DE69712667D1 - Unverbrückte substituierte Indenyl-Metallocene - Google Patents

Unverbrückte substituierte Indenyl-Metallocene

Info

Publication number
DE69712667D1
DE69712667D1 DE69712667T DE69712667T DE69712667D1 DE 69712667 D1 DE69712667 D1 DE 69712667D1 DE 69712667 T DE69712667 T DE 69712667T DE 69712667 T DE69712667 T DE 69712667T DE 69712667 D1 DE69712667 D1 DE 69712667D1
Authority
DE
Germany
Prior art keywords
substituted indenyl
indenyl metallocenes
unbridged
unbridged substituted
metallocenes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69712667T
Other languages
English (en)
Other versions
DE69712667T2 (de
Inventor
Claudia Schmid
Helmut G Alt
Melvin Bruce Welch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of DE69712667D1 publication Critical patent/DE69712667D1/de
Application granted granted Critical
Publication of DE69712667T2 publication Critical patent/DE69712667T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69712667T 1996-03-29 1997-03-27 Unverbrückte substituierte Indenyl-Metallocene Expired - Fee Related DE69712667T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/622,907 US5780659A (en) 1996-03-29 1996-03-29 Substituted indenyl unbridged metallocenes

Publications (2)

Publication Number Publication Date
DE69712667D1 true DE69712667D1 (de) 2002-06-27
DE69712667T2 DE69712667T2 (de) 2002-10-17

Family

ID=24495992

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69712667T Expired - Fee Related DE69712667T2 (de) 1996-03-29 1997-03-27 Unverbrückte substituierte Indenyl-Metallocene

Country Status (13)

Country Link
US (2) US5780659A (de)
EP (1) EP0798306B1 (de)
JP (1) JPH107692A (de)
KR (1) KR970065549A (de)
CN (1) CN1065868C (de)
AT (1) ATE217877T1 (de)
AU (1) AU701588B2 (de)
CA (1) CA2198954C (de)
DE (1) DE69712667T2 (de)
ES (1) ES2173350T3 (de)
HU (1) HU218358B (de)
NO (1) NO971461L (de)
SG (1) SG96172A1 (de)

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CA2067525C (en) * 1991-05-09 1998-09-15 Helmut G. Alt Organometallic fluorenyl compounds, preparation and use
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes
DE19637669A1 (de) 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
EP0839834B1 (de) 1996-10-30 2001-06-13 Repsol Quimica S.A. Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
DE69703728T2 (de) * 1996-10-31 2001-06-28 Repsol Quimica Sa Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
US6180736B1 (en) * 1996-12-20 2001-01-30 Exxon Chemical Patents Inc High activity metallocene polymerization process
US5886202A (en) * 1997-01-08 1999-03-23 Jung; Michael Bridged fluorenyl/indenyl metallocenes and the use thereof
CA2292538A1 (en) * 1997-06-14 1998-12-23 Charles L. Myers Ethylene enhancement of processes for synthesis of high melting thermoplastic elastomeric .alpha.-olefin polymers (pre/epe effects)
CA2295734C (en) 1997-07-09 2005-02-08 Maruzen Petrochemical Co., Ltd. Catalyst component for polymerization of olefins, polymerization catalysts and process of polymerization of olefins by using the same
DE69909757T2 (de) * 1998-02-17 2004-04-15 Exxonmobil Chemical Patents Inc., Baytown Ethylencopolymerisationsverfahren
ES2211013T3 (es) 1998-04-27 2004-07-01 Repsol Quimica S.A. Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas.
DE69916358T2 (de) * 1998-04-29 2005-04-21 Repsol Quimica Sa Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation
US6262201B1 (en) 1998-06-19 2001-07-17 Phillips Petroleum Company Aryl substituted metallocene catalysts and their use
US6482905B1 (en) * 1999-08-16 2002-11-19 Phillips Petroleum Company Unsymmetric unbridged bis-indenyl metallocenes and their use
IT1314261B1 (it) * 1999-12-03 2002-12-06 Enichem Spa Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.
KR100404780B1 (ko) 2000-02-18 2003-11-07 대림산업 주식회사 메탈로센 화합물과 이로부터 제조되는 메탈로센 촉매 및이를 이용한 올레핀의 중합 방법
KR100447799B1 (ko) * 2001-01-03 2004-09-08 대림산업 주식회사 메탈로센 화합물 및 이를 포함하는 촉매 조성물
KR100677869B1 (ko) * 2004-07-01 2007-02-02 대림산업 주식회사 다중핵 금속 화합물, 이를 포함하는 촉매 시스템 및 이를이용한 올레핀의 중합 방법
US7226886B2 (en) * 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7312283B2 (en) * 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
US7598329B2 (en) 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
BR112012032745A2 (pt) 2010-07-06 2016-11-08 Ticona Gmbh processo para produção de polietileno de alto peso molecular
JP5937071B2 (ja) 2010-07-06 2016-06-22 ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング 高分子量ポリエチレンの製造方法
JP5916724B2 (ja) 2010-07-06 2016-05-11 ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング 高分子量ポリエチレンの製造方法
US8993704B2 (en) 2010-07-06 2015-03-31 Ticona Gmbh High molecular weight polyethylene fibers and membranes, their production and use
KR20130089166A (ko) 2010-07-06 2013-08-09 티코나 게엠베하 고 분자량 폴리에틸렌의 제조 방법
US20140329921A1 (en) 2011-12-19 2014-11-06 Ticona Gmbh Process for producing high molecular weight polyethylene
EP2679594A1 (de) 2012-06-25 2014-01-01 Daelim Industrial Co., Ltd. Metallocenverbindung, Katalysatorzusammensetzung damit und Olefinpolymerisierungsverfahren damit
RU2529020C2 (ru) * 2012-10-17 2014-09-27 ЭлДжи КЕМ, ЛТД. Новое металлоценовое соединение, содержащая его каталитическая композиция и способ получения полимеров на основе олефинов с ее применением
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
US9809667B2 (en) * 2014-02-11 2017-11-07 Univation Technologies, Llc Producing polyolefin products
KR101566328B1 (ko) * 2014-06-03 2015-11-05 주식회사 엘지화학 메탈로센 화합물 및 그 제조방법
KR101926833B1 (ko) 2015-06-05 2019-03-07 주식회사 엘지화학 메탈로센 화합물
KR101973191B1 (ko) 2015-06-05 2019-04-26 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법
BR112019005191B1 (pt) 2016-09-30 2022-12-20 Univation Technologies, Llc Catalisador de polimerização e método de produção de polietileno tendo encadeamento de etileno aprimorado
CA3137149A1 (en) * 2019-04-30 2020-11-05 Dow Global Technologies Llc Metal-ligand complexes
US11667777B2 (en) 2019-10-04 2023-06-06 Chevron Phillips Chemical Company Lp Bimodal polyethylene copolymers
US11186665B2 (en) 2019-10-04 2021-11-30 Chevron Phillips Chemical Company Lp Catalyst composition and method for preparing polyethylene
WO2023150480A1 (en) 2022-02-07 2023-08-10 Exxonmobil Chemical Patents Inc. C1 symmetric 5-ome-6-alkyl substituted metallocenes

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US5084534A (en) * 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
US5223467A (en) * 1988-07-15 1993-06-29 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
IT8919252A0 (it) * 1989-01-31 1989-01-31 Ilano Catalizzatori per la polimerizzazione di olefine.
IT1237398B (it) * 1989-01-31 1993-06-01 Ausimont Srl Catalizzatori per la polimerizzazione di olefine.
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DE69201180T2 (de) * 1991-10-21 1995-06-14 Mitsubishi Petrochemical Co Propylencopolymerzusammensetzung.
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DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
US5498581A (en) * 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
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US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes

Also Published As

Publication number Publication date
NO971461D0 (no) 1997-03-26
DE69712667T2 (de) 2002-10-17
EP0798306A1 (de) 1997-10-01
MX9702083A (es) 1998-03-31
HU218358B (hu) 2000-08-28
AU701588B2 (en) 1999-02-04
KR970065549A (ko) 1997-10-13
HUP9700674A3 (en) 2000-03-28
CA2198954C (en) 2000-09-05
CN1164535A (zh) 1997-11-12
EP0798306B1 (de) 2002-05-22
CA2198954A1 (en) 1997-09-29
JPH107692A (ja) 1998-01-13
US5780659A (en) 1998-07-14
CN1065868C (zh) 2001-05-16
US6037427A (en) 2000-03-14
SG96172A1 (en) 2003-05-23
AU1638997A (en) 1997-10-02
ES2173350T3 (es) 2002-10-16
NO971461L (no) 1997-09-30
ATE217877T1 (de) 2002-06-15
HUP9700674A2 (en) 1997-12-29

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee