DE60203355D1 - Verfahren zur Herstellung von Copolyestern unter Verwendung von titandioxyd/Siliciumdioxyd co-präzipitierten Katalisatoren, die in Form einer Suspension in Glycol vorliegen - Google Patents

Verfahren zur Herstellung von Copolyestern unter Verwendung von titandioxyd/Siliciumdioxyd co-präzipitierten Katalisatoren, die in Form einer Suspension in Glycol vorliegen

Info

Publication number
DE60203355D1
DE60203355D1 DE60203355T DE60203355T DE60203355D1 DE 60203355 D1 DE60203355 D1 DE 60203355D1 DE 60203355 T DE60203355 T DE 60203355T DE 60203355 T DE60203355 T DE 60203355T DE 60203355 D1 DE60203355 D1 DE 60203355D1
Authority
DE
Germany
Prior art keywords
catalisers
copolyesters
titania
precipitated
glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60203355T
Other languages
English (en)
Other versions
DE60203355T2 (de
Inventor
Jae-Young Jeon
Yoon-Hee Hong
Sung-Gi Kim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SK Chemicals Co Ltd
Original Assignee
SK Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SK Chemicals Co Ltd filed Critical SK Chemicals Co Ltd
Application granted granted Critical
Publication of DE60203355D1 publication Critical patent/DE60203355D1/de
Publication of DE60203355T2 publication Critical patent/DE60203355T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
DE60203355T 2001-10-12 2002-08-01 Verfahren zur Herstellung von Copolyestern unter Verwendung von titandioxyd/Siliciumdioxyd co-präzipitierten Katalisatoren, die in Form einer Suspension in Glycol vorliegen Expired - Lifetime DE60203355T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020010063073A KR100459654B1 (ko) 2001-10-12 2001-10-12 1,4-사이클로헥산디메탄올이 공중합된 폴리에스테르수지의 제조방법
KR2001063073 2001-10-12

Publications (2)

Publication Number Publication Date
DE60203355D1 true DE60203355D1 (de) 2005-04-28
DE60203355T2 DE60203355T2 (de) 2006-04-06

Family

ID=19715079

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60203355T Expired - Lifetime DE60203355T2 (de) 2001-10-12 2002-08-01 Verfahren zur Herstellung von Copolyestern unter Verwendung von titandioxyd/Siliciumdioxyd co-präzipitierten Katalisatoren, die in Form einer Suspension in Glycol vorliegen

Country Status (6)

Country Link
US (1) US6559272B1 (de)
EP (1) EP1302498B1 (de)
JP (1) JP3438072B2 (de)
KR (1) KR100459654B1 (de)
DE (1) DE60203355T2 (de)
ES (1) ES2238548T3 (de)

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US20070298243A1 (en) * 2004-08-30 2007-12-27 Kanae Suzuki Polyester Film
US20060286327A1 (en) * 2005-06-17 2006-12-21 Crawford Emmett D Retort containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
JP4514641B2 (ja) * 2005-04-11 2010-07-28 アルパイン株式会社 処理装置および画像表示方法
US20060270806A1 (en) * 2005-05-26 2006-11-30 Hale Wesley R Miscible high Tg polyester/polymer blend compositions and films formed therefrom
US20060270773A1 (en) * 2005-05-26 2006-11-30 Hale Wesley R Polyester-polycarbonate blends for diffuser sheets with improved luminance
US7704605B2 (en) 2006-03-28 2010-04-27 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US20100298523A1 (en) * 2005-06-17 2010-11-25 Eastman Chemical Company Polyester Compositions Which Comprise Cyclobutanediol and at Least One Phosphorus Compound
KR20080042101A (ko) * 2005-07-29 2008-05-14 도이체 인스티튜트 퓌어 텍스틸-운트 파저포슝 덴켄도르프 테레프탈산 폴리에스테르, 이의 제조 방법 및 이의 사용방법
US20070100125A1 (en) * 2005-10-28 2007-05-03 Crawford Emmett D Polyester compositions comprising minimal amounts of cyclobutanediol
US20070100122A1 (en) * 2005-10-28 2007-05-03 Crawford Emmett D Polyester compositions containing cyclobutanediol and articles made therefrom
US20100096589A1 (en) * 2005-10-28 2010-04-22 Emmett Dudley Crawford Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
MX2008005531A (es) * 2005-10-28 2008-10-17 Eastman Chem Co Composiciones de poliester que contienen ciclobutanodiol que tienen alta temperatura de transicion vitrea y articulos hechos a partir de las misma.
US20100087574A1 (en) * 2005-10-28 2010-04-08 Emmett Dudley Crawford Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US8193302B2 (en) 2005-10-28 2012-06-05 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof
US9598533B2 (en) 2005-11-22 2017-03-21 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US7737246B2 (en) * 2005-12-15 2010-06-15 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
US20070142511A1 (en) * 2005-12-15 2007-06-21 Crawford Emmett D Polyester compositions which comprise cyclobutanediol ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor
US20070232779A1 (en) * 2006-03-28 2007-10-04 Leslie Shane Moody Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid
US9169388B2 (en) 2006-03-28 2015-10-27 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
US20070232778A1 (en) * 2006-03-28 2007-10-04 Leslie Shane Moody Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid
CN101367919B (zh) * 2007-08-16 2011-07-20 广州金发科技股份有限公司 一种钛硅催化剂及其制备方法与应用
CN101868340B (zh) 2007-11-21 2016-04-20 伊士曼化工公司 塑料乳瓶、其它吹塑物品及其制备方法
US8501287B2 (en) 2007-11-21 2013-08-06 Eastman Chemical Company Plastic baby bottles, other blow molded articles, and processes for their manufacture
CN101565499B (zh) * 2008-04-23 2011-12-21 中国科学院化学研究所 一种聚酯缩聚催化剂及其制备方法与应用
US8198371B2 (en) 2008-06-27 2012-06-12 Eastman Chemical Company Blends of polyesters and ABS copolymers
US8895654B2 (en) 2008-12-18 2014-11-25 Eastman Chemical Company Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid
KR101558574B1 (ko) * 2008-12-31 2015-10-08 에스케이케미칼주식회사 아이소소르바이드가 공중합된 폴리에스테르 수지의 제조방법
KR101496634B1 (ko) * 2008-12-31 2015-02-27 에스케이케미칼주식회사 네오펜틸글리콜이 공중합된 폴리에스테르 수지의 제조방법
CN101891884B (zh) * 2009-05-22 2012-07-18 中国科学院化学研究所 一种聚酯缩聚催化剂及其制备方法与应用
CN102050942A (zh) * 2009-11-02 2011-05-11 远东新世纪股份有限公司 含钛组合物及以含钛组合物催化聚酯化反应的方法
US8420868B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8420869B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8394997B2 (en) 2010-12-09 2013-03-12 Eastman Chemical Company Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US9156941B2 (en) 2010-12-20 2015-10-13 Eastman Chemical Company Color in titanium catalyzed polyesters
US8796395B2 (en) 2010-12-20 2014-08-05 Eastman Chemical Company Polyesters containing particular phosphorus compounds blended with other polymers
US20130217830A1 (en) 2012-02-16 2013-08-22 Eastman Chemical Company Clear Semi-Crystalline Articles with Improved Heat Resistance
EP2899220A4 (de) * 2012-09-24 2016-06-01 Sk Chemicals Co Ltd Verfahren zur herstellung von polycyclohexylendimethylenterephthalatharz mit ausgezeichneter farbenqualität und in diesem verfahren hergestelltes polycyclohexylendimethylenterephthalatharz
JP7128802B2 (ja) 2016-08-18 2022-08-31 イーストマン ケミカル カンパニー 改良された触媒系による、テトラメチルシクロブタンジオール及びエチレングリコールを含むポリエステル組成物
EP3878888A1 (de) 2016-08-18 2021-09-15 Eastman Chemical Company Polyesterzusammensetzungen, die tetramethyl-cyclobutandiol und ethylen-glykol enthalten, mit verbessertem katalysatorsystem
EP3500615A1 (de) 2016-08-18 2019-06-26 Eastman Chemical Company Orientierte folien und schrumpffolien mit polyestern mit tetramethylcyclobutandiol und ethylenglykol
KR20190076681A (ko) * 2017-12-22 2019-07-02 서울대학교산학협력단 폴리알킬렌테레프탈레이트 글리콜의 제조방법

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DE4400300A1 (de) * 1994-01-07 1995-07-13 Akzo Nobel Nv Verfahren zur Herstellung von film- und faserbildenden Polyestern und Copolyestern
TW354305B (en) 1994-12-22 1999-03-11 Eastman Chem Co Production of particular polyesters using a novel catalyst system
US5789528A (en) 1995-12-08 1998-08-04 Akzo Nobel Nv Process for the preparation of polyesters and copolyesters
TW381104B (en) 1996-02-20 2000-02-01 Eastman Chem Co Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol
DE19705249A1 (de) * 1997-02-12 1998-08-13 Zimmer Ag Verfahren zur Herstellung von Polypropylenterphthalat
JP3652495B2 (ja) * 1998-03-23 2005-05-25 三菱化学株式会社 透明性に優れたポリエステルの製造方法
JP2000128969A (ja) * 1998-10-26 2000-05-09 Toray Ind Inc 粒子含有ポリエステル組成物の製造方法
JP2001019751A (ja) * 1999-07-07 2001-01-23 Toray Ind Inc ポリエステルの製造方法
EP1156070B1 (de) * 2000-05-17 2004-07-14 SK Chemicals Co., Ltd. Verfahren zur Herstellung von mit 1,4-Cyclohexandimethanol copolymersierten Polyestern

Also Published As

Publication number Publication date
KR20030030726A (ko) 2003-04-18
ES2238548T3 (es) 2005-09-01
DE60203355T2 (de) 2006-04-06
US6559272B1 (en) 2003-05-06
JP2003128775A (ja) 2003-05-08
EP1302498A1 (de) 2003-04-16
KR100459654B1 (ko) 2004-12-03
EP1302498B1 (de) 2005-03-23
JP3438072B2 (ja) 2003-08-18

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