AU2002303921B2 - Multistage process for removal of sulfur from components for blending of transportation fuels - Google Patents
Multistage process for removal of sulfur from components for blending of transportation fuels Download PDFInfo
- Publication number
- AU2002303921B2 AU2002303921B2 AU2002303921A AU2002303921A AU2002303921B2 AU 2002303921 B2 AU2002303921 B2 AU 2002303921B2 AU 2002303921 A AU2002303921 A AU 2002303921A AU 2002303921 A AU2002303921 A AU 2002303921A AU 2002303921 B2 AU2002303921 B2 AU 2002303921B2
- Authority
- AU
- Australia
- Prior art keywords
- sulfur
- feedstock
- catalyst
- contacting
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 212
- 229910052717 sulfur Inorganic materials 0.000 title claims description 207
- 239000011593 sulfur Substances 0.000 title claims description 205
- 238000000034 method Methods 0.000 title claims description 147
- 230000008569 process Effects 0.000 title claims description 137
- 239000000446 fuel Substances 0.000 title claims description 37
- 238000002156 mixing Methods 0.000 title claims description 20
- 239000003054 catalyst Substances 0.000 claims description 207
- 238000009835 boiling Methods 0.000 claims description 142
- 238000005804 alkylation reaction Methods 0.000 claims description 92
- 230000029936 alkylation Effects 0.000 claims description 91
- 239000000463 material Substances 0.000 claims description 78
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 77
- 239000012535 impurity Substances 0.000 claims description 75
- 230000002378 acidificating effect Effects 0.000 claims description 74
- 150000001336 alkenes Chemical class 0.000 claims description 65
- 239000007788 liquid Substances 0.000 claims description 57
- 150000002430 hydrocarbons Chemical class 0.000 claims description 56
- 239000007787 solid Substances 0.000 claims description 55
- 229930195733 hydrocarbon Natural products 0.000 claims description 51
- 238000005984 hydrogenation reaction Methods 0.000 claims description 44
- -1 nitrogen-containing organic compounds Chemical class 0.000 claims description 44
- 239000000203 mixture Substances 0.000 claims description 38
- 239000003463 adsorbent Substances 0.000 claims description 37
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 35
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 35
- 150000002894 organic compounds Chemical class 0.000 claims description 35
- 238000004523 catalytic cracking Methods 0.000 claims description 34
- 239000001257 hydrogen Substances 0.000 claims description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims description 29
- 238000004821 distillation Methods 0.000 claims description 25
- 238000001179 sorption measurement Methods 0.000 claims description 23
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 20
- 230000000694 effects Effects 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 239000003208 petroleum Substances 0.000 claims description 12
- 230000000536 complexating effect Effects 0.000 claims description 11
- 150000002739 metals Chemical class 0.000 claims description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 11
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims description 10
- 239000011733 molybdenum Substances 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 150000002898 organic sulfur compounds Chemical class 0.000 claims description 10
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 8
- 229910052721 tungsten Inorganic materials 0.000 claims description 8
- 239000010937 tungsten Substances 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 238000010348 incorporation Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000000887 hydrating effect Effects 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 238000004227 thermal cracking Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 96
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 56
- 238000006243 chemical reaction Methods 0.000 description 40
- 235000011007 phosphoric acid Nutrition 0.000 description 35
- 229960004838 phosphoric acid Drugs 0.000 description 32
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- 239000004215 Carbon black (E152) Substances 0.000 description 28
- 229910052757 nitrogen Inorganic materials 0.000 description 28
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 24
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 17
- 239000003502 gasoline Substances 0.000 description 17
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 16
- 230000003197 catalytic effect Effects 0.000 description 16
- 239000007789 gas Substances 0.000 description 16
- 239000002168 alkylating agent Substances 0.000 description 15
- 229940100198 alkylating agent Drugs 0.000 description 15
- 229930192474 thiophene Natural products 0.000 description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 14
- 238000005336 cracking Methods 0.000 description 13
- 230000009467 reduction Effects 0.000 description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 11
- 150000003464 sulfur compounds Chemical class 0.000 description 11
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 9
- 238000004508 fractional distillation Methods 0.000 description 9
- 150000003568 thioethers Chemical class 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
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- 239000010457 zeolite Substances 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 8
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- 239000003209 petroleum derivative Substances 0.000 description 8
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- 150000007513 acids Chemical class 0.000 description 7
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- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 238000006477 desulfuration reaction Methods 0.000 description 6
- 230000023556 desulfurization Effects 0.000 description 6
- 229940059867 sulfur containing product ectoparasiticides Drugs 0.000 description 6
- 150000003577 thiophenes Chemical class 0.000 description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000000571 coke Substances 0.000 description 5
- 239000010779 crude oil Substances 0.000 description 5
- 230000009849 deactivation Effects 0.000 description 5
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 5
- 230000036571 hydration Effects 0.000 description 5
- 238000006703 hydration reaction Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229940005657 pyrophosphoric acid Drugs 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000011949 solid catalyst Substances 0.000 description 5
- ZRKMQKLGEQPLNS-UHFFFAOYSA-N 1-Pentanethiol Chemical compound CCCCCS ZRKMQKLGEQPLNS-UHFFFAOYSA-N 0.000 description 4
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 4
- 239000012263 liquid product Substances 0.000 description 4
- KJRCEJOSASVSRA-UHFFFAOYSA-N propane-2-thiol Chemical compound CC(C)S KJRCEJOSASVSRA-UHFFFAOYSA-N 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- QENGPZGAWFQWCZ-UHFFFAOYSA-N 3-Methylthiophene Chemical class CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 3
- 239000002952 polymeric resin Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 3
- 229910052815 sulfur oxide Inorganic materials 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 3
- 229940048102 triphosphoric acid Drugs 0.000 description 3
- XQQBUAPQHNYYRS-UHFFFAOYSA-N 2-methylthiophene Chemical class CC1=CC=CS1 XQQBUAPQHNYYRS-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- 241001469893 Oxyzygonectes dovii Species 0.000 description 2
- 229910018287 SbF 5 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 230000002152 alkylating effect Effects 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
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- IOPLHGOSNCJOOO-UHFFFAOYSA-N methyl 3,4-diaminobenzoate Chemical compound COC(=O)C1=CC=C(N)C(N)=C1 IOPLHGOSNCJOOO-UHFFFAOYSA-N 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
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- 238000007670 refining Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
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- XLUBVTJUEUUZMR-UHFFFAOYSA-B silicon(4+);tetraphosphate Chemical class [Si+4].[Si+4].[Si+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XLUBVTJUEUUZMR-UHFFFAOYSA-B 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
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- 150000003463 sulfur Chemical class 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- ZERULLAPCVRMCO-UHFFFAOYSA-N sulfure de di n-propyle Natural products CCCSCCC ZERULLAPCVRMCO-UHFFFAOYSA-N 0.000 description 2
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
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- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- DGUACJDPTAAFMP-UHFFFAOYSA-N 1,9-dimethyldibenzo[2,1-b:1',2'-d]thiophene Natural products S1C2=CC=CC(C)=C2C2=C1C=CC=C2C DGUACJDPTAAFMP-UHFFFAOYSA-N 0.000 description 1
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- 229910015900 BF3 Inorganic materials 0.000 description 1
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- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
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- 231100001243 air pollutant Toxicity 0.000 description 1
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
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- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
