DE69502744D1 - Sprühgetrocknete Füllstoffe enthaltende Metallocenkatalysatorzusammensetzung zur Herstellung von Polyolefinen - Google Patents

Sprühgetrocknete Füllstoffe enthaltende Metallocenkatalysatorzusammensetzung zur Herstellung von Polyolefinen

Info

Publication number
DE69502744D1
DE69502744D1 DE69502744T DE69502744T DE69502744D1 DE 69502744 D1 DE69502744 D1 DE 69502744D1 DE 69502744 T DE69502744 T DE 69502744T DE 69502744 T DE69502744 T DE 69502744T DE 69502744 D1 DE69502744 D1 DE 69502744D1
Authority
DE
Germany
Prior art keywords
metallocene catalyst
polyolefins
production
spray
catalyst composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69502744T
Other languages
English (en)
Other versions
DE69502744T2 (de
Inventor
Eric Paul Wasserman
Timothy Roger Lynn
Mark Wilton Smale
Iii Robert Converse Brady
Frederick John Karol
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Univation Technologies LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Application granted granted Critical
Publication of DE69502744D1 publication Critical patent/DE69502744D1/de
Publication of DE69502744T2 publication Critical patent/DE69502744T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69502744T 1994-02-17 1995-02-16 Sprühgetrocknete Füllstoffe enthaltende Metallocenkatalysatorzusammensetzung zur Herstellung von Polyolefinen Expired - Lifetime DE69502744T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US19792294A 1994-02-17 1994-02-17

Publications (2)

Publication Number Publication Date
DE69502744D1 true DE69502744D1 (de) 1998-07-09
DE69502744T2 DE69502744T2 (de) 1998-10-01

Family

ID=22731286

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69502744T Expired - Lifetime DE69502744T2 (de) 1994-02-17 1995-02-16 Sprühgetrocknete Füllstoffe enthaltende Metallocenkatalysatorzusammensetzung zur Herstellung von Polyolefinen

Country Status (9)

Country Link
EP (1) EP0668295B1 (de)
JP (1) JP2989512B2 (de)
AT (1) ATE166887T1 (de)
AU (1) AU689178B2 (de)
BR (1) BR9500663A (de)
CA (1) CA2142669C (de)
DE (1) DE69502744T2 (de)
ES (1) ES2117829T3 (de)
MX (1) MX9500982A (de)

