DE60203360D1 - Neuer asymmetrischer Phosphin-Ligand - Google Patents
Neuer asymmetrischer Phosphin-LigandInfo
- Publication number
- DE60203360D1 DE60203360D1 DE60203360T DE60203360T DE60203360D1 DE 60203360 D1 DE60203360 D1 DE 60203360D1 DE 60203360 T DE60203360 T DE 60203360T DE 60203360 T DE60203360 T DE 60203360T DE 60203360 D1 DE60203360 D1 DE 60203360D1
- Authority
- DE
- Germany
- Prior art keywords
- alkyl group
- carbon atoms
- phosphine ligand
- linear
- hydrogen atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title abstract 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 title abstract 2
- 239000003446 ligand Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- -1 phosphine compound Chemical class 0.000 abstract 2
- 238000009876 asymmetric hydrogenation reaction Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
- B01J31/2471—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom
- B01J31/2476—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/16—Preparation of optical isomers
- C07C231/18—Preparation of optical isomers by stereospecific synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0033—Iridium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/006—Palladium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5027—Polyphosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
- C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001375218A JP4005800B2 (ja) | 2001-12-10 | 2001-12-10 | 新規不斉ホスフィン配位子 |
JP2001375218 | 2001-12-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60203360D1 true DE60203360D1 (de) | 2005-04-28 |
DE60203360T2 DE60203360T2 (de) | 2006-03-23 |
Family
ID=19183629
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60203360T Expired - Lifetime DE60203360T2 (de) | 2001-12-10 | 2002-11-21 | Neuer asymmetrischer Phosphin-Ligand |
Country Status (6)
Country | Link |
---|---|
US (1) | US6624320B2 (de) |
EP (1) | EP1318155B1 (de) |
JP (1) | JP4005800B2 (de) |
AT (1) | ATE291581T1 (de) |
DE (1) | DE60203360T2 (de) |
ES (1) | ES2239195T3 (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4226847B2 (ja) * | 2001-07-24 | 2009-02-18 | 高砂香料工業株式会社 | ホスフィン−ホスホラン化合物と遷移金属とを含有する遷移金属錯体の存在下、α,β−不飽和アミド誘導体から光学活性アミド類を製造する方法。 |
JP4005801B2 (ja) * | 2001-12-10 | 2007-11-14 | 高砂香料工業株式会社 | 新規なホスフィン配位子 |
WO2004058982A2 (en) * | 2002-11-06 | 2004-07-15 | Penn State Research Foundation | Asymmetric reductive amination of ketones |
DE102005014055A1 (de) * | 2005-03-23 | 2006-09-28 | Degussa Ag | Unsymmetrisch substituierte Phospholankatalysatoren |
CA2717943C (en) * | 2008-03-11 | 2014-01-28 | Fukuoka University | Phosphine compound, process for producing the same, and peroxide scavenger using the same |
EP2187182B1 (de) * | 2008-11-12 | 2015-08-05 | Sensirion AG | Verfahren zum Betrieb eines Durchflusssensors, der wiederholt einem thermischen und/oder chemischen Reinigungsprozess ausgesetzt ist, und Durchflussmessgerät |
US9382279B2 (en) | 2013-06-14 | 2016-07-05 | Wisconsin Alumni Research Foundation | Copper catalyzed halogenaton and reaction products |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US47113A (en) | 1865-04-04 | Improvement in the manufacture of bolts | ||
US5008457A (en) | 1990-05-17 | 1991-04-16 | E. I. Du Pont De Nemours And Company | Chiral phospholane transition metal catalysts |
US5206398A (en) * | 1990-05-17 | 1993-04-27 | E. I. Du Pont De Nemours And Company | Chiral phospholane transition metal catalysts |
US5171892A (en) | 1991-07-02 | 1992-12-15 | E. I. Du Pont De Nemours And Company | Chiral phospholanes via chiral 1,4-diol cyclic sulfates |
DE19620023C2 (de) * | 1996-05-17 | 2001-03-08 | Celanese Chem Europe Gmbh | Verfahren zur Herstellung von Phosphinat- oder Phosphonatgruppen enthaltenden tertiären Phosphanen und neue Phosphinatgruppen enthaltende tertiäre Phosphane |
DE69602586T2 (de) * | 1995-11-22 | 2000-03-02 | Firmenich & Cie | Rutheniumkatalysatoren und deren verwendung zur asymmetrischen cyclopentenonhydrierung |