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- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step
- C10G69/123—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step alkylation
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/918,984 | 2001-07-31 | ||
| US09/918,984 US6733660B2 (en) | 2001-07-31 | 2001-07-31 | Multistage process for removal of sulfur from components for blending of transportation fuels |
| PCT/US2002/017064 WO2003012010A2 (en) | 2001-07-31 | 2002-05-31 | Multistage process for removal of sulfur from components for blending of transportation fuels |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2002303921A1 AU2002303921A1 (en) | 2003-05-29 |
| AU2002303921B2 true AU2002303921B2 (en) | 2007-07-26 |
Family
ID=25441278
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2002303921A Ceased AU2002303921B2 (en) | 2001-07-31 | 2002-05-31 | Multistage process for removal of sulfur from components for blending of transportation fuels |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6733660B2 (enExample) |
| EP (1) | EP1412456B1 (enExample) |
| JP (1) | JP4417104B2 (enExample) |
| AT (1) | ATE377064T1 (enExample) |
| AU (1) | AU2002303921B2 (enExample) |
| DE (1) | DE60223259T2 (enExample) |
| ES (1) | ES2292760T3 (enExample) |
| WO (1) | WO2003012010A2 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2857973B1 (fr) * | 2003-07-25 | 2008-02-22 | Inst Francais Du Petrole | Procede de desulfuration des essences par adsorption |
| FR2857975B1 (fr) * | 2003-07-25 | 2008-01-11 | Inst Francais Du Petrole | Procede de disulfuration des essences |
| US7288181B2 (en) * | 2003-08-01 | 2007-10-30 | Exxonmobil Research And Engineering Company | Producing low sulfur naphtha products through improved olefin isomerization |
| US7473349B2 (en) * | 2004-12-30 | 2009-01-06 | Bp Corporation North America Inc. | Process for removal of sulfur from components for blending of transportation fuels |
| US20110054227A1 (en) * | 2009-08-26 | 2011-03-03 | Chevron Phillips Chemical Company Lp | Process to Protect Hydrogenation and Isomerization Catalysts Using a Guard Bed |
| CN104511244B (zh) * | 2013-10-08 | 2018-09-25 | 中国石油化工股份有限公司 | 一种利用烷基化反应脱除气态烃中硫醇的方法 |
| CN105561759B (zh) * | 2014-10-14 | 2018-09-25 | 中国石油化工股份有限公司 | 利用烷基化反应同时脱除工业气体中硫化氢和硫醇类物质的方法 |
| CN104772164B (zh) * | 2014-12-18 | 2017-08-29 | 神华集团有限责任公司 | 一种催化裂化汽油烷基化脱硫催化剂及其脱硫工艺 |
| CN106554839A (zh) * | 2015-09-29 | 2017-04-05 | 中国石油化工股份有限公司 | 采用固定床反应器同时脱除液化石油气中硫化氢和硫醇的方法 |
| US11214489B1 (en) | 2020-11-28 | 2022-01-04 | Ceres Technology, LLC | Crossflow scrubbing method and apparatus to produce a product such as potassium thiosulfate or ammonium thiosulfate |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3996128A (en) | 1974-04-01 | 1976-12-07 | Mobil Oil Corporation | Isobutane conversion of naphtha in pretreater desulfurization |
| JPH06128570A (ja) * | 1992-10-14 | 1994-05-10 | Nippon Oil Co Ltd | 無鉛高オクタン価ガソリン |
| US5336820A (en) * | 1993-08-11 | 1994-08-09 | Mobil Oil Corporation | Process for the alkylation of benzene-rich gasoline |
| US5863419A (en) * | 1997-01-14 | 1999-01-26 | Amoco Corporation | Sulfur removal by catalytic distillation |
| US6059962A (en) * | 1998-09-09 | 2000-05-09 | Bp Amoco Corporation | Multiple stage sulfur removal process |
| US6024865A (en) * | 1998-09-09 | 2000-02-15 | Bp Amoco Corporation | Sulfur removal process |
-
2001
- 2001-07-31 US US09/918,984 patent/US6733660B2/en not_active Expired - Fee Related
-
2002
- 2002-05-31 AT AT02731986T patent/ATE377064T1/de not_active IP Right Cessation
- 2002-05-31 EP EP02731986A patent/EP1412456B1/en not_active Expired - Lifetime
- 2002-05-31 DE DE60223259T patent/DE60223259T2/de not_active Expired - Lifetime
- 2002-05-31 WO PCT/US2002/017064 patent/WO2003012010A2/en not_active Ceased
- 2002-05-31 JP JP2003517189A patent/JP4417104B2/ja not_active Expired - Fee Related
- 2002-05-31 ES ES02731986T patent/ES2292760T3/es not_active Expired - Lifetime
- 2002-05-31 AU AU2002303921A patent/AU2002303921B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP1412456A2 (en) | 2004-04-28 |
| US6733660B2 (en) | 2004-05-11 |
| US20030029776A1 (en) | 2003-02-13 |
| ATE377064T1 (de) | 2007-11-15 |
| WO2003012010A3 (en) | 2003-05-30 |
| ES2292760T3 (es) | 2008-03-16 |
| DE60223259T2 (de) | 2008-07-31 |
| WO2003012010A2 (en) | 2003-02-13 |
| EP1412456B1 (en) | 2007-10-31 |
| JP4417104B2 (ja) | 2010-02-17 |
| DE60223259D1 (de) | 2007-12-13 |
| JP2004536951A (ja) | 2004-12-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) | ||
| PC | Assignment registered |
Owner name: IFP ENERGIES NOUVELLES Free format text: FORMER OWNER WAS: BP CORPORATION NORTH AMERICA INC. |
|
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |