DE69517771T2 - Propylen Blockcopolymer und Verfahren zu seiner Herstellung - Google Patents

Propylen Blockcopolymer und Verfahren zu seiner Herstellung

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Publication number
DE69517771T2
DE69517771T2 DE69517771T DE69517771T DE69517771T2 DE 69517771 T2 DE69517771 T2 DE 69517771T2 DE 69517771 T DE69517771 T DE 69517771T DE 69517771 T DE69517771 T DE 69517771T DE 69517771 T2 DE69517771 T2 DE 69517771T2
Authority
DE
Germany
Prior art keywords
manufacture
block copolymer
propylene block
propylene
copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69517771T
Other languages
English (en)
Other versions
DE69517771D1 (de
Inventor
Kazuyuki Watanabe
Hisayoshi Yanagihara
Shimako Matsumoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Holdings Corp
Original Assignee
Showa Denko KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Denko KK filed Critical Showa Denko KK
Publication of DE69517771D1 publication Critical patent/DE69517771D1/de
Application granted granted Critical
Publication of DE69517771T2 publication Critical patent/DE69517771T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/02Heterophasic composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
DE69517771T 1994-11-21 1995-11-20 Propylen Blockcopolymer und Verfahren zu seiner Herstellung Expired - Fee Related DE69517771T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP31124194 1994-11-21
JP31124294 1994-11-21

Publications (2)

Publication Number Publication Date
DE69517771D1 DE69517771D1 (de) 2000-08-10
DE69517771T2 true DE69517771T2 (de) 2000-11-23

Family

ID=26566639

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69517771T Expired - Fee Related DE69517771T2 (de) 1994-11-21 1995-11-20 Propylen Blockcopolymer und Verfahren zu seiner Herstellung

Country Status (7)

Country Link
US (2) US5703172A (de)
EP (1) EP0714923B1 (de)
KR (1) KR100372473B1 (de)
CN (1) CN1128767A (de)
AU (1) AU705455B2 (de)
CA (1) CA2162946C (de)
DE (1) DE69517771T2 (de)

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TW425414B (en) * 1997-02-18 2001-03-11 Chisso Corp Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method
WO1998044042A1 (fr) 1997-04-02 1998-10-08 Chisso Corporation Composition (co)polymere d'olefine modifiee, procede pour preparer cette composition et produit moule de cette composition (co)polymere
JPH10287707A (ja) * 1997-04-10 1998-10-27 Chisso Corp オレフィン(共)重合体組成物及びその製造方法
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
DE69817558T2 (de) * 1997-05-15 2004-07-01 Chisso Corp. Ungestreckte polypropylen-formasse
GB9712663D0 (en) 1997-06-16 1997-08-20 Borealis As Process
FI111848B (fi) * 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
JP4037468B2 (ja) 1997-06-24 2008-01-23 ボレアリス エー/エス プロピレンを含む異相ポリマーの製造方法
FI111847B (fi) * 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä propeenin kopolymeerien valmistamiseksi
TW504515B (en) 1997-08-07 2002-10-01 Chisso Corp Olefin (co)polymer composition
KR20010041560A (ko) 1998-03-04 2001-05-25 엑손 케미칼 패턴츠 인코포레이티드 이피디엠형 중합에서 디엔 전환을 증가시키는 방법
US6319998B1 (en) 1998-03-04 2001-11-20 Exxon Mobil Chemical Patents Inc. Method for making polymer blends by using series reactors
AU2796899A (en) 1998-03-04 1999-09-20 Exxon Chemical Patents Inc. Product and method for making polyolefin polymer dispersions
US6211300B1 (en) 1998-04-10 2001-04-03 Chisso Corporation Propylene-ethylene block copolymer compositions and processes for production thereof
EP0962474B1 (de) * 1998-06-04 2004-04-07 Japan Polychem Corporation Propylenblockcopolymer und Harzzusammensetzung
US6429270B2 (en) * 1998-09-14 2002-08-06 Union Carbide Chemicals & Plastics Technology Corporation Process for preparing olefin polymerization catalyst mixture
IL137651A0 (en) * 1998-12-24 2001-10-31 Montell Technology Company Bv Bottle closures made of polyolefins
JP2001172453A (ja) * 1999-12-14 2001-06-26 Basell Technology Co Bv プロピレン系樹脂組成物
JP2002037939A (ja) * 2000-07-25 2002-02-06 Idemitsu Petrochem Co Ltd 軟質ポリプロピレン系樹脂組成物
EP1211289A1 (de) * 2000-11-29 2002-06-05 Borealis GmbH Polyolefin Zusammensetzung mit verbesserten Eigenschaften
US6855656B2 (en) * 2001-03-30 2005-02-15 Toho Catalyst Co., Ltd. Polymerization and propylene block copolymer
EP1260545A1 (de) * 2001-05-21 2002-11-27 Borealis Technology OY Industrielles Leitungssystem aus Polyolefin
EP1260547A1 (de) 2001-05-21 2002-11-27 Borealis Technology OY Mit Polyolefin beschichtete Stahlrohre
EP1260546A1 (de) * 2001-05-21 2002-11-27 Borealis Technology OY Mehrschichtiges Polyolefinrohr
EP1260529A1 (de) * 2001-05-21 2002-11-27 Borealis Technology OY Propylenpolymere mit verbesserten Eigenschaften
EP1260528A1 (de) * 2001-05-21 2002-11-27 Borealis Technology OY Polypropylenrohre für Pipelines
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
JP5036964B2 (ja) * 2003-08-22 2012-09-26 三井化学株式会社 プロピレン系重合体及びその用途
EP1774485B1 (de) 2004-07-08 2016-05-04 ExxonMobil Chemical Patents Inc. Polymerproduktion unter superkritischen bedingungen
EP1669403A1 (de) * 2004-12-07 2006-06-14 Borealis Technology OY Neue Mischung von Propylenpolymeren
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
WO2008150572A1 (en) 2007-06-04 2008-12-11 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US9938400B2 (en) * 2008-04-23 2018-04-10 Exxonmobil Chemical Patents Inc. Propylene copolymers in soft thermoplastic blends
EP3333222A1 (de) * 2016-12-12 2018-06-13 SABIC Global Technologies B.V. Zusammensetzung mit heterophasischem propylencopolymer
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Also Published As

Publication number Publication date
EP0714923A1 (de) 1996-06-05
CA2162946C (en) 2004-01-06
AU3790395A (en) 1996-05-30
DE69517771D1 (de) 2000-08-10
CA2162946A1 (en) 1996-05-22
KR960017711A (ko) 1996-06-17
EP0714923B1 (de) 2000-07-05
AU705455B2 (en) 1999-05-20
US5703172A (en) 1997-12-30
CN1128767A (zh) 1996-08-14
KR100372473B1 (ko) 2003-05-12
US5804665A (en) 1998-09-08

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