DE60223259T2 - Mehrstufenverfahren zur entfernung von schwefel aus brennstoffkomponenten für einsatz in fahrzeugen - Google Patents
Mehrstufenverfahren zur entfernung von schwefel aus brennstoffkomponenten für einsatz in fahrzeugen Download PDFInfo
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- DE60223259T2 DE60223259T2 DE60223259T DE60223259T DE60223259T2 DE 60223259 T2 DE60223259 T2 DE 60223259T2 DE 60223259 T DE60223259 T DE 60223259T DE 60223259 T DE60223259 T DE 60223259T DE 60223259 T2 DE60223259 T2 DE 60223259T2
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- Prior art keywords
- sulfur
- catalyst
- contact stage
- starting material
- compounds
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 149
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 149
- 239000011593 sulfur Substances 0.000 title claims abstract description 147
- 238000000034 method Methods 0.000 title claims abstract description 126
- 239000000446 fuel Substances 0.000 title abstract description 36
- 238000009835 boiling Methods 0.000 claims abstract description 105
- 230000008569 process Effects 0.000 claims abstract description 83
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 60
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 48
- 239000007787 solid Substances 0.000 claims abstract description 47
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 43
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 30
- 239000001257 hydrogen Substances 0.000 claims abstract description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 29
- -1 nitrogen-containing organic compounds Chemical class 0.000 claims abstract description 29
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 28
- 239000003463 adsorbent Substances 0.000 claims abstract description 21
- 239000003208 petroleum Substances 0.000 claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims description 177
- 239000007858 starting material Substances 0.000 claims description 83
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 73
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- 239000011733 molybdenum Substances 0.000 claims description 10
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- 229940059867 sulfur containing product ectoparasiticides Drugs 0.000 description 6
- BDFAOUQQXJIZDG-UHFFFAOYSA-N 2-methylpropane-1-thiol Chemical compound CC(C)CS BDFAOUQQXJIZDG-UHFFFAOYSA-N 0.000 description 5
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- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 5
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- QENGPZGAWFQWCZ-UHFFFAOYSA-N 3-Methylthiophene Chemical class CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 4
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- 241001469893 Oxyzygonectes dovii Species 0.000 description 2
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- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step
- C10G69/123—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step alkylation
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US918984 | 2001-07-31 | ||
| US09/918,984 US6733660B2 (en) | 2001-07-31 | 2001-07-31 | Multistage process for removal of sulfur from components for blending of transportation fuels |
| PCT/US2002/017064 WO2003012010A2 (en) | 2001-07-31 | 2002-05-31 | Multistage process for removal of sulfur from components for blending of transportation fuels |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60223259D1 DE60223259D1 (de) | 2007-12-13 |
| DE60223259T2 true DE60223259T2 (de) | 2008-07-31 |
Family
ID=25441278
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60223259T Expired - Lifetime DE60223259T2 (de) | 2001-07-31 | 2002-05-31 | Mehrstufenverfahren zur entfernung von schwefel aus brennstoffkomponenten für einsatz in fahrzeugen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6733660B2 (enExample) |
| EP (1) | EP1412456B1 (enExample) |
| JP (1) | JP4417104B2 (enExample) |
| AT (1) | ATE377064T1 (enExample) |
| AU (1) | AU2002303921B2 (enExample) |
| DE (1) | DE60223259T2 (enExample) |
| ES (1) | ES2292760T3 (enExample) |
| WO (1) | WO2003012010A2 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2857973B1 (fr) * | 2003-07-25 | 2008-02-22 | Inst Francais Du Petrole | Procede de desulfuration des essences par adsorption |
| FR2857975B1 (fr) * | 2003-07-25 | 2008-01-11 | Inst Francais Du Petrole | Procede de disulfuration des essences |
| US7288181B2 (en) * | 2003-08-01 | 2007-10-30 | Exxonmobil Research And Engineering Company | Producing low sulfur naphtha products through improved olefin isomerization |
| US7473349B2 (en) * | 2004-12-30 | 2009-01-06 | Bp Corporation North America Inc. | Process for removal of sulfur from components for blending of transportation fuels |
| US20110054227A1 (en) * | 2009-08-26 | 2011-03-03 | Chevron Phillips Chemical Company Lp | Process to Protect Hydrogenation and Isomerization Catalysts Using a Guard Bed |
| CN104511244B (zh) * | 2013-10-08 | 2018-09-25 | 中国石油化工股份有限公司 | 一种利用烷基化反应脱除气态烃中硫醇的方法 |
| CN105561759B (zh) * | 2014-10-14 | 2018-09-25 | 中国石油化工股份有限公司 | 利用烷基化反应同时脱除工业气体中硫化氢和硫醇类物质的方法 |
| CN104772164B (zh) * | 2014-12-18 | 2017-08-29 | 神华集团有限责任公司 | 一种催化裂化汽油烷基化脱硫催化剂及其脱硫工艺 |
| CN106554839A (zh) * | 2015-09-29 | 2017-04-05 | 中国石油化工股份有限公司 | 采用固定床反应器同时脱除液化石油气中硫化氢和硫醇的方法 |
| US11214489B1 (en) | 2020-11-28 | 2022-01-04 | Ceres Technology, LLC | Crossflow scrubbing method and apparatus to produce a product such as potassium thiosulfate or ammonium thiosulfate |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3996128A (en) | 1974-04-01 | 1976-12-07 | Mobil Oil Corporation | Isobutane conversion of naphtha in pretreater desulfurization |
| JPH06128570A (ja) * | 1992-10-14 | 1994-05-10 | Nippon Oil Co Ltd | 無鉛高オクタン価ガソリン |
| US5336820A (en) * | 1993-08-11 | 1994-08-09 | Mobil Oil Corporation | Process for the alkylation of benzene-rich gasoline |
| US5863419A (en) * | 1997-01-14 | 1999-01-26 | Amoco Corporation | Sulfur removal by catalytic distillation |
| US6059962A (en) * | 1998-09-09 | 2000-05-09 | Bp Amoco Corporation | Multiple stage sulfur removal process |
| US6024865A (en) * | 1998-09-09 | 2000-02-15 | Bp Amoco Corporation | Sulfur removal process |
-
2001
- 2001-07-31 US US09/918,984 patent/US6733660B2/en not_active Expired - Fee Related
-
2002
- 2002-05-31 AT AT02731986T patent/ATE377064T1/de not_active IP Right Cessation
- 2002-05-31 EP EP02731986A patent/EP1412456B1/en not_active Expired - Lifetime
- 2002-05-31 DE DE60223259T patent/DE60223259T2/de not_active Expired - Lifetime
- 2002-05-31 WO PCT/US2002/017064 patent/WO2003012010A2/en not_active Ceased
- 2002-05-31 JP JP2003517189A patent/JP4417104B2/ja not_active Expired - Fee Related
- 2002-05-31 ES ES02731986T patent/ES2292760T3/es not_active Expired - Lifetime
- 2002-05-31 AU AU2002303921A patent/AU2002303921B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP1412456A2 (en) | 2004-04-28 |
| AU2002303921B2 (en) | 2007-07-26 |
| US6733660B2 (en) | 2004-05-11 |
| US20030029776A1 (en) | 2003-02-13 |
| ATE377064T1 (de) | 2007-11-15 |
| WO2003012010A3 (en) | 2003-05-30 |
| ES2292760T3 (es) | 2008-03-16 |
| WO2003012010A2 (en) | 2003-02-13 |
| EP1412456B1 (en) | 2007-10-31 |
| JP4417104B2 (ja) | 2010-02-17 |
| DE60223259D1 (de) | 2007-12-13 |
| JP2004536951A (ja) | 2004-12-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |