DE60024680D1 - Polymerisationsverfahren - Google Patents

Polymerisationsverfahren

Info

Publication number
DE60024680D1
DE60024680D1 DE60024680T DE60024680T DE60024680D1 DE 60024680 D1 DE60024680 D1 DE 60024680D1 DE 60024680 T DE60024680 T DE 60024680T DE 60024680 T DE60024680 T DE 60024680T DE 60024680 D1 DE60024680 D1 DE 60024680D1
Authority
DE
Germany
Prior art keywords
polymerization
carboxylic acid
relates
compound
metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60024680T
Other languages
English (en)
Other versions
DE60024680T2 (de
Inventor
Kyriacos Agapiou
Chi-I Kuo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Univation Technologies LLC
Original Assignee
Univation Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Technologies LLC filed Critical Univation Technologies LLC
Publication of DE60024680D1 publication Critical patent/DE60024680D1/de
Application granted granted Critical
Publication of DE60024680T2 publication Critical patent/DE60024680T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Devices For Conveying Motion By Means Of Endless Flexible Members (AREA)
DE60024680T 1999-12-15 2000-10-03 Polymerisationsverfahren Expired - Lifetime DE60024680T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US17098599P 1999-12-15 1999-12-15
US170985P 1999-12-15
US66360800A 2000-09-18 2000-09-18
US663608 2000-09-18
PCT/US2000/027236 WO2001044323A1 (en) 1999-12-15 2000-10-03 Polymerization process

Publications (2)

Publication Number Publication Date
DE60024680D1 true DE60024680D1 (de) 2006-01-12
DE60024680T2 DE60024680T2 (de) 2006-08-24

Family

ID=26866621

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60024680T Expired - Lifetime DE60024680T2 (de) 1999-12-15 2000-10-03 Polymerisationsverfahren

Country Status (10)

Country Link
US (1) US6803430B2 (de)
EP (1) EP1255783B1 (de)
JP (1) JP4376485B2 (de)
AT (1) ATE312124T1 (de)
AU (1) AU782695B2 (de)
BR (1) BR0017020A (de)
CA (1) CA2394533A1 (de)
DE (1) DE60024680T2 (de)
ES (1) ES2253262T3 (de)
WO (1) WO2001044323A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6818585B2 (en) * 1998-12-30 2004-11-16 Univation Technologies, Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
EP2172214A3 (de) * 1999-03-12 2011-03-16 Aventis Pasteur Limited Chlamydia-Antigene und entsprechende DNA-Fragmente sowie Verwendungen davon
US6593267B2 (en) * 2000-12-18 2003-07-15 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
DE602004027473D1 (de) * 2003-03-21 2010-07-15 Dow Global Technologies Inc Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
JP5095909B2 (ja) * 2003-06-24 2012-12-12 ローム・アンド・ハース・エレクトロニック・マテリアルズ，エル．エル．シー． 触媒組成物および析出方法
CN100513429C (zh) * 2004-01-02 2009-07-15 尤尼威蒂恩技术有限责任公司 控制气相反应器中的结皮的方法
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
JP2008509277A (ja) * 2004-08-09 2008-03-27 ダウ グローバル テクノロジーズ インコーポレイティド ポリマーの製造のための担持ビス（ヒドロキシアリールアリールオキシ）触媒
EP1659136A1 (de) * 2004-11-19 2006-05-24 Total Petrochemicals Research Feluy Feststoffeigenschaften von Polyethylen hergestellt mit einem Katalysatorsystem basierend auf Tetrahydroindenylliganden
DE102006022255A1 (de) * 2006-05-11 2007-11-15 Basell Polyolefine Gmbh Antistatikum für die Olefinpolymerisation und Verfahren zu dessen Herstellung
US7790816B2 (en) 2006-08-04 2010-09-07 Univation Technologies, Llc Method of maintaining heat transfer capacity in a polymerization reaction system
CA2733208A1 (en) * 2008-08-06 2010-02-11 Union Carbide Chemicals & Plastics Technology Llc Ziegler-natta catalyst compositions for producing polyethylenes with a high molecular weight tail and methods of making the same
KR102287064B1 (ko) * 2018-12-11 2021-08-05 한화솔루션 주식회사 올레핀 중합용 촉매의 제조방법
US11352375B2 (en) 2018-12-28 2022-06-07 Braskem S.A. Auxiliaries for olefin polymerization process
US11820879B2 (en) 2018-12-28 2023-11-21 Braskem S.A. Continuous feed of antistatic agent for gas phase polymerization process
CN114901391A (zh) 2019-11-26 2022-08-12 埃克森美孚化学专利公司 生产负载型催化剂的系统和方法
EP4073131A1 (de) 2019-12-11 2022-10-19 ExxonMobil Chemical Patents Inc. Niedrigaromatische polyolefine

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1124750A (en) * 1914-02-27 1915-01-12 Joseph A Kraker Lever-filler fountain-pen.
US3082198A (en) * 1958-08-25 1963-03-19 Goodrich Gulf Chem Inc Process for polymerizing ethylene in the process of aluminum alkyl, titanium tetrachloride, and carboxylic acid
JPS5038158B2 (de) * 1972-01-22 1975-12-08
GB1443074A (en) * 1974-01-14 1976-07-21 Ici Ltd Olefin polymerisation process
CA1125268A (en) 1978-04-14 1982-06-08 Exxon Research And Engineering Company Trialkyl aluminum cocatalyst
US4310439A (en) 1979-03-07 1982-01-12 Exxon Research & Engineering Co. Novel trialkyl aluminum cocatalyst
DE3881728T3 (de) * 1987-03-14 1998-01-15 Mitsubishi Chem Ind Verfahren zur Herstellung eines Propylen-alpha-Olefin-Blockkopolymers.
DE3833444A1 (de) * 1988-10-01 1990-04-05 Basf Ag Vermeidung von farbigen verunreinigungen bei der herstellung von ultrahochmolekularen ethylenpolymerisaten mittels eines titan enthaltenden katalysatorsystems
FR2660926B1 (fr) * 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
CA2126796A1 (en) 1993-06-28 1994-12-29 Robert Converse Brade, Iii Use of lewis bases for activity reduction in metallocene catalyzed olefin polymerization process
DE69525679T2 (de) 1994-05-18 2002-11-07 Mitsubishi Chemical Corp., Tokio/Tokyo Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins
US6124230A (en) * 1995-07-13 2000-09-26 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
ATE276284T1 (de) * 1995-12-01 2004-10-15 Chevron Phillips Chemical Co Polymerisationsverfahren
DE19615953A1 (de) * 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
US7354880B2 (en) * 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
US6593267B2 (en) * 2000-12-18 2003-07-15 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process

Also Published As

Publication number Publication date
AU7849500A (en) 2001-06-25
EP1255783A1 (de) 2002-11-13
JP2003517060A (ja) 2003-05-20
AU782695B2 (en) 2005-08-18
WO2001044323A1 (en) 2001-06-21
US20020132944A1 (en) 2002-09-19
BR0017020A (pt) 2003-01-07
JP4376485B2 (ja) 2009-12-02
ES2253262T3 (es) 2006-06-01
DE60024680T2 (de) 2006-08-24
CA2394533A1 (en) 2001-06-21
ATE312124T1 (de) 2005-12-15
US6803430B2 (en) 2004-10-12
EP1255783B1 (de) 2005-12-07

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