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US6166153A (en) * 1995-07-18 2000-12-26 Fina Technology, Inc. Process for the syndiotactic propagation of olefins
CA2181413A1 (en) * 1995-07-18 1998-01-18 Edwar S. Shamshoum Process for the syndiotactic propagation of olefins
ATE153675T1 (de) * 1995-09-13 1997-06-15 Witco Gmbh Verfahren zur herstellung von metallocen- katalysatorsystemen auf inerten trägermaterialien unter verwendung von gasphasenreaktoren
EP0763545B1 (de) * 1995-09-13 1997-04-23 Witco GmbH Verfahren zur Herstellung von Metallocen-Katalysatorsystemen auf inerten Trägermaterialien
KR100505842B1 (ko) * 1996-04-10 2005-11-21 유니로얄 캐미칼 캄파니, 인크. 폴리올레핀탄성중합체의제조를위한중합반응방법,메탈로센프로촉매의활성화를위한양이온-생성조촉매,물리적특성의특이한결합을지니는폴리올레핀탄성중합체및그들로부터제조된제품
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
PT839835E (pt) * 1996-10-30 2000-08-31 Repsol Quimica Sa Catalisadores organometalicos para a polimerizacao e copolimerizacao de alfa-olefinas
US6635778B1 (en) 1996-10-30 2003-10-21 Repsol Quimica S.A. Catalysts systems for the polymerization and copolymerization of alpha-olefins
JP3955140B2 (ja) 1996-10-31 2007-08-08 レプソル・ケミカ・ソシエダ・アノニマ アルフアオレフインの重合及び共重合用触媒系
US6180736B1 (en) * 1996-12-20 2001-01-30 Exxon Chemical Patents Inc High activity metallocene polymerization process
DE69829423T2 (de) 1997-08-21 2006-04-13 Sumitomo Chemical Co., Ltd. Modifizierte Teilchen, daraus hergestellter Träger, daraus hergestellte Polymerisationskatalysatorkomponente sowie Polymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren
CA2215444C (en) * 1997-09-15 2005-08-02 Stephen John Brown Catalyst having a ketimide ligand
US20060293470A1 (en) * 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US8497330B2 (en) 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
US6166152A (en) * 1998-02-26 2000-12-26 Phillips Petroleum Company Process to produce low density polymer in a loop reactor
PT953581E (pt) 1998-04-27 2004-07-30 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas
EP0969019A1 (de) * 1998-07-02 2000-01-05 Fina Research S.A. Polyolefinenherstellung
US6060568A (en) * 1998-12-18 2000-05-09 The Governors Of The University Of Alberta Carbene transition metal catalysts
US6235919B1 (en) 1999-08-17 2001-05-22 The Governors Of The University Of Alberta Aluminum complexes for olefin polymerization
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6476245B1 (en) * 2000-07-26 2002-11-05 The Governors Of The University Of Alberta Phosphinimine methanide transition metal catalysts
US6444834B1 (en) 2000-08-09 2002-09-03 The Governors Of The University Of Alberta Aluminum complexes for olefin polymerization
US6858767B1 (en) * 2000-08-11 2005-02-22 Uniroyal Chemical Company, Inc. Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
US6656866B2 (en) * 2000-12-04 2003-12-02 Univation Technologies, Llc Catalyst preparation method
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DE10163154A1 (de) * 2001-12-20 2003-07-03 Basell Polyolefine Gmbh Pyrogene Kieselsäuren enthaltender Katalysatorfeststoff zur Olefinpolymerisation
JP2005526175A (ja) * 2002-06-03 2005-09-02 ユニベーション・テクノロジーズ・エルエルシー 固体粒状で不均質の噴霧乾燥された触媒組成物
US20110034324A1 (en) * 2008-04-28 2011-02-10 Univation Technologies, Llc Methods for Preparing Catalyst Systems
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WO2012158260A1 (en) 2011-05-13 2012-11-22 Univation Technologies, Llc Spray-dried catalyst compositions and polymerization processes employing the same
KR102022132B1 (ko) * 2011-11-08 2019-09-17 유니베이션 테크놀로지즈, 엘엘씨 촉매 시스템의 제조 방법
CN104918947A (zh) 2012-12-28 2015-09-16 尤尼威蒂恩技术有限责任公司 将铝氧烷的生产整合到催化剂生产中的方法
RU2647855C2 (ru) * 2013-01-14 2018-03-21 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Способы получения каталитических систем с повышенной производительностью
JP6644714B2 (ja) * 2014-06-12 2020-02-12 トタル リサーチ アンド テクノロジー フエリユイ 少なくとも一つの連続撹拌タンク反応器でポリエチレンを製造する方法
KR20170005199A (ko) * 2015-07-01 2017-01-12 한국생산기술연구원 제올라이트-금속염화물 하이브리드 수분흡착제의 개선된 제조방법, 및 이에 의해 제조된 수분흡착제, 및 이를 포함하는 표면코팅용 수분흡착 조성물의 제조방법

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Also Published As

Publication number Publication date
BR9500663A (pt) 1995-10-31
JP2989512B2 (ja) 1999-12-13
MX9500982A (es) 1997-02-28
JPH07258324A (ja) 1995-10-09
CA2142669C (en) 1999-11-23
EP0668295A1 (de) 1995-08-23
DE69502744T2 (de) 1998-10-01
AU1227895A (en) 1995-08-24
CA2142669A1 (en) 1995-08-18
EP0668295B1 (de) 1998-06-03
ATE166887T1 (de) 1998-06-15
ES2117829T3 (es) 1998-08-16
AU689178B2 (en) 1998-03-26

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