US6207868B1 (en) | 1997-06-13 | 2001-03-27 | The Penn State Research Foundation | Asymmetric synthesis catalyzed by transition metal complexes with chiral ligands |
DE19725796A1 (de) * | 1997-06-18 | 1998-12-24 | Basf Ag | Herstellung optisch aktiver Phospholane, deren Metallkomplexe und Anwendung in der asymmetrischen Synthese |
WO1999059721A1 (en) | 1998-05-18 | 1999-11-25 | The Penn State Research Foundation | Catalytic asymmetric hydrogenation, hydroformylation, and hydrovinylation via transition metal catalysts with phosphines and phosphites |
JP2002523419A (ja) | 1998-08-21 | 2002-07-30 | ザ・ペン・ステイト・リサーチ・ファウンデイション | キラルホスホランに基づく不斉触媒作用 |
GB9823716D0 (en) | 1998-10-29 | 1998-12-23 | Isis Innovation | Diphosphines |
JP4226847B2 (ja) * | 2001-07-24 | 2009-02-18 | 高砂香料工業株式会社 | ホスフィン−ホスホラン化合物と遷移金属とを含有する遷移金属錯体の存在下、α,β−不飽和アミド誘導体から光学活性アミド類を製造する方法。 |
-
2001
- 2001-12-10 JP JP2001375218A patent/JP4005800B2/ja not_active Expired - Fee Related
-
2002
- 2002-11-12 US US10/291,364 patent/US6624320B2/en not_active Expired - Lifetime
- 2002-11-21 EP EP02026339A patent/EP1318155B1/de not_active Expired - Lifetime
- 2002-11-21 AT AT02026339T patent/ATE291581T1/de not_active IP Right Cessation
- 2002-11-21 ES ES02026339T patent/ES2239195T3/es not_active Expired - Lifetime
- 2002-11-21 DE DE60203360T patent/DE60203360T2/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE60203360T2 (de) | 2006-03-23 |
ATE291581T1 (de) | 2005-04-15 |
US20030144138A1 (en) | 2003-07-31 |
EP1318155A1 (de) | 2003-06-11 |
JP2003171389A (ja) | 2003-06-20 |
US6624320B2 (en) | 2003-09-23 |
ES2239195T3 (es) | 2005-09-16 |
JP4005800B2 (ja) | 2007-11-14 |
EP1318155B1 (de) | 2005-03-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ATE427992T1 (de) | Dna-synthesepromotoren, mit dna-polymerase assoziierte faktoren und nutzung davon | |
RS50334B (sr) | Rutenijumski kompleksi kao (pred)-katalizatori metateznih reakcija | |
MXPA04001348A (es) | NUEVOS COMPUESTOS DE FOSFITOS Y SUS COMPLEJOS METaLICOS. | |
PT2192109E (pt) | Derivado de -aminoácido bicíclico | |
ATE339430T1 (de) | Katalysator für asymmetrische hydrogenierung | |
DE60237128D1 (de) | Verfahren zur Herstellung von Isopulegol | |
TR200003273A2 (tr) | Olefinler'den katalitik olarak aldehit imalatına yönelik usul | |
BR0200846A (pt) | Sìntese de ligandos de bisfosfinas não-c2-simétricas como catalisadores para hidrogenação assimétrica | |
ATE291581T1 (de) | Neuer asymmetrischer phosphin-ligand | |
BR0212763B1 (pt) | difosfinas e sua utilizaÇço em sÍntese assimÉtrica. | |
ES2192852T3 (es) | Proceso de obtencion de 3-aril-benzofuranonas. | |
ATE455781T1 (de) | Neue asymmetrische phosphin-ligande | |
ATE337327T1 (de) | Substituierte ferrocenyldiphosphinligande für homogene hydrogenieringskatalysatoren | |
CA2531167A1 (en) | Asymmetric urea compound and process for producing asymmetric compound by asymmetric conjugate addition reaction with the same as catalyst | |
PT1191030E (pt) | Fosfinetes-oxazolinas e complexos metalicos | |
DE602006017249D1 (de) | Herstellung von katalysatoren | |
AU2002362688A1 (en) | Ligands for asymmetric reactions | |
ATE278697T1 (de) | Katalysatoren | |
ATE332907T1 (de) | Racemoselektive herstellung rac- diorganosilylbis(2- methylbenzo eöindenyl)zirconium-verbindungen | |
EA200300930A1 (ru) | Способ получения n-замещенных 2,6-диалкилморфолинов | |
ATE435069T1 (de) | ßKOMPLEXKATALYSATOR, VERFAHREN ZUR HERSTELLUNG DES KOMPLEXKATALYSATORS UND VERFAHREN ZUR HERSTELLUNG VON ALKOHOLDERIVATEN MIT DEM KOMPLEXKATALYSATORß | |
DE60307724D1 (de) | Neue Diphosphinverbindung, Zwischenprodukte für deren Herstellung, Übergangsmetallkomplex enthaltend die Verbindung als Ligand und Katalysator für asymmetrische Hydrierungen, welcher den Komplex enthält | |
RU2008130889A (ru) | Способ асимметричного восстановления | |
ATE319724T1 (de) | Neue phosphinverbindung, übergangsmetallkomplex der diese verbindung als ligand enthält und katalysator welcher diesen komplex enthält für asymmetrische synthesen | |
MX2008008526A (es) | Método de reducción asimétrico. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |