DE602006006347D1 - Zeolith-doppelkatalysator enthaltend ein metall der gruppe viii und ein metall der gruppe iva, und seine verwendung bei der isomerisierung von aromatischen c8-verbindungen - Google Patents

Zeolith-doppelkatalysator enthaltend ein metall der gruppe viii und ein metall der gruppe iva, und seine verwendung bei der isomerisierung von aromatischen c8-verbindungen

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Publication number
DE602006006347D1
DE602006006347D1 DE602006006347T DE602006006347T DE602006006347D1 DE 602006006347 D1 DE602006006347 D1 DE 602006006347D1 DE 602006006347 T DE602006006347 T DE 602006006347T DE 602006006347 T DE602006006347 T DE 602006006347T DE 602006006347 D1 DE602006006347 D1 DE 602006006347D1
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Prior art keywords
metal
group
isomerization
zeolite
zeolith
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DE602006006347T
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English (en)
Inventor
Emmanuelle Guillon
Eric Sanchez
Sylvie Lacombe
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/22—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7415—Zeolite Beta
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE602006006347T 2005-12-22 2006-11-03 Zeolith-doppelkatalysator enthaltend ein metall der gruppe viii und ein metall der gruppe iva, und seine verwendung bei der isomerisierung von aromatischen c8-verbindungen Active DE602006006347D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0513175A FR2895282B1 (fr) 2005-12-22 2005-12-22 Catallyseur bizeolithique comprenant un metal du groupe viii et un metal du groupe iiia et son utilisation en isomerisation des composes c8 aromatiques
PCT/FR2006/002361 WO2007080238A1 (fr) 2005-12-22 2006-11-03 Catalyseur bizeolithique comprenant un metal du groupe viii et un metal du groupe iiia et son utilisation en isomerisation des composes c8 aromatiques

Publications (1)

Publication Number Publication Date
DE602006006347D1 true DE602006006347D1 (de) 2009-05-28

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DE602006006347T Active DE602006006347D1 (de) 2005-12-22 2006-11-03 Zeolith-doppelkatalysator enthaltend ein metall der gruppe viii und ein metall der gruppe iva, und seine verwendung bei der isomerisierung von aromatischen c8-verbindungen

Country Status (9)

Country Link
US (1) US8183172B2 (de)
EP (1) EP1965913B1 (de)
JP (1) JP5508717B2 (de)
KR (1) KR101388261B1 (de)
CN (1) CN101340976B (de)
AT (1) ATE428498T1 (de)
DE (1) DE602006006347D1 (de)
FR (1) FR2895282B1 (de)
WO (1) WO2007080238A1 (de)

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FR2895283B1 (fr) * 2005-12-22 2008-02-01 Inst Francais Du Petrole Catalyseur comprenant une zeolithe euo, une zeolithe 10mr et une zeolithe 12mr et son utilisation en isomerisation des composes c8 aromatiques
CN101898145B (zh) * 2009-05-27 2012-12-12 中国石油化工股份有限公司 烷基芳烃异构化催化剂及其制备方法
CN102039161B (zh) * 2009-10-16 2012-12-26 中国石油化工股份有限公司 C8芳烃异构化催化剂及其应用
US8435909B2 (en) * 2010-02-18 2013-05-07 King Fahd University Of Petroleum And Minerals Dual-zeolite catalyst for production of ethylbenzene
US20110230333A1 (en) * 2010-03-16 2011-09-22 Uop Llc Olefin Cracking Catalyst and Manufacturing Process
US8058496B2 (en) * 2010-03-31 2011-11-15 Uop Llc Process for xylene and ethylbenzene isomerization using UZM-35
US8466080B2 (en) * 2010-09-15 2013-06-18 Uop Llc Catalysts, processes for preparing the catalysts, and processes for transalkylating aromatic hydrocarbon compounds
CN102463135B (zh) * 2010-11-04 2013-11-20 中国石油化工股份有限公司 Eu-1/mor复合分子筛及其制备方法
FR2976941B1 (fr) * 2011-06-24 2014-11-21 IFP Energies Nouvelles Procede ameliore d'isomerisation d'une coupe c8 aromatique
CN102861606B (zh) * 2011-07-07 2014-04-16 中国石油化工股份有限公司 一种双微孔复合分子筛及其制备方法和应用
CN103120949B (zh) * 2011-11-18 2015-02-11 中国石油化工股份有限公司 增产邻二甲苯和对二甲苯的甲苯甲基化催化剂及其制备方法
FR2984308B1 (fr) 2011-12-20 2013-12-20 IFP Energies Nouvelles Procede d'isomerisation d'une coupe c8 aromatique en presence d'un catalyseur a base d'une zeolithe euo et d'un liant particulier
EP2874944A4 (de) 2011-12-22 2016-04-27 Uop Llc Geschichtete konversionssynthese von zeolithen
ES2734982T3 (es) 2011-12-22 2019-12-13 Uop Llc Zeolita de aluminosilicato UZM-39
EP2794525B1 (de) 2011-12-22 2018-10-10 Uop Llc Aromatische transformation durch verwendung von uzm-39 aluminosilikat-zeolith
WO2014093461A1 (en) 2012-12-12 2014-06-19 Uop Llc Conversion of methane to aromatic compounds using uzm-39 aluminosilicate zeolite
WO2014093416A1 (en) 2012-12-12 2014-06-19 Uop Llc Dehydrocyclodimerization using uzm-39 aluminosilicate zeolite
US8609921B1 (en) 2012-12-12 2013-12-17 Uop Llc Aromatic transalkylation using UZM-44 aluminosilicate zeolite
WO2014093440A1 (en) 2012-12-12 2014-06-19 Uop Llc Conversion of methane to aromatic compounds using uzm-44 aluminosilicate zeolite
US8609910B1 (en) 2012-12-12 2013-12-17 Uop Llc Catalytic pyrolysis using UZM-39 aluminosilicate zeolite
US8609919B1 (en) 2012-12-12 2013-12-17 Uop Llc Aromatic transformation using UZM-44 aluminosilicate zeolite
US8618343B1 (en) 2012-12-12 2013-12-31 Uop Llc Aromatic transalkylation using UZM-39 aluminosilicate zeolite
US8609911B1 (en) 2012-12-12 2013-12-17 Uop Llc Catalytic pyrolysis using UZM-44 aluminosilicate zeolite
US8889939B2 (en) 2012-12-12 2014-11-18 Uop Llc Dehydrocyclodimerization using UZM-44 aluminosilicate zeolite
US8623321B1 (en) 2012-12-12 2014-01-07 Uop Llc UZM-44 aluminosilicate zeolite
SG11201804523QA (en) * 2015-12-11 2018-06-28 Shell Int Research Catalyst composition and isomerisation process
CN107297221A (zh) * 2017-07-11 2017-10-27 太原大成环能化工技术有限公司 一种乙苯脱烷基催化剂及其制备方法
US11884615B2 (en) 2021-01-27 2024-01-30 Saudi Arabian Oil Company Modified beta zeolitic (*BEA) catalyst for isomerization of alkylated aromatics, and method for isomerization of alkylated aromatics
CN113042098B (zh) * 2021-03-24 2022-09-06 中国科学技术大学 一种PtIn@MFI催化剂及其制备方法和应用

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EP0923987A1 (de) * 1997-12-22 1999-06-23 Institut Français du Pétrole Zeolith EUO enthaltender Katalysator und dessen Verwendung in der Isomerisierung von aromatischen C8 Verbindungen
FR2777275B1 (fr) * 1998-04-08 2000-05-19 Inst Francais Du Petrole Procede d'isomerisation des composes aromatiques a huit atomes de carbone utilisant un catalyseur contenant une zeolithe de type structural euo
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DE602005015154D1 (de) * 2004-04-14 2009-08-13 Inst Francais Du Petrole Katalysator enthaltend einen 10MR Zeolith und einen 12MR Zeolith und seine Verwendung zur Transalkylierung von alkylaromatischen Kohlenwasserstoffen
FR2877665B1 (fr) * 2004-11-09 2006-12-29 Inst Francais Du Petrole Procede de transalkylation d'hydrocarbures alkylaromatiques mis en oeuvre dans deux zones reactionnelles
FR2895283B1 (fr) * 2005-12-22 2008-02-01 Inst Francais Du Petrole Catalyseur comprenant une zeolithe euo, une zeolithe 10mr et une zeolithe 12mr et son utilisation en isomerisation des composes c8 aromatiques
FR2895281B1 (fr) * 2005-12-22 2008-09-19 Inst Francais Du Petrole Catalyseur comprenant une zeolithe de type structural nes et une zeolithe de type structural euo et son utilisation en isomerisation des composes c8 aromatiques

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Publication number Publication date
KR101388261B1 (ko) 2014-04-22
FR2895282A1 (fr) 2007-06-29
FR2895282B1 (fr) 2008-02-01
JP2009520591A (ja) 2009-05-28
ATE428498T1 (de) 2009-05-15
EP1965913B1 (de) 2009-04-15
JP5508717B2 (ja) 2014-06-04
US20090299115A1 (en) 2009-12-03
US8183172B2 (en) 2012-05-22
CN101340976B (zh) 2011-04-20
CN101340976A (zh) 2009-01-07
WO2007080238A1 (fr) 2007-07-19
EP1965913A1 (de) 2008-09-10
KR20080080995A (ko) 2008-09-05

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