SG11201804523QA - Catalyst composition and isomerisation process - Google Patents

Catalyst composition and isomerisation process

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Publication number
SG11201804523QA
SG11201804523QA SG11201804523QA SG11201804523QA SG11201804523QA SG 11201804523Q A SG11201804523Q A SG 11201804523QA SG 11201804523Q A SG11201804523Q A SG 11201804523QA SG 11201804523Q A SG11201804523Q A SG 11201804523QA SG 11201804523Q A SG11201804523Q A SG 11201804523QA
Authority
SG
Singapore
Prior art keywords
international
carrier material
material component
total weight
catalyst
Prior art date
Application number
SG11201804523QA
Inventor
Der Hauw Menno Van
Richard Mauer
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of SG11201804523QA publication Critical patent/SG11201804523QA/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7446—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7469—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/073—Ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80—Mixtures of different zeolites
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property -' Organization International Bureau (43) International Publication Date ..... ...sr ,„,„1 15 June 2017(15.06.2017) WIPO I PCT (10) WO International 111111111111311111111111111111111111111111111111111111111111111111111311111111111111111 2017/097880 Publication Number Al (51) International Patent Classification: AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, B01.12 9 / 8 0 (2006.01) CO7C 5/27 (2006.01) BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (21) International Application Number: HN HR, HU ID IL IN, IR IS JP KE KG, KH KN, PCT/EP2016/080197 KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, (22) International Filing Date: MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, 8 December 2016 (08.12.2016) NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, (25) Filing Language: English TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, (26) Publication Language: English ZA, ZM, ZW. (30) Priority Data: (84) Designated States (unless otherwise indicated, for every 15199643.6 11 December 2015 (11.12.2015) EP kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, (71) Applicant (for all designated States except US): SHELL TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, INTERNATIONALE RESEARCH MAATSCHAPPIJ TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, B.V. [NL/NL]; Carel van Bylandtlaan 30, 2596 HR The DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, Hague (NL). LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, (71) Applicant (for US only): SHELL OIL COMPANY SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, [US/US]; Shell Plaza 1, Houston, Texas 77252-2463 (US). GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: (72) Inventors: VAN DER HAUW, Menno, Feico; Grasweg 31, 1031 HW Amsterdam (NL). MAUER, Richard, — as to applicant's entitlement to apply for and be granted a Berend; Grasweg 31, 1031 HW Amsterdam (NL). patent (Rule 4.170) (74) Agent: MATTHEZING, Robert, Maarten; Shell Interna- Published: tional B.V., PO Box 384, 2501 CJ The Hague (NL). — with international search report (Art 21(3)) Designated States indicated, (81) (unless otherwise for every kind of national available): AE, AG, AL, AM, protection 1-1 .4t C::: , Ot (54) Title: CATALYST COMPOSITION AND ISOMERISATION PROCESS GC IN (57) : The invention relates to a catalyst composition which comprises a carrier material component and a metal (s) com - C\ o ponent that is supported on the carrier material component, wherein the carrier material component comprises (i) a ZSM-12 type ---. zeolite in an amount of 2 to 20 %wt, based on total weight of carrier material component, the ZSM-12 type zeolite having a silica to IN alumina molar ratio in the range of from 60 to 200; (ii) a EU-1 type zeolite in an amount of from 2 to 30 %wt, based on total weight c:::, of carrier material component, the EU-1 type zeolite having a silica to alumina molar ratio in the range of from 20 to 200; and (iii) N an inorganic binder in an amount in the range of from 55 to 96 %wt, based on total weight of carrier material component; and 0 wherein the metal (s) component comprises a Group VIII metal in an amount of at least 0.01 %wt, based on total weight of catalyst. ,1 . The invention further relates to a process for preparing the present catalyst, and a process for the isomerisation of alkylaromatics wherein use is made of the catalyst.
SG11201804523QA 2015-12-11 2016-12-08 Catalyst composition and isomerisation process SG11201804523QA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP15199643 2015-12-11
PCT/EP2016/080197 WO2017097880A1 (en) 2015-12-11 2016-12-08 Catalyst composition and isomerisation process

Publications (1)

Publication Number Publication Date
SG11201804523QA true SG11201804523QA (en) 2018-06-28

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ID=55068757

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201804523QA SG11201804523QA (en) 2015-12-11 2016-12-08 Catalyst composition and isomerisation process

Country Status (11)

Country Link
US (1) US10722873B2 (en)
EP (1) EP3386633B1 (en)
KR (1) KR102683463B1 (en)
CN (1) CN108367281B (en)
BR (1) BR112018011634B1 (en)
MY (1) MY192190A (en)
PL (1) PL3386633T3 (en)
RU (1) RU2739200C2 (en)
SA (1) SA518391731B1 (en)
SG (1) SG11201804523QA (en)
WO (1) WO2017097880A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113646287B (en) * 2019-03-29 2025-04-25 埃克森美孚化学专利公司 Novel zeolite, method for preparing the zeolite and use of the zeolite for converting aromatic hydrocarbons
RU2707179C1 (en) * 2019-08-02 2019-11-25 федеральное государственное автономное образовательное учреждение высшего образования "Российский государственный университет нефти и газа (национальный исследовательский университет) имени И.М. Губкина" Bizeolitic catalyst for isomerization of aromatic hydrocarbons c-8

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3856872A (en) * 1973-09-13 1974-12-24 Mobil Oil Corp Xylene isomerization
US4762957A (en) * 1987-06-10 1988-08-09 Uop Inc. Process for isomerization of alkylaromatics
US4899012A (en) * 1988-10-17 1990-02-06 Uop Catalyst for the isomerization of aromatics
ID18446A (en) * 1996-05-29 1998-04-09 Exxon Chemical Patents Inc PROCESS FOR ISOMERIZATION OF ALCILAROMATIC HYDROCARBONES
FR2895283B1 (en) * 2005-12-22 2008-02-01 Inst Francais Du Petrole CATALYST COMPRISING EUO ZEOLITHE, 10MR ZEOLITE AND 12MR ZEOLITE AND ITS USE IN ISOMERIZATION OF AROMATIC C8 COMPOUNDS
FR2895282B1 (en) * 2005-12-22 2008-02-01 Inst Francais Du Petrole BIZEOLITHIC CATALYST COMPRISING A GROUP VIII METAL AND A GROUP IIIA METAL AND ITS USE IN ISOMERIZATION OF C8 AROMATIC COMPOUNDS
US7939701B2 (en) * 2007-12-12 2011-05-10 Uop Llc Aromatic isomerization catalyst and a process of use thereof
BRPI0914603A2 (en) * 2008-07-04 2015-12-08 Shell Internationale Res Maartschappij B V alkylaromatic isomerization catalyst; and, process for the isomerization of alkylaromatics to provide a reaction mixture.
FR2974801B1 (en) * 2011-05-04 2013-04-26 IFP Energies Nouvelles PROCESS FOR ISOMERIZING AN AROMATIC C8 CUT IN THE PRESENCE OF A SPECIFIC CATALYST CONSISTING OF A ZEOLITE / SILICON CARBIDE COMPOSITE AND HYDRO-DEHYDROGENANT FUNCTION
KR20150003253A (en) * 2012-04-02 2015-01-08 사우디 아라비안 오일 컴퍼니 Multimetal zeolites based catalyst for transalkylation of heavy reformate to produce xylenes and petrochemical feedstocks
US9517979B2 (en) * 2015-03-19 2016-12-13 Exxonmobil Chemical Patents Inc. Process and apparatus for the production of para-xylene

Also Published As

Publication number Publication date
US10722873B2 (en) 2020-07-28
BR112018011634B1 (en) 2021-06-01
CN108367281B (en) 2021-10-15
WO2017097880A1 (en) 2017-06-15
EP3386633A1 (en) 2018-10-17
KR102683463B1 (en) 2024-07-09
KR20180084082A (en) 2018-07-24
CN108367281A (en) 2018-08-03
EP3386633B1 (en) 2020-05-13
MY192190A (en) 2022-08-05
US20180369797A1 (en) 2018-12-27
RU2739200C2 (en) 2020-12-21
BR112018011634A2 (en) 2018-11-27
PL3386633T3 (en) 2020-09-07
RU2018125264A (en) 2020-01-13
RU2018125264A3 (en) 2020-03-19
SA518391731B1 (en) 2021-09-12

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