713343T DE 69713343 T2 DE69713343 T2 DE 69713343T2
- Authority
- DE
- Germany
- Prior art keywords
- group
- polymer
- different
- comonomer
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001155 polypropylene Polymers 0.000 title claims description 41
- 229920000642 polymer Polymers 0.000 claims description 138
- 238000000034 method Methods 0.000 claims description 59
- 239000000203 mixture Substances 0.000 claims description 58
- 238000006116 polymerization reaction Methods 0.000 claims description 56
- 239000003054 catalyst Substances 0.000 claims description 42
- 238000009826 distribution Methods 0.000 claims description 39
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 35
- 230000008569 process Effects 0.000 claims description 33
- 239000012968 metallocene catalyst Substances 0.000 claims description 30
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 30
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 24
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 21
- 239000005977 Ethylene Substances 0.000 claims description 21
- 229920001577 copolymer Polymers 0.000 claims description 21
- 229920001519 homopolymer Polymers 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 20
- 239000012190 activator Substances 0.000 claims description 14
- -1 polypropylene Polymers 0.000 claims description 14
- 229920001384 propylene homopolymer Polymers 0.000 claims description 14
- 125000005843 halogen group Chemical group 0.000 claims description 12
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 8
- 125000004122 cyclic group Chemical group 0.000 claims description 8
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 8
- 229910052726 zirconium Inorganic materials 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 6
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000004429 atom Chemical group 0.000 claims description 5
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052732 germanium Inorganic materials 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 3
- 125000003860 C1-C20 alkoxy group Chemical group 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 239000010955 niobium Substances 0.000 claims description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims 3
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims 2
- 125000005018 aryl alkenyl group Chemical group 0.000 claims 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 239000000523 sample Substances 0.000 description 59
- 229910007928 ZrCl2 Inorganic materials 0.000 description 38
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 36
- 239000000243 solution Substances 0.000 description 25
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 239000000047 product Substances 0.000 description 19
- 150000001450 anions Chemical class 0.000 description 16
- 239000000377 silicon dioxide Substances 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 14
- 239000011148 porous material Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 13
- 238000012545 processing Methods 0.000 description 12
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 238000010348 incorporation Methods 0.000 description 10
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 10
- 150000001768 cations Chemical class 0.000 description 8
- 230000000379 polymerizing effect Effects 0.000 description 8
- 239000002243 precursor Substances 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 230000007935 neutral effect Effects 0.000 description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- 230000004888 barrier function Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 239000012632 extractable Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229920005604 random copolymer Polymers 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920001038 ethylene copolymer Polymers 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 150000002367 halogens Chemical group 0.000 description 4
- 229910052809 inorganic oxide Inorganic materials 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002516 radical scavenger Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 3
- 239000002841 Lewis acid Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000007517 lewis acids Chemical class 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000005026 oriented polypropylene Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 238000004260 weight control Methods 0.000 description 3
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- FLFNHHSXSLXYQB-UHFFFAOYSA-L CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 FLFNHHSXSLXYQB-UHFFFAOYSA-L 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 101100311330 Schizosaccharomyces pombe (strain 972 / ATCC 24843) uap56 gene Proteins 0.000 description 2
- 206010040925 Skin striae Diseases 0.000 description 2
- 208000031439 Striae Distensae Diseases 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 229910007926 ZrCl Inorganic materials 0.000 description 2
- NDJMNNSJDIFFTH-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 NDJMNNSJDIFFTH-UHFFFAOYSA-L 0.000 description 2
- CGELJBSWQTYCIY-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2ccccc2[C@H]1[Zr++]([C@@H]1C(C)=Cc2ccccc12)=[Si](C)C Chemical compound [Cl-].[Cl-].CC1=Cc2ccccc2[C@H]1[Zr++]([C@@H]1C(C)=Cc2ccccc12)=[Si](C)C CGELJBSWQTYCIY-UHFFFAOYSA-L 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 2
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000013628 high molecular weight specie Substances 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920005629 polypropylene homopolymer Polymers 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- 101150018444 sub2 gene Proteins 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OJVWBQRZCJLURF-UHFFFAOYSA-L C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)=[Si](C)C)=CC=CC2=C1 Chemical compound C1=CC=C2C(C3=CC=CC4=C3C=C(C)C4[Zr](Cl)(Cl)(C3C4=C(C(=CC=C4)C=4C5=CC=CC=C5C=CC=4)C=C3C)=[Si](C)C)=CC=CC2=C1 OJVWBQRZCJLURF-UHFFFAOYSA-L 0.000 description 1
- CZPSTFVUNSZYCA-UHFFFAOYSA-L CC(C)c1cc2C(C(C)=Cc2c(c1)C(C)C)[Zr](Cl)(Cl)(C1C(C)=Cc2c1cc(cc2C(C)C)C(C)C)=[Si](C)C Chemical compound CC(C)c1cc2C(C(C)=Cc2c(c1)C(C)C)[Zr](Cl)(Cl)(C1C(C)=Cc2c1cc(cc2C(C)C)C(C)C)=[Si](C)C CZPSTFVUNSZYCA-UHFFFAOYSA-L 0.000 description 1
- ZQVDTPHKVJVFGG-UHFFFAOYSA-L CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr](Cl)(Cl)(C1C(CC)=Cc2c1cccc2-c1ccccc1)=[Si](C)C Chemical compound CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr](Cl)(Cl)(C1C(CC)=Cc2c1cccc2-c1ccccc1)=[Si](C)C ZQVDTPHKVJVFGG-UHFFFAOYSA-L 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- AECTWRMNKTVPEM-UHFFFAOYSA-L [Cl-].[Cl-].CC1=C(C(C2=CC=CC=C12)[Zr+2](C1C=CC2=CC=CC=C12)=[SiH2])C Chemical compound [Cl-].[Cl-].CC1=C(C(C2=CC=CC=C12)[Zr+2](C1C=CC2=CC=CC=C12)=[SiH2])C AECTWRMNKTVPEM-UHFFFAOYSA-L 0.000 description 1
- IOEZEGGCMNVLHK-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2cc(C)c(C)cc2C1[Zr++](C1C(C)=Cc2cc(C)c(C)cc12)=[Si](C)C Chemical compound [Cl-].[Cl-].CC1=Cc2cc(C)c(C)cc2C1[Zr++](C1C(C)=Cc2cc(C)c(C)cc12)=[Si](C)C IOEZEGGCMNVLHK-UHFFFAOYSA-L 0.000 description 1
- PNRJUCXJBYLCRR-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2cccc(C)c2C1[Zr++](C1C(C)=Cc2cccc(C)c12)=[Si](C)C Chemical compound [Cl-].[Cl-].CC1=Cc2cccc(C)c2C1[Zr++](C1C(C)=Cc2cccc(C)c12)=[Si](C)C PNRJUCXJBYLCRR-UHFFFAOYSA-L 0.000 description 1
- JQHPURQXTURPDS-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](C)=[Zr++]([C@H]1C=CC2=C1CCCC2)[C@@H]1C=CC2=C1CCCC2 Chemical compound [Cl-].[Cl-].C[Si](C)=[Zr++]([C@H]1C=CC2=C1CCCC2)[C@@H]1C=CC2=C1CCCC2 JQHPURQXTURPDS-UHFFFAOYSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
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- 229920005601 base polymer Polymers 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
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- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000008395 clarifying agent Substances 0.000 description 1
- 238000010954 commercial manufacturing process Methods 0.000 description 1
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- 239000013068 control sample Substances 0.000 description 1
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- 238000012718 coordination polymerization Methods 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 239000003484 crystal nucleating agent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000005595 deprotonation Effects 0.000 description 1
- 238000010537 deprotonation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
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- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910001504 inorganic chloride Inorganic materials 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 229920001580 isotactic polymer Polymers 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
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- 238000006263 metalation reaction Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
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- 230000004048 modification Effects 0.000 description 1
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- 239000002667 nucleating agent Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
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- 229920006254 polymer film Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
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- 238000012546 transfer Methods 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2539896P | 1996-09-04 | 1996-09-04 | |
| PCT/US1997/014612 WO1998010016A1 (en) | 1996-09-04 | 1997-08-25 | Improved propylene polymers for oriented films |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69713343D1 DE69713343D1 (de) | 2002-07-18 |
| DE69713343T2 true DE69713343T2 (de) | 2002-10-10 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69713343T Expired - Lifetime DE69713343T2 (de) | 1996-09-04 | 1997-08-25 | Verbesserte propylenpolymere für orientierte filme |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6806316B2 (enExample) |
| EP (1) | EP0923618B1 (enExample) |
| JP (1) | JP4195095B2 (enExample) |
| KR (1) | KR20000068428A (enExample) |
| CN (1) | CN1115360C (enExample) |
| CA (1) | CA2262468A1 (enExample) |
| DE (1) | DE69713343T2 (enExample) |
| ES (1) | ES2174278T3 (enExample) |
| WO (1) | WO1998010016A1 (enExample) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CA2262468A1 (en) | 1996-09-04 | 1998-03-12 | Exxon Chemical Patents, Inc. | Improved propylene polymers for oriented films |
| US6576306B2 (en) * | 1996-09-04 | 2003-06-10 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
| US7919561B2 (en) * | 1996-09-04 | 2011-04-05 | Exxonmobil Chemical Patents Inc. | Process of producing thermoplastic polymer blends |
| US6583227B2 (en) * | 1996-09-04 | 2003-06-24 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
| US6444774B1 (en) * | 1997-10-10 | 2002-09-03 | Exxonmobil Chemical Patents, Inc. | Propylene polymers for fibers and fabrics |
| US6784269B2 (en) | 1998-05-13 | 2004-08-31 | Exxonmobil Chemical Patents Inc. | Polypropylene compositions methods of making the same |
| US6306960B1 (en) | 1998-05-13 | 2001-10-23 | Exxonmobil Chemical Patents Inc. | Articles formed from foamable polypropylene polymer |
| HK1039495B (zh) | 1998-05-13 | 2004-10-08 | 埃克森美孚化学专利公司 | 丙烯均聚物及其制备方法 |
| AU4962399A (en) | 1998-07-01 | 2000-01-24 | Exxon Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
| US6797375B1 (en) | 1998-11-12 | 2004-09-28 | 3M Innovative Properties Company | Oriented polypropylene films for adhesive tape |
| US6174930B1 (en) | 1999-04-16 | 2001-01-16 | Exxon Chemical Patents, Inc. | Foamable polypropylene polymer |
| DE50012267D1 (de) * | 1999-12-21 | 2006-04-27 | Basell Polyolefine Gmbh | Teilkristalline propylenpolymerisat-zusammensetzung zur herstellung von biaxial gereckten polypropylenfolien |
| US7098277B2 (en) * | 2000-08-22 | 2006-08-29 | Exxonmobil Chemical Patents Inc. | Polypropylene films |
| ATE353379T1 (de) * | 2000-08-22 | 2007-02-15 | Exxonmobil Chem Patents Inc | Polypropylenfasern und gewebe |
| WO2002060957A2 (en) | 2001-01-16 | 2002-08-08 | Exxonmobil Chemical Patents Inc. | Catalysts with at least two transition metal compounds and polymerization processes using them |
| JP2002294010A (ja) * | 2001-03-30 | 2002-10-09 | Sumitomo Chem Co Ltd | 延伸フィルム用ポリプロピレン系樹脂組成物および延伸フィルム |
| ATE278723T1 (de) * | 2001-06-27 | 2004-10-15 | Borealis Tech Oy | Propylen-copolymer mit zufälliger comonomerverteilung und verfahren zu seiner herstellung |
| ES2291651T3 (es) * | 2002-06-12 | 2008-03-01 | Basell Polyolefine Gmbh | Composiciones de copolimeros de propileno que presentan una buena tenacidad al impacto a baja temperatura y una alta transparencia. |
| US7732530B2 (en) | 2002-06-12 | 2010-06-08 | Basell Polyolefine Gmbh | Flexible propylene copolymer compositions having a high transparency |
| EP2261292B1 (en) * | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| WO2004037872A2 (en) | 2002-10-24 | 2004-05-06 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| US7390575B2 (en) | 2003-10-31 | 2008-06-24 | Japan Polypropylene Corporation | Propylene-ethylene random block copolymer and biaxially oriented multi-layer film using the same as a surface layer |
| CN100450785C (zh) * | 2003-12-26 | 2009-01-14 | 东丽株式会社 | 热敏转印记录用聚丙烯膜及其形成的热敏转印记录用载片 |
| JP4879882B2 (ja) * | 2004-03-17 | 2012-02-22 | ダウ グローバル テクノロジーズ エルエルシー | より高次のオレフィンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
| JP5133050B2 (ja) * | 2004-03-17 | 2013-01-30 | ダウ グローバル テクノロジーズ エルエルシー | エチレンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
| GB2420348B (en) * | 2004-10-28 | 2009-11-18 | Exxonmobil Chem Patents Inc | Syndiotactic rich polyolefins |
| CN101163738B (zh) * | 2005-04-21 | 2011-07-13 | 巴塞尔聚烯烃意大利有限责任公司 | 双轴取向丙烯聚合物膜 |
| US7662888B2 (en) | 2005-04-29 | 2010-02-16 | Japan Polypropylene Corporation | Polypropylene based heat shrinkable film |
| US8022142B2 (en) | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
| EP1762577A1 (en) * | 2005-09-02 | 2007-03-14 | Total Petrochemicals Research Feluy | Impact copolymer of propylene prepared in single reactor |
| EP1788023A1 (en) * | 2005-11-21 | 2007-05-23 | Borealis Technology Oy | Multimodal polypropylene polymer composition |
| US20070203299A1 (en) * | 2006-02-27 | 2007-08-30 | Novolen Technology Holdings C.V. | High melt strength polypropylene |
| DE602006004987D1 (de) | 2006-07-10 | 2009-03-12 | Borealis Tech Oy | Elektrischer Isolierfilm |
| EP1886806B1 (en) | 2006-07-10 | 2010-11-10 | Borealis Technology Oy | Biaxially oriented polypropylene film |
| US7977435B2 (en) | 2006-07-12 | 2011-07-12 | Lin Chon-Yie | Propylene polymer compositions and processes for making the same |
| EP1892264A1 (en) | 2006-08-25 | 2008-02-27 | Borealis Technology Oy | Extrusion coated substrate |
| EP1900764B1 (en) | 2006-08-25 | 2009-04-01 | Borealis Technology Oy | Polypropylene foam |
| EP1903579B1 (en) | 2006-09-25 | 2010-03-24 | Borealis Technology Oy | Coaxial cable |
| ATE424424T1 (de) | 2006-12-28 | 2009-03-15 | Borealis Tech Oy | Verfahren zur herstellung von verzweigtem polypropylen |
| ATE547469T1 (de) * | 2007-04-09 | 2012-03-15 | Exxonmobil Chem Patents Inc | Weiche heterogene isotaktische polypropylenzusammensetzungen |
| JP5315773B2 (ja) * | 2008-04-24 | 2013-10-16 | 住友化学株式会社 | プロピレン系樹脂組成物 |
| US8093335B2 (en) * | 2008-12-15 | 2012-01-10 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin in-reactor blends and molded articles therefrom |
| US8101685B2 (en) * | 2008-12-15 | 2012-01-24 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom |
| US8410217B2 (en) * | 2008-12-15 | 2013-04-02 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin blends |
| US8106127B2 (en) * | 2008-12-15 | 2012-01-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-reactor polymer blends |
| US8497325B2 (en) | 2008-12-15 | 2013-07-30 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin blends and films therefrom |
| CA2789948C (en) * | 2010-02-19 | 2014-10-14 | Exxonmobil Chemical Patents Inc. | Elastomeric polymer blends and processes for their production |
| US8278403B2 (en) * | 2010-07-08 | 2012-10-02 | Fina Technology, Inc. | Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers |
| JP2014505155A (ja) | 2011-02-15 | 2014-02-27 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 熱可塑性ポリオレフィンブレンド |
| WO2015123334A1 (en) * | 2014-02-11 | 2015-08-20 | Flint Hills Resources, Lp | Blended compositions, methods for making same, and articles made therefrom |
| RU2723242C2 (ru) | 2015-12-11 | 2020-06-09 | Базелл Полиолефин Италия С.Р.Л. | Сополимеры пропиленовые |
| JP7284821B2 (ja) | 2019-08-08 | 2023-05-31 | 株式会社プライムポリマー | プロピレン系重合体組成物および成形体 |
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| US3865903A (en) | 1973-04-16 | 1975-02-11 | Mobil Oil Corp | Heat sealable isotactic polypropylene and 1,3 pentadiene polymer |
| DE3750776T2 (de) | 1987-09-11 | 1995-04-27 | Fina Technology | Katalysatorsystem für Polyolefinproduktion mit breiter Molekulargewichtsverteilung. |
| IT1227893B (it) | 1988-12-14 | 1991-05-14 | Himont Inc Centerville Road Ne | Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto |
| DE3921358A1 (de) | 1989-06-29 | 1991-01-10 | Hoechst Ag | Biaxial orientierte polypropylenfolie mit hoher mechanischer festigkeit |
| JP2894823B2 (ja) | 1989-12-06 | 1999-05-24 | 三井化学株式会社 | 耐放射線ポリプロピレン樹脂組成物及び耐放射線成形物の製造方法 |
| DE3942364A1 (de) * | 1989-12-21 | 1991-06-27 | Hoechst Ag | Verfahren zur herstellung einer polypropylen-formmasse |
| DE3942363A1 (de) | 1989-12-21 | 1991-06-27 | Hoechst Ag | Verfahren zur herstellung einer polypropylen-formmasse |
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| ES2155492T3 (es) * | 1991-05-27 | 2001-05-16 | Basell Polyolefine Gmbh | Procedimiento para la obtencion de poliolefinas con una amplia distribucion de pesos moleculares. |
| EP0516019B1 (de) | 1991-05-27 | 1995-12-27 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung von syndiotaktischen Polyolefinen mit breiter Molmassenverteilung |
| JP3402473B2 (ja) | 1991-08-20 | 2003-05-06 | 日本ポリケム株式会社 | オレフィン重合用触媒 |
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-
1997
- 1997-08-25 CA CA002262468A patent/CA2262468A1/en not_active Abandoned
- 1997-08-25 WO PCT/US1997/014612 patent/WO1998010016A1/en not_active Ceased
- 1997-08-25 CN CN97197656A patent/CN1115360C/zh not_active Expired - Fee Related
- 1997-08-25 JP JP51268698A patent/JP4195095B2/ja not_active Expired - Lifetime
- 1997-08-25 KR KR1019997001793A patent/KR20000068428A/ko not_active Withdrawn
- 1997-08-25 DE DE69713343T patent/DE69713343T2/de not_active Expired - Lifetime
- 1997-08-25 ES ES97938441T patent/ES2174278T3/es not_active Expired - Lifetime
- 1997-08-25 EP EP97938441A patent/EP0923618B1/en not_active Expired - Lifetime
-
2002
- 2002-11-25 US US10/303,448 patent/US6806316B2/en not_active Expired - Lifetime
-
2004
- 2004-08-31 US US10/930,477 patent/US7026040B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20050032983A1 (en) | 2005-02-10 |
| US7026040B2 (en) | 2006-04-11 |
| EP0923618B1 (en) | 2002-06-12 |
| CN1115360C (zh) | 2003-07-23 |
| JP2001500176A (ja) | 2001-01-09 |
| KR20000068428A (ko) | 2000-11-25 |
| EP0923618A1 (en) | 1999-06-23 |
| ES2174278T3 (es) | 2002-11-01 |
| DE69713343D1 (de) | 2002-07-18 |
| WO1998010016A1 (en) | 1998-03-12 |
| CA2262468A1 (en) | 1998-03-12 |
| US20030153689A1 (en) | 2003-08-14 |
| JP4195095B2 (ja) | 2008-12-10 |
| US6806316B2 (en) | 2004-10-19 |
| CN1229420A (zh) | 1999-09-22 |